http://dx.doi.org/10.1595/147106714X682643 Johnson Matthey Technol. Rev., 2014, 58, (3), 142–155 JOHNSON MATTHEY TECHNOLOGY REVIEW www.technology.matthey.com Dennis Dowden and the Development of Catalytic Science Celebrating a twentieth century pioneer in the scientifi c understanding of catalysis By Martyn V. Twigg* Dowden, worked at the Wills Tobacco Company, and TST Ltd, Caxton, Cambridge CB23 3PQ, UK the family situation was made very much more diffi cult when he, a pacifi st, a committed socialist and a local * Correspondence may be sent via the political labour leader, spent two years in Dartmoor Editorial Team: [email protected] Prison as a conscientious objector. His mother, Ada, left alone with young Dennis, worked as a seamstress Michael S. Spencer and somehow managed to support them both. At that Cardiff Catalysis Institute, School of Chemistry, Cardiff time not “going to war” was seen as unpatriotic and University, Park Place, Cardiff CF10 3AT, UK very much looked down upon, and this made life even more diffi cult as they were shunned by shop keepers and many townsfolk. However, they survived and when In the twentieth century Dennis Albert Dowden, his father returned home he eventually got a job in a affectionately referred to as DAD by friends and warehouse through church contacts. Later, in 1920, colleagues, was an important fi gure in the development the family was enlarged by the birth of a daughter, of an understanding of the structure of industrial Joan. Dowden’s parents thought that everything could heterogeneous catalysts, the species present and the be achieved through education and they encouraged processes taking place on them. He was born in Bristol, their children to do well at school. When he was eleven UK, and following education at the University of Bristol or twelve Dowden was taken by his mother to the and a short period at Amherst College in the USA, in opening of the new University of Bristol (previously it 1938 he joined Imperial Chemical Industries (ICI) at was University College) by King George V. He said Billingham in the North East of England. He worked he looked up at the great tower and thought, “I will go there on catalysis, catalyst manufacture and catalytic there one day”, and he did! processes for the next thirty-seven years. His major 1.2 Academic Studies contribution was to bring a wide range of sciences and a rational approach into what had been until then Dowden excelled academically and he won a regarded as “black art”, capable of only empirical scholarship both to Merrywood Secondary School analysis. His infl uence extended across ICI, which at and subsequently to the University of Bristol where he that time operated many industrial catalytic processes, studied Chemistry from 1932 to 1937 and his record and academically he was infl uential worldwide and card shows he had a “very satisfactory fi rst year”. especially in the USA. In fact he later graduated with fi rst class honours. Chemistry at Bristol was particularly strong in the area 1. Dowden’s Early Career and Domestic Life of interfacial chemistry, and as early as 1913 Professor James W. McBain postulated the existence of ‘colloidal 1.1 Early Family Life ions’, now known as micelles, to explain the electrolytic Dowden was born in Bristol, UK, on 15th August 1914, conductivity of sodium palmitate solutions (1), while in just a few days after the start of the First World War. His the Physics Department, where Dowden studied for family was far from wealthy. His father, Charles Henry two years, there were eminent researchers like Nott, 142 © 2014 Johnson Matthey http://dx.doi.org/10.1595/147106714X682643 Johnson Matthey Technol. Rev., 2014, 58, (3) Jones, Lennard Jones, Gurney, Frolich, Heitler, the two research funds he perpetuated the connection through Londons and Sucksmith. having visiting Bristol postdoctoral students, of whom In the Chemistry Department Professor William Dowden was the fi rst. Dowden went to Amherst E. Garner worked on the gas solid interface developing College in 1937 and continued research on heats of adsorption calorimetry (2). During his time at the adsorption of gases on chromia. He measured the University of Bristol Dowden did postgraduate research heats of adsorption of argon, hydrogen, deuterium, (Figure 1) with Professor Garner on the heats of carbon monoxide, nitrogen, and oxygen on reduced adsorption of gases on high surface area solids that chromia by calorimetry at low temperatures. The results at the time was a research frontier. Indeed, the now were interpreted in terms of an initial ‘van der Waals familiar BET method for estimating surface areas of adsorption’ followed, in some situations, by a slow catalysts was published (3) about the time Dowden exothermic change leading to ‘activated adsorption’. left the University of Bristol. Although he had done But his time in the USA was not all devoted to work, good careful topical research, like many others at for Dowden found time to drive across the USA to that time at the University of Bristol he did not submit California with a friend calling at some universities a thesis for a PhD, something in later life he said he on the way and returning by Greyhound bus, at regretted. Notwithstanding this it was an exceptional the height of the Great Depression! The research achievement then for a child from his working class, Dowden did at Amherst and Bristol resulted in two anti-establishment background to go to university and substantial publications, the fi rst in the Journal of the do so well. American Chemical Society (5) and the second in the In the USA Professor Beebe at Amherst College had Journal of the Chemical Society (6). The latter paper become involved with the measurement of heats of was received on 29th March 1939 and the authors chemisorptions (4). He had spent several sabbatical expressed their thanks for grants for the purchase years at Bristol where he developed a long-standing of apparatus to ICI Ltd, and to the Colston Research friendship with Professor Garner, so when he obtained Society. This Society was founded in Bristol in 1899 as the ‘University College Colston Society’, by Bristol citizens who wanted to assist the University College. From 1908 to 1948 it gave grants to specifi c research projects in various departments. Since 1948 the Society has supported symposia. 1.3 Return to the UK and Start of Industrial Career Dowden returned to the UK in 1938, probably in part because of the impending Second World War, and he joined the Billingham Division of ICI in the North East of England (Figure 2). ICI there at the time had a general policy for recruiting preferentially graduates with DPhils or PhDs from Oxford, Cambridge or Imperial College London. It is therefore quite remarkable that in the late 1930s ICI employed Dowden who came from the University of Bristol without a PhD. Professor Garner may have infl uenced the situation since he had contacts at ICI and their fi nancial support was acknowledged in Dowden’s paper (6). However, it is clear Dowden’s Fig. 1. Dennis Dowden when a postgraduate research exceptional abilities were recognised early in his career. student at The University of Bristol, UK, in 1935/36. His At fi rst at Billingham he was a Safety Offi cer in the supervisor was Professor William E. Garner and his research involved measurement of the heats of adsorption Research Department, and a little later he moved to the of gases on chromic oxide, work he continued with catalyst manufacturing factory at Clitheroe in Lancashire, Professor Beebe at Amherst College in the USA as a plant manager. Here catalyst for the production of high octane fuel for fi ghter planes and other catalysts were 143 © 2014 Johnson Matthey http://dx.doi.org/10.1595/147106714X682643 Johnson Matthey Technol. Rev., 2014, 58, (3) Fig. 2. An original image showing the layout and details of part of the Billingham Site in 1930. The site would have been somewhat enlarged by the time Dennis Dowden went to work there just before World War II produced. During this time Dowden learnt about large- fathers’ occupations were given as Warehouseman scale catalyst manufacture and the underlying inorganic (Charles H. Dowden) and Boilersmith (Thomas chemistries involved before getting deeply involved in Coxall), and the witnesses were Charles H. Dowden industrial catalyst research and development. He once and Lavinia M. Coxall. said that the real impact of catalysis was not revealed At fi rst they lived in a company fl at in Norton, a to him until after he had joined ICI. village only a short distance from Billingham, and later they bought a house in Eaglescliffe close to 1.4 Research at Billingham and Domestic Life Yarm-on-Tees a few miles south of Billingham. They Still during the war Dowden returned to do research had two children, Diana born in 1952 and Simon born at the main site at Billingham, where he worked on in 1956. In 1965 a property in Javea in Spain was catalysts and catalytic processes for almost four purchased and this provided the family with many decades. He was confronted with a broad spectrum unforgettable happy summer holidays. Dowden liked of exploratory catalytic chemistry involving to think of himself as something of a thespian, and hydrogenation and oxidation as well as related pilot for many years he had acting roles in Middlesbrough plant and full scale plant problems, and he said he did amateur dramatic society productions at The Little his first ‘plant training’ on coal liquefaction, though Theatre and he appeared in Norton Hall Club ‘Smoker’ it is not clear if this was before or after going to the productions.