90 This article is available in PDF-format, in colour, at: http://www.wydawnictwa.ipo.waw.pl/materialy-wysokoenergetyczne/materialy-wysokoenergetyczne12_1/HEM_0114_E.pdf Materiały Wysokoenergetyczne / High Energy Materials, 2020, 12 (1), 90 − 110; DOI 10.22211/matwys/0114E ISSN 2083-0165 Copyright © 2020 Łukasiewicz Research Network - Institute of Industrial Organic Chemistry, Poland Article is available under the Creative Commons Attribution-Noncommercial-NoDerivs 3.0 license CC BY-NC-ND 3.0. Review / Przegląd First published in Polish in 2015. New energetic materials derived from common explosives. Review 2,4,6-Trinitrotoluen jako źródło nowoczesnych materiałów wybuchowych. Przegląd Mateusz Szala*,1), Tomasz Sałaciński2) 1) Military University of Technology, Faculty of Advanced Technologies and Chemistry, Laboratory of Explosives, 2 gen. S. Kaliskiego Street, 00-908 Warsaw, Poland 2) Institute of Industrial Organic Chemistry**, 6 Annopol Street, 03-236 Warsaw, Poland * E-mail:
[email protected] ** now called: Łukasiewicz Research Network – Institute of Industrial Organic Chemistry Abstract: The review discusses the products of 2,4,6-trinitrotoluene reactions which have explosive properties or are potentially high-energy compounds. The following compounds are discussed: trinitrobenzene, cyanotrinitrobenzene, trinitroxylene, aminotrinitrotoluenes, trinitronitromethylbenzene, methylene bis(2,4,6-trinitrobenzene), hexanitrostilbene, nitromethyldiphenylamines, 4,4’,6,6’-tetranitro- 2,2’-azoxytoluene and 2,4,6-trinitrobenzylideneamine