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Hazardous Substances (Chemicals) Transfer Notice 2006
16551655 OF THURSDAY, 22 JUNE 2006 WELLINGTON: WEDNESDAY, 28 JUNE 2006 — ISSUE NO. 72 ENVIRONMENTAL RISK MANAGEMENT AUTHORITY HAZARDOUS SUBSTANCES (CHEMICALS) TRANSFER NOTICE 2006 PURSUANT TO THE HAZARDOUS SUBSTANCES AND NEW ORGANISMS ACT 1996 1656 NEW ZEALAND GAZETTE, No. 72 28 JUNE 2006 Hazardous Substances and New Organisms Act 1996 Hazardous Substances (Chemicals) Transfer Notice 2006 Pursuant to section 160A of the Hazardous Substances and New Organisms Act 1996 (in this notice referred to as the Act), the Environmental Risk Management Authority gives the following notice. Contents 1 Title 2 Commencement 3 Interpretation 4 Deemed assessment and approval 5 Deemed hazard classification 6 Application of controls and changes to controls 7 Other obligations and restrictions 8 Exposure limits Schedule 1 List of substances to be transferred Schedule 2 Changes to controls Schedule 3 New controls Schedule 4 Transitional controls ______________________________ 1 Title This notice is the Hazardous Substances (Chemicals) Transfer Notice 2006. 2 Commencement This notice comes into force on 1 July 2006. 3 Interpretation In this notice, unless the context otherwise requires,— (a) words and phrases have the meanings given to them in the Act and in regulations made under the Act; and (b) the following words and phrases have the following meanings: 28 JUNE 2006 NEW ZEALAND GAZETTE, No. 72 1657 manufacture has the meaning given to it in the Act, and for the avoidance of doubt includes formulation of other hazardous substances pesticide includes but -
Cyclometalation of Phosphinines Via C-H Activation : Towards Functional Coordination Compounds
Cyclometalation of phosphinines via C-H activation : towards functional coordination compounds Citation for published version (APA): Broeckx, L. E. E. (2013). Cyclometalation of phosphinines via C-H activation : towards functional coordination compounds. Technische Universiteit Eindhoven. https://doi.org/10.6100/IR760622 DOI: 10.6100/IR760622 Document status and date: Published: 04/12/2013 Document Version: Publisher’s PDF, also known as Version of Record (includes final page, issue and volume numbers) Please check the document version of this publication: • A submitted manuscript is the version of the article upon submission and before peer-review. There can be important differences between the submitted version and the official published version of record. People interested in the research are advised to contact the author for the final version of the publication, or visit the DOI to the publisher's website. • The final author version and the galley proof are versions of the publication after peer review. • The final published version features the final layout of the paper including the volume, issue and page numbers. Link to publication General rights Copyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights. • Users may download and print one copy of any publication from the public portal for the purpose of private study or research. • You may not further distribute the material or use it for any profit-making activity or commercial gain • You may freely distribute the URL identifying the publication in the public portal. -
George Andrew Olah Across Conventional Lines
GENERAL ARTICLE George Andrew Olah Across Conventional Lines Ripudaman Malhotra, Thomas Mathew and G K Surya Prakash Hungarian born American chemist, George Andrew Olah was aprolific researcher. The central theme of his career was the 12 pursuit of structure and mechanisms in chemistry, particu- larly focused on electron-deficient intermediates. He leaves behind a large body of work comprising almost 1500 papers and twenty books for the scientific community. Some selected works have been published in three aptly entitled volumes, 3 Across Conventional Lines. There is no way to capture the many contributions of Olah in a short essay. For this appreciation, we have chosen to high- 1 light some of those contributions that to our mind represent Ripudaman Malhotra, a student of Prof. Olah, is a asignificant advance to the state of knowledge. retired chemist who spent his entire career at SRI International working mostly Organofluorine Chemistry on energy-related issues. He co-authored the book on Early on in his career, while still in Hungary, Olah began studying global energy – A Cubic Mile organofluorine compounds. Olah’s interest in fluorinated com- of Oil. pounds was piqued by the theoretical ramifications of a strong 2 Thomas Mathew, a senior C-F bond. Thus, whereas chloromethanol immediately decom- scientist at the Loker Hydrocarbon Research poses into formaldehyde and HCl, he reasoned that the stronger Institute, has been a close C-F bond might render fluoromethanol stable. He succeeded in associate of Prof. Olah over preparing fluoromethanol by the reduction of ethyl flouorofor- two decades. 3 mate with lithium aluminum hydride [1]. -
Silver Products
Silver products Silver truly packs a punch given its unique combination of intrinsic antimicrobial properties, high electric conductivity and ductility. This combined with the commitment to quality and delivery means the Alfa Aesar™ portfolio of silver products have been used extensively in a wide range of applications from medical and pharmaceutical to catalysis, energy and advanced optoelectronics that touch everyday life. Our specialized silver compounds are available in catalog sizes to bulk quantities. We offer the capability to produce batch sizes up to 200 kg. Bulk packing sizes are customized to meet our customers’ requirements. Key Features: • Large selection of silver compounds can be manufactured up to a purity of 99.999%. • Most other silver products are manufactured to 99.9% purity as standard. • A batch specific certificate of analysis is produced for each product. • Each silver product batch has: - Full metallic impurities typically measured by ICP-MS to ppm - Measured silver content • Specialized silver compounds outside our catalog range can be manufactured on request. Application highlights: Chemical Many silver salts are the chemical precursors for other silver derivatives or metallic silver. Silver carbonate has been employed in the Koenigs-Knorr reaction, a substitution reaction of a glycosyl halide with an alcohol to give a glycoside. Silver salts of carboxylic acids are used to produce organic halides (Hunsdiecker reaction). Silver products also play a critical role in the catalysis of chemical manufacturing processes that provide the building blocks for many day-to-day products. Order our products online alfa.com Pharmaceutical The medicinal properties of silver salts have been used in a range of pharmaceutical compositions. -
Silver (I) Coordination Chemistry: from 1-D Chains to Molecular Rectangles
This is the author’s final, peer-reviewed manuscript as accepted for publication. The publisher-formatted version may be available through the publisher’s web site or your institution’s library. Silver (I) coordination chemistry: from 1-D chains to molecular rectangles Mohammad Abul-Haj, Christer B. Aakeröy, and John Desper How to cite this manuscript If you make reference to this version of the manuscript, use the following information: Abul-Haj, M., Aakeröy, C. B., & Desper, J. (2013). Silver (I) coordination chemistry: From 1-D chains to molecular rectangles. Retrieved from http://krex.ksu.edu Published Version Information Citation: Abul Haj, M., Aakeröy, C. B., & Desper, J. (2013). Silver (I) coordination chemistry: From 1-D chains to molecular rectangles. New Journal of Chemistry, 37(1), 204-211. Copyright: © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2013 Digital Object Identifier (DOI): doi:10.1039/c2nj40669a Publisher’s Link: http://pubs.rsc.org/en/content/articlelanding/2013/nj/c2nj40669a This item was retrieved from the K-State Research Exchange (K-REx), the institutional repository of Kansas State University. K-REx is available at http://krex.ksu.edu New Journal of Chemistry Dynamic Article Links ► Cite this: DOI: 10.1039/c0xx00000x www.rsc.org/xxxxxx ARTICLE TYPE Silver (I) coordination chemistry: from 1-D chains to molecular rectangles Mohammad Abul-Haj,a Christer B. Aakeröy,*b and John Desperb Received (in XXX, XXX) Xth XXXXXXXXX 20XX, Accepted Xth XXXXXXXXX 20XX 5 DOI: 10.1039/b000000x A series of silver(I) coordination compounds with the ligand 2-(4-pyridyl)imidazole 4-PyIm has been synthesized and crystallographically characterized in order to explore the role of counter ion, solvent and ligand charge on the resulting supramolecular architectures. -
Precious Metal Compounds and Catalysts
Precious Metal Compounds and Catalysts Ag Pt Silver Platinum Os Ru Osmium Ruthenium Pd Palladium Ir Iridium INCLUDING: • Compounds and Homogeneous Catalysts • Supported & Unsupported Heterogeneous Catalysts • Fuel Cell Grade Products • FibreCat™ Anchored Homogeneous Catalysts • Precious Metal Scavenger Systems www.alfa.com Where Science Meets Service Precious Metal Compounds and Table of Contents Catalysts from Alfa Aesar When you order Johnson Matthey precious metal About Us _____________________________________________________________________________ II chemicals or catalyst products from Alfa Aesar, you Specialty & Bulk Products _____________________________________________________________ III can be assured of Johnson Matthey quality and service How to Order/General Information ____________________________________________________IV through all stages of your project. Alfa Aesar carries a full Abbreviations and Codes _____________________________________________________________ 1 Introduction to Catalysis and Catalysts ________________________________________________ 3 range of Johnson Matthey catalysts in stock in smaller catalog pack sizes and semi-bulk quantities for immediate Precious Metal Compounds and Homogeneous Catalysts ____________________________ 19 shipment. Our worldwide plants have the stock and Asymmetric Hydrogenation Ligand/Catalyst Kit __________________________________________________ 57 Advanced Coupling Kit _________________________________________________________________________ 59 manufacturing capability to -
Nuclear Magnetic Resonance Studies of Boron Trifluoride and Some of Its
NUCLEAR MAGNETIC R:~SONANCE S'I'UDH~S OF BORON TRIFLUORIDE AND SOME OF ITS COMPLEXES NUCLEAR MAGNETIC RESONANCE STUDIES OF BORON 'l1RIFLUORIDE AND SOME OF ITS COMPLEXES by JOI-frJ ST.2;PH_c;N HARTMAN, B.Sc. 1 M.Sc. A Thesis Submitted to the Faculty of Graduate Studies in Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy McMaster University January, 1967 DOCTOR OF PHILOSOPHY (1967) McM.J'l.STER UNIVERSITY (Chemistry) Hamilton, Ontario. TITLE: Nuclear Magnetic Resonance Studies of Boron Trifluoride and Some of Its Complexes AUTHOR: John Stephen Hartman, B.Sc. (Queen's University), M.Sc. (University of Ottav,a) SUPVERVISOR: Professor R. J. Gillespie NUMB8R OF PJ\GES: xi, 231 SCOPE Al\JD com:ENTS: Nuclear magnetic resonance spectroscopy has been used to study donor'.'"acceptor complexes of boron trifluoride with ketones, water, and methanol. Various NMR techniques have been applied which, in certain favourable cases, hDve yielded information on the stoichiometry, struc ture, relative stabilities, and reactions of the complexes in soluUon. A new method is proposed for the detection of BF complexes having low 3 formation constants. The me.gni tude and sign of the B-F. coupling constant in the tetra fluoroborate anion have been found to be dependent on the solvent. This solvent dependence is interpreted in terms of salvation and association of the ion in solution. 19 10 F spectra of BF over a ranc;e of temperatures agree well 3 with line shapes calculated, using Pople's expressions, for coupling of fluorine-19 with boron-10 (1=3) which is undergoing partial quadru pole relaxation. -
IN W O 2009/111300 A3 Clisadtcerpbihdi H Vn Frcito
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization IN International Bureau (10) International Publication Number (43) International Publication Date 11 September 2009 (11.09.2009) PCT W O 2009/111300 A3 (51) International Patent Classification: (81) Designated States (unless otherwise indicated,for every A6L 27/30 (2006.01) A6L 27/12 (2006.01) kind of nationalprotection available): AE, AG, AL, AM, A6L 27/34 (2006.01) A61F2/28 (2006.01) AO, AT, AU, AZ, BA, BB, BG, BH, BR, BW, BY, BZ, A6L 27/50 (2006.01) CA, CH, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, (21) International Application Number:E, EG, ES, Fl, GB, GD, GE, GH, GM, GT, N, KN, KP, KR, PCT/US2009/035444PCT/5209/03444 KZ,HR, LA,H, LC,ID, IL,LK, IN, LR, IS, LS, JP, LT,KE, LU, KG, LY, KM, MA, MD, ME, (22) International Filing Date: MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, 27 February 2009 (27.02.2009) NZ, OM, PG, PH, PL, PT, RO, RS, RU, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TJ, TM, TN, TR, TT, TZ, UA, (25) Filing Language: English UG, US, UZ, VC, VN, ZA, ZM, ZW. (26) Publication Language: English (84) Designated States (unless otherwise indicated, for every (30) Priority Data: kind of regionalprotection available>: ARIPO (BW, GIL 61/032,767 29 February 2008 (29.02.2008) us GM, KE, LS, MW, MZ, NA, SD, SL, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, MD, RU, TJ, (71) Applicant (for all designated States except US>: SMITH TM), European (AT, BE, BG, CH, CY, CZ, DE, DK, EE, & NEPHEW, INC. -
Technical Bulletin Reaction Solvent Dimethyl Sulfoxide (Dmso)
TECHNICAL BULLETIN REACTION SOLVENT DIMETHYL SULFOXIDE (DMSO) O S H C CH 3 3 CAS Name: Methane, sulfinylbis CAS Registry Number: 67- 68- 5 Dimethyl sulfoxide as manufactured by Gaylord Chemical, is a water-white almost odorless liquid, boiling at 189°C. and melting at above 18.2° C. It is relatively stable and easy to recover, miscible in all proportions with water and most common organic solvents and has a low order of toxicity. Gaylord Chemical Corporation P.O. Box 1209 Slidell, LA 70459-1209 (985) 649-5464 1 TABLE OF CONTENTS Page INTRODUCTION 5 PART I. PROPERTIES OF DMSO 6 Physical Properties 6 Thermal and Chemical Stability 6 Recovery from Aqueous Solutions 12 PART II. SOLVENCY CHARACTERISTICS OF D MSO 12 Solubility of Salts 13 Solubility of Resins and Polymers 14 Solubility of Miscellaneous Materials 15 Solubility of Gases 16 PART III. REACTIONS OF DMSO 17 1. Oxidation of DMSO 17 2. Reduction of DMSO 17 3. Reaction with Metals 17 4. Reaction with Strong Bases -Dimsyl Ion 17 5. Reaction with Acid Halides 18 6. Reaction with Acid Anhydrides 18 7. Halogenation of DMSO 19 8. Reaction with Phenols and Aniline 19 9. Alcohol Oxidation with DMSO 20 a) Acetic Anhydride 21 b) Trifluoroacetic Anhydride 21 c) Dicyclohexylcarbodiimide 21 d) Phosphorus Pentoxide 22 e) Sulfur Trioxide-Pyridine 22 f) Oxalyl Chloride 23 10. Kornblum Reaction 23 11. Mehoxydimethylsulfonium Salts and 23 Trimethyloxosulfonium Salts PART IV. DMSO AS A REACTION SOLVENT 24 A. DISPLACEMENT REACTIONS IN DMSO 24 Anions-Nucleophiles (Bases): 1. Acetylide Ion 24 2. Alkoxide Ion 24 3. -
Specialty Silver Compounds
Specialty Silver Compounds • Selection of silver compounds can be manufactured up to a purity of 99.999% • Batch production capability from grams to 200 Kg www.alfa.com Alfa Aesar have the capability of Specialized Silver Compounds producing batch sizes up to 200 Kg. Bulk packing sizes are customized to • Our specialized silver compounds are meet our customers’ requirements. available in catalog sizes to bulk quantities. Many silver compounds are • We can manufacture our silver compounds to specific purity on request. photosensitive. All our specialized silver compounds are packaged in lightproof • If you require a specialized silver compound containers. not listed we can discuss its manufacture. KEY FEATURES Manufacturing • A batch specific certificate of analysis is produced for each product. Alfa Aesar’s production operations offer a single source for silver salts from research to pilot plant • Each silver product batch has; scale. Full-scale production of these products is 1. Full metallic impurities typically measured available. by ICP-MS to ppm. 2. The silver content measured. Development • A selection of silver compounds can be With our extensive development capability, we manufactured up to a purity of 99.999% are able to supply advanced silver materials to meet your technical requirements. • Most other silver products are manufactured to 99.9% purity as standard. Quality Control We employ advanced quality control for both in-process and final product testing phases. The high standard of our modern quality control and assurance facilities is matched by the expertise of our experienced staff. Further details and prices for catalog quantities are available in the Alfa Aesar Catalog or via the web site www.alfa.com. -
Antimicrobial Silver-Containing Biomaterials Antimikrobielle Silberhaltige Biomaterialien Biomatériaux Antimicrobes Contenant De L’Argeant
(19) TZZ ¥_T (11) EP 2 464 236 B1 (12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) Int Cl.: of the grant of the patent: A01N 37/36 (2006.01) A01N 61/00 (2006.01) 16.10.2019 Bulletin 2019/42 A01N 59/16 (2006.01) A01N 43/16 (2006.01) A01N 47/44 (2006.01) A01N 31/16 (2006.01) (2006.01) (2006.01) (21) Application number: 10808706.5 A01N 25/34 A61K 31/202 A61K 31/232 (2006.01) A61K 31/765 (2006.01) A61K 31/09 (2006.01) A61K 31/155 (2006.01) (22) Date of filing: 11.08.2010 A61K 31/35 (2006.01) A61K 31/28 (2006.01) A61L 29/16 (2006.01) A61L 31/16 (2006.01) A61L 15/44 (2006.01) A01P 1/00 (2006.01) A61K 33/38 (2006.01) A61K 45/06 (2006.01) (86) International application number: PCT/US2010/045194 (87) International publication number: WO 2011/019834 (17.02.2011 Gazette 2011/07) (54) ANTIMICROBIAL SILVER-CONTAINING BIOMATERIALS ANTIMIKROBIELLE SILBERHALTIGE BIOMATERIALIEN BIOMATÉRIAUX ANTIMICROBES CONTENANT DE L’ARGEANT (84) Designated Contracting States: • MARTAKOS, Paul AL AT BE BG CH CY CZ DE DK EE ES FI FR GB Pelham GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO NH 03076 (US) PL PT RO SE SI SK SM TR (74) Representative: Helbig, Christian et al (30) Priority: 11.08.2009 US 539282 Wagner + Helbig Patentanwälte (43) Date of publication of application: Pfarrstrasse 14 20.06.2012 Bulletin 2012/25 80538 München (DE) (73) Proprietor: Atrium Medical Corporation (56) References cited: Hudson, NH 03051 (US) WO-A1-2009/091900 WO-A1-2010/042241 US-A1- 2006 110 457 US-A1- 2006 204 738 (72) Inventors: US-A1- 2006 263 330 US-A1- 2008 109 017 • FAUCHER, Keith, M. -
Tânia Ereira Sintra Síntese De Líquidos Iónicos Mais Benignos Para Aplicações Específicas Synthesis of More Benign Ioni
Universidade de Aveiro Departamento de Química 2017 TÂNIA EREIRA SÍNTESE DE LÍQUIDOS IÓNICOS MAIS BENIGNOS SINTRA PARA APLICAÇÕES ESPECÍFICAS SYNTHESIS OF MORE BENIGN IONIC LIQUIDS FOR SPECIFIC APPLICATIONS Universidade de Aveiro Departamento de Química 2017 TÂNIA EREIRA SÍNTESE DE LÍQUIDOS IÓNICOS MAIS BENIGNOS SINTRA PARA APLICAÇÕES ESPECÍFICAS SYNTHESIS OF MORE BENIGN IONIC LIQUIDS FOR SPECIFIC APPLICATIONS Tese apresentada à Universidade de Aveiro para cumprimento dos requisitos necessários à obtenção do grau de Doutor em Química, realizada sob a orientação científica do Professor Doutor João Manuel da Costa e Araújo Pereira Coutinho, Professor Catedrático do Departamento de Química da Universidade de Aveiro, e co-orientação da Doutora Sónia Patrícia Marques Ventura, Investigadora Auxiliar no Instituto de Materiais de Aveiro (CICECO), do Departamento de Química da Universidade de Aveiro. Apoio financeiro através da Apoio financeiro do POCTI no âmbito O doutorando agradece o apoio FCT/MEC, no âmbito do projeto do III Quadro Comunitário de Apoio. financeiro da FCT no âmbito do III PTDC/ATP-EAM/5331/2014. Co-financiamento do POPH/FSE. Quadro Comunitário de Apoio (SFRH/BD/85871/2012). Dedico este trabalho ao nº 128 da Rua 21 de Maio, Antões. o júri presidente Prof. Doutor António Manuel Rosa Pereira Caetano professor catedrático da Universidade de Aveiro Prof. Doutor Carlos Alberto Mateus Afonso professor catedrático da Faculdade de Farmácia da Universidade de Lisboa Prof. Doutor Artur Manuel Soares da Silva professor catedrático da Universidade