NFPA 704 Placard Guidelines WFPD.Pdf

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WOODSIDE FIRE PROTECTION DISTRICT NFPA 704 Placard Guidelines January 2020 808 Portola Rd. #C Portola Valley, CA 94028 Fire Prevention 650-423-1405 Fax 650-851-3960 NFPA 704 Placards are required for any business or commercial building that has a quantity of hazardous materials equal to or greater than a total weight of 500 pounds solid, 55 gallons liquid, 200 cubic feet of gas or where a radioactive product is used, stored or handled. Placards may also be required where the hazardous materials could present a hazard to emergency responders. Placards provide emergency responders notification of potential hazards that may increase their risk while entering into a building, room or storage area. You may be required to place a placard on the outside and/or the inside of your business. Placards are designed to warn of health, flammability, reactivity or special hazards that may exist. Placards will be 16 inches square on outside locations and 12 inches square on inside locations. Listed below are the some of the most common materials used in commercial applications. Refer to your MSDS sheets for those not on this list. FLAMMABILITY Example of placard for Oxygen 0 HEALTH 1 0 REACTIVITY OXY SPECIAL COMMON MATERIALS Chemical Name Health Flammability Reactivity Special Acetone 2 3 0 Acetylene 1 4 2 Acetylene Argon (compressed) 1 0 0 Aromatic hydrocarbon 2 3 0 (paint thinner) Carbon dioxide (compressed) 1 0 0 Chlorine gas 3 0 0 OXY Diesel Fuel 0 2 0 Ethylene glycol (antifreeze) 1 0 0 Freon Refrigerant 2 0 0 Gasoline 1 3 0 Helium (compressed) 1 0 0 Hydrogen (compressed) 1 4 0 Isopropyl alcohol 2 3 0 Kerosene 1 2 0 Lead Acid Batteries 2 0 0 Muriatic Acid (hydrochloric) 3 0 0 Nitrogen (compressed) 1 0 0 Nitrous Oxide 1 0 2 OXY Oil 0 1 0 Oxygen (compressed) 1 0 0 OXY Oxygen (cryogenic) 3 0 0 OXY Propane (LPG) 2 4 0 Safety Kleen Parts Cleaner 1 2 0 Sodium Hydroxide 3 0 1 Stoddard solvent (part cleaner) 2 2 0 Sulfuric Acid 3 0 2 W *For materials not listed above please see product manufacturer data sheet* WFPD January 2020 .

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Health Hazard Flammability Instability
Health Hazard Very short exposure could cause death or serious 4 residual injury even though prompt medical attention was given. Short exposure could cause serious temporary or 3 residual injury even though prompt medical attention was given. Intense or continued exposure could cause temporary 2 incapacitation or possible residual injury unless prompt medical attention is given. Exposure could cause irritation but only minor residual 1 injury even if no treatment is given. Exposure under fire conditions would offer no hazard 0 beyond that of ordinary combustible materials. Flammability Will rapidly or completely vaporize at normal pressure 4 and temperature, or is readily dispersed in air and will burn readily. Liquids and solids that can be ignited under almost all 3 ambient conditions. Must be moderately heated or exposed to relatively high 2 temperature before ignition can occur. 1 Must be preheated before ignition can occur. 0 Materials that will not burn. Instability1 Readily capable of detonation or of explosive 4 decomposition or reaction at normal temperatures and pressures. Capable of detonation or explosive reaction, but 3 requires a strong initiating source or must be heated under confinement before initiation, or reacts Normally unstable and readily undergo violent decomposition but do not detonate. Also: may react 2 violently with water or may form potentially explosive mixtures with water. Normally stable, but can become unstable at elevated 1 temperatures and pressures or may react with water with some release of energy, but not violently. 0 Normally stable, even under fire exposure conditions, Special Hazards This section is used to denote special hazards.
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National Fire Protection Association Pamphlet 704 Identification of Hazard Materials for Emergency Response
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Understanding NFPA Labeling
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Safety Data Sheet Tetrino
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Fd Spec #25 Exhibit 1 Nfpa 704 Frequently Asked Questions
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SDS # : 001180 Supplier's Details : Airgas USA, LLC and Its Affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253
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Download the Carbon Dioxide Liquid (Airgas) Safety Data Sheet
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HEALTH HAZARD DATA Division
MATERIAL LindeAGA GAS, Gas LLCINC. (216) 642-6600 SAFETY P.O.6055 Box ROCKSIDE 94737 WOODS BLVD DATA SHEET Cleveland,P.O. BOX 94737 Ohio 44101 www.us.lindegas.comCLEVELAND, OH 44101-4737 PRODUCT NAME CAS # 7664-41-7 Ammonia DOT I.D. No.: TRADE NAME AND SYNONYMS UN 1005 RQ 100 (45.5) Ammonia, Anhydrous (D.O.T.) DOT Hazard Class: Division 2.2 CHEMICAL NAME AND SYNONYMS Formula Ammonia NH3 ISSUE DATES AND REVISIONS Chemical Family: Nitrogen Hydride Revised March 1998 HEALTH HAZARD DATA TIME WEIGHTED AVERAGE EXPOSURE LIMIT TWA = 25 Molar PPM; STEL = 35 Molar PPM (ACGIH 1997,). OSHA 1995 PEL (8 hr. TWA) 50 Molar PPM. SYMPTOMS OF EXPOSURE Corrosive and irritating to the skin, eyes, upper respiratory system and all mucosal tissue. Depending on the concentration inhaled, it may cause burning sensations, coughing, wheezing, shortness of breath, headache, nausea, with eventual collapse. Mild concentrations of vapor will cause dermatitis or conjunctivitis. Higher concentrations of vapor or liquid contact will cause caustic-like dermal burns and inflammation and swelling of the eyes with possible loss of vision. Rapidly evaporating liquid contacting dermal tissue or the eyes can cause cryoqenic “burns.” TOXICOLOGICAL PROPERTIES Inhalation: Affects the upper airway (larynx and bronchi) by causing caustic-like burning resulting in edema and chemical pneumonitis. If it enters the deep lung, pulmonary edema will result. Toxic level exposure to dermal tissue causes caustic-like burns and skin lesions resulting in early necrosis and scarring. Burns to the eye result in lesions and possible loss of vision. Cryogenic “burns” are like frostbite with a change in skin color to gray or white possibly followed by blistering.
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NFPA 704 Markings
704 MARKING SYSTEM The NFPA 704 Marking System is a system developed by the National Fire Protection Association to alert emergency personnel of the type and degree of hazards within an area enabling them to more easily decide whether to evacuate the area or to commence control procedures. The Virginia Fire Prevention Code requires the use of this system to identify the contents of stationary containers and above-ground storage tanks and to identify locations where hazardous materials are stored, dispensed, used or handled in quantities requiring an Operational Permit. Storage tanks of 300 gallons capacity or less used for heating and cooking fuels at single-family homes are exempted from this requirement. When displayed: Used for hazards in facilities and may be found on non-bulk packaging. How displayed: The system uses a diamond shaped symbol, positioned on point, divided into four smaller diamonds. Symbol description: The four smaller diamond shapes or quadrants have specific meanings as follows: • Blue quadrant (left) indicates health hazard • Red quadrant (top) indicates health hazard • Yellow quadrant (right) indicates reactivity hazard • Lower quadrant (bottom) contains symbols indicating special hazards, such as OXY for oxidizers, radioactive trefoil (propeller), W for water reactive materials Degree of Hazard: Each of the colored quadrants contains a number from 0 to 4 indicating the relative degree of hazard of the material stored in the container or area. NFPA 704 MARKING SYSTEM HEALTH HAZARD FLAMMABILITY HAZARD REACTIVITY
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