Thermal Break Strategies for Cladding Systems in Building Structures: Part 1
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Supporting Information Carbazole-Based Copolymers Via
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is © The Royal Society of Chemistry 2017 Supporting Information Carbazole-Based Copolymers via Direct Arylation Polymerization (DArP) for Suzuki- Convergent Polymer Solar Cell Performance Nemal S. Gobalasingham,a Seyma Ekiz,a Robert M. Pankow,a Francesco Livi,a,b Eva Bundgaard,b* and Barry C. Thompsona* aDepartment of Chemistry and Loker Hydrocarbon Research Institute, University of Southern California, Los Angeles, California 90089-1661 bDTU Energy, Technical University of Denmark, Frederiksborgvej 399, 4000, Roskilde, Denmark *email: [email protected] or [email protected] S1 1 Figure S1. H NMR of 2,7-dibromo-9-(heptadecan-9-yl)-9H-carbazole in CDCl3 S2 Figure S2. 1H NMR of 2,5-diethylhexyl-3,6-di(thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole- 1,4-dione in CDCl3 S3 Figure S3. 1H NMR of 4,10-bis(diethylhexyl)-thieno[2',3':5,6]pyrido[3,4-g]thieno[3,2- c]isoquinoline-5,11-dione in CDCl3 S4 Figure S4. 1H NMR of 5-octyl-1,3-di(thiophen-2-yl)-4H-thieno[3,4-c]pyrrole-4,6(5H)-dione in CDCl3 S5 1 Figure S5. H NMR of 2,5-bis(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)pyridine in CDCl3 S6 2.13 2.29 2.57 2.13 2.11 2.19 1.00 5.38 7.15 8.05 23.31 7.67 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 1 Figure S6. High Temperature H NMR of P1 in C2D2Cl4 S7 7.66 3.37 22.18 8.41 4.78 3.66 1.00 2.15 2.12 1.86 2.23 2.24 2.07 12 11 10 9 8 7 6 5 4 3 2 1 0 -1 -2 -3 1 Figure S7. -
Thermal Bridges in Building Envelopes – an Overview of Impacts and Solutions
Int. Rev. Appl. Sci. Eng. 9 (2018) 1, 31–40 DOI: 10.1556/1848.2018.9.1.5 THERMAL BRIDGES IN BUILDING ENVELOPES – AN OVERVIEW OF IMPACTS AND SOLUTIONS A. ALHAWARI, P. MUKHOPADHYAYA* University of Victoria, Canada *E-mail: [email protected] Increasing building energy performance has become an obligatory objective in many countries. Thermal bridge is a major cause of poor energy performance, durability, and indoor air quality of buildings. This paper starts with a review of thermal bridges and their negative impacts on building energy effi ciency. Based on published literatures, various types of building thermal bridges are discussed in this paper, including the most effective solutions to diminish their impacts. In addition, various numerical and exper- imental studies on the balcony thermal bridge are explored. Results show that among all types of thermal bridges, the exposed bal- cony slab produces the most challenging thermal bridging problem where an integrated thermal and structural design is required. Using low thermal conductivity materials in building construction could help in reducing the impact of thermal bridges. Finally, further investigations are needed to develop more innovative and effective solutions for the balcony thermal bridge. Keywords: thermal bridges, thermal break, energy performance, balcony 1. Introduction ers. According to Passive House standards, the total heat transfer coeffi cient of opaque wall components in Globally, over the past decades, demand for energy cool climate zone must not exceed 0.15 W/(m2 K) [3]. is increasing rapidly every year and a signifi cant por- Various types of high energy effi cient walls, roofs, and tion of this demand is consumed by residential build- windows have been developed to reduce the buildings ings sector. -
Thermal Bridge Concepts
The Why of Psi The Why of Psi Workshop Presenters: for CertiPHIers Cooperative… o Chris Petit, CPHD, PHI-accredited Certifier Regenerative Design, LLC o Rolf Jacobson, LEED AP, CPHC Research Fellow, Center for Sustainable Building Research, U of M Copyright © 2017 Chris Petit and Rolf Jacobson. All rights reserved. No part of this presentation may be reproduced without written permission. Outline for the Course • Thermal Bridge Theory • Principles of thermal bridge modeling • Flixo orientation/walkthrough • Module 0 Warm up • Module 1 EQ Layers • Module 2 Wall Corner • Module 3 Brick Ledge • Module 4 Lintel 3 The Why of Psi Thermal Bridge Theory • Thermal bridge definition, types of TBs, and why controlling them is critical for super-insulated buildings. • Typical thermal bridge details and design techniques to reduce thermal bridge heat loss. • How to use and input psi values with the PHPP/ WUFI Passive 4 Section 1 – Background + Basics What is a thermal bridge? 5 Section 1 – Background + Basics What is a thermal bridge? Short answer: A discontinuity in the thermal envelope. 6 Section 1 – Background + Basics What is a thermal bridge? Short answer: A discontinuity in the thermal envelope. What types of discontinuities might there be in a thermal envelope? 7 Section 1 – Background + Basics What is a thermal bridge? Short answer: A discontinuity in the thermal envelope. What types of discontinuities might there be in a thermal envelope? • Repetitive bridges (studs, floor joists, rafters) • Material changes (windows, insulation) • Penetrations (pipes, fasteners) • Assembly junctions (roof to wall, wall to floor, etc) • Corners 8 Section 1 – Background + Basics Repetitive TBs Point TBs Linear TBs (penetrations) (assembly junctions) Should be accounted Usually use side Three types: for in calculation of calculators instead of 1) Structural (ex – rim assembly U-values in thermal bridge joists, prefab wall the PHPP modeling software. -
X-Ray Structural Analyses of Cyclodecasulfur (S10) and of A
X-Ray Structural Analyses of Cyclodecasulfur (S10) and of a Cyclohexasulfur-Cyclodecasulfur Molecular Addition Compound (S6 • S10) [1] Ralf Steudel*, Jürgen Steidel Institut für Anorganische und Analytische Chemie, Technische Universität Berlin, Sekr. C2, D-1000 Berlin 12 Richard Reinhardt** Institut für Kristallographie der Freien Universität Berlin, Takustraße 6, D-1000 Berlin 33 Dedicated to Professor Dr. Karl Winnacker on the occasion of his 80th birthday Z. Naturforsch. 38 b, 1548-1556 (1983); received August 11, 1983 Elemental Sulfur, Sulfur Rings, Molecular Structure, Crystal Structure, Vibrational Spectra Low temperature X-ray structural analyses of monoclinic single crystals of Sio and Sö • Sio (prepared from the components) show that the cyclic Sio molecule exhibits the same D2 conformation in both compounds with bond distances between 203.3 and 208.0pm, bond angles (a) between 103 and 111°, and torsional angles (r) between 73 and 124°. The Sß molecule (site symmetry Ci) in Sö • Sio is very similar to the one in pure Sö (dss = 206.2 pm, a= 103°, r = 74°). All intermolecular interactions are of van-der-Waals type. The Raman spectrum of S6 • Sio can be explained by a superposition of the Se and Sio spectra. Introduction In all cases the reason for the differing bond distances is the variation of the torsional angles The tremendous industrial importance of ele- leading to a varying degree of lone-pair-lone-pair mental sulfur and its surplus expected for the near repulsion between neighboring atoms. In fact, the future (and occasionally already experienced in the torsional angles r in sulfur rings Sre vary between 0° past) have stimulated considerable research ac- and 140° resulting in a bond length variation of tivities with the result that 19 well characterized 19 pm or 9% [18]. -
Fundamentals of Thermal Bridging
Thermal Bridging: Small Details with a Large Impact Jay H. Crandell, P.E. ABTG / ARES Consulting Applied Building Technology Group (ABTG) is committed to using sound science and generally accepted engineering practice to develop research supporting the reliable design and installation of foam sheathing. ABTG’s educational program work with respect to foam sheathing is supported by the Foam Sheathing Committee (FSC) of the American Chemistry Council. ABTG is a professional engineering firm, an approved source as defined in Chapter 2 and independent as defined in Chapter 17 of the IBC. DISCLAIMER: While reasonable effort has been made to ensure the accuracy of the information presented, the actual design, suitability and use of this information for any particular application is the responsibility of the user. Where used in the design of buildings, the design, suitability and use of this information for any particular building is the responsibility of the Owner or the Owner’s authorized agent. Foam sheathing research reports, code compliance documents, educational programs and best practices can be found at www.continuousinsulation.org. Copyright © 2021 Applied Building Technology Group Outline . Types of Thermal Bridges & Implications . Design and Mitigation Concepts . Examples of Thermal Bridge Mitigation Strategies . Calculation Methods and Design Data . Design Example . Status of ASHRAE 90.1 Thermal Bridging Work . Conclusions . Bibliography (design resources) What is a thermal bridge? A thermal bridge is not a burning bridge, although both have something to do with heat transfer. Source: Steve Dadds; as published in azfamily.com by 3TV/CBS 5, posted Aug. 17, 2015. What do codes require? . Framing thermal bridges (studs, tracks, headers, etc.) are accounted for in the prescriptive R-values and U-factor calculations for individual assemblies (walls, roofs, floors, etc.) . -
Inhibition of Steel Corrosion and Alkaline Zinc Oxide
www.nature.com/scientificreports OPEN Inhibition of Steel Corrosion and Alkaline Zinc Oxide Dissolution by Dicarboxylate Bola-Amphiphiles: Received: 10 March 2017 Accepted: 18 April 2017 Self-Assembly Supersedes Host- Published: xx xx xxxx Guest Conception Dirk Schmelter1, Arthur Langry2, Andrej Koenig1, Patrick Keil1, Fabrice Leroux2 & Horst Hintze-Bruening 1 For many decorative applications like industrial and architectural paints, prevention of metal substrates from corrosion is a primary function of organic coatings. Triggered release of inhibitor species is generally accepted as a remedy for starting corrosion in case of coatings damage. A polyurethane based coating, doped with bola-amphiphiles of varying molecular weight but with a common head group motif that stems from ring-opened alkenyl succinic anhydride, enables passivation of the defect and mitigates cathodic delamination, if applied on cold rolled steel. An antagonistic effect results from the intercalation of the bola-amphiphiles into layered double hydroxide Zn2Al(OH)6 and subsequent incorporation of the hybrid phase into the organic matrix. In particular higher molecular weight bola- amphiphiles get immobilized through alkaline degradation of the layered framework in the basic milieu at the cathode. By means of sediments from colloidal states it is demonstrated that in-situ formed zinc oxide encapsulates the hybrid phase, evidenced by impeded dissolution of the ZnO based shell into caustic soda. While inhibition of steel corrosion results from a Donnan barrier layer, impeded zinc oxide dissolution is rooted in zinc catalyzed bola-amphiphile hydrolysis and layered deposition of the crystalline spacer diol hydrogenated bisphenol-A. Iron, aluminum and their respective alloys are the most widely used metals in civil engineering, infrastructure, transportation and industry1. -
Balcony and Slab Edge Thermal Bridges and Solutions on Effective R-Values and North American Energy Code Compliance
The Importance of Slab Edge & Balcony Thermal Bridges Report # 1 : Impact of Slab Thermal Breaks on Effective R-Values and Energy Code Compliance Prepared by Preparedby Ltd. RDHEngineering Building 2013 24, September Date The Importance of Slab Edge & Balcony Thermal Bridges Report # 1 - Impact on Effective R-Values and Energy Code Compliance Thermal bridging occurs when heat flow bypasses the insulated elements of the building enclosure. Bridging occurs through structural components such as the studs/plates, framing, and cladding supports as well as the larger columns, shear walls, and exposed floor slab edges and protruding balconies. While thermal bridging occurs through the roofs, floors, and below-grade assemblies, it is often most pronounced in above-grade wall assemblies. The heat flow through thermal bridges is significant and disproportionate to the overall enclosure area so that a seemingly well insulated building can often fail to meet energy code requirements, designer intent, or occupant expectations. Windows are often seen as the largest thermal bridge in buildings, as the thermal performance is often quite low compared to the surrounding walls (i.e., an R-2 metal frame window within an R-20 insulated wall); however, exposed concrete slab edges and balconies can have almost as large of an influence having effective R-values of approximately R-1. After accounting for windows and doors, exposed concrete slab edges and balconies can account for the second greatest source of thermal bridging in a multi-storey building. With a better understanding of the impacts of thermal bridging, the building industry has started to thermally improve building enclosures; for example, the use of exterior continuous insulation in walls is becoming more common. -
World Para Swimming World Records Long Course
World Para Swimming World Records Long Course World Para Swimming World Records created by IPC Sport Data Management System Gender: Men | Course: Long Course Men's 50 m Freestyle Class Name NPC Birth Time Date City Country S1 Mamistvalov, Itzhak ISR 1979 01:03.80 2014-03-09 Esbjerg Denmark S2 Zou, Liankang CHN 1995 00:50.65 2016-09-11 Rio de Janeiro Brazil S3 Huang, Wenpan CHN 1995 00:38.81 2017-12-06 Mexico City Mexico S4 Leslie, Cameron NZL 1990 00:37.14 2019-09-13 London Great Britain S5 Fantin, Antonio ITA 2001 00:30.16 2019-06-01 Lignano Sabbiadoro Italy S6 Xu, Qing CHN 1992 00:28.57 2012-09-04 London Great Britain S7 Trusov, Andrii UKR 2000 00:27.07 2019-09-15 London Great Britain S8 Tarasov, Denis RUS 1993 00:25.32 2014-08-10 Eindhoven Netherlands S9 Barlaam, Simone ITA 2000 00:24.00 2019-09-15 London Great Britain S10 Brasil, Andre BRA 1984 00:23.16 2012-08-31 London Great Britain S11 Yang, Bozun CHN 1986 00:25.27 2012-09-01 London Great Britain S12 Veraksa, Maksym UKR 1984 00:22.99 2009-10-21 Reykjavik Iceland S13 Boki, Ihar BLR 1994 00:23.20 2015-07-13 Glasgow Great Britain IPC Sport Data Management System Page 1 of 22 29 September 2021 at 00:11:44 CEST World Para Swimming World Records Long Course Men's 100 m Freestyle Class Name NPC Birth Time Date City Country S1 Mamistvalov, Itzhak ISR 1979 02:15.83 2012-09-01 London Great Britain S2 Liu, Benying CHN 1996 01:46.63 2016-09-11 Rio de Janeiro Brazil S3 Lopez Diaz, Diego MEX 1994 01:32.69 2018-06-08 Berlin Germany S4 Dadaon, Ami Omer ISR 2000 01:19.77 2021-05-17 Funchal Portugal -
Seasonal Characteristics of Organic Aerosol Chemical Composition and Volatility in Stuttgart, Germany
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acp-2019-364 Manuscript under review for journal Atmos. Chem. Phys. Discussion started: 30 April 2019 c Author(s) 2019. CC BY 4.0 License. Seasonal characteristics of organic aerosol chemical composition and volatility in Stuttgart, Germany Wei Huang1,2, Harald Saathoff1, Xiaoli Shen1,2, Ramakrishna Ramisetty1,3, Thomas Leisner1,4, Claudia Mohr5,* 5 1Institute of Meteorology and Climate Research, Karlsruhe Institute of Technology, Eggenstein-Leopoldshafen, 76344, Germany 2Institute of Geography and Geoecology, Working Group for Environmental Mineralogy and Environmental System Analysis, Karlsruhe Institute of Technology, Karlsruhe, 76131, Germany 3Now at: TSI Instruments India Private Limited, Bangalore, 560102, India 10 4Institute of Environmental Physics, Heidelberg University, Heidelberg, 69120, Germany 5Department of Environmental Science and Analytical Chemistry, Stockholm University, Stockholm, 11418, Sweden *Correspondence to: [email protected] Abstract. Chemical composition and volatility of organic aerosol (OA) particles were investigated during July– 15 August 2017 and February–March 2018 in the city of Stuttgart, one of the most polluted cities in Germany. Total non-refractory particle mass was measured with a high-resolution time-of-flight aerosol mass spectrometer (HR- ToF-AMS; hereafter AMS). Aerosol particles were collected on filters and analyzed in the laboratory with a filter inlet for gases and aerosols coupled to a high-resolution time-of-flight chemical ionization mass spectrometer (FIGAERO-HR-ToF-CIMS; hereafter CIMS), yielding the molecular composition of oxygenated OA (OOA) 20 compounds. While the average organic mass loadings are lower in the summer period (5.1 ± 3.2 µg m-3) than in the winter period (8.4 ± 5.6 µg m-3), we find relatively larger mass contributions of organics measured by AMS in summer (68.8 ± 13.4 %) compared to winter (34.8 ± 9.5 %). -
Train Simulator - Right Through Berlin
Train Simulator - Right through Berlin © Historical S-Bahn Berlin e.V. 2020 Page 1 Train Simulator - Right through Berlin Manual "Mitten durch Berlin" - Operation Series 476 Table of contents Table of contents ....................................................................................................... 2 0. authors ................................................................................................................ 3 1. introduction .......................................................................................................... 3 2. system requirements .............................................................................................. 4 3. the driver's cab ..................................................................................................... 5 4. upgrading .......................................................................................................... 10 4.1 Train is cold (full upgrade) .............................................................................. 10 4.2 Transfer of trains from other Tf ......................................................................... 10 4.3 Train is fully upgraded .................................................................................... 10 4.4 Change of driver's cab ................................................................................... 11 5. door control ....................................................................................................... 11 6. driving and braking ........................................................................................... -
New Subway Breaks Cover at Innotrans
THE INTERNATIONAL LIGHT RAIL MAGAZINE www.lrta.org www.tautonline.com NOVEMBER 2018 NO. 971 NEW SUBWAY BREAKS COVER AT INNOTRANS Highlights from the world’s biggest mobility fair Success at the Global Light Rail Awards FTA demands Honolulu ‘rescue plan’ Five shortlisted for Tyne & Wear Metro Zürich Stuttgart at 150 11> £4.60 Further improving Celebrating one of an LRT world-leader the tramway greats 9 771460 832067 Congratulations to all those honoured at this year’s Global Light Rail Awards and a big thank you to the evening’s supporters: HEADLINE SUPPORTER ColTram Next year’s event will be held in London on 2 October 2019 2019 Register your interest by emailing [email protected] or by calling +44 (0)1733 367600 CONTENTS The official journal of the Light Rail Transit Association 410 NOVEMBER 2018 Vol. 81 No. 971 www.tautonline.com EDITORIAL EDITOR – Simon Johnston [email protected] 404 ASSOCIATE EDITOr – Tony Streeter [email protected] WORLDWIDE EDITOR – Michael Taplin [email protected] 422 NewS EDITOr – John Symons [email protected] SenIOR CONTRIBUTOR – Neil Pulling WORLDWIDE CONTRIBUTORS Tony Bailey, Richard Felski, Ed Havens, Andrew Moglestue, Paul Nicholson, Herbert Pence, Mike Russell, Nikolai Semyonov, Alain Senut, Vic Simons, Witold Urbanowicz, Bill Vigrass, Francis Wagner, Thomas Wagner, Philip Webb, Rick Wilson PRODUCTION – Lanna Blyth Tel: +44 (0)1733 367604 [email protected] NEWS 404 SYSTEMS FACTFILE: ZÜRich 422 Achievement and excellence at the Global Neil Pulling explores the recent projects and DESIGN – Debbie Nolan Light Rail Awards; Two openings in a week future prospects for a city that continues to ADVertiSING grow Wuhan’s metro by over 50km; Honolulu invest in high-quality urban transport. -
Science Journals
SCIENCE ADVANCES | RESEARCH ARTICLE CLIMATOLOGY Copyright © 2021 The Authors, some rights reserved; Denitrifying pathways dominate nitrous exclusive licensee American Association oxide emissions from managed grassland for the Advancement of Science. No claim to during drought and rewetting original U.S. Government E. Harris1*, E. Diaz-Pines2, E. Stoll1, M. Schloter3,4, S. Schulz3, C. Duffner3,4, K. Li5, K. L. Moore5, Works. Distributed 1 1 2 6 7 1 under a Creative J. Ingrisch , D. Reinthaler , S. Zechmeister-Boltenstern , S. Glatzel , N. Brüggemann , M. Bahn Commons Attribution NonCommercial Nitrous oxide is a powerful greenhouse gas whose atmospheric growth rate has accelerated over the past License 4.0 (CC BY-NC). decade. Most anthropogenic N2O emissions result from soil N fertilization, which is converted to N2O via oxic nitri- fication and anoxic denitrification pathways. Drought-affected soils are expected to be well oxygenated; however, using high-resolution isotopic measurements, we found that denitrifying pathways dominated N2O emissions during a severe drought applied to managed grassland. This was due to a reversible, drought-induced enrich- ment in nitrogen-bearing organic matter on soil microaggregates and suggested a strong role for chemo- or codenitrification. Throughout rewetting, denitrification dominated emissions, despite high variability in fluxes. Total N2O flux and denitrification contribution were significantly higher during rewetting than for control plots at the same soil moisture range. The observed feedbacks between