Chapter 5 Treatment and Disposal of Hazardous Waste
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Combustion, Thermal Treatment, & Air Pollution Control Engineering
Call us today at 865.694.7517 | Email: [email protected] Web: www.focusenv.com Combustion, Thermal Treatment, & Air Pollution Control Engineering Capabilities OVERVIEW evaluate fans, ductwork, hooding, and general air Focus personnel have extensive experience in the handling systems. design, evaluation, and operation of combustion Emissions Estimates and Waste Characterization systems and associated air pollution control equipment for our clients. This Focus engineers have extensive experience estimating capability extends to emissions from processes including estimation of virtually all kinds of removal efficiencies across various types of air processes and air pollution control systems using both theoretical and pollution control real world estimation techniques. Focus maintains a equipment. Hands-on stack testing database to verify emissions estimates experience enables us to very effectively evaluate and generated for specific applications. These estimates recommend alternative/comparable energy sources as form the basis for air permit applications and design. well as troubleshoot combustion problems and air For the proper design of any treatment system, an pollution control equipment. accurate accounting of all process inputs is an Focus has experience with the following combustion essential requirement. Focus has developed special equipment applications: expertise and engineering analytical tools to ensure emissions and wastes are adequately characterized, Hospital / Medical / Infectious Waste Incinerators categorized, and inventoried. -
The Complete Chemical Storage Guide for Wastewater Treatment
The Complete Chemical Storage Guide for Wastewater Treatment How to build effective storage solutions for chemicals commonly used in the wastewater treatment process Introduction In addition to physical treatment (such as screening and filtering processes) and biological treatment (which includes oxidation ponds and lagoons), chemicals are essential in wastewater treatment. Wastewater treatment requires even more aggressive usage and larger amounts of chemicals than municipal drinking water treatment. As a result, proper and safe storage of the chemicals used in the wastewater treatment process is always an important consideration. This guide was developed to address common chemical storage challenges found in wastewater treatment and to provide sensible storage solutions. In the first section, we outline the five steps of a wastewater treatment process, as well as the common chemicals involved in each step. In the second section, you’ll learn more about each chemical, along with its appropriate storage considerations. Contact Us at 877-591-4827 www.polyprocessing.com E-MAIL: [email protected] Table of CONTENTS The Roles of Chemicals in the Wastewater 3 Starting with the Chemical–Tailored Storage for Lifetime Cost Savings 4 Sodium Hypochlorite 5 Sulfuric Acid 6 Ferric Chloride, Aluminum Chloride, and Polymers 7 Sodium Hydroxide 8 Hydrochloric Acid 9 How to Build the Perfect Storage System for Your Wastewater Application 10 About Poly Processing 10 p. 2 The Roles of Chemicals in the Wastewater Treatment Process Removing Solid Particles To facilitate the removal of solid particles within wastewater, chemicals such as ferric chloride, polymers, and alums are used to produce positive charges. These are intended to neutralize negatively charged solid particles. -
Health Effects of Residence Near Hazardous Waste Landfill Sites: a Review of Epidemiologic Literature
Health Effects of Residence Near Hazardous Waste Landfill Sites: A Review of Epidemiologic Literature Martine Vrijheid Environmental Epidemiology Unit, Department of Public Health and Policy, London School of Hygiene and Tropical Medicine, London, United Kingdom This review evaluates current epidemiologic literature on health effects in relation to residence solvents, polychlorinated biphenyls (PCBs), near landfill sites. Increases in risk of adverse health effects (low birth weight, birth defects, certain and heavy metals, have shown adverse effects types of cancers) have been reported near individual landfill sites and in some multisite studies, on human health or in animal experiments. and although biases and confounding factors cannot be excluded as explanations for these A discussion of findings from either epi findings, they may indicate real risks associated with residence near certain landfill sites. A general demiologic or toxicologic research on health weakness in the reviewed studies is the lack of direct exposure measurement. An increased effects related to specific chemicals is beyond prevalence of self-reported health symptoms such as fatigue, sleepiness, and headaches among the scope of this review. residents near waste sites has consistently been reported in more than 10 of the reviewed papers. It is difficult to conclude whether these symptoms are an effect of direct toxicologic action of Epidemiologic Studies on chemicals present in waste sites, an effect of stress and fears related to the waste site, or an Health Effects of Landfill Sites risks to effect of reporting bias. Although a substantial number of studies have been conducted, The majority of studies evaluating possible is insufficient exposure information and effects health from landfill sites are hard to quantify. -
Integrated Thermal Treatment Systems Study U.S. Department of Energy Internal Review Panel Report
DOE/EM —0268-96003365 Integrated Thermal Treatment Systems Study U.S. Department of Energy Internal Review Panel Report April 1995 Cudahy, J. Escarda, T. Gimpel, R. Huffman, G. Kolts, J. Musgrave, D. Peters, R. Seeker, R. Swartz, V. Torbert, M. Vavruska, J. U.S. Department of Energy Assistant Secretary for Environmental Management r 5 j Office of Technology Development - •* « ,^ ~ r i" • x Washington DC, 20585 j "^ ' [^ , DISTRIBUTION OF THIS DOCUMENT IS UNLIMITED INTEGRATED THERMAL TREATMENT SYSTEMS STUDY INTERNAL REVIEW PANEL REPORT EXECUTIVE SUMMARY The U.S. Department of Energy's (DOE's) Office of Technology Development (OTD) commissioned two studies to uniformly evaluate nineteen thermal treatment technologies. These studies were called the Integrated Thermal Treatment System (ITTS) Phase I and Phase II. With the advice and guidance of the DOE Office of Environmental Management's (EM's) Mixed Waste Focus Group, OTD formed an ITTS Internal Review Panel, composed of scientists and engineers from throughout the DOE complex, the U.S. Environmental Protection Agency (EPA), the California EPA, and private experts. The Panel met from November 15-18, 1994, to review and comment on the ITTS studies, to make recommendations on the most promising thermal treatment systems for DOE mixed low level wastes (MLLW), and to make recommendations on research and development necessary to prove the performance of the technologies on MLLW. The ITTS evaluated thermal treatment technologies integrated into systems that could likely be implemented as regional treatment facilities for MLLW typical of that in the DOE complex. The Panel's primary observations are: Thermal Treatment Technologies • The integrated systems that appear to have the most versatility (capability to treat a wide variety of waste) include variations of the rotary kiln, plasma arc, and direct vitrification. -
Possibilities for Reducing CO and TOC Emissions in Thermal Waste Treatment Plants: a Case Study
energies Article Possibilities for Reducing CO and TOC Emissions in Thermal Waste Treatment Plants: A Case Study Janusz Bujak 1,*, Piotr Sitarz 2 and Rafał Pasela 1 1 Faculty of Environmental Engineering, University of Science and Technology in Bydgoszcz, Kaliskiego 7, 85-796 Bydgoszcz, Poland; [email protected] 2 PPM PROMONT Bujak Sp. z o.o.—Sp. K., Bydgoszcz, Jagiello´nska35, 85-097 Bydgoszcz, Poland; [email protected] * Correspondence: [email protected] or [email protected]; Tel.: +48-501-541185; Fax: +48-523-220853 Abstract: The technology of waste-management thermal processing may pose a threat to the natural environment through the emission of harmful substances, such as CO, NOx, SO2, HCl, HF, total organic carbon (TOC) and dust, as well as dioxins and furans. Due to the advantages of thermal waste treatment, including the small volume of solid residue produced and possible thermal energy recovery, thermal waste treatment is widely applied. Continuous research is necessary to develop methods for reducing the risk of harmful substances being produced and methods for the effective removal of pollutants resulting from flue gases. This paper presents an analysis of the results and conditions of the experimental redesign of a thermal industrial waste (polypropylene) treatment plant. The purpose of the redesign was to improve the quality of gasification and afterburning processes taking place in the combustion and afterburner chambers (through the installation of an additional section), thus resulting in a reduction in the concentrations of CO and total organic carbon (TOC) in flue gases. The research concerned a facility implementing the combustion process on an industrial scale. -
Chapter 9 Agricultural Waste Management Systems
Part 651 Agricultural Waste Management Field Handbook Chapter 9 Agricultural Waste Management Systems (210–VI–AWMFH, Amend. 47, December 2011) Chapter 9 Agricultural Waste Management Systems Part 651 Agricultural Waste Management Field Handbook Issued December 2011 The U.S. Department of Agriculture (USDA) prohibits discrimination in all its programs and activities on the basis of race, color, national origin, age, disability, and where applicable, sex, marital status, familial status, parental status, religion, sexual orientation, genetic information, political beliefs, reprisal, or because all or a part of an individual’s income is derived from any public assistance program. (Not all prohibited bases apply to all pro- grams.) Persons with disabilities who require alternative means for commu- nication of program information (Braille, large print, audiotape, etc.) should contact USDA’s TARGET Center at (202) 720-2600 (voice and TDD). To file a complaint of discrimination, write to USDA, Director, Office of Civil Rights, 1400 Independence Avenue, SW., Washington, DC 20250–9410, or call (800) 795-3272 (voice) or (202) 720-6382 (TDD). USDA is an equal opportunity provider and employer. (210–VI–AWMFH, Amend. 47, December 2011) Acknowledgments Chapter 9 was originally prepared and printed in 1992 under the direction of James N. Krider (retired), national environmental engineer, Soil Conser- vation Service (SCS), now Natural Resources Conservation Service (NRCS). James D. Rickman (retired), environmental engineer, NRCS, Fort Worth, Texas, provided day-to-day coordination in the development of the hand- book. Authors for chapter 9 included L.M. “Mac” Safley, North Carolina State University, Raleigh, NC; William H. Boyd, environmental engineer, Lincoln, Nebraska; A. -
Chemical Waste Disposal
Unknown Chemical Waste Disposal An unknown is defined as a chemical in an unlabeled container for which the identity is unknown. Federal, state and local regulations specifically prohibit the transportation, storage, or disposal of wastes of unknown identity. In addition, hazardous waste disposal companies will not accept unknowns without proper analysis. Unknown or unlabeled chemicals require analysis prior to disposal Unknown chemicals present serious legal and safety problems for the university. The process for identifying an unknown chemical can be tedious and costly. However, some activities can be done to prevent the generation of an unknown as well as identifying an. Unknown chemicals must be properly identified according to hazard class before proper disposal. The hazards that should be noted include: corrosive, ignitable, oxidizer, reactive, toxic and radioactive. Every effort should be made by laboratory personnel to identify unknown chemicals. Here are a few steps that can be taken to help this effort: 1. Consult with the Principal Investigator (PI) or Supervisor/Manager about the type of work that was being conducted. 2. Ask other laboratory personnel if they are responsible for, or can help identify the unknown chemical. Someone may remember its contents 3. The type of research currently being conducted in the laboratory can provide useful information for making this determination. Eliminating certain chemicals as a possibility helps narrow the problem as well. This is especially important for Mercury, PCB, or dioxin compounds because they must be managed separately from other hazardous waste. 4. Contact groups that previously used the area and see if they can recall the waste’s identity. -
Sewage Sludge and Wastewater for Use in Agriculture
IAEA-TECDOC-971 Sewage sludge and wastewater for use in agriculture Proceedings of consultants meetings organized by the Joint FAO/IAEA Division of Nuclear Techniques in Food and Agriculture and the IAEA Division Physicalof Chemicaland Sciences, and held Vienna,in December5-9 1994 <> INTERNATIONAL ATOMIC ENERGY AGENCY The IAEA does not normally maintain stocks of reports in this series. However, microfiche copies of these reports can be obtained from IN IS Clearinghouse International Atomic Energy Agency Wagramerstrasse 5 P.O. Box 100 A-1400 Vienna, Austria Orders shoul accompaniee db prepaymeny db f Austriao t n Schillings 100, in the form of a cheque or in the form of IAEA microfiche service coupons which may be ordered separately from the INIS Clearinghouse. The originating Sections of this publication in the IAEA were Soil Fertility, Irrigatio Crod nan p Production Section Joint FAO/IAEA Division and Industrial Application Chemistrd san y Section International Atomic Energy Agency Wagramerstrasse5 PO Box 100 A-1400 Vienna, Austria SEWAGE SLUDG WASTEWATED AGRICULTUREN AN I E US R RFO E IAEA, VIENNA, 1997 IAEA-TECDOC-971 ISSN 1011-4289 ©IAEA, 1997 Printed by the IAEA in Austria October 1997 FOREWORD Wastes have been produced by mankind since ancient nomadic tribes settled into villages and started utilizing cultivatinfird ean g land. Archaeological evidence trace practice sth wastf eo e disposal back to antiquity. However, the concept of community-wide systematic collection, treatment, and disposa solif o l d waste wastewated san t evolvno d erdi unti late th le 19th century. The disposal of sewage sludge is a serious problem in many countries due to rapid urbanization Agriculture offers one solution: land application of municipal sewage sludge is practised throughout the world, with beneficial effects on crop yields, soil organic matter, cation exchange capacity, water holding capacit soid yan l fertilit generalym . -
Compliance Tools
HazCom 30 CFR Part 47 Telling Miners About Chemi cal Hazards ♦ U.S. Depart ment of Labor Mine Safety and Health Admin is tra tion Other Training Mate rial OT 49 July 2002 ~ ffi~te fill CORROSIVE MATERIALS EYEWASH ~ GASOLINE FOUNTAIN ft _____, TOXIC VAPORS Visit our web site at http://www.msha.gov HazCom 30 CFR Part 47 Telling Miners About Chemi cal Hazards U. S. Depart ment of Labor Elaine L. Chao Sec re tary Mine Safety and Health Admin is tra tion Dave D. Lauriski As sis tant Secre tary Other Training Mate rial OT 49 July 2002 HazCom Tool Kit Welcome to the Hazard Communication (HazCom) Tool Kit. This package is designed to help you develop an effective, mine-specific HazCom program that meets the provisions of Part 47. This package is divided into eight sections. These sections contain information you can copy or customize to meet your needs. You may want to put this material in a three-ring binder. Let’s take a brief look at each section. Introduction - Brief review of the rule with important dates to remember Hazard Determination HazCom Program Labeling Material Safety Data Sheets (MSDSs) HazCom Training Contacts for HazCom Assistance HazCom Rule 1 HazCom HELP IS AS CLOSE AS… Your Telephone MSHA District & Field Offices State Grants Program (See Section on HazCom Assistance) EFS Eastern U.S. Toll Free 1-800-678-6746 EFS Western U.S. Toll Free 1-800-579-2647 Your Computer Information available on the internet: www.msha.gov Your Local Field Office MSHA inspection and educational field services staff will be distributing compliance assistance materials to your site. -
In Situ Thermal Treatment Methods
United States Office of Solid Waste and EPA 542-F-01-012 Environmental Protection Emergency Response May 2001 Agency (5102G) www.epa.gov/superfund/sites www.cluin.org A Citizen’s Guide to In Situ Thermal Treatment Methods EPA uses many methods to clean up pollution at Superfund and other sites. Some, like in situ thermal treatment methods, are considered new or innovative. Such methods can be quicker and cheaper than more common methods. If you live, work, or go to school near a Superfund site, you may want to learn more about cleanup methods. Perhaps they are being used or are proposed for use at your site. How do they work? Are they safe? This Citizen’s Guide is one in a series to help answer your questions. ? What are in situ thermal treatment methods? In situ thermal treatment methods, in general, are ways to move or mobilize harmful chemicals through soil and groundwater by heating them. The heated chemicals move through the soil and ? groundwater toward underground wells where they are collected and piped to the ground surface. There the chemicals can be treated above ground by one of the many cleanup methods available. How do they work? All thermal methods work by heating polluted soil and groundwater. The heat helps push chemicals through the soil toward collection wells. The heat also can destroy or evaporate certain types of chemicals. When they evaporate, the chemicals change into gases, which move more easily through the soil. Collection wells capture the harmful chemicals and gases and pipe them to the ground surface for cleanup. -
LCA of Thermal Conversion of Poultry Litter at BMC Moerdijk
LCA of thermal conversion of poultry litter at BMC Moerdijk LCA of thermal conversion of poultry litter at BMC Moerdijk Authors: Lonneke de Graaff Ingrid Odegard Sanne Nusselder Delft, CE Delft, March 2017 Publication code: 17.2H94.01 Energy technology / Biomass / Animal manure / Poultry/ Thermal treatment / Electricity / Ash / LCA / Environmental factors Commissioned by: BMC Moerdijk All public CE publications are available at www.cedelft.eu More information on this study can be obtained from the project leader Lonneke de Graaff. © copyright, CE Delft, Delft CE Delft Committed to the Environment CE Delft draagt met onafhankelijk onderzoek en advies bij aan een duurzame samenleving. Wij zijn toonaangevend op het gebied van energie, transport en grondstoffen. Met onze kennis van techniek, beleid en economie helpen we overheden, NGO’s en bedrijven structurele veranderingen te realiseren. Al 35 jaar werken betrokken en kundige medewerkers bij CE Delft om dit waar te maken. 1 March 2017 – LCA of thermal conversion of poultry litter at BMC Moerdijk Contents Summary 5 1 Introduction 12 2 Methodology 13 2.1 Aim and intended readership 13 2.2 ISO standard 13 2.3 Function and functional unit 14 2.4 Routes 14 2.5 System boundaries 16 2.6 Environmental impact categories 17 2.7 LCA method – further scope definition 18 2.8 Nutrient balance method 19 2.9 Software and databases 20 3 Inventory and data quality 21 3.1 Carbon fixation inventory 21 3.2 Fertilizer substitution inventory 22 3.3 Inventory and data quality per route 23 4 Nutrient balance 27 -
Tobacco Product Waste: Frequently Asked Questions
August 2020 TOBACCO PRODUCT WASTE: FREQUENTLY ASKED QUESTIONS Many discarded commercial tobacco1 products and their packaging are toxic to both human and environmental health, often due to overlapping and cumulative toxicity impacts. For example, cigarette filters, or “butts,” are made of the plastic material cellulose acetate, which does not biodegrade, but merely breaks down into microplastics, moving deeper into the food chain and water supply. Used cigarette butts are known to leach toxic amounts of nicotine, pesticides, polycyclic aromatic hydrocarbons, arsenic, and heavy metals such as lead and cadmium, potentially for years after use. Even unsmoked cigarette butts are toxic to animals, plants and aquatic life.2 Recent research also shows that smoked butts create localized air pollution long after use. In addition to cigarettes, emerging tobacco products, such as e-cigarettes, create many public health and environmental problems. The United States Environmental Protection Agency of liquid nicotine in e-cigarettes has resulted (EPA) has listed nicotine chemical waste as in significant health harms. Since 2007, when an acute hazardous waste since 1980. The use e-cigarettes were first introduced to the U.S. www.publichealthlawcenter.org/caltobacco August 2020 market, the nation has seen a substantial increase in poisonings of young children from nicotine e-liquids. Between 2012 and 2015, the National Poison Data System recorded a 1,500 percent increase in nicotine poisonings of children under the age of six, and one documented nicotine- caused death in 2014. Furthermore, discarded devices may leach lead, cobalt, and other substances into the environment in toxic amounts. Toxic chemicals from commercial tobacco product waste can accumulate in animals, soil, and aquatic ecosystems, contaminating drinking water and foods, posing additional downstream risks to human health and the environment.