A Path Integral for Classical Dynamics, Entanglement, and Jaynes-Cummings Model at
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Motion of the Reduced Density Operator
Motion of the Reduced Density Operator Nicholas Wheeler, Reed College Physics Department Spring 2009 Introduction. Quantum mechanical decoherence, dissipation and measurements all involve the interaction of the system of interest with an environmental system (reservoir, measurement device) that is typically assumed to possess a great many degrees of freedom (while the system of interest is typically assumed to possess relatively few degrees of freedom). The state of the composite system is described by a density operator ρ which in the absence of system-bath interaction we would denote ρs ρe, though in the cases of primary interest that notation becomes unavailable,⊗ since in those cases the states of the system and its environment are entangled. The observable properties of the system are latent then in the reduced density operator ρs = tre ρ (1) which is produced by “tracing out” the environmental component of ρ. Concerning the specific meaning of (1). Let n) be an orthonormal basis | in the state space H of the (open) system, and N) be an orthonormal basis s !| " in the state space H of the (also open) environment. Then n) N) comprise e ! " an orthonormal basis in the state space H = H H of the |(closed)⊗| composite s e ! " system. We are in position now to write ⊗ tr ρ I (N ρ I N) e ≡ s ⊗ | s ⊗ | # ! " ! " ↓ = ρ tr ρ in separable cases s · e The dynamics of the composite system is generated by Hamiltonian of the form H = H s + H e + H i 2 Motion of the reduced density operator where H = h I s s ⊗ e = m h n m N n N $ | s| % | % ⊗ | % · $ | ⊗ $ | m,n N # # $% & % &' H = I h e s ⊗ e = n M n N M h N | % ⊗ | % · $ | ⊗ $ | $ | e| % n M,N # # $% & % &' H = m M m M H n N n N i | % ⊗ | % $ | ⊗ $ | i | % ⊗ | % $ | ⊗ $ | m,n M,N # # % &$% & % &'% & —all components of which we will assume to be time-independent. -
Arxiv:1911.07386V2 [Quant-Ph] 25 Nov 2019
Ideas Abandoned en Route to QBism Blake C. Stacey1 1Physics Department, University of Massachusetts Boston (Dated: November 26, 2019) The interpretation of quantum mechanics known as QBism developed out of efforts to understand the probabilities arising in quantum physics as Bayesian in character. But this development was neither easy nor without casualties. Many ideas voiced, and even committed to print, during earlier stages of Quantum Bayesianism turn out to be quite fallacious when seen from the vantage point of QBism. If the profession of science history needed a motto, a good candidate would be, “I think you’ll find it’s a bit more complicated than that.” This essay explores a particular application of that catechism, in the generally inconclusive and dubiously reputable area known as quantum foundations. QBism is a research program that can briefly be defined as an interpretation of quantum mechanics in which the ideas of agent and ex- perience are fundamental. A “quantum measurement” is an act that an agent performs on the external world. A “quantum state” is an agent’s encoding of her own personal expectations for what she might experience as a consequence of her actions. Moreover, each measurement outcome is a personal event, an expe- rience specific to the agent who incites it. Subjective judgments thus comprise much of the quantum machinery, but the formalism of the theory establishes the standard to which agents should strive to hold their expectations, and that standard for the relations among beliefs is as objective as any other physical theory [1]. The first use of the term QBism itself in the literature was by Fuchs and Schack in June 2009 [2]. -
Density Matrix Description of NMR
Density Matrix Description of NMR BCMB/CHEM 8190 Operators in Matrix Notation • It will be important, and convenient, to express the commonly used operators in matrix form • Consider the operator Iz and the single spin functions α and β - recall ˆ ˆ ˆ ˆ ˆ ˆ Ix α = 1 2 β Ix β = 1 2α Iy α = 1 2 iβ Iy β = −1 2 iα Iz α = +1 2α Iz β = −1 2 β α α = β β =1 α β = β α = 0 - recall the expectation value for an observable Q = ψ Qˆ ψ = ∫ ψ∗Qˆψ dτ Qˆ - some operator ψ - some wavefunction - the matrix representation is the possible expectation values for the basis functions α β α ⎡ α Iˆ α α Iˆ β ⎤ ⎢ z z ⎥ ⎢ ˆ ˆ ⎥ β ⎣ β Iz α β Iz β ⎦ ⎡ α Iˆ α α Iˆ β ⎤ ⎡1 2 α α −1 2 α β ⎤ ⎡1 2 0 ⎤ ⎡1 0 ⎤ ˆ ⎢ z z ⎥ 1 Iz = = ⎢ ⎥ = ⎢ ⎥ = ⎢ ⎥ ⎢ ˆ ˆ ⎥ 1 2 β α −1 2 β β 0 −1 2 2 0 −1 ⎣ β Iz α β Iz β ⎦ ⎣⎢ ⎦⎥ ⎣ ⎦ ⎣ ⎦ • This is convenient, as the operator is just expressed as a matrix of numbers – no need to derive it again, just store it in computer Operators in Matrix Notation • The matrices for Ix, Iy,and Iz are called the Pauli spin matrices ˆ ⎡ 0 1 2⎤ 1 ⎡0 1 ⎤ ˆ ⎡0 −1 2 i⎤ 1 ⎡0 −i ⎤ ˆ ⎡1 2 0 ⎤ 1 ⎡1 0 ⎤ Ix = ⎢ ⎥ = ⎢ ⎥ Iy = ⎢ ⎥ = ⎢ ⎥ Iz = ⎢ ⎥ = ⎢ ⎥ ⎣1 2 0 ⎦ 2 ⎣1 0⎦ ⎣1 2 i 0 ⎦ 2 ⎣i 0 ⎦ ⎣ 0 −1 2⎦ 2 ⎣0 −1 ⎦ • Express α , β , α and β as 1×2 column and 2×1 row vectors ⎡1⎤ ⎡0⎤ α = ⎢ ⎥ β = ⎢ ⎥ α = [1 0] β = [0 1] ⎣0⎦ ⎣1⎦ • Using matrices, the operations of Ix, Iy, and Iz on α and β , and the orthonormality relationships, are shown below ˆ 1 ⎡0 1⎤⎡1⎤ 1 ⎡0⎤ 1 ˆ 1 ⎡0 1⎤⎡0⎤ 1 ⎡1⎤ 1 Ix α = ⎢ ⎥⎢ ⎥ = ⎢ ⎥ = β Ix β = ⎢ ⎥⎢ ⎥ = ⎢ ⎥ = α 2⎣1 0⎦⎣0⎦ 2⎣1⎦ 2 2⎣1 0⎦⎣1⎦ 2⎣0⎦ 2 ⎡1⎤ ⎡0⎤ α α = [1 0]⎢ ⎥ -
Two-State Systems
1 TWO-STATE SYSTEMS Introduction. Relative to some/any discretely indexed orthonormal basis |n) | ∂ | the abstract Schr¨odinger equation H ψ)=i ∂t ψ) can be represented | | | ∂ | (m H n)(n ψ)=i ∂t(m ψ) n ∂ which can be notated Hmnψn = i ∂tψm n H | ∂ | or again ψ = i ∂t ψ We found it to be the fundamental commutation relation [x, p]=i I which forced the matrices/vectors thus encountered to be ∞-dimensional. If we are willing • to live without continuous spectra (therefore without x) • to live without analogs/implications of the fundamental commutator then it becomes possible to contemplate “toy quantum theories” in which all matrices/vectors are finite-dimensional. One loses some physics, it need hardly be said, but surprisingly much of genuine physical interest does survive. And one gains the advantage of sharpened analytical power: “finite-dimensional quantum mechanics” provides a methodological laboratory in which, not infrequently, the essentials of complicated computational procedures can be exposed with closed-form transparency. Finally, the toy theory serves to identify some unanticipated formal links—permitting ideas to flow back and forth— between quantum mechanics and other branches of physics. Here we will carry the technique to the limit: we will look to “2-dimensional quantum mechanics.” The theory preserves the linearity that dominates the full-blown theory, and is of the least-possible size in which it is possible for the effects of non-commutivity to become manifest. 2 Quantum theory of 2-state systems We have seen that quantum mechanics can be portrayed as a theory in which • states are represented by self-adjoint linear operators ρ ; • motion is generated by self-adjoint linear operators H; • measurement devices are represented by self-adjoint linear operators A. -
(Ab Initio) Pathintegral Molecular Dynamics
(Ab initio) path-integral Molecular Dynamics The double slit experiment Sum over paths: Suppose only two paths: interference The double slit experiment ● Introduce of a large number of intermediate gratings, each containing many slits. ● Electrons may pass through any sequence of slits before reaching the detector ● Take the limit in which infinitely many gratings → empty space Do nuclei really behave classically ? Do nuclei really behave classically ? Do nuclei really behave classically ? Do nuclei really behave classically ? Example: proton transfer in malonaldehyde only one quantum proton Tuckerman and Marx, Phys. Rev. Lett. (2001) Example: proton transfer in water + + Classical H5O2 Quantum H5O2 Marx et al. Nature (1997) Proton inWater-Hydroxyl (Ice) Overlayers on Metal Surfaces T = 160 K Li et al., Phys. Rev. Lett. (2010) Proton inWater-Hydroxyl (Ice) Overlayers on Metal Surfaces Li et al., Phys. Rev. Lett. (2010) The density matrix: definition Ensemble of states: Ensemble average: Let©s define: ρ is hermitian: real eigenvalues The density matrix: time evolution and equilibrium At equilibrium: ρ can be expressed as pure function of H and diagonalized simultaneously with H The density matrix: canonical ensemble Canonical ensemble: Canonical density matrix: Path integral formulation One particle one dimension: K and Φ do not commute, thus, Trotter decomposition: Canonical density matrix: Path integral formulation Evaluation of: Canonical density matrix: Path integral formulation Matrix elements of in space coordinates: acts on the eigenstates from the left: Canonical density matrix: Path integral formulation Where it was used: It can be Monte Carlo sampled, but for MD we need momenta! Path integral isomorphism Introducing a chain frequency and an effective potential: Path integral molecular dynamics Fictitious momenta: introducing a set of P Gaussian integrals : convenient parameter Gaussian integrals known: (adjust prefactor ) Does it work? i. -
Structure of a Spin ½ B
Structure of a spin ½ B. C. Sanctuary Department of Chemistry, McGill University Montreal Quebec H3H 1N3 Canada Abstract. The non-hermitian states that lead to separation of the four Bell states are examined. In the absence of interactions, a new quantum state of spin magnitude 1/√2 is predicted. Properties of these states show that an isolated spin is a resonance state with zero net angular momentum, consistent with a point particle, and each resonance corresponds to a degenerate but well defined structure. By averaging and de-coherence these structures are shown to form ensembles which are consistent with the usual quantum description of a spin. Keywords: Bell states, Bell’s Inequalities, spin theory, quantum theory, statistical interpretation, entanglement, non-hermitian states. PACS: Quantum statistical mechanics, 05.30. Quantum Mechanics, 03.65. Entanglement and quantum non-locality, 03.65.Ud 1. INTRODUCTION In spite of its tremendous success in describing the properties of microscopic systems, the debate over whether quantum mechanics is the most fundamental theory has been going on since its inception1. The basic property of quantum mechanics that belies it as the most fundamental theory is its statistical nature2. The history is well known: EPR3 showed that two non-commuting operators are simultaneously elements of physical reality, thereby concluding that quantum mechanics is incomplete, albeit they assumed locality. Bohr4 replied with complementarity, arguing for completeness; thirty years later Bell5, questioned the locality assumption6, and the conclusion drawn that any deeper theory than quantum mechanics must be non-local. In subsequent years the idea that entangled states can persist to space-like separations became well accepted7. -
Chapter 2 Outline of Density Matrix Theory
Chapter 2 Outline of density matrix theory 2.1 The concept of a density matrix Aphysical exp eriment on a molecule usually consists in observing in a macroscopic 1 ensemble a quantity that dep ends on the particle's degrees of freedom (like the measure of a sp ectrum, that derives for example from the absorption of photons due to vibrational transitions). When the interactions of each molecule with any 2 other physical system are comparatively small , it can b e describ ed by a state vector j (t)i whose time evolution follows the time{dep endent Schrodinger equation i _ ^ j (t)i = iH j (t)i; (2.1) i i ^ where H is the system Hamiltonian, dep ending only on the degrees of freedom of the molecule itself. Even if negligible in rst approximation, the interactions with the environment usually bring the particles to a distribution of states where many of them b ehave in a similar way b ecause of the p erio dic or uniform prop erties of the reservoir (that can just consist of the other molecules of the gas). For numerical purp oses, this can 1 There are interesting exceptions to this, the \single molecule sp ectroscopies" [44,45]. 2 Of course with the exception of the electromagnetic or any other eld probing the system! 10 Outline of density matrix theory b e describ ed as a discrete distribution. The interaction b eing small compared to the internal dynamics of the system, the macroscopic e ect will just be the incoherent sum of the observables computed for every single group of similar particles times its 3 weight : 1 X ^ ^ < A>(t)= h (t)jAj (t)i (2.2) i i i i=0 If we skip the time dep endence, we can think of (2.2) as a thermal distribution, in this case the would b e the Boltzmann factors: i E i k T b e := (2.3) i Q where E is the energy of state i, and k and T are the Boltzmann constant and the i b temp erature of the reservoir, resp ectively . -
Pilot-Wave Theory, Bohmian Metaphysics, and the Foundations of Quantum Mechanics Lecture 6 Calculating Things with Quantum Trajectories
Pilot-wave theory, Bohmian metaphysics, and the foundations of quantum mechanics Lecture 6 Calculating things with quantum trajectories Mike Towler TCM Group, Cavendish Laboratory, University of Cambridge www.tcm.phy.cam.ac.uk/∼mdt26 and www.vallico.net/tti/tti.html [email protected] – Typeset by FoilTEX – 1 Acknowledgements The material in this lecture is to a large extent a summary of publications by Peter Holland, R.E. Wyatt, D.A. Deckert, R. Tumulka, D.J. Tannor, D. Bohm, B.J. Hiley, I.P. Christov and J.D. Watson. Other sources used and many other interesting papers are listed on the course web page: www.tcm.phy.cam.ac.uk/∼mdt26/pilot waves.html MDT – Typeset by FoilTEX – 2 On anticlimaxes.. Up to now we have enjoyed ourselves freewheeling through the highs and lows of fundamental quantum and relativistic physics whilst slagging off Bohr, Heisenberg, Pauli, Wheeler, Oppenheimer, Born, Feynman and other physics heroes (last week we even disagreed with Einstein - an attitude that since the dawn of the 20th century has been the ultimate sign of gibbering insanity). All tremendous fun. This week - we shall learn about finite differencing and least squares fitting..! Cough. “Dr. Towler, please. You’re not allowed to use the sprinkler system to keep the audience awake.” – Typeset by FoilTEX – 3 QM computations with trajectories Computing the wavefunction from trajectories: particle and wave pictures in quantum mechanics and their relation P. Holland (2004) “The notion that the concept of a continuous material orbit is incompatible with a full wave theory of microphysical systems was central to the genesis of wave mechanics. -
Violation of Bell Inequalities: Mapping the Conceptual Implications
International Journal of Quantum Foundations 7 (2021) 47-78 Original Paper Violation of Bell Inequalities: Mapping the Conceptual Implications Brian Drummond Edinburgh, Scotland. E-mail: [email protected] Received: 10 April 2021 / Accepted: 14 June 2021 / Published: 30 June 2021 Abstract: This short article concentrates on the conceptual aspects of the violation of Bell inequalities, and acts as a map to the 265 cited references. The article outlines (a) relevant characteristics of quantum mechanics, such as statistical balance and entanglement, (b) the thinking that led to the derivation of the original Bell inequality, and (c) the range of claimed implications, including realism, locality and others which attract less attention. The main conclusion is that violation of Bell inequalities appears to have some implications for the nature of physical reality, but that none of these are definite. The violations constrain possible prequantum (underlying) theories, but do not rule out the possibility that such theories might reconcile at least one understanding of locality and realism to quantum mechanical predictions. Violation might reflect, at least partly, failure to acknowledge the contextuality of quantum mechanics, or that data from different probability spaces have been inappropriately combined. Many claims that there are definite implications reflect one or more of (i) imprecise non-mathematical language, (ii) assumptions inappropriate in quantum mechanics, (iii) inadequate treatment of measurement statistics and (iv) underlying philosophical assumptions. Keywords: Bell inequalities; statistical balance; entanglement; realism; locality; prequantum theories; contextuality; probability space; conceptual; philosophical International Journal of Quantum Foundations 7 (2021) 48 1. Introduction and Overview (Area Mapped and Mapping Methods) Concepts are an important part of physics [1, § 2][2][3, § 1.2][4, § 1][5, p. -
Quantum Retrodiction: Foundations and Controversies
S S symmetry Article Quantum Retrodiction: Foundations and Controversies Stephen M. Barnett 1,* , John Jeffers 2 and David T. Pegg 3 1 School of Physics and Astronomy, University of Glasgow, Glasgow G12 8QQ, UK 2 Department of Physics, University of Strathclyde, Glasgow G4 0NG, UK; [email protected] 3 Centre for Quantum Dynamics, School of Science, Griffith University, Nathan 4111, Australia; d.pegg@griffith.edu.au * Correspondence: [email protected] Abstract: Prediction is the making of statements, usually probabilistic, about future events based on current information. Retrodiction is the making of statements about past events based on cur- rent information. We present the foundations of quantum retrodiction and highlight its intimate connection with the Bayesian interpretation of probability. The close link with Bayesian methods enables us to explore controversies and misunderstandings about retrodiction that have appeared in the literature. To be clear, quantum retrodiction is universally applicable and draws its validity directly from conventional predictive quantum theory coupled with Bayes’ theorem. Keywords: quantum foundations; bayesian inference; time reversal 1. Introduction Quantum theory is usually presented as a predictive theory, with statements made concerning the probabilities for measurement outcomes based upon earlier preparation events. In retrodictive quantum theory this order is reversed and we seek to use the Citation: Barnett, S.M.; Jeffers, J.; outcome of a measurement to make probabilistic statements concerning earlier events [1–6]. Pegg, D.T. Quantum Retrodiction: The theory was first presented within the context of time-reversal symmetry [1–3] but, more Foundations and Controversies. recently, has been developed into a practical tool for analysing experiments in quantum Symmetry 2021, 13, 586. -
Towards a Categorical Account of Conditional Probability
Towards a Categorical Account of Conditional Probability Robert Furber and Bart Jacobs Institute for Computing and Information Sciences (iCIS), Radboud University Nijmegen, The Netherlands. Web addresses: www.cs.ru.nl/~rfurber and www.cs.ru.nl/~bart This paper presents a categorical account of conditional probability, covering both the classical and the quantum case. Classical conditional probabilities are expressed as a certain “triangle-fill-in” condition, connecting marginal and joint probabilities, in the Kleisli category of the distribution monad. The conditional probabilities are induced by a map together with a predicate (the condition). The latter is a predicate in the logic of effect modules on this Kleisli category. This same approach can be transferred to the category of C∗-algebras (with positive unital maps), whose predicate logic is also expressed in terms of effect modules. Conditional probabilities can again be expressed via a triangle-fill-in property. In the literature, there are several proposals for what quantum conditional probability should be, and also there are extra difficulties not present in the classical case. At this stage, we only describe quantum systems with classical parametrization. 1 Introduction In the categorical description of probability theory, several monads play an important role. The main ones are the discrete probability monad D on the category Sets of sets and functions, and the Giry monad G , for continuous probability, on the category Meas of measurable spaces and measurable functions. The Kleisli categories of these monads have suitable probabilistic matrices as morphisms, which capture probabilistic transition systems (and Markov chains). Additionally, more recent monads of interest are the expectation monad [8] and the Radon monad [5]. -
The Minimal Modal Interpretation of Quantum Theory
The Minimal Modal Interpretation of Quantum Theory Jacob A. Barandes1, ∗ and David Kagan2, y 1Jefferson Physical Laboratory, Harvard University, Cambridge, MA 02138 2Department of Physics, University of Massachusetts Dartmouth, North Dartmouth, MA 02747 (Dated: May 5, 2017) We introduce a realist, unextravagant interpretation of quantum theory that builds on the existing physical structure of the theory and allows experiments to have definite outcomes but leaves the theory's basic dynamical content essentially intact. Much as classical systems have specific states that evolve along definite trajectories through configuration spaces, the traditional formulation of quantum theory permits assuming that closed quantum systems have specific states that evolve unitarily along definite trajectories through Hilbert spaces, and our interpretation extends this intuitive picture of states and Hilbert-space trajectories to the more realistic case of open quantum systems despite the generic development of entanglement. We provide independent justification for the partial-trace operation for density matrices, reformulate wave-function collapse in terms of an underlying interpolating dynamics, derive the Born rule from deeper principles, resolve several open questions regarding ontological stability and dynamics, address a number of familiar no-go theorems, and argue that our interpretation is ultimately compatible with Lorentz invariance. Along the way, we also investigate a number of unexplored features of quantum theory, including an interesting geometrical structure|which we call subsystem space|that we believe merits further study. We conclude with a summary, a list of criteria for future work on quantum foundations, and further research directions. We include an appendix that briefly reviews the traditional Copenhagen interpretation and the measurement problem of quantum theory, as well as the instrumentalist approach and a collection of foundational theorems not otherwise discussed in the main text.