Download the Scanned
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Uraninite Alteration in an Oxidizing Environment and Its Relevance to the Disposal of Spent Nuclear Fuel
TECHNICAL REPORT 91-15 Uraninite alteration in an oxidizing environment and its relevance to the disposal of spent nuclear fuel Robert Finch, Rodney Ewing Department of Geology, University of New Mexico December 1990 SVENSK KÄRNBRÄNSLEHANTERING AB SWEDISH NUCLEAR FUEL AND WASTE MANAGEMENT CO BOX 5864 S-102 48 STOCKHOLM TEL 08-665 28 00 TELEX 13108 SKB S TELEFAX 08-661 57 19 original contains color illustrations URANINITE ALTERATION IN AN OXIDIZING ENVIRONMENT AND ITS RELEVANCE TO THE DISPOSAL OF SPENT NUCLEAR FUEL Robert Finch, Rodney Ewing Department of Geology, University of New Mexico December 1990 This report concerns a study which was conducted for SKB. The conclusions and viewpoints presented in the report are those of the author (s) and do not necessarily coincide with those of the client. Information on SKB technical reports from 1977-1978 (TR 121), 1979 (TR 79-28), 1980 (TR 80-26), 1981 (TR 81-17), 1982 (TR 82-28), 1983 (TR 83-77), 1984 (TR 85-01), 1985 (TR 85-20), 1986 (TR 86-31), 1987 (TR 87-33), 1988 (TR 88-32) and 1989 (TR 89-40) is available through SKB. URANINITE ALTERATION IN AN OXIDIZING ENVIRONMENT AND ITS RELEVANCE TO THE DISPOSAL OF SPENT NUCLEAR FUEL Robert Finch Rodney Ewing Department of Geology University of New Mexico Submitted to Svensk Kämbränslehantering AB (SKB) December 21,1990 ABSTRACT Uraninite is a natural analogue for spent nuclear fuel because of similarities in structure (both are fluorite structure types) and chemistry (both are nominally UOJ. Effective assessment of the long-term behavior of spent fuel in a geologic repository requires a knowledge of the corrosion products produced in that environment. -
Iidentilica2tion and Occurrence of Uranium and Vanadium Identification and Occurrence of Uranium and Vanadium Minerals from the Colorado Plateaus
IIdentilica2tion and occurrence of uranium and Vanadium Identification and Occurrence of Uranium and Vanadium Minerals From the Colorado Plateaus c By A. D. WEEKS and M. E. THOMPSON A CONTRIBUTION TO THE GEOLOGY OF URANIUM GEOLOGICAL S U R V E Y BULL E TIN 1009-B For jeld geologists and others having few laboratory facilities.- This report concerns work done on behalf of the U. S. Atomic Energy Commission and is published with the permission of the Commission. UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1954 UNITED STATES DEPARTMENT OF THE- INTERIOR FRED A. SEATON, Secretary GEOLOGICAL SURVEY Thomas B. Nolan. Director Reprint, 1957 For sale by the Superintendent of Documents, U. S. Government Printing Ofice Washington 25, D. C. - Price 25 cents (paper cover) CONTENTS Page 13 13 13 14 14 14 15 15 15 15 16 16 17 17 17 18 18 19 20 21 21 22 23 24 25 25 26 27 28 29 29 30 30 31 32 33 33 34 35 36 37 38 39 , 40 41 42 42 1v CONTENTS Page 46 47 48 49 50 50 51 52 53 54 54 55 56 56 57 58 58 59 62 TABLES TABLE1. Optical properties of uranium minerals ______________________ 44 2. List of mine and mining district names showing county and State________________________________________---------- 60 IDENTIFICATION AND OCCURRENCE OF URANIUM AND VANADIUM MINERALS FROM THE COLORADO PLATEAUS By A. D. WEEKSand M. E. THOMPSON ABSTRACT This report, designed to make available to field geologists and others informa- tion obtained in recent investigations by the Geological Survey on identification and occurrence of uranium minerals of the Colorado Plateaus, contains descrip- tions of the physical properties, X-ray data, and in some instances results of chem- ical and spectrographic analysis of 48 uranium arid vanadium minerals. -
Thn Auertcan M Rlueralocrsr
THn AUERTcANM rluERALocrsr JOURNAL OF TIIE MINDRALOGICAL SOCIETY OF ANIERICA vbl.41 JULY-AUGUST, 1956 Nos. 7 and 8 MTNERAL COMPOSTTTON OF G'UMMTTE*f Crrllonl FnoNonr, H artard Llniaersity,Cambrid,ge, M ass., and. U. S. GeologicalSurwy, Washington, D.C. ABSTRACT The name gummite has been wideiy used for more than 100 years as a generic term to designate fine-grained yellow to orange-red alteration products of uraninite whose true identity is unknown. A study of about 100 specimens of gummite from world-wide localities has been made by r-ray, optical, and chemical methods. rt proved possible to identify almost all of the specimens with already known uranium minerals. Gummite typicalty occurs as an alteration product of uraninite crystals in pegmatite. Such specimensshow a characteristic sequenceof alteration products: (1) A central core of black or brownish-black uraninite. (2) A surrounding zone, yellow to orange-red, composed chiefly of hydrated lead uranyl oxides. This zone constitutes the traditional gummite. It is principally composed of fourmarierite, vandendriesscheite and two unidentified phases (Mineral -4 and Mineral c). Less common constituents are clarkeite, becquerelite, curite, and schoepite. (3) An outer silicate zone. This usually is dense with a greenish-yellow color and is composed of uranophane or beta-uranophane; it is sometimes soft and earthy with a straw-yellow to pale-brown color and is then usually composed of kasolite or an unidenti- fied phase (Minerat B). Soddyite and sklodowskite occur rarely. There are minor variations in the above general sequence. rt some specimens the core may be orange-red gummite without residual uraninite or the original uraninite crystal may be wholly converted to silicates. -
New Mineral Names*
American Mineralogist, Volume 68, pages 1248-1252,1983 NEW MINERAL NAMES* Perr J. DUNN, MrcHeE'r-FLerscHen, Gr,oncB Y. CHno, Lours J. Cesnr, AND JosEpHA. MexoanrNo Biivoetite* Lcpersonnite* bright yellow and is transparent and translucent. No fluores- Unnamed CeNi-Mg uranyl silicate cence was observed under short- or long-wave UV. The mea- sureddensity is 3.97g/cmr. It is opticallybiaxial negative,2V = M. Deliensand P. Piret (1982)Bijvoetite et lepersonnite,carbon- 73" calc.,a = 1.638, : 1.666,y : 1.682;pleochroic with X pale ates hydratds d'uranyle et des terres rares de Shinkolobwe, B yellow, bright yellow and Z bnght yellow; orientation, only Zaire. Can. Mineral.. 20.231J38. I=cisgiven. = Bijvoetite The mineral is orthorhombic, Pnnm or Pnn2 with a 16.23(3), b = 38.7aQ),c : rr.73Q)4, Z : 2, (V : 7375(50)43,J.A.M.). Blivoetite and lepersonniteoccur with hydrated uranium ox- The density calculated from the unit cell parameters and the ides near primary uraninite in the lower part of the oxidation empirical formula is 4.01 g/cm3. Strongest lines in the X-ray zone at Shinkolobwe, Zaire. Bijvoetite is rare and is known only powder diffraction pattern (for CuKa) are: 8.15(100X200), from a single specimen. Associated minerals are: lepersonnite, 4.06(I 5X400),3.65(70X1 33), 3.2I (50X0.I 2.0) and 2.86(40)(283). sklodowskite, curite, uranophane, becquerelite, rutherfordine, An electronmicroprobe analysis gave: SiO22.79, UOj76.14, studtite and a CeMg-Ni uranyl silicate structurally related to Gd2O32.W,Dy2O3 1.07, Y2O3 0.41, Tb2O3 0.(D, CaO 0.45,CO2 uranophane. -
Kasolite Pb(UO2)Sio4 ² H2O C 2001 Mineral Data Publishing, Version 1.2 ° Crystal Data: Monoclinic
Kasolite Pb(UO2)SiO4 ² H2O c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Monoclinic. Point Group: 2=m: Crystals stout prismatic, °attened on 001 and lathlike by extension along [010], to several mm. As groups of divergent crystals, rosettefs, angd radial ¯brous aggregates; in dense gumlike crusts and compact, colloform masses. Physical Properties: Cleavage: Perfect on 001 , indistinct on 100 and 010 . Tenacity: Brittle. Hardness = 4{5 D(meas.) =f 5.8g3{6.5 D(calc.) f= 6.g256 Rfadiogactive. Optical Properties: Transparent to translucent, opaque. Color: Ocher-yellow to brownish yellow; amber-brown when transparent; rarely lemon-yellow to green or reddish orange. Streak: Pale yellow-brown. Luster: Subadamantine to greasy, dull to earthy when massive. Optical Class: Biaxial (+). Pleochroism: Weak, rarely; X = Y = very pale yellow; Z = colorless to slightly grayish. Orientation: X = b; Z c. ® = 1.877{1.900 ¯ = 1.880{1.910 ' ° = 1.935{1.970 2V(meas.) = 43± Cell Data: Space Group: P 21=a: a = 13.24 b = 6.94 c = 6.70 ¯ = 104±200 Z = 4 X-ray Powder Pattern: Kasolo, Congo. 3.26 (10), 2.93 (9), 4.19 (8b), 3.53 (7), 6.61 (6), 3.07 (5), 1.962 (5) Chemistry: (1) (2) SiO2 9.42 10.23 UO3 49.28 48.70 Fe2O3 0.41 PbO 36.2 38.00 MgO 0.03 CaO 0.06 H2O 3.59 3.07 CO2 0.85 Total 99.84 100.00 (1) Kasolo, Congo. (2) Pb(UO2)SiO4 ² H2O: Occurrence: An oxidization product of uraninite. Association: Uraninite, torbernite, curite, dewindtite (Kasolo, Congo); rutherfordine, sklodowskite, curite (Nabarlek, Australia). -
2•4H2o, a New Basic Uranyl Carbonate Mineral
1685 The Canadian Mineralogist Vol. 39, pp. 1685-1689 (2001) OSWALDPEETERSITE, (UO2)2CO3(OH)2•4H2O, A NEW BASIC URANYL CARBONATE MINERAL FROM THE JOMAC URANIUM MINE, SAN JUAN COUNTY, UTAH, U.S.A. RENAUD VOCHTEN§ Department of Subatomic and Radiation Physics, Division of Nuclear Material Physics, Universiteit Gent, Proeftuinstraat 86, B-9000 Gent, Belgium MICHEL DELIENS Institut royal des Sciences naturelles de Belgique, Section de Minéralogie et de Pétrographie, Rue Vautier 29, B-1000 Bruxelles, Belgium OLAF MEDENBACH Institut für Mineralogie, Ruhr-Universität Bochum, Universitätsstrasse 150, D-44780 Bochum, Germany ABSTRACT Oswaldpeetersite, ideally (UO2)2CO3(OH)2•4H2O, is a newly discovered hydrated basic uranyl carbonate mineral found in the Jomac uranium mine, Brown’s Rim, San Juan County, Utah, U.S.A. It occurs along some bedding planes of a layer of siltstone within the Triassic Shinarump conglomerate. Associated minerals are gypsum, cuprite, antlerite, goethite, lepidocrocite, mbobomkulite, hydrombobomkulite, sklodowskite and two undefined uranium minerals. Oswaldpeetersite occurs as micrometric prismatic crystals (approximately 0.1 0.01 0.002 mm). These are canary yellow and transparent, with a vitreous luster and 3 pale yellow streak. It does not fluoresce in ultraviolet radiation. The HMohs is in the range 2–3. Dmeas > 4.10 g/cm , Dcalc = 4.54 g/ 3 3 cm (empirical formula), 4.50 g/cm (idealized formula). Optically biaxial negative, ␣ 1.583(2),  1.669(2), ␥ 1.712(2), and 2Vcalc = 67.4(2)°. Orientation Z || a and elongation positive. The pleochroism is X and Y very pale yellow to colorless, and Z pale yellow. The cleavage and parting are along the elongation. -
Mineralogy, Crystallography and Structural Complexity of Natural Uranyl Silicates
minerals Review Mineralogy, Crystallography and Structural Complexity of Natural Uranyl Silicates Jakub Plášil Institute of Physics ASCR, v.v.i., Na Slovance 1999/2, 18221 Prague 8, Czech Republic; [email protected]; Tel.: +420-775-21-27-57 Received: 10 October 2018; Accepted: 19 November 2018; Published: 27 November 2018 Abstract: Naturally occurring uranyl silicates are common constituents of the oxidized parts (i.e., supergene zone) of various types of uranium deposits. Their abundance reflects the widespread distribution of Si4+ in the Earth’s crust and, therefore, in groundwaters. Up to date, 16 uranyl silicate minerals are known. Noteworthy is that the natural uranyl silicates are not extremely diverse regarding their crystal structures; it is a result of possible concentrations (activity) of Si4+ in aqueous solutions derived from dissolution of primary Si minerals or the composition of late hydrothermal fluids. Therefore, in natural systems, we distinguish in fact among two groups of uranyl silicate minerals: uranophane and weeksite-group. They differ in U:Si ratio (uranophane, 1:1; weeksite, 2:5) and they form under different conditions, reflected in distinctive mineral associations. An overview of crystal-chemistry is provided in this paper, along with the new structure data for few members of the uranophane group. Calculations of the structural complexity parameters for natural uranyl silicates are commented about as well as other groups of uranyl minerals; these calculations are also presented from the point of view of the mineral paragenesis and associations. Keywords: uranyl silicate; crystal structure; structural hierarchy; chemical composition; complexity measures; evolution 1. Introduction Uranyl silicates minerals are typical representatives of the oxidized parts of uranium deposits worldwide [1–5], forming during oxidizing weathering of uraninite, ideally UO2, or coffinite, ideally 4+ U(SiO4). -
Identification and Occurrence of Uranium and Vanadium Minerals from the Colorado Plateaus
Identification and Occurrence of Uranium and Vanadium Minerals From the Colorado Plateaus GEOLOGICAL SURVEY BULLETIN 1009-B IDENTIFICATION AND OCCURRENCE OF URANIUM AND VANADIUM MINERALS FROM THE COLORADO PLATEAUS By A. D. WEEKS and M. E. THOMPSON ABSTRACT This report, designed to make available to field geologists and others informa tion obtained in recent investigations by the Geological Survey on identification and occurrence of uranium minerals of the Colorado Plateaus, contains descrip tions of the physical properties, X-ray data, and in some instances results of chem ical and spectrographic analysis of 48 uranium and vanadium minerals. Also included is a list of locations of mines from which the minerals have been identified. INTRODUCTION AND ACKNOWLEDGMENTS The 48 uranium and vanadium minerals described in this report are those studied by the writers and their colleagues during recent mineralogic investigation of uranium ores from the Colorado Plateaus. This work is part of a program undertaken by the Geological Survey on behalf of the Division of Raw Materials of the U. S. Atomic Energy Commission. Thanks are due many members of the Geological Survey who have worked on one or more phases of the study, including chemical, spec trographic, and X-ray examination,' as well as collecting of samples. The names of these Survey members are given in the text where the contribution of each is noted. The writers are grateful to George Switzer of the U. S. National Museum and to Clifford Frondel of Harvard University who kindly lent type mineral specimens and dis cussed various problems. PURPOSE The purpose of this report is to make available to field geologists and others who do not have extensive laboratory facilities, information obtained in recent investigations by the Geological Survey on the identification and occurrence of the uranium and vanadium minerals of ores from the plateaus. -
Rx-Sktodowskrte
STUDIESOF RADIOACTIVECOMPOUNDS: rx-sKtoDowsKrTE D. H. CORMAN Unfuersity of Toronto, Toronto, Canad,a AsstRAcr New r-ray data are presented for the uranium silicate, sklodowskite. The mineral is monoclinic, C2/m; a-: L7.2.84,D : 7.03, c - 6.56; F - 106o63'. Isomorphism vith uranophane is discussed,Conditions for the forrnation of this rare mineral are reviewed, Of the several speciesof uranium silicate minerals, sklodowskite has the most limited geographicaldistribution, the only recorded occurrence being that at Shinkolobwe, Katanga, Belgian Congo. It was first des- cribed by Schoep (1924a).The analogy with uranophanewas recognized by Schoep (Ig24b) who subsequently (L927) described its. isomorphism with this mineral. Billiet (1936) obtained an rc-raypowder pattern, and establishedcell dimensionsand a symmetry based upon rotation photo- graphs. As was the casewith his work on uranophane,erroneous results were obtained owing to the non-amenability of the crystals to the r-ray technique employed. In 1923 Schoep published two brief notes describing a new mineral speciesfrom the Shinkolobwe deposits, which he called chinkolobwite. However, in 1926 he wrote on tie identity of chinkolobwite and the specieswhich he had previously named sklodowskite. It was pointed out to Schoep by Buttgenbach that the narne sklodor+'skitewa6 the more appropriate for the speciesowing to the fact that the mineral does not actually occur at the village of Shinkolobwe, but at Kasolo Hill, and that the honor paid to Maria Sklodowska (later Madame Curie) should be perpetuated. Physical, Prpperties Sklodowskite occurs as minute acicular crystals in tightly compacted parallel aggregates, often reticulate, radiating divergent or stellate. Exceedingly small crystals form velvety coatings on host rock. -
~Ew Mineral Names*
American Mineralogist, Volume 68, pages 1248-1252, 1983 ~EW MINERAL NAMES* PETE J. DUNN, MICHAEL FLEISCHER, GEORGE Y. CHAO, LOUIS J. CABRI, AND JOSEPH A. MANDARINO Bijvoetite* Lepersonnite* bright yellow and is transparent and translucent. No fluores- Unnamed Co-Ni-Mg uranyl silicate cence was observed under short- or long-wave VV. The mea- sured density is 3.97 g/cm3. It is optically biaxial negative, 2V M. Deliens and P. Piret (1982) Bijvoetite et lepersonnite, carbon- = 1.638, (3 1.666, 1.682; pleochroic with X pale ates hydrates d'uranyle et des terres rares de Shinkolobwe, 73° calc., a = = 'Y= yellow, Y bright yellow and Z bright yellow; orientation, only Zaire. Can. Mineral., 20, 231-238. Y = c is given. The mineral is orthorhombic, Pnnm or Pnn2 with a 16.23(3), Bijvoetite = b = 38.74(9), c = 11.73(3)A, Z = 2, (V = 7375(50)A3, J .A.M.). Bijvoetite and lepersonnite occur with hydrated uranium ox- The density calculated from the unit cell parameters and the ides near primary uraninite in the lower part of the oxidation empirical formula is 4.01 g/cm3. Strongest lines in the X-ray zone at Shinkolobwe, Zaire. Bijvoetite is rare and is known only powder diffraction pattern (for CuKa) are: 8.15(100)(200), from a single specimen. Associated minerals are: lepersonnite, 4.06(15)(400), 3.65(70)(133), 3.21(50)(0.12.0) and 2.86(40)(283). sklodowskite, curite, uranophane, becquerelite, rutherfordine, An electron microprobe analysis gave: Si02 2.79, V03 76.14, studtite and a Co-Mg-Ni uranyl silicate structurally related to Gd203 2.09, DY203 1.07, Y203 0.41, Tb203 0.09, CaO 0.45, C02 uranophane. -
Vandenbrandeite Cu(UO2)(OH)4 C 2001-2005 Mineral Data Publishing, Version 1
Vandenbrandeite Cu(UO2)(OH)4 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Triclinic. Point Group: 1. Crystals, flattened on {001}, may be lathlike, rounded, to 0.5 cm; in parallel aggregates, lamellar, scaly; massive. Physical Properties: Cleavage: {110}, perfect; two others, in the [001] zone, indistinct. Hardness = 4 D(meas.) = 4.91–5.03 D(calc.) = [5.14] Radioactive. Optical Properties: Translucent, transparent in thin fragments. Color: Dark green to nearly black; green in transmitted light. Streak: Green. Luster: Vitreous. Optical Class: Biaxial, (+) or (–). Pleochroism: Yellow-green to blue-green. Orientation: Z ∧ elongation ' 40◦. Dispersion: Strong. α = 1.76–1.77 β = 1.78–1.79 γ = 1.78–1.82 2V(meas.) = ∼90◦ Cell Data: Space Group: P 1 (probable). a = 7.855(5) b = 5.449(4) c = 6.089(4) α =91.44(5)◦ β = 101.90(5)◦ γ =89.2(5)◦ Z=2 X-ray Powder Pattern: Kalongwe, Congo. 4.29 (10), 2.92 (8), 5.06 (4), 2.56 (4), 2.09 (3), 1.85 (3), 1.47 (3) Chemistry: (1) (2) UO3 71.23 71.22 CuO 19.20 19.81 H2O 9.57 8.97 Total [100.00] 100.00 (1) Shinkolobwe, Congo; recalculated to 100% after deduction of SiO2 0.28%, MgO 0.57%, CaO 0.26% as impurities. (2) Cu(UO2)(OH)4. Occurrence: A rare secondary mineral in the oxide zone of hydrothermal copper-bearing uranium deposits. Association: Cuprosklodowskite, kasolite, sklodowskite, malachite, chalcocite, chalcopyrite, uraninite, goethite (Kalongwe, Congo); curite, uranophane, sharpite (Shinkolobwe, Congo). Distribution: In Congo (Zaire), in Katanga (Shaba) Province, from the Luiswishi mine; at Kalongwe; from Shinkolobwe; at Kambove; from Swambo; and in the Musonoi mine, near Kolwezi.