Pt and Structural Constraints of Lawsonite
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Heat Capacity of High Pressure Minerals and Phase Equilibria of Cretan Blueschists
Heat capacity of high pressure minerals and phase equilibria of Cretan blueschists by Matthew Rahn Manon A dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy (Geology) in The University of Michigan 2008 Doctoral Committee: Professor Eric J. Essene, Chair Professor Rebecca Ann Lange Professor Youxue Zhang Associate Professor Steven M. Yalisove Matthew Rahn Manon 2008 Acknowledgments Cheers to all the grad students who have gone and come through CC-Little over the years. Zeb, Steven, Jim, Chris, Katy, Phillip, Franek, Eric, Tom, Darius, Sarah, Sara, Abir, Laura, Casey, Sam, John and anyone else I’ve been to learned something from, or argued something with. From early nights at Dominicks for subductology “seminars” through to the FWC, Michigan has been a fun place to live. Thanks to Anne Hudon, whos made sure I haven’t been able to place myself in inextricable holes. Thanks also to those from earlier in my life. College professors like Ken Hess or Barbara Nimmersheim who, in their very different ways inspired me to explore what it is I know. I’ll always remember time spent with Bob Wiebe who introduced me to the wild unknown of geology. Immeasurable thanks go to Eric Essene. The fieldtrips we took the first few years were good adventures. He’s always put aside his own issues to be there for me to talk to, especially when I didn’t deserve it. Eric’s scientific curiosity, and mental rigor are deservedly well known. His patience with me may be one of his great, unsung virtues. -
I. Thermal Expansion of Lawsonite, Zoisite, Clinozoisite, and Diaspore
American Mineralogist, Volume 81, pages 335-340, 1996 Volume behavior of hydrous minerals at high pressure and temperature: I. Thermal expansion of lawsonite, zoisite, clinozoisite, and diaspore A.R. PAWLEY,I,* S.A.T. REDFERN,2 ANDT.J.B. HOLLAND2 'Department of Geology, University of Bristol, Wills Memorial Building, Queens Road, Bristol BS8 lRJ, U.K. 2Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB2 3EQ, U.K. ABSTRACT The temperature dependence of the lattice parameters of synthetic lawsonite [Ca- A12Si2 07 (OH)2 . H20], natural zoisite [Ca2A13 Si3 0'2 (OH)], natural clinozoisite [Ca2Al3Si3012(OH)], and synthetic diaspore [AIO(OH)] have been measured at ambient pressure. The volume thermal expansion coefficients for lawsonite, zoisite, and clinozoisite are approximately constant over the measured temperature ranges (25-590 DCfor lawson- ite, 25-750 DCfor zoisite, and 25-900 DCfor clinozoisite), whereas the thermal expansion of diaspore increases slightly over the range 25-300 DC.Interestingly, the room-tempera- ture volume of clinozoisite is greater than that of zoisite, but this situation is reversed above -300 DC.The experimental results may be summarized as follows: lawsonite: VI Vo= 1 + 3.16 (:to.05) x 10-5 (T - 298), Vo = 101.51 (:to.Ol) cm3/mol; zoisite: VIVo = 1 + 3.86 (:to.05) x 10-5 (T - 298), Vo = 136.10 (:to.02) cm3/mol; clinozoisite: VIVo = 1 + 2.94 (:to.05) x 10-5 (T - 298), Vo = 136.42 (:to.05) cm3/mol; diaspore: VIVo = 1 + 7.96 (:to.28) x 10-5 [T - 298 - 20 (VT- ~)], Vo = 17.74 (:to.Ol) cm3/mol. -
1 Revision 1 1 the High-Pressure Phase of Lawsonite
1 Revision 1 2 The high-pressure phase of lawsonite: A single crystal study of a key mantle hydrous phase 3 4 Earl O’Bannon III,1* Christine M. Beavers1,2, Martin Kunz2, and Quentin Williams1 5 1Department of Earth and Planetary Sciences, University of California, Santa Cruz, 1156 High 6 Street, Santa Cruz, California 95064, U.S.A. 7 2Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California, 94720, 8 U.S.A. 9 *Corresponding Author 10 1 11 Abstract 12 Lawsonite CaAl2Si2O7(OH)2·H2O is an important water carrier in subducting oceanic 13 crusts, and the primary hydrous phase in basalt at depths greater than ~80 km. We have 14 conducted high-pressure synchrotron single-crystal x-ray diffraction experiments on natural 15 lawsonite at room temperature up to ~10.0 GPa to study its high-pressure polymorphism. We 16 find that lawsonite remains orthorhombic with Cmcm symmetry up to ~9.3 GPa, and shows 17 nearly isotropic compression. Above ~9.3 GPa, lawsonite becomes monoclinic with P21/m 18 symmetry. Across the phase transition, the Ca polyhedron becomes markedly distorted, and 19 the average positions of the H2O molecules and hydroxyls change. The changes observed in the 20 H-atom positions under compression are different than the low temperature changes in this 21 material. We resolve for the first time the H-bonding configuration of the high-pressure 22 monoclinic phase of lawsonite. A bond valence approach is deployed to determine that the 23 phase transition from orthorhombic to monoclinic is primarily driven by the Si2O7 groups, and in 24 particular it's bridging oxygen atom (O1). -
Zoisite-Clinozoisite Relations in Low- to Medium-Grade High-Pressure Metamorphic Rocks and Their Implications
MINERALOGICAL MAGAZINE, DECEMBER I980, VOL. 43, PP. IOO5-I3 Zoisite-clinozoisite relations in low- to medium-grade high-pressure metamorphic rocks and their implications MASAKI ENAMI Department of Earth Sciences, Nagoya University, Nagoya 464, Japan AND SHOHEI BANNO Department of Earth Sciences, Kanazawa University, Kanazawa 920, Japan SUMMARY. Coexisting zoisite and clinozoisite in seven- electron-probe microanalysis of coexisting zoisite teen specimens from six localities in Japan have been and clinozoisite are described below, with our view studied with the electron-probe microanalyser. Zoisite on the temperature-dependence of the gap in the and clinozoisite are commonly zoned, but compositional temperature range of low- to medium-grade meta- gaps between them are systematic. Referring to the metamorphic grade of the host rocks, a temporary and morphism of high-pressure intermediate type. schematic phase-diagram for the system Ca2AIaSi3OI2- (OH)-Ca2AI2Fea+Si3012(OH) is presented. With in- Mode of occurrence of coexisting zoisite and creasing temperature, in the range of low- to medium- clinozoisite grade metamorphism, the compositional gap between the two epidote-group minerals shifts towards higher Fe 3+ Fig. I shows specimens localities. Brief accounts compositions. of the geology and petrology of these areas and the mode of occurrence of coexisting zoisite and EPIDOTE-GROUP minerals with the general for- clinozoisite are described below. mula Ca2(A1,Fea+)aSi3012(OH) have two series Iratsu and Tonaru epidote-amphibolite masses. of solid solutions, zoisite and clinozoisite-pistacite. The Iratsu and Tonaru masses are metamorphosed The chemical compositions of coexisting zoisite and layered gabbros that occur in the epidote clinozoisite have been reported by many authors amphibolite-facies area in central Shikoku (Banno (Banno, I964; Myer, 1966; Ackermand and Raase, et al., 1976; also for general petrology, cf. -
List of Abbreviations
List of Abbreviations Ab albite Cbz chabazite Fa fayalite Acm acmite Cc chalcocite Fac ferroactinolite Act actinolite Ccl chrysocolla Fcp ferrocarpholite Adr andradite Ccn cancrinite Fed ferroedenite Agt aegirine-augite Ccp chalcopyrite Flt fluorite Ak akermanite Cel celadonite Fo forsterite Alm almandine Cen clinoenstatite Fpa ferropargasite Aln allanite Cfs clinoferrosilite Fs ferrosilite ( ortho) Als aluminosilicate Chl chlorite Fst fassite Am amphibole Chn chondrodite Fts ferrotscher- An anorthite Chr chromite makite And andalusite Chu clinohumite Gbs gibbsite Anh anhydrite Cld chloritoid Ged gedrite Ank ankerite Cls celestite Gh gehlenite Anl analcite Cp carpholite Gln glaucophane Ann annite Cpx Ca clinopyroxene Glt glauconite Ant anatase Crd cordierite Gn galena Ap apatite ern carnegieite Gp gypsum Apo apophyllite Crn corundum Gr graphite Apy arsenopyrite Crs cristroballite Grs grossular Arf arfvedsonite Cs coesite Grt garnet Arg aragonite Cst cassiterite Gru grunerite Atg antigorite Ctl chrysotile Gt goethite Ath anthophyllite Cum cummingtonite Hbl hornblende Aug augite Cv covellite He hercynite Ax axinite Czo clinozoisite Hd hedenbergite Bhm boehmite Dg diginite Hem hematite Bn bornite Di diopside Hl halite Brc brucite Dia diamond Hs hastingsite Brk brookite Dol dolomite Hu humite Brl beryl Drv dravite Hul heulandite Brt barite Dsp diaspore Hyn haiiyne Bst bustamite Eck eckermannite Ill illite Bt biotite Ed edenite Ilm ilmenite Cal calcite Elb elbaite Jd jadeite Cam Ca clinoamphi- En enstatite ( ortho) Jh johannsenite bole Ep epidote -
Reaction Textures and Fluid Behaviour in Very High- Pressure Calc-Silicate Rocks of the Münchberg Gneiss Complex, Bavaria, Germany
J. metamorphic Ceol., 1994, 12, 735-745 Reaction textures and fluid behaviour in very high- pressure calc-silicate rocks of the Münchberg gneiss complex, Bavaria, Germany R. KLEMD,1 S. MATTHES2 AND U. SCHÜSSLER2 Fachbereich Geowissenschaften, Universität Bremen, PO Box 330440, 28334 Bremen, Germany 2lnstitut für Mineralogie, Universität Würzburg, Am Hubland, 97074 Würzburg, Germany ABSTRACT Calc-silicate rocks occur as elliptical bands and boudins intimately interlayered with eclogites and high-pressure gneisses in the Munchberg gneiss complex of NE Bavaria. Core assemblages of the boudins consist of grossular-rich garnet, diopside, quartz, zoisite, clinozoisite, calcite, rutile and titanite. The polygonal granoblastic texture commonly displays mineral relics and reaction textures such as post- kinematic grossular-rich garnet coronas. Reactions between these mineral phases have been modelled in the CaO-Al203-Si02-C02-H20 system with an internally consistent thermodynamic data base. High-pressure metamorphism in the calc-silicate rocks has been estimated at a minimum pressure of 31 kbar at a temperature of 630°C with X^oSQ.Gi. Small volumes of a C02-N2-rich fluid whose composition was buffered on a local scale were present at peak-metamorphic conditions. The P-T conditions for the onset of the amphibolite facies overprint are about 10 kbar at the same temperature. A'co., of the H20-rich fluid phase is regarded to have been <0.03 during amphibolite facies conditions. These P-T estimates are interpreted as representing different stages of recrystallization during isothermal decompression. The presence of multiple generations of mineral phases and the preservation of very high-pressure relics in single thin sections preclude pervasive post-peak metamorphic fluid flow as a cause of a re-equilibration within the calc-silicates. -
Serpentinization, Rodingitization, and Sea Floor Carbonate Chimney
Geochimica et Cosmochimica Acta, Vol. 68, No. 5, pp. 1115–1133, 2004 Copyright © 2004 Elsevier Ltd Pergamon Printed in the USA. All rights reserved 0016-7037/04 $30.00 ϩ .00 doi:10.1016/j.gca.2003.08.006 Geochemical models of metasomatism in ultramafic systems: Serpentinization, rodingitization, and sea floor carbonate chimney precipitation JAMES L. PALANDRI* and MARK H. REED U.S. Geological Survey, 345 Middlefield Rd., MS 427, Menlo Park, CA 94025, USA (Received April 9, 2003; accepted in revised form August 15, 2003) Abstract—In a series of water-rock reaction simulations, we assess the processes of serpentinization of harzburgite and related calcium metasomatism resulting in rodingite-type alteration, and seafloor carbonate chimney precipitation. At temperatures from 25 to 300°C (P ϭ 10 to 100 bar), using either fresh water or seawater, serpentinization simulations produce an assemblage commonly observed in natural systems, dominated by serpentine, magnetite, and brucite. The reacted waters in the simulations show similar trends in composition with decreasing water-rock ratios, becoming hyper-alkaline and strongly reducing, with increased ϳ dissolved calcium. At 25°C and w/r less than 32, conditions are sufficiently reducing to yield H2 gas, nickel-iron alloy and native copper. Hyperalkalinity results from OHϪ production by olivine and pyroxene dissolution in the absence of counterbalancing OHϪ consumption by alteration mineral precipitation except at very high pH; at moderate pH there are no stable calcium minerals and only a small amount of chlorite forms, limited by aluminum, thus allowing Mg2ϩ and Ca2ϩ to accumulate in the aqueous phase in exchange for Hϩ. -
What We Know About Subduction Zones from the Metamorphic Rock Record
What we know about subduction zones from the metamorphic rock record Sarah Penniston-Dorland University of Maryland Subduction zones are complex We can learn a lot about processes occurring within active subduction zones by analysis of metamorphic rocks exhumed from ancient subduction zones Accreonary prism • Rocks are exhumed from a wide range of different parts of subduction zones. • Exhumed rocks from fossil subduction zones tell us about materials, conditions and processes within subduction zones • They provide complementary information to observations from active subduction systems Tatsumi, 2005 The subduction interface is more complex than we usually draw Mélange (Bebout, and Penniston-Dorland, 2015) Information from exhumed metamorphic rocks 1. Thermal structure The minerals in exhumed rocks of the subducted slab provide information about the thermal structure of subduction zones. 2. Fluids Metamorphism generates fluids. Fossil subduction zones preserve records of fluid-related processes. 3. Rheology and deformation Rocks from fossil subduction zones record deformation histories and provide information about the nature of the interface and the physical properties of rocks at the interface. 4. Geochemical cycling Metamorphism of the subducting slab plays a key role in the cycling of various elements through subduction zones. Thermal structure Equilibrium Thermodynamics provides the basis for estimating P-T conditions using mineral assemblages and compositions Systems act to minimize Gibbs Free Energy (chemical potential energy) Metamorphic facies and tectonic environment SubduconSubducon zone metamorphism zone metamorphism Regional metamorphism during collision Mid-ocean ridge metamorphism Contact metamorphism around plutons Determining P-T conditions from metamorphic rocks Assumption of chemical equilibrium Classic thermobarometry Based on equilibrium reactions for minerals in rocks, uses the compositions of those minerals and their thermodynamic properties e.g. -
Decomposition of Kyanite and Solubility of Al2o3 in Stishovite at High Pressure and High Temperature Conditions
Phys Chem Minerals (2006) 33:711–721 DOI 10.1007/s00269-006-0122-x ORIGINAL PAPER Decomposition of kyanite and solubility of Al2O3 in stishovite at high pressure and high temperature conditions Xi Liu Æ Norimasa Nishiyama Æ Takeshi Sanehira Æ Toru Inoue Æ Yuji Higo Æ Shizue Sakamoto Received: 9 August 2006 / Accepted: 9 October 2006 / Published online: 3 November 2006 Ó Springer-Verlag 2006 Abstract In order to constrain the high-pressure Keywords Al2O3 solubility in stishovite Á Corundum Á behavior of kyanite, multi-anvil experiments have been Kyanite Á Phase equilibrium Á Stishovite carried out from 15 to 25 GPa, and 1,350 to 2,500°C. Both forward and reversal approaches to phase equi- libria were adopted in these experiments. We find that Introduction kyanite breaks down to stishovite + corundum at pressures above ~15 GPa, and stishovite + corundum Kyanite (Ky, Al2SiO5), commonly found in peralumi- should be the stable phase assemblage at the pressure– nous eclogites and amphibolites, has been soundly temperature conditions of the transition zone and the demonstrated to be an important constituent phase for uppermost part of the lower mantle of the Earth, the materials of continental crust and pelagic sediment in agreement with previous multi-anvil experimental at pressures from ~1 to 16 GPa (Irifune et al. 1994; studies and ab initio calculation results, but in dis- Schmidt et al. 2004). Its role at higher pressures, how- agreement with some of the diamond-anvil cell ever, remains unclear. With some preliminary experi- experimental studies in the literature. The Al2O3 sol- ments in a Bridgman–anvil apparatus, Ringwood and ubility in nominally dry stishovite has been tightly Reid (1969) tentatively suggested that Ky appears sta- bracketed by forward and reversal experiments; it is ble up to 15 GPa and 1,000°C. -
Staurolite|Bearing Gneiss and Re|Examination of Metamorphic
Staurolite-bearingJournal gneiss of Mineralogical and re-examination and Petrological of metamorphic Sciences, zonal Volume mapping 99 ,of page the Higo1─ 18, metamorphic2004 terrane 1 Staurolite-bearing gneiss and re-examination of metamorphic zonal mapping of the Higo metamorphic terrane in the Kosa area, central Kyushu, Japan * * ** Kenshi MAKI , Yoshihisa ISHIZAKA and Tadao NISHIYAMA *Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan **Department of Earth Sciences, Faculty of Science, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan This paper describes the finding of staurolite-bearing gneiss from the Higo metamorphic terrane and proposes new mineral zones in the Kosa area, Kumamoto Prefecture. Previous mineral zones of the Higo metamorphic terrane proposed by Obata et al. (1994) consist of five zones: Zone A characterized by Chl + Ms, Zone B by Bt + Ms + And, Zone C by Kfs + Sil + Bt, Zone D by Grt + Crd + Bt, and Zone E by Opx in metapelites. They identified three zones from B to D in the Kosa area. However, we found that sillimanite appears together with Grt + Crd, hence this paper shows that Zone C is absent in the Kosa area. New finding of Opx in the southern- most part of the area made it possible to define three mineral zones; Bt zone, Grt-Crd zone, and Opx zone, in the order of increasing grade from north to south in the Kosa area. Analysis of staurolite-bearing assemblage in a KFMASH system together with textural evidence reveals that the following reactions occurred in the stauro- - lite bearing gneiss in the excess of Kfs, Qtz and H2O: [Sil] Str + Bt = Grt + Crd [Bt] Str = Grt + Crd + Sil Chemographic analysis of these reactions together with Grt-Bt geothermometers shows the metamorphic condition of P = 200 MPa and T = 600-620°C, which is much lower in pressure than that estimated by Osanai et al. -
Minerals Found in Michigan Listed by County
Michigan Minerals Listed by Mineral Name Based on MI DEQ GSD Bulletin 6 “Mineralogy of Michigan” Actinolite, Dickinson, Gogebic, Gratiot, and Anthonyite, Houghton County Marquette counties Anthophyllite, Dickinson, and Marquette counties Aegirinaugite, Marquette County Antigorite, Dickinson, and Marquette counties Aegirine, Marquette County Apatite, Baraga, Dickinson, Houghton, Iron, Albite, Dickinson, Gratiot, Houghton, Keweenaw, Kalkaska, Keweenaw, Marquette, and Monroe and Marquette counties counties Algodonite, Baraga, Houghton, Keweenaw, and Aphrosiderite, Gogebic, Iron, and Marquette Ontonagon counties counties Allanite, Gogebic, Iron, and Marquette counties Apophyllite, Houghton, and Keweenaw counties Almandite, Dickinson, Keweenaw, and Marquette Aragonite, Gogebic, Iron, Jackson, Marquette, and counties Monroe counties Alunite, Iron County Arsenopyrite, Marquette, and Menominee counties Analcite, Houghton, Keweenaw, and Ontonagon counties Atacamite, Houghton, Keweenaw, and Ontonagon counties Anatase, Gratiot, Houghton, Keweenaw, Marquette, and Ontonagon counties Augite, Dickinson, Genesee, Gratiot, Houghton, Iron, Keweenaw, Marquette, and Ontonagon counties Andalusite, Iron, and Marquette counties Awarurite, Marquette County Andesine, Keweenaw County Axinite, Gogebic, and Marquette counties Andradite, Dickinson County Azurite, Dickinson, Keweenaw, Marquette, and Anglesite, Marquette County Ontonagon counties Anhydrite, Bay, Berrien, Gratiot, Houghton, Babingtonite, Keweenaw County Isabella, Kalamazoo, Kent, Keweenaw, Macomb, Manistee, -
Electronic Supplementary Material (ESI) for Journal of Analytical Atomic Spectrometry This Journal Is © the Royal Society of Chemistry 2012
Electronic Supplementary Material (ESI) for Journal of Analytical Atomic Spectrometry This journal is © The Royal Society of Chemistry 2012 ELECTRONIC SUPPLEMENTARY INFORMATION FOR Iron oxidation state in garnet from a subduction setting: a micro-XANES and electron microprobe (“flank method”) comparative study Elisa Borfecchia2, Lorenzo Mino2*, Diego Gianolio2, Chiara Groppo1*, Nadia Malaspina3, Gema Martinez-Criado5, Juan Angel Sans Tresserras5, Stefano Poli4, Daniele Castelli1 and Carlo Lamberti2 1 – Dept. Earth Sciences, University of Torino, via Valperga Caluso 35, I-10125 Torino (Italy) 2 – Dept. of Chemistry, University of Torino, via Giuria 7, I-10125 Torino (Italy); NIS Centre of Excellence and INSTM Centro di Riferimento, via Quarello 11, I-10135, Torino (Italy) 3 – Dept. of Geological Sciences and Geotechnology, Università degli Studi di Milano-Bicocca, Piazza della Scienza 4, I-20126 Milano (Italy) 4 – Dept. of Earth Sciences, Università degli Studi di Milano, via Botticelli 23, I-20133 Milano (Italy) 5 - European Synchrotron Radiation Facility, ID22, 6, rue Jules Horowitz, B.P. 220, F-38043 Grenoble cedex (France) Sample description The studied sample OF2727 is a fine-grained eclogitized metagabbro from the Monviso meta- ophiolite (western Alps), consisting of omphacite, garnet and rutile with minor blue amphibole and very minor lawsonite, talc and jadeite, as described by Groppo and Castelli.1 Garnet occurs as small idioblasts (up to 0.5 mm in diameter) set in a matrix mainly consisting of omphacite. Garnet cores (1a-1e in Fig. S1) are crowded of very small inclusions mostly of omphacite, whereas garnet rims (2a-2c in Fig. S1) are almost free of inclusions. Both SEM-EDS and EMP analytical techniques have been used to analyze the major element concentrations across garnet crystals.