Structures and Mechanical Properties of Natural and Synthetic Diamonds
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Graphene – Diamond Nanomaterials: a Status Quo Review
Preprints (www.preprints.org) | NOT PEER-REVIEWED | Posted: 29 July 2021 doi:10.20944/preprints202107.0647.v1 Article Graphene – diamond nanomaterials: a status quo review 1 Jana Vejpravová ,* 1 Department of Condensed Matter Physics, Faculty of Mathematics and Physics, Charles University, Ke Karlovu 5, 121 16 Prague 2, Czech Republic. * Correspondence: JV, [email protected] Abstract: Carbon nanomaterials with a different character of the chemical bond – graphene (sp2) and nanodiamond (sp3) are the building bricks for a new class of all-carbon hybrid nanomaterials, where the two different carbon networks with the sp3 and sp2 hybridization coexist, interact and even transform into one another. The unique electronic, mechanical, and chemical properties of the two border nanoallotropes of carbon ensure the immense application potential and versatility of these all-carbon graphene – diamond nanomaterials. The review gives an overview of the current state of the art of graphene – diamond nanomaterials, including their composites, heterojunctions, and other hybrids for sensing, electronic, energy storage, and other applications. Also, the graphene- to-diamond and diamond-to-graphene transformations at the nanoscale, essential for innovative fabrication, and stability and chemical reactivity assessment are discussed based on extensive theo- retical, computational, and experimental studies. Keywords: graphene; diamond; nanodiamond; diamane; graphene-diamond nanomaterials; all car- bon materials; electrochemistry; mechanochemistry; sensor; supercapacitor; -
X-Ray Topographic Investigation of Diamond Anvils for High Pressure Generation - Correlation Between Defects and Early Failure
X-ray topographic investigation of diamond anvils for high pressure generation - Correlation between defects and early failure Dewaele A. and Loubeyre P. CEA/DPTA, BP12, 91680 Bruyères le Châtel The diamond anvil cell technique revolutionized high pressure physics some 25 years ago. This device takes advantage of the unusual mechanical properties of the diamond. A metallic gasket with a hole in it to confine the sample is compressed between two diamond anvils. This device allows the generation of pressures that reach 300 GPa (3 millions times atmospheric pressure), pressure at which the diamond exhibits large elastic strain [1]. The pressure reached in diamond anvil cells is very often limited by the failure of a diamond anvil. In order to prevent this phenomenon, anvils are selected on the basis of their chemical purity, and their internal strains. However, the chemical purity does not guarantee the resistance of diamond anvils under high pressure operation. In particular, when the diamonds are used in contact with H2 or Helium samples, species which diffuse in diamond. Unfortunately, helium is known to be the best pressure transmitting medium, and is often loaded for that use in diamonds anvil cells [2]. A better understanding of early breakdown of diamond anvils and an a priori diagnostic of their resistance would thus constitute a major improvement for high pressure techniques. X-ray topography helps to establish this anvils quality diagnostic, because this method evidences intrinsic crystallographic defects of the anvils. These defects are likely to influence the mechanical properties of the anvil [3]. However, the liability of x-ray topography diagnostic had to be proven. -
Ecological Comparison of Synthetic Versus Mined Diamonds
Ecological Comparison of Synthetic versus Mined Diamonds Saleem H. Ali Working Paper, Institute for Environmental Diplomacy and Security University of Vermont, January, 2011 http://www.uvm.edu/ieds Abstract The energy usage and emissions in mined versus lab-created diamonds was evaluated, based on industrial data, since these two factors are often a general indicator of environmental impact that can be useful in product comparisons. Depending on the process and the location of the mine, the data can be highly divergent and cannot be used as a singular measure of environmental impact. There is a need to develop life cycle analysis techniques from industrial ecology to conduct a detailed comparison of synthetic versus mined stones. Introduction Synthetic diamonds have come of age, and the year 2010 will be remembered as a landmark year in this regard since for the first time labs of the Gemological Institute of America (GIA) in New York were able to grade a gem quality near-colorless synthetic diamond (formed by chemical vapor deposition) , greater than 1 carat. The history of synthetic diamonds at the industrial level, goes back to patents for super-abrasives at General Electric can be traced back to several decades (Hazen, 1996). However, gem quality synthetic diamonds have only risen to prominence in the last decade with the rise of a few key companies who are taking on this growing market in concert with boutique jewelry brands. As jewelers consider environmental social responsibility more seriously in marketing their gemstone products, energy usage in mined versus lab-created gems can be an important factor in determining comparative environmental impact. -
OF SYNTHETIC DIAMONDS. Introduction
PI ^ AU9817130 IONOLUMINESCENCE (IL) OF SYNTHETIC DIAMONDS. A. A. Bettiol, K. W. Nugent, D. N. Jamieson and S. Prawer School of Physics, Microanalytical Research Centre, University of Melbourne, Parkville, 3052, AUSTRALIA. Introduction The optical properties of natural and synthetic diamonds have been extensively characterized in the past by absorption and luminescence. The use of such techniques as cathodoluminescence, photoluminescence, photoluminescence excitation and electron spin and paramagnetic resonance has resulted in the identification of many impurity and defect related optical centres in diamond [1-2]. Of the impurities found in diamond, nitrogen is by far the most abundant and hence responsible for most of the optical properties [3]. The development of diamond synthesis methods has resulted in the discovery of a number of a new optically active impurities and defects which are introduced during the growth process. These include Si, O, Ni and B [1-2]. In this study we identify a number of defect and impurity related centres in two commercially produced synthetic diamond samples by using the novel technique of ionoluminescence (IL) [4]. The first sample characterized is a Norton polycrystalline diamond detector. Signal produced in any charged particle detector is degraded if recombination of the electrons and holes occurs before the charge can be swept out by the electric field in the detector. In diamonds where the radiative recombination cross-section can be quite high, signal degradation can occur depending on the optical centres present and their lifetimes. Recombination centres with lifetimes much longer than the sweep out time will potentially saturate hence only cause a degradation of signal. -
DIAMOND Natural Colorless Type Iab Diamond with Silicon-Vacancy
Editors Thomas M. Moses | Shane F. McClure DIAMOND logical and spectroscopic features con- Natural Colorless Type IaB firmed the diamond’s natural origin, – Diamond with Silicon-Vacancy despite the occurrence of [Si-V] emis- Defect Center sions. No treatment was detected. Examination of this stone indicated The silicon-vacancy defect, or [Si-V]–, that the [Si-V]– defect can occur, albeit is one of the most important features rarely, in multiple types of natural dia- in identifying CVD synthetic dia- monds. Therefore, all properties should monds. It can be effectively detected be carefully examined in reaching a using laser photoluminescence tech- conclusion when [Si-V]– is present. nology to reveal sharp doublet emis- sions at 736.6 and 736.9 nm. This Carmen “Wai Kar” Lo defect is extremely rare in natural dia- monds (C.M. Breeding and W. Wang, “Occurrence of the Si-V defect center Figure 1. Emissions from the Screening of Small Yellow Melee for in natural colorless gem diamonds,” silicon-vacancy defect at 736.6 and Treatment and Synthetics Diamond and Related Materials, Vol. 736.9 nm were detected in this Diamond treatment and synthesis 17, No. 7–10, pp. 1335–1344) and has 0.40 ct type IaB natural diamond. have undergone significant develop- been detected in very few natural type ments in the last decade. During this IIa and IaAB diamonds over the past showed blue fluorescence with natural time, the trade has grown increasingly several years. diamond growth patterns. These gemo- concerned about the mixing of treated Recently, a 0.40 ct round brilliant diamond with D color and VS2 clarity (figure 1) was submitted to the Hong Figure 2. -
The World of Pink Diamonds and Identifying Them
GEMOLOGY GEMOLOGY as to what dealers can do to spot them using standard, geologists from Ashton Joint Venture found certain indicator The World of Pink Diamonds inexpensive instruments. The commercial signifcance of minerals (such as ilmenite, chromite, chrome diopside, the various types will also be touched on. and pyrope garnet) in stream-gravel concentrates which indicated the presence of diamond-bearing host rocks. and Identifying Them Impact of Auction Sales Lamproites are special ultrapotassic magnesium-rich In the late 1980s, the public perception surrounding fancy- mantle-derived volcanic rocks with low CaO, Al2O3, Na2O colored diamonds began to change when the 0.95-carat and high K2O. Leucite, glass, K-richterite, K-feldspar and Cr- By Branko Deljanin, Dr Adolf Peretti, ‘Hancock Red’ from Brazil was sold for almost $1 million per spinel are unique to lamproites and are not associated with and Matthias Alessandri carat at a Christie’s auction. This stone was studied by one kimberlites. The diamonds in lamproites are considered to be of the authors (Dr. Adolf Peretti) at that time. Since then, xenocrysts and derived from parts of the lithospheric mantle Dr. Peretti has documented the extreme impact this one that lies above the regions of lamproite genesis. Kimberlites sale has had on subsequent prices and the corresponding are also magmatic rocks but have a different composition recognition of fancy diamonds as a desirable asset class. The and could contain non-Argyle origin pink diamonds. demand for rare colors increased and the media began to play a more active role in showcasing new and previously Impact of Mining Activities unknown such stones. -
New Generations of Boron-Doped Diamond Structures by Delta-Doping Technique for Power Electronics : CVD Growth and Characterization Alexandre Fiori
New generations of boron-doped diamond structures by delta-doping technique for power electronics : CVD growth and characterization Alexandre Fiori To cite this version: Alexandre Fiori. New generations of boron-doped diamond structures by delta-doping technique for power electronics : CVD growth and characterization. Electronics. Université de Grenoble, 2012. English. NNT : 2012GRENI018. tel-00967208v2 HAL Id: tel-00967208 https://tel.archives-ouvertes.fr/tel-00967208v2 Submitted on 28 Jun 2017 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. THÈSE Pour obtenir le grade de DOCTEUR DE L’UNIVERSITÉ DE GRENOBLE Spécialité : Matériaux, Mécanique, Génie civil, Electrochimie Arrêté ministériel : 7 août 2006 Présentée par Alexandre FIORI Thèse dirigée par Franck Omnès et codirigée par Julien Pernot préparée au sein de l’institut Néel au CNRS à Grenoble dans l'École Doctorale I-MEP2 : Ingénierie – Matériaux, mécanique, Environnement, Energétique, Procédés, Production Nouvelles générations de structures en diamant dopé au bore par technique de delta-dopage pour l’électronique de puissance : croissance par CVD et caractérisation Thèse soutenue publiquement le 24 octobre 2012, devant le jury composé de : M. Christophe VALLEE Professeur, Université de Grenoble, Président M. Ken HAENEN Professeur, Université de Hasselt, Rapporteur M. -
De Beers Natural Versus Synthetic Diamond Verification Instruments
DE BEERSNATURAL VERSUS By Christopher M.Welbourn, Martin Cooper, and Paul M,Spear Twoinstruments have been developed at he subject of cuttable-quality synthetic diamonds De Beers DTC Research Centre, has been receiving much attention in the gem trade Maidenhead, to distinguish synthetic dia- recently. Yellow to yellow-brown synthetic diamonds grown monds from natural diamonds. The in Russia have been offered for sde at a number of recent DiainondSureTMenables the rapid exami- gem and jewelry trade shows (Shor and Weldon, 1996; nation of large numbers of polished dia- monds, both loose and set in jewehy. Reinitz, 1996; Johnson and Koivula, 1996))and a small num- Automatically and with high sensitivity, ber of synthetic diamonds have been submitted to gem grad- this instrument detects the presence of the ing laboratories for identification reports (Fryer, 1987; 415 nm optical absorption line, which is Reinitz, 1996; Moses et al., 1993a and b; Emms, 1994; found in the vast majority of natural dia- Kammerling et al., 1993, 1995; Kammerling and McClure, monds but not in synthetic diamonds. 1995). Particular concern was expressed following recent Those stones in which this line is detected announcements of the production and planned marketing of are "passed" by the instrument, and those near-colorless synthetic diamonds (Koivula et al., 1994; in which it is not detected are "referredfor "Upfront," 1995). further tests." The DiamondViewTRfpro- Synthetic diamonds of cuttable size and quality, and the duces a fluorescence image of the surface of technology to produce them, are not new. In 1971, researchers a polished diamond, from which the growth structure of the stone may be deter- at the General Electric Company published the results of mined. -
PGDNET Education
ALCHEMY ABOVE EARTH ABOUT PURE GROWN DIAMONDS Conceived in 2014, Pure Grown Diamonds (PGD) has been growing steadily in the USA’s big and small multi-brand jewelry retail stores. It distinguishes itself sharply in the very source of the jewels – they are grown above the earth. A state of the art facility uses cutting edge technology in an environment that mimics nature below the earth. PGD is built on an intensely sharp competitive advantage – ability to produce very high quality Type IIa diamonds that can go upto 5 carat stone in cut and polished form. Since these diamonds are sustainably grown above earth with fair production practices, they are ethical in the truest sense and leave a significantly smaller carbon footprint when compared to mined diamonds. OUR PRODUCT Pure Grown Diamonds are grown above the earth using cutting-edge technology that allows consistent production of high quality, stunning Type IIa diamonds with unmatched brilliance. Our diamonds range go up to 5 carats, making them the perfect representation of the unique relationship the couple shares. We offer a variety of loose diamonds and finished jewelry. What are Type IIa diamonds? Diamond is 99.95 percent carbon. The other 0.05 percent can include one or more trace elements, or impurities, which are atoms that aren’t part of the diamond’s essential chemistry. Diamond type is a method of scientifically classifying diamonds, both grown and mined, by the level and type of their chemical impurities. Extremely rare in nature, Type IIa diamonds account for less than 2% of the world’s mined diamonds. -
A Defect Study and Classification of Brown Diamonds with Deformation
minerals Article A Defect Study and Classification of Brown Diamonds with Deformation-Related Color Thomas Hainschwang 1,*, Franck Notari 2 and Gianna Pamies 1 1 GGTL Laboratories, Gnetsch 42, 9496 Balzers, Liechtenstein; [email protected] 2 GGTL Laboratories, 2 bis route des Jeunes, 1227 Geneva, Switzerland; [email protected] * Correspondence: [email protected]; Tel.: +423-262-24-64 Received: 3 September 2020; Accepted: 7 October 2020; Published: 12 October 2020 Abstract: For this study, the properties of a large sample of various types of brown diamonds with a deformation-related (referred to as “DR” in this work) color were studied to properly characterize and classify such diamonds, and to compare them to pink to purple to red diamonds. The acquisition of low temperature NIR spectra for a large range of brown diamonds and photoexcitation studies combined with various treatment experiments have opened new windows into certain defect characteristics of brown diamonds, such as the amber centers and naturally occurring H1b and H1c centers. It was determined that the amber centers (referred to as “AC” in this work) exhibit rather variable behaviors to annealing and photoexcitation; the annealing temperature of these defects were determined to 1 range from 1150 to >1850 ◦C and it was found that the 4063 cm− AC was the precursor defect of many other ACs. It is suggested that the amber centers in diamonds that contain at least some C centers are essentially identical to the ones seen in diamonds without C centers, but that they likely have a negative charge. -
Large Man-Made Diamond Single Crystals: Manufacture, Properties and Application
Large man-made diamond single crystals: manufacture, properties and application Dr. Sergey A.Terentjev , the head of Department of Single Crystal Growth. Technological Institute for Superhard and Novel Carbon Materials ( ТISN СМ ) E-mail: Diamond is a material possessing a unique complex of physical and chemical properties which potentially allow using it, besides traditional application in the processing industry, in Hi- Tech branches also. Such use of diamond restrains by insufficient quantity of natural perfect raw material of so-called "device" quality. Single crystals of diamond grown up in laboratory conditions differ from natural, first of all, in high reproducibility of physical properties (impurities level, an optical transparency, heat conductivity, specific electric resistance, etc.). Creation of technologies for cultivation a high purity «nitrogen free» (IIa type) and semi- conductor (IIb type) large diamond single crystals, which are extremely rare among natural diamonds and very expensive, is of the great interest and simultaneously of the greatest difficulty. Technologies for manufacture of both IIa and IIb diamond single crystals 0.5 to 5.0 carat in weight (characteristic size 3÷8 mm) from solvent/catalyst melt of transitive metals at high static pressures and temperatures (based on a temperature gradient growth technique) have been developed by Dr. Terentiev’s research team some years ago and successfully introduced in industrial department of ТISN СМ . Man-made IIa type single crystals are characterized by an optical transparency in a less than 25 µm wave lengths region and have fundamental absorption edge at 225 nanometers. Their thermal conductivity reaches 2000 Wt/m• К. Nitrogen concentration (a basic impurity element) level does not exceed 2 рр m (usually less than 1 рр m). -
Method of Making Synthetic Diamond Film
Europaisches Patentamt European Patent Office © Publication number: 0 597 445 A2 Office europeen des brevets EUROPEAN PATENT APPLICATION © Application number: 93118150.7 int. Ci.5; C23C 16/00, C23C 16/26 @ Date of filing: 09.11.93 ® Priority: 10.11.92 US 973994 32 Cornell Street Arlington, MA 02174(US) @ Date of publication of application: Inventor: Frey, Robert M. 18.05.94 Bulletin 94/20 77 Santa Isabel Nr.2-14 Laguna Vista, Texas 78578(US) © Designated Contracting States: DE FR GB 0 Representative: Diehl, Hermann, Dr. © Applicant: NORTON COMPANY Dipl.-Phys. et al 1 New Bond Street DIEHL, GLASER, HILTL & PARTNER Worcester, MA 01615-0008(US) Patentanwalte Fluggenstrasse 13 @ Inventor: Simpson, Matthew D-80639 Munchen (DE) © Method of making synthetic diamond film. © The invention describes a method for making a free-standing synthetic diamond film of desired thickness, comprising the steps of: no SELECT TARGET providing a substrate; X THICKNESS OF DIAMOND selecting a target thickness of diamond to be TO BE PRODUCED produced, said target thickness being in the range 200 urn to 1000 urn; finishing a surface of the substrate to a rough- 1 20 finish surface of ness, RA that is a function of the target thickness, substrate to prescribed said roughness being determined from ra Roughness 0.38t/600 urn ^ Ra = 0.50 urn 200 urn < t ^ 600 urn 0.38 urn ^ Ra = 0.50 urn 600 urn < t < 1000 1 30, urn DEPOSIT INTERLAYER where t is the target thickness; said the inter- CM depositing an interlayer on substrate, layer having a thickness in the range 1 to 20 urn; depositing synthetic diamond on said interlayer, by I40.