Download the Scanned

Total Page:16

File Type:pdf, Size:1020Kb

Download the Scanned JOURNAL MINERALOGICAL SOCIETY OF AMERICA 131 NEW MINERALS: NEW SPECIBS CLASS: PHOSPHATES.ETC. Sincosite. War,nnuen T. Scuerr,un; The Occurrenceand Propertiesof Sincosite,a new VanadiumMineral from Peru. Am. Jott. 9ci.,8,462, (1924).(Preliminary note in f our. Wash.Aca.d.. Sc'i.,12, (8), 195,1922. Cf. Am. Min.,7, 163,1922.) New: From the locality, Sincos,Pent. Csnurcar- Pnoprnrrrs. A hydrous vanadyl, lime phosphate, VzOr. CaO. P2O6.5H2O. Analysis: V2O436.3, VrO6 0 0, CaO12.1, P zOr31.7, HzO 19.9,insol., 0.3; sum 100.3. Solublein dilute acidsgiving a blue solution. Cnvsu.lr,ocnepRrc Propnnrrns. Tetragonal, basal plates bounded by the prismc (100).Basalplanestriatedparalleltotheedges. Twinningplane m(ll0). Psvsrcer, ANDOprrcAr, Pnopenrrcs: Color leek green. Uniaxial, but some crystalsare biaxial with 2E varying. Negative. e:1.655, o:1.680. Dispersion strong p)2. Pleochroismstrong, €:nearly colorlessto pale yellow, o:gray green. Plates changefrom uniaxial to biaxial with 2V as high as 83o. Dispersion increasesvrith 2E. a:1.675, 9:1.690,7:1.693. The biaxialphase is probablya lowerhydrate. Sp. Gr. 2.84. Cleavagebasal and o (100)good, rz (110)poor. Occunruwcr: Found in a black carbonaceousshale associatedwith black nodules of coaly material. Drscussrol.r: Believed by Schaller to be a member of the uranite group, to- getherwith torbernite and metatorbernite,which the sincositegreatly resembles. W. F, Fossle CLASS: PHOSPHATES.ETC, Dumontite. Ar,r'r-ao Scnotp: La Dumontite, nouveau Min6ral radioactif. (Dumontite, a new radioactivemineral). Compt.Renil., 179,693 (1924). Neur: In honor of Andr1 Dumont, Belgian geologist. Cururcar, Pnopnnrrrs: A hydrous phosphate of lead and uranium, 2PbO. 3UOe.PzOs.SHzO. Analysis: HzO 5.78,PgOr 8.65, UOa 56.49,PbO 27.19,TeOs 1.01;sum 99.12. Cnvstr.t tocnepurc PRo"ERrrEs: Probably orthorhombic,prismatic, flattened paralleltotheaaxis.Forms: (001), (010), (100), (013), (011). c:b:1.327 (approx.) Pnvsrcal erw Orrrc-Lr,Pnopnnrms: Color yellow. Streakyellow. Translucent. Biaxial with 2V large, positive. Plane of the optic axesparallel to the elongation. n greater than 1.78. Extinction parallel. Pleochroismstrong, Z:deep yellow, )f :pale yellow. Occur.r-eNcn: Found in pockets in torbernite from Chinkolobwe, Belgian Congo. W. F. F. 132 THE AMERICAN MI NERAINGIST CLASS: SILICATES Sklodowskite Ar.rrrno Scuonp: La Sklodowskite,nouveau Min6ral radioactif. (Sklodowskite, a new radioactive mineral). Compl.Renil., 179,413 (1924). Neue: fn honor of Mme. Curie-SftXod.owska. Cnrutcer- Pnopnnrms: A hydrous silicate of uranium and magnesium,MgO. 2UOr. 2SiOr. 7HzO. Analysis: HzO 13.41,SiO, 14.28,UOa 64.72,MgO 3.74, TeO31.08, NarO+K2O 1.79,NiO 0.20;sum 99.40. Analysison materialshown to be hornogeneousby microscopicexamination. Cnvsrerrocnepnrc PnopnnrrBs: Orthorhombic, prismatic, Psvsrcar,'eNnOprrcar, Pnopnnrrns: Color, palelemon yellow. Brilliant luster. Translucent. Streakyellow. Pleochroism,7:yellow, y:pale yellow, X:color- less. Biaxial, negative. Dispersion distinct. (Plane of the optic axesacross the prisms.)o:1.613, 0:1.635, t:1.657. Sp.Gr. 3.54. Occunnnwcr: Found in cracks in a siliceousbreccia carrying somefragments of kasolite. W. F. F. CLASS: SILICATES Kalithomsonite. Sauulr, G. Gonron: Minerals obtained in Greenlandon the SecondAcaderhy -Vaux Expedition, 1923. Proc. Acad. Nat. Sci. Phila., 76, 261 (1924). N,q,un: In allusion to its composition, a thomsonitewith a considerableper- centageof potash(Kaliam). Cnau.rcer,Pnorpnrrns: A hydrous silicate of soda,potash, lime and alumina, (Na,K)zO.CaO. 2AlzOs. ssior. sHrO. Analysis: SiOr38.09, AlzOs26.6l, FezOs tr'' MnO 0.79,CaO 5.72, MgO 0.87,NazO 3.62, KzO 5.65,HrO+ 12.00,HzO- 6.t10; sum 99.75. Cnvsmr,r,ocnepgrcPRopERTrrs: Orthorhombic. Pnvsrcar, nlm Oprrcer, Pnopnnnos: Color, pale vinaceouspink, Biaxial, positive.c:1.535, 0:I.537, z:1.545. X:b,Y:a,Z:e. Cleavage,b perfect, o lessso, c imperfect. Occunncncr: Found as a matted massof small prisms in a pocket in augite- syeniteat Narsarsuk,Greenland,associated with quartz, microcline,fluorite, epidi- dymite,elpidite, calcite, albite and aegyrite. Drscussrou: The high content of potash, equalling the soda molecularly, shouldgive this mineral a speciesrank. If the sodaand potashare not isomorphous theformula becomes KzO. NarO. 2CaO. 4AlrO3. 10SiOr.10HrO. W. F. F. IOURNAL MINERALOGICAL SOCIETY OF AMERICA 133 DOUBTFUL SFECIES CLASS:SULPIIIDES: DIVISION: R',: S:2:1(?) Violarite Wer,oruan LrxocnnN and Mvnox Davv: Nickel Ores from the Key West Mine, Nevada. Econ. GeoI., 19, 3O9 (1924). Na.un: From the Latin oi,olaris:violet, in allusion to its violet-gray color on the polished surface. Csrurcer PnopERrrES: A sulfide of nickel, suggested to be NirS, but no analysis is given. Pnvsrcar- Ptopnnrrns: Color violet gray. Brittle. Alters rapidly in air and tarnishes readily. OccunoNcn: Found with pyrite, chalcopyrite and pentlandite at the Key West Mine, Clark Co., Nevada, as a replacement of the pentlandite. The Sudbury polydymite is shown to be a mixture of pentlandite and violarite in about equal amounts. DtscussroN: The same mineral has been found in S. E. Alaska by Dr. A. F. Buddington (Econ. Geol., 19. 527, 1924). He gives the following additional data: Cleavage in three directions. H:4-4rA. Non-magnetic. This mineral is possibly a member of the pyrite group; the sulfide analogue of chloanthite or of the marcasite group analogous to rammelsbergite. Until accurate analyses of the pure material is given the mineral is doubtful. W. F. Fossec. I t'R.tt CLASS : PHOSPHATES, BTC. DIVISION : R"'F.t "' "' :H,O : 1:2 :6:X. Rauvite FnlNr L. Hrss: New and Known Minerals from the Utah-Colorado Carnotite Region. Bultr. U. S. Geol'.Surrey,75O,63, (1924). Neur: Fromthechemicalsymbolsof radium, Ro, uranitun, U, and vanadium, v. Cnnurcal Pnopnntrns: A hydrous calcium uranium vanadate, CaO. 2UOs. 6VzOo. 20HrO. Analysis: VOa 20.82, VzOr 2.05, VrO6 36.33, CaO 2.00, KzO tr., As:Ortr., FejO:2.39,H2O 13.38, Se tr., MgO 0.12,SOr 0.13,insol. 24.06, sum 101.28. Puvsrcer,AND OprrcAL Pnopnntres: Compactwith slickensidedsurface. Color purplish black. Streak light brown. n:I.88. Apparently metacolloidal. Occunnptcas: Found in cracksin sandstoneassociated with carnotite,hewettite, gypsum,hyalite and meta-torberniteat Temple Mt., San Rafael Swell, Utah. DrscussroN: While this material is apparently new its metacolloidal nature makes it impossibleto determine whether this is a single mineral or not. fts exact nature must be considered doubtful. w. F. F. 134 TIIE AMEKICAN MINERALOGIST CLASS:PHOSPHATES, ETC. DIVISION: R"':R""':H,O:3:2:8. Ferrisymplessite T. L. Werrnn and A. L. Pensoxs: The Arsenatesof Cobalt,Nickel and Iron Observedin the Silver-bearingVeins at Cobalt, Ontario. Contri,butionsto Canad.i,an Mineralogy,p. 16, 1924. Neuu: From its composition,aJerric arsenatewith the ratios of symplessdte. CsBurclr, Pnopnnrrrs: A hydrous arsenate of ferric iron, 3Fe2O3.2As2O6. 16 H,O. Analysis: As,Os38.79, CoO 16.86,NiO 5.73,CaO 7.46,MgO 1.05,FezOs 11.67,AI2OB 0.31, HrO 24.05,insol. 0.88, sum 100.80. (Analysis made on material containing much erythrite and annabergite). Pnvsrcnr.aNo Oprrcar Pnolrnrrrs: Color deepamber brown. Luster resinous. Fibrous. Under the'microscopeslightly pleochroic,strongly birefracting.n:1.650. Sp.Gr. 2.885. OccunnrNcn: Found associatedwith erythrite and annabergitein the upper workings of the Hudson Bay Mine, Colbalt, Ontario. DrscussroN: Suggestedto be the arsenateanalogue of kertschenitebut the min- eral needs further study. w. F. F. CLASS: PHOSPHATES, ETC. DIVISION: R":R""':CO2:HrO:6:2:l:X. Grodsolite M.J.Monozrwrcz: LaGrodnolite,PhosphatecolloidaldeCalcium. (Grodnolite, a colloidal phosphate of calcium). Bwll. Soc. Fr. Min,47, 46 (1924). Naur: From the locality at which it was found, Grodno, Poland. Cneurcel Pnorcnrrns: A carbonato-phosphate of calcium. Analysis: P2O6 32.65, COr 5.10, SiOr 3.13, FerO33.68, Al2Or 1.43,CaO 51.24,Hp 3.23. Pnvsrclr, Pnolnnrrns: Color Brown. fsotropic, n:1.605. Sp. Gr. 2.974. H: less than 4. OccrrnnnNcn: Found as 4odules in a sandy marl near Grodno, Poland. Drscussrom: This mineral differs in no essential respect from collophanite and is undoubtedly that mineral. The alumina and silica may be adsorbed but since microscopic examination showed inclusions of quartz, microcline, etc. they are more likely derived from soluble lilicates. fn the latter case the mineral is a normal collophanite. (See A. F. Rogers: Collophane, a much neglected rr,ineral, Am. J our. Sci., 3, 269, 1922.) w. F. F. CLASS: SILICATES Bardolite M. J. Monozrwcz: Sur la Bardolite, mineral chloritique pyrog6ne. (Bardolite, a pyrogene,chlorititic mineral.)BuIl. Soc.Fr. Mi,n.47, 49 (1924). Nnun: From the locality at which it was found, Barilo, poland. Cnrlrrcnt- Pnolnnrms: A hydrous silicate of iron, alumina, magnesiaand potash. Analysis: SiOz38.45, AIrOB 6.09, FerO317.00, FeO 4.74, CaO 0.59, MgO 9.68,KrO 4.65,Na,O 0.35,HrO 19.50,sum 99.78. Psysrc.n.r,AND OprrcAL Pnopnnrrss: Sp. Gr. 2.73. Birefringencestrong, pleo- chroismfeeble. JOURNAL MINERALOGICAL SOCIETY OF AMERICA I.'J Occunnnwcn: Occurs as radiated plates in a fresb diabase. Believed by Moroze- wicz to be a primary mineral. DrscussroN: This mineral falls within the range of the mineral stilpnomelane, being, however, somewhat higher in potash. It can then be appropriately grouped with stilpnomelane unless more detailed work on this group shows it to be distinct. (See Frank F. Grout and George A. Thiel: Notes on stilpnomelane, Am. Mi,n.g, 228,t924.) w. F. F. CLASS : SILICATES. SUB-CLASS : HYDROUS SIICATES. DIVISION: R":Si : H,O:2:1;1. Radio-active Chrysocolla E. Puxroou and E. Maxce. Radioactive Chrysocolla from the Benade Padru Mine. Ann. Chim. Appli,cata, A, 123 (1924). Nllra. Suggested to be new but no name given to it. Cnnurcer Pnoponnns: A hydrous silicate of copper, Cu2SiOn*HrO. Analysis: SiO, 20, CUO 72.1, HzO (loss at 100') 4.5, (loss at 200") 6.9, PbO 0.6, Fe2O3 0.3, cor 1.1, s 2.0.
Recommended publications
  • Mineral Processing
    Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19
    [Show full text]
  • Uraninite Alteration in an Oxidizing Environment and Its Relevance to the Disposal of Spent Nuclear Fuel
    TECHNICAL REPORT 91-15 Uraninite alteration in an oxidizing environment and its relevance to the disposal of spent nuclear fuel Robert Finch, Rodney Ewing Department of Geology, University of New Mexico December 1990 SVENSK KÄRNBRÄNSLEHANTERING AB SWEDISH NUCLEAR FUEL AND WASTE MANAGEMENT CO BOX 5864 S-102 48 STOCKHOLM TEL 08-665 28 00 TELEX 13108 SKB S TELEFAX 08-661 57 19 original contains color illustrations URANINITE ALTERATION IN AN OXIDIZING ENVIRONMENT AND ITS RELEVANCE TO THE DISPOSAL OF SPENT NUCLEAR FUEL Robert Finch, Rodney Ewing Department of Geology, University of New Mexico December 1990 This report concerns a study which was conducted for SKB. The conclusions and viewpoints presented in the report are those of the author (s) and do not necessarily coincide with those of the client. Information on SKB technical reports from 1977-1978 (TR 121), 1979 (TR 79-28), 1980 (TR 80-26), 1981 (TR 81-17), 1982 (TR 82-28), 1983 (TR 83-77), 1984 (TR 85-01), 1985 (TR 85-20), 1986 (TR 86-31), 1987 (TR 87-33), 1988 (TR 88-32) and 1989 (TR 89-40) is available through SKB. URANINITE ALTERATION IN AN OXIDIZING ENVIRONMENT AND ITS RELEVANCE TO THE DISPOSAL OF SPENT NUCLEAR FUEL Robert Finch Rodney Ewing Department of Geology University of New Mexico Submitted to Svensk Kämbränslehantering AB (SKB) December 21,1990 ABSTRACT Uraninite is a natural analogue for spent nuclear fuel because of similarities in structure (both are fluorite structure types) and chemistry (both are nominally UOJ. Effective assessment of the long-term behavior of spent fuel in a geologic repository requires a knowledge of the corrosion products produced in that environment.
    [Show full text]
  • Iidentilica2tion and Occurrence of Uranium and Vanadium Identification and Occurrence of Uranium and Vanadium Minerals from the Colorado Plateaus
    IIdentilica2tion and occurrence of uranium and Vanadium Identification and Occurrence of Uranium and Vanadium Minerals From the Colorado Plateaus c By A. D. WEEKS and M. E. THOMPSON A CONTRIBUTION TO THE GEOLOGY OF URANIUM GEOLOGICAL S U R V E Y BULL E TIN 1009-B For jeld geologists and others having few laboratory facilities.- This report concerns work done on behalf of the U. S. Atomic Energy Commission and is published with the permission of the Commission. UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1954 UNITED STATES DEPARTMENT OF THE- INTERIOR FRED A. SEATON, Secretary GEOLOGICAL SURVEY Thomas B. Nolan. Director Reprint, 1957 For sale by the Superintendent of Documents, U. S. Government Printing Ofice Washington 25, D. C. - Price 25 cents (paper cover) CONTENTS Page 13 13 13 14 14 14 15 15 15 15 16 16 17 17 17 18 18 19 20 21 21 22 23 24 25 25 26 27 28 29 29 30 30 31 32 33 33 34 35 36 37 38 39 , 40 41 42 42 1v CONTENTS Page 46 47 48 49 50 50 51 52 53 54 54 55 56 56 57 58 58 59 62 TABLES TABLE1. Optical properties of uranium minerals ______________________ 44 2. List of mine and mining district names showing county and State________________________________________---------- 60 IDENTIFICATION AND OCCURRENCE OF URANIUM AND VANADIUM MINERALS FROM THE COLORADO PLATEAUS By A. D. WEEKSand M. E. THOMPSON ABSTRACT This report, designed to make available to field geologists and others informa- tion obtained in recent investigations by the Geological Survey on identification and occurrence of uranium minerals of the Colorado Plateaus, contains descrip- tions of the physical properties, X-ray data, and in some instances results of chem- ical and spectrographic analysis of 48 uranium arid vanadium minerals.
    [Show full text]
  • Thn Auertcan M Rlueralocrsr
    THn AUERTcANM rluERALocrsr JOURNAL OF TIIE MINDRALOGICAL SOCIETY OF ANIERICA vbl.41 JULY-AUGUST, 1956 Nos. 7 and 8 MTNERAL COMPOSTTTON OF G'UMMTTE*f Crrllonl FnoNonr, H artard Llniaersity,Cambrid,ge, M ass., and. U. S. GeologicalSurwy, Washington, D.C. ABSTRACT The name gummite has been wideiy used for more than 100 years as a generic term to designate fine-grained yellow to orange-red alteration products of uraninite whose true identity is unknown. A study of about 100 specimens of gummite from world-wide localities has been made by r-ray, optical, and chemical methods. rt proved possible to identify almost all of the specimens with already known uranium minerals. Gummite typicalty occurs as an alteration product of uraninite crystals in pegmatite. Such specimensshow a characteristic sequenceof alteration products: (1) A central core of black or brownish-black uraninite. (2) A surrounding zone, yellow to orange-red, composed chiefly of hydrated lead uranyl oxides. This zone constitutes the traditional gummite. It is principally composed of fourmarierite, vandendriesscheite and two unidentified phases (Mineral -4 and Mineral c). Less common constituents are clarkeite, becquerelite, curite, and schoepite. (3) An outer silicate zone. This usually is dense with a greenish-yellow color and is composed of uranophane or beta-uranophane; it is sometimes soft and earthy with a straw-yellow to pale-brown color and is then usually composed of kasolite or an unidenti- fied phase (Minerat B). Soddyite and sklodowskite occur rarely. There are minor variations in the above general sequence. rt some specimens the core may be orange-red gummite without residual uraninite or the original uraninite crystal may be wholly converted to silicates.
    [Show full text]
  • New Mineral Names*
    American Mineralogist, Volume 68, pages 1248-1252,1983 NEW MINERAL NAMES* Perr J. DUNN, MrcHeE'r-FLerscHen, Gr,oncB Y. CHno, Lours J. Cesnr, AND JosEpHA. MexoanrNo Biivoetite* Lcpersonnite* bright yellow and is transparent and translucent. No fluores- Unnamed CeNi-Mg uranyl silicate cence was observed under short- or long-wave UV. The mea- sureddensity is 3.97g/cmr. It is opticallybiaxial negative,2V = M. Deliensand P. Piret (1982)Bijvoetite et lepersonnite,carbon- 73" calc.,a = 1.638, : 1.666,y : 1.682;pleochroic with X pale ates hydratds d'uranyle et des terres rares de Shinkolobwe, B yellow, bright yellow and Z bnght yellow; orientation, only Zaire. Can. Mineral.. 20.231J38. I=cisgiven. = Bijvoetite The mineral is orthorhombic, Pnnm or Pnn2 with a 16.23(3), b = 38.7aQ),c : rr.73Q)4, Z : 2, (V : 7375(50)43,J.A.M.). Blivoetite and lepersonniteoccur with hydrated uranium ox- The density calculated from the unit cell parameters and the ides near primary uraninite in the lower part of the oxidation empirical formula is 4.01 g/cm3. Strongest lines in the X-ray zone at Shinkolobwe, Zaire. Bijvoetite is rare and is known only powder diffraction pattern (for CuKa) are: 8.15(100X200), from a single specimen. Associated minerals are: lepersonnite, 4.06(I 5X400),3.65(70X1 33), 3.2I (50X0.I 2.0) and 2.86(40)(283). sklodowskite, curite, uranophane, becquerelite, rutherfordine, An electronmicroprobe analysis gave: SiO22.79, UOj76.14, studtite and a CeMg-Ni uranyl silicate structurally related to Gd2O32.W,Dy2O3 1.07, Y2O3 0.41, Tb2O3 0.(D, CaO 0.45,CO2 uranophane.
    [Show full text]
  • Kasolite Pb(UO2)Sio4 ² H2O C 2001 Mineral Data Publishing, Version 1.2 ° Crystal Data: Monoclinic
    Kasolite Pb(UO2)SiO4 ² H2O c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Monoclinic. Point Group: 2=m: Crystals stout prismatic, °attened on 001 and lathlike by extension along [010], to several mm. As groups of divergent crystals, rosettefs, angd radial ¯brous aggregates; in dense gumlike crusts and compact, colloform masses. Physical Properties: Cleavage: Perfect on 001 , indistinct on 100 and 010 . Tenacity: Brittle. Hardness = 4{5 D(meas.) =f 5.8g3{6.5 D(calc.) f= 6.g256 Rfadiogactive. Optical Properties: Transparent to translucent, opaque. Color: Ocher-yellow to brownish yellow; amber-brown when transparent; rarely lemon-yellow to green or reddish orange. Streak: Pale yellow-brown. Luster: Subadamantine to greasy, dull to earthy when massive. Optical Class: Biaxial (+). Pleochroism: Weak, rarely; X = Y = very pale yellow; Z = colorless to slightly grayish. Orientation: X = b; Z c. ® = 1.877{1.900 ¯ = 1.880{1.910 ' ° = 1.935{1.970 2V(meas.) = 43± Cell Data: Space Group: P 21=a: a = 13.24 b = 6.94 c = 6.70 ¯ = 104±200 Z = 4 X-ray Powder Pattern: Kasolo, Congo. 3.26 (10), 2.93 (9), 4.19 (8b), 3.53 (7), 6.61 (6), 3.07 (5), 1.962 (5) Chemistry: (1) (2) SiO2 9.42 10.23 UO3 49.28 48.70 Fe2O3 0.41 PbO 36.2 38.00 MgO 0.03 CaO 0.06 H2O 3.59 3.07 CO2 0.85 Total 99.84 100.00 (1) Kasolo, Congo. (2) Pb(UO2)SiO4 ² H2O: Occurrence: An oxidization product of uraninite. Association: Uraninite, torbernite, curite, dewindtite (Kasolo, Congo); rutherfordine, sklodowskite, curite (Nabarlek, Australia).
    [Show full text]
  • 2•4H2o, a New Basic Uranyl Carbonate Mineral
    1685 The Canadian Mineralogist Vol. 39, pp. 1685-1689 (2001) OSWALDPEETERSITE, (UO2)2CO3(OH)2•4H2O, A NEW BASIC URANYL CARBONATE MINERAL FROM THE JOMAC URANIUM MINE, SAN JUAN COUNTY, UTAH, U.S.A. RENAUD VOCHTEN§ Department of Subatomic and Radiation Physics, Division of Nuclear Material Physics, Universiteit Gent, Proeftuinstraat 86, B-9000 Gent, Belgium MICHEL DELIENS Institut royal des Sciences naturelles de Belgique, Section de Minéralogie et de Pétrographie, Rue Vautier 29, B-1000 Bruxelles, Belgium OLAF MEDENBACH Institut für Mineralogie, Ruhr-Universität Bochum, Universitätsstrasse 150, D-44780 Bochum, Germany ABSTRACT Oswaldpeetersite, ideally (UO2)2CO3(OH)2•4H2O, is a newly discovered hydrated basic uranyl carbonate mineral found in the Jomac uranium mine, Brown’s Rim, San Juan County, Utah, U.S.A. It occurs along some bedding planes of a layer of siltstone within the Triassic Shinarump conglomerate. Associated minerals are gypsum, cuprite, antlerite, goethite, lepidocrocite, mbobomkulite, hydrombobomkulite, sklodowskite and two undefined uranium minerals. Oswaldpeetersite occurs as micrometric prismatic crystals (approximately 0.1 0.01 0.002 mm). These are canary yellow and transparent, with a vitreous luster and 3 pale yellow streak. It does not fluoresce in ultraviolet radiation. The HMohs is in the range 2–3. Dmeas > 4.10 g/cm , Dcalc = 4.54 g/ 3 3 cm (empirical formula), 4.50 g/cm (idealized formula). Optically biaxial negative, ␣ 1.583(2), ␤ 1.669(2), ␥ 1.712(2), and 2Vcalc = 67.4(2)°. Orientation Z || a and elongation positive. The pleochroism is X and Y very pale yellow to colorless, and Z pale yellow. The cleavage and parting are along the elongation.
    [Show full text]
  • Mineralogy, Crystallography and Structural Complexity of Natural Uranyl Silicates
    minerals Review Mineralogy, Crystallography and Structural Complexity of Natural Uranyl Silicates Jakub Plášil Institute of Physics ASCR, v.v.i., Na Slovance 1999/2, 18221 Prague 8, Czech Republic; [email protected]; Tel.: +420-775-21-27-57 Received: 10 October 2018; Accepted: 19 November 2018; Published: 27 November 2018 Abstract: Naturally occurring uranyl silicates are common constituents of the oxidized parts (i.e., supergene zone) of various types of uranium deposits. Their abundance reflects the widespread distribution of Si4+ in the Earth’s crust and, therefore, in groundwaters. Up to date, 16 uranyl silicate minerals are known. Noteworthy is that the natural uranyl silicates are not extremely diverse regarding their crystal structures; it is a result of possible concentrations (activity) of Si4+ in aqueous solutions derived from dissolution of primary Si minerals or the composition of late hydrothermal fluids. Therefore, in natural systems, we distinguish in fact among two groups of uranyl silicate minerals: uranophane and weeksite-group. They differ in U:Si ratio (uranophane, 1:1; weeksite, 2:5) and they form under different conditions, reflected in distinctive mineral associations. An overview of crystal-chemistry is provided in this paper, along with the new structure data for few members of the uranophane group. Calculations of the structural complexity parameters for natural uranyl silicates are commented about as well as other groups of uranyl minerals; these calculations are also presented from the point of view of the mineral paragenesis and associations. Keywords: uranyl silicate; crystal structure; structural hierarchy; chemical composition; complexity measures; evolution 1. Introduction Uranyl silicates minerals are typical representatives of the oxidized parts of uranium deposits worldwide [1–5], forming during oxidizing weathering of uraninite, ideally UO2, or coffinite, ideally 4+ U(SiO4).
    [Show full text]
  • Identification and Occurrence of Uranium and Vanadium Minerals from the Colorado Plateaus
    Identification and Occurrence of Uranium and Vanadium Minerals From the Colorado Plateaus GEOLOGICAL SURVEY BULLETIN 1009-B IDENTIFICATION AND OCCURRENCE OF URANIUM AND VANADIUM MINERALS FROM THE COLORADO PLATEAUS By A. D. WEEKS and M. E. THOMPSON ABSTRACT This report, designed to make available to field geologists and others informa­ tion obtained in recent investigations by the Geological Survey on identification and occurrence of uranium minerals of the Colorado Plateaus, contains descrip­ tions of the physical properties, X-ray data, and in some instances results of chem­ ical and spectrographic analysis of 48 uranium and vanadium minerals. Also included is a list of locations of mines from which the minerals have been identified. INTRODUCTION AND ACKNOWLEDGMENTS The 48 uranium and vanadium minerals described in this report are those studied by the writers and their colleagues during recent mineralogic investigation of uranium ores from the Colorado Plateaus. This work is part of a program undertaken by the Geological Survey on behalf of the Division of Raw Materials of the U. S. Atomic Energy Commission. Thanks are due many members of the Geological Survey who have worked on one or more phases of the study, including chemical, spec­ trographic, and X-ray examination,' as well as collecting of samples. The names of these Survey members are given in the text where the contribution of each is noted. The writers are grateful to George Switzer of the U. S. National Museum and to Clifford Frondel of Harvard University who kindly lent type mineral specimens and dis­ cussed various problems. PURPOSE The purpose of this report is to make available to field geologists and others who do not have extensive laboratory facilities, information obtained in recent investigations by the Geological Survey on the identification and occurrence of the uranium and vanadium minerals of ores from the plateaus.
    [Show full text]
  • Rx-Sktodowskrte
    STUDIESOF RADIOACTIVECOMPOUNDS: rx-sKtoDowsKrTE D. H. CORMAN Unfuersity of Toronto, Toronto, Canad,a AsstRAcr New r-ray data are presented for the uranium silicate, sklodowskite. The mineral is monoclinic, C2/m; a-: L7.2.84,D : 7.03, c - 6.56; F - 106o63'. Isomorphism vith uranophane is discussed,Conditions for the forrnation of this rare mineral are reviewed, Of the several speciesof uranium silicate minerals, sklodowskite has the most limited geographicaldistribution, the only recorded occurrence being that at Shinkolobwe, Katanga, Belgian Congo. It was first des- cribed by Schoep (1924a).The analogy with uranophanewas recognized by Schoep (Ig24b) who subsequently (L927) described its. isomorphism with this mineral. Billiet (1936) obtained an rc-raypowder pattern, and establishedcell dimensionsand a symmetry based upon rotation photo- graphs. As was the casewith his work on uranophane,erroneous results were obtained owing to the non-amenability of the crystals to the r-ray technique employed. In 1923 Schoep published two brief notes describing a new mineral speciesfrom the Shinkolobwe deposits, which he called chinkolobwite. However, in 1926 he wrote on tie identity of chinkolobwite and the specieswhich he had previously named sklodowskite. It was pointed out to Schoep by Buttgenbach that the narne sklodor+'skitewa6 the more appropriate for the speciesowing to the fact that the mineral does not actually occur at the village of Shinkolobwe, but at Kasolo Hill, and that the honor paid to Maria Sklodowska (later Madame Curie) should be perpetuated. Physical, Prpperties Sklodowskite occurs as minute acicular crystals in tightly compacted parallel aggregates, often reticulate, radiating divergent or stellate. Exceedingly small crystals form velvety coatings on host rock.
    [Show full text]
  • ~Ew Mineral Names*
    American Mineralogist, Volume 68, pages 1248-1252, 1983 ~EW MINERAL NAMES* PETE J. DUNN, MICHAEL FLEISCHER, GEORGE Y. CHAO, LOUIS J. CABRI, AND JOSEPH A. MANDARINO Bijvoetite* Lepersonnite* bright yellow and is transparent and translucent. No fluores- Unnamed Co-Ni-Mg uranyl silicate cence was observed under short- or long-wave VV. The mea- sured density is 3.97 g/cm3. It is optically biaxial negative, 2V M. Deliens and P. Piret (1982) Bijvoetite et lepersonnite, carbon- = 1.638, (3 1.666, 1.682; pleochroic with X pale ates hydrates d'uranyle et des terres rares de Shinkolobwe, 73° calc., a = = 'Y= yellow, Y bright yellow and Z bright yellow; orientation, only Zaire. Can. Mineral., 20, 231-238. Y = c is given. The mineral is orthorhombic, Pnnm or Pnn2 with a 16.23(3), Bijvoetite = b = 38.74(9), c = 11.73(3)A, Z = 2, (V = 7375(50)A3, J .A.M.). Bijvoetite and lepersonnite occur with hydrated uranium ox- The density calculated from the unit cell parameters and the ides near primary uraninite in the lower part of the oxidation empirical formula is 4.01 g/cm3. Strongest lines in the X-ray zone at Shinkolobwe, Zaire. Bijvoetite is rare and is known only powder diffraction pattern (for CuKa) are: 8.15(100)(200), from a single specimen. Associated minerals are: lepersonnite, 4.06(15)(400), 3.65(70)(133), 3.21(50)(0.12.0) and 2.86(40)(283). sklodowskite, curite, uranophane, becquerelite, rutherfordine, An electron microprobe analysis gave: Si02 2.79, V03 76.14, studtite and a Co-Mg-Ni uranyl silicate structurally related to Gd203 2.09, DY203 1.07, Y203 0.41, Tb203 0.09, CaO 0.45, C02 uranophane.
    [Show full text]
  • Vandenbrandeite Cu(UO2)(OH)4 C 2001-2005 Mineral Data Publishing, Version 1
    Vandenbrandeite Cu(UO2)(OH)4 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Triclinic. Point Group: 1. Crystals, flattened on {001}, may be lathlike, rounded, to 0.5 cm; in parallel aggregates, lamellar, scaly; massive. Physical Properties: Cleavage: {110}, perfect; two others, in the [001] zone, indistinct. Hardness = 4 D(meas.) = 4.91–5.03 D(calc.) = [5.14] Radioactive. Optical Properties: Translucent, transparent in thin fragments. Color: Dark green to nearly black; green in transmitted light. Streak: Green. Luster: Vitreous. Optical Class: Biaxial, (+) or (–). Pleochroism: Yellow-green to blue-green. Orientation: Z ∧ elongation ' 40◦. Dispersion: Strong. α = 1.76–1.77 β = 1.78–1.79 γ = 1.78–1.82 2V(meas.) = ∼90◦ Cell Data: Space Group: P 1 (probable). a = 7.855(5) b = 5.449(4) c = 6.089(4) α =91.44(5)◦ β = 101.90(5)◦ γ =89.2(5)◦ Z=2 X-ray Powder Pattern: Kalongwe, Congo. 4.29 (10), 2.92 (8), 5.06 (4), 2.56 (4), 2.09 (3), 1.85 (3), 1.47 (3) Chemistry: (1) (2) UO3 71.23 71.22 CuO 19.20 19.81 H2O 9.57 8.97 Total [100.00] 100.00 (1) Shinkolobwe, Congo; recalculated to 100% after deduction of SiO2 0.28%, MgO 0.57%, CaO 0.26% as impurities. (2) Cu(UO2)(OH)4. Occurrence: A rare secondary mineral in the oxide zone of hydrothermal copper-bearing uranium deposits. Association: Cuprosklodowskite, kasolite, sklodowskite, malachite, chalcocite, chalcopyrite, uraninite, goethite (Kalongwe, Congo); curite, uranophane, sharpite (Shinkolobwe, Congo). Distribution: In Congo (Zaire), in Katanga (Shaba) Province, from the Luiswishi mine; at Kalongwe; from Shinkolobwe; at Kambove; from Swambo; and in the Musonoi mine, near Kolwezi.
    [Show full text]