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Chemistry of the Corrosion of Metals in Presence of Molten Vanadium Pentoxide
CHEMISTRY OF THE CORROSION OF METALS IN PRESENCE OF MOLTEN VANADIUM PENTOXIDE THESIS Submitted for the Degree of DOCTOR OF PHILOSOPHY THE UNIVERSITY OF LONDON by KAILATHUVALAPPIL INNIRI VASU February, 1964 Department of Metallurgy, Royal School of Mines, Imperial College, London, S.W.7. The author is grateful to Dr. D. A. Pantony, who supervised this research project, for his constant encouragement, numerous suggestions and stimulating discussions; to his colleagues and the members of the teaching and technical staff of the Department of Metallurgy, Imperial College, for their helpful co—operation; and to the British Petroleum Company Limited for financial assistance. CONTENTS ABSTRACT NOMENCLATURE vi I. INTRODUCTION A. HISTORY 1 B. NATURE OF CORROSION 2 C. ACTIVATION - AND DIFFUSION - CONTROLLED PROCESSES 4 D. RELEVANT PREVIOUS INVESTIGATIONS 6 E. APPROACH TO THE PROBLEM 9 (a) PHYSICAL-CHEMICAL STUDIES ON VANADIC MELTS (1)Dissociation Equilibrium 10 (2)Kinetics of the Oxidation of Vanadium Dioxide 11 (3)Cryoscopy 11 (4)Conductivity of Vanadic Melts 11 (5)Viscosity and Density 12 (b) CORROSION OF METALS IN THE PRESENCE OF MOLTEN VANADIUM PENTOXIDE (1)General Nature 12 (2)In Relation to Gas-Turbine Corrosion 13 (3)A Model for Study 14 (3a) The Corrosion Layer 19 (4)Metal Surface and Corrosion 23 (5)Prevention of Corrosion 23 II. EXPERIMENTAL A. MATERIALS (a)Vanadium Pentoxide 25 (b)Metals 25 (c)Metal Oxides 27 (d)Oxygen, Nitrogen, and Oxygen- Nitrogen Mixtures 28 B. SPECIMENS FOR CORROSION STUDIES 30 C. EXPERIMENTAL PROCEDURE (a)Container -
S42004-019-0231-3.Pdf — Adobe
ARTICLE https://doi.org/10.1038/s42004-019-0231-3 OPEN Niobium pentoxide nanomaterials with distorted structures as efficient acid catalysts Kai Skrodczky1, Margarida M. Antunes2, Xianying Han1, Saveria Santangelo 3, Gudrun Scholz1, Anabela A. Valente 2*, Nicola Pinna 1* & Patrícia A. Russo1* 1234567890():,; Niobium pentoxides are promising acid catalysts for the conversion of biomass into fuels and chemicals. Developing new synthesis routes is essential for designing niobium pentoxide catalysts with improved activity for specific practical processes. Here we show a synthesis approach in acetophenone, which produces nanostructured niobium pentoxides with varying structure and acidity that act as efficient acid catalysts. The oxides have orthorhombic structures with different extents of distortions and coordinatively unsaturated metal atoms. A strong dependence is observed between the type and strength of the acid sites and specific structural motifs. Ultrasmall niobium pentoxide nanoparticles, which have strong Brønsted acidity, as well as Lewis acidity, give product yields of 96% (3 h, 140 °C, 100% conversion), 85% (3 h, 140 °C, 86% conversion), and 100% (3 h, 110 °C, 100% conversion) in the reac- tions of furfuryl alcohol, 5-(hydroxymethyl)furfural, and α-angelica lactone with ethanol, respectively. 1 Institut für Chemie and IRIS Adlershof, Humboldt-Universität zu Berlin, Berlin, Germany. 2 Department of Chemistry, CICECO, University of Aveiro, Aveiro, Portugal. 3 Dipartimento di Ingegneria Civile, dell’Energia, dell’Ambiente e dei Materiali (DICEAM), Università “Mediterranea”, Reggio Calabria, Italy. *email: [email protected]; [email protected]; [email protected] COMMUNICATIONS CHEMISTRY | (2019) 2:129 | https://doi.org/10.1038/s42004-019-0231-3 | www.nature.com/commschem 1 ARTICLE COMMUNICATIONS CHEMISTRY | https://doi.org/10.1038/s42004-019-0231-3 iobium pentoxides show high potential as acid catalysts will also allow getting insights into the structure–acidity–activity Nfor the sustainable production of fuels and chemicals from relationships. -
Enrichment Strategies for Phosphoproteomics: State-Of-The-Art
Rev Anal Chem 31 (2012): 29–41 © 2012 by Walter de Gruyter • Berlin • Boston. DOI 10.1515/revac-2011-0025 Enrichment strategies for phosphoproteomics: state-of-the-art Barbora Salovska 1,2, *, Ales Tichy 1,2 , Martina MIP molecularly imprinted polymer Rezacova 1 , Jirina Vavrova 2 and Eva Novotna 2 MOAC metal oxide affi nity chromatography MS mass spectrometry 1 Department of Medical Biochemistry , Faculty of NTA nitriloacetic acid Medicine in Hradec Kralove, Charles University in PTMs post-translational modifi cations Prague, Hradec Kr á lov é , Czech Republic , pS phosphoserine e-mail: [email protected] pT phosphothreonine 2 Department of Radiobiology , Faculty of Military Health pY phosphotyrosine Sciences, University of Defence, Hradec Kralove , RPLC reversed phase liquid chromatography Czech Republic SAX strong anion-exchange chromatography SCX strong cation-exchange chromatography * Corresponding author Introduction Abstract Protein phosphorylation is a key regulator in many biological The human genome involves approximately 30,000 protein- processes, such as homeostasis, cellular signaling and com- coding genes; the human proteome contains several million munication, transcriptional and translational regulation, and different protein effectors. This is due to alternative splic- apoptosis. The defects in this tightly controlled reversible post- ing of genes and post-translational modifi cations (PTMs). translational modifi cation have been described to contribute Several hundred PTMs are currently known, among them to genesis and -
Short Description of the Gulaim Seisenbaeva´S Research Profile
Short description of the Gulaim Seisenbaeva´s research profile My research work has always been concentrated on development of chemical synthetic approaches to new materials, aiming to influence purpose characteristics of the material by varying chemical and physicochemical parameters of its synthesis. In my projects I am always trying to trace and understand the transformation from molecular precursors to materials with desired properties. The focus of my work is in the search for Molecular Chemistry approaches to nano-level defined materials. During the work at SLU for the last 18 years my research became strongly directed toward the use of bio-based materials and to applications in the Green Sector in the domains of environmental science and protection of the environment, bio-energy and bio-catalysis. My original scientific training was in the field of chemical technology and heterogeneous catalysis. In my Master Thesis entitled “Applied ruthenium and copper-ruthenium catalysts in the liquid phase hydrogenation reactions” I investigated thermal decomposition of metal complexes at different temperatures and the influence of decomposition temperature on the activity of prepared catalysts [1]. Since then I have become interested in molecular chemistry tools for production of functional solid materials, in particular, thermal decomposition mechanisms and their influence on morphology and chemical composition of the resulting products. The Ph.D. research work, “Tricarboxylatouranylates(VI) of protonated amines”, was devoted to the development of synthetic approaches to anionic carboxylate complexes of uranium(VI), and investigation of their thermal decomposition mechanisms leading to formation of highly disperse uranium dioxide for application in nuclear fuel blocks. There have been developed general approaches to the synthesis of anionic carboxylate complexes of uranium(VI) using interaction of uranyl carboxylates with hydrated amines in aqueous solutions of carboxylic acids. -
Niobium(V) Oxide Patinal®
Product Information Niobium(V) Oxide Patinal ® GENERAL INFORMATION Niobium pentoxide is especially suited for IAD processes and a suitable alternative to TiO 2 with its high refractive index and low absorption. However the layers may show some absorption when deposited by conventional thermal evaporation. Similar to tantalum pentoxide, niobium pentoxide emits oxygen during melting and evaporation, requiring reactive evaporation. Due to the similarities in the process for those two materials, Nb 2O5 is a close alternative to Ta 2O5 and, in contrary to tantalum, not included on the list of “conflict minerals” mentioned in the Dodd-Franck Wall Street Reform and Consumer Protection Act. AREAS OF APPLICATION • Multi-layer coatings for laser mirrors and beam splitters • Anti-reflection coatings on glass in VIS and NIR THIN FILM PROPERTIES Chemical Formula Nb 2O5 Range of Transparency 380 nm – 7 µm Refractive index at 500 nm • conventional T s = 300 °C / no IAD ~ 2.25 – 2.30 • IAD – Ts = RT ~ 2.30 – 2.35 Thin film stress Compressive The optical properties of the thin film are strongly dependent on the deposition rate, substrate temperature and oxygen partial pressure. Strict control of these parameters allows excellent reproducibility. wavl / nm 375 450 550 700 900 1200 n - IAD 2.495 2.341 2.266 2.220 2.196 2.181 k - IAD 2.5E-03 4.6E-04 2.0E-04 1.1E-04 6.9E-05 4.6E-05 Status: 02 / 2018, Page 1 of 4 EMD Performance Materials* One International Plaza Suite 300 / Philadelphia, PA / 19113 USA +888 367 3275 / [email protected] / patinal.com -
Experimental Studies on the Dynamic Memcapacitance Modulation of the Reo3@Res2 Composite Material-Based Diode
nanomaterials Article Experimental Studies on the Dynamic Memcapacitance Modulation of the ReO3@ReS2 Composite Material-Based Diode Joanna Borowiec 1,2,* , Mengren Liu 3 , Weizheng Liang 4, Theo Kreouzis 2 , Adrian J. Bevan 2 , Yi He 1, Yao Ma 1 and William P. Gillin 1,2 1 College of Physics, Sichuan University, Chengdu 610064, China; [email protected] (Y.H.); [email protected] (Y.M.); [email protected] (W.P.G.) 2 Materials Research Institute and School of Physics and Astronomy, Queen Mary University of London, Mile End Road, London E1 4NS, UK; [email protected] (T.K.); [email protected] (A.J.B.) 3 Sichuan University—Pittsburgh Institute, Chengdu 610207, China; [email protected] 4 The Peac Institute of Multiscale Sciences, Chengdu 610031, China; [email protected] * Correspondence: [email protected]; Tel.: +86-028-854-12323 Received: 4 October 2020; Accepted: 19 October 2020; Published: 23 October 2020 Abstract: In this study, both memcapacitive and memristive characteristics in the composite material based on the rhenium disulfide (ReS2) rich in rhenium (VI) oxide (ReO3) surface overlayer (ReO3@ReS2) and in the indium tin oxide (ITO)/ReO3@ReS2/aluminum (Al) device configuration is presented. Comprehensive experimental analysis of the ReO3@ReS2 material properties’ dependence on the memcapacitor electrical characteristics was carried out by standard as well as frequency-dependent current–voltage, capacitance–voltage, and conductance–voltage studies. Furthermore, determination of the charge carrier conduction model, charge carrier mobility, density of the trap states, density of the available charge carrier, free-carrier concentration, effective density of states in the conduction band, activation energy of the carrier transport, as well as ion hopping was successfully conducted for the ReO3@ReS2 based on the experimental data. -
Niobium Pentoxide Based Materials for High Rate Rechargeable Electrochemical Energy Storage Cite This: Mater
Materials Horizons View Article Online REVIEW View Journal | View Issue Niobium pentoxide based materials for high rate rechargeable electrochemical energy storage Cite this: Mater. Horiz., 2021, 8, 1130 Fei Shen,a Zhongti Sun,ab Qinggang He, *c Jingyu Sun, abd Richard B. Kaner *e and Yuanlong Shao*abd The demand for high rate energy storage systems is continuously increasing driven by portable electronics, hybrid/electric vehicles and the need for balancing the smart grid. Accordingly, Nb2O5 based materials have gained great attention because of their fast cation intercalation faradaic charge storage that endows them with high rate energy storage performance. In this review, we describe the crystalline features of the five main phases of Nb2O5 and analyze their specific electrochemical characteristics with an emphasis on the intrinsic ion intercalation pseudocapacitive behavior of T-Nb2O5. The charge Received 14th September 2020, storage mechanisms, electrochemical performance and state-of-the-art characterization techniques for Accepted 9th December 2020 Nb2O5 anodes are summarized. Next, we review recent progress in developing various types of Nb2O5 DOI: 10.1039/d0mh01481h based fast charging electrode materials, including Nb2O5 based mixed metal oxides and composites. Finally, we highlight the major challenges for Nb2O5 based materials in the realm of high rate rechargeable rsc.li/materials-horizons energy storage and provide perspectives for future research. 1. Introduction Due to the increasing demand for rapid charging and high power a College of Energy, Soochow Institute for Energy and Materials InnovationS delivery for portable electronics and electricvehicles,highrate (SIEMIS), Jiangsu Provincial Key Laboratory for Advanced Carbon Materials and energy storage systems (ESSs) that can store/release charge in Wearable Energy Technologies, Soochow University, 215006 Suzhou, P. -
Synthesis, Characterization of Nb2o5\Cdsnanocomposites, And
International Journal of ChemTech Research CODEN (USA): IJCRGG, ISSN: 0974-4290, ISSN(Online):2455-9555 Vol.9, No.10 pp 149-156, 2016 Synthesis, Characterization of Nb2O5\Cds Nanocomposites and Study of High Photo Catalytic Activity of Transition Metal Ion Zena T Omran, and Nada Y Fairooz* Department of Chemistry, College of Science, University of Babylon,Hilla-Iraq Abstract : This work includes the study of preparing the new Nb2O5/CdS coupled photocatalyst was prepare by wet commixing method at different ratios of (0.75:0.25, 0.6:0.4,0.5:0.5, 0.85:0.15,0:1 ,1:0) and calcinations at different temperature 200 0C,500 0C and8000C for4 hours .The prepared powder was characterized by X-ray diffraction, and Fourier Transform Technique (FT-IR).The photocatalytic activity was estimated under mercury high pressure lamp for degradation Co(NO3)2 solution after find the wavelength at λ max510nm . The result showed that (0.85:0.15) percentage at 800 0C has high activity than other ratio at different temperature. After this study some measure such as best of mass for the catalyst, initial of concentration for Co(NO3)2, effect of temperature, effect of PH. Keywords: Co(NO3)2, couple Nb2o5/CdS, Degradation, photocatalytic. Introduction: Niobium pentoxide (Nb2O5) is considered one of the most committed transition metal oxides (TMO) for 1 pseudocapacitive energy storage. Nb2O5 is to a great degreestudied in lithium-ion batteries (LIB) , electrochemical hydrogenation catalysts2.gas sensing3, electrochromic devices4 and solar cells5. Nb2O5 exhibits a different of crystalline allotropes,with orthorhombic (T-Nb2O5), pseudo-hexagonal 6,7 (TT-Nb2O5), tetragonal (M-Nb2O5) and monoclinic(H-Nb2O5) . -
1 Thermodynamic Evaluation of the Propensity of Niobium to Absorb
Thermodynamic Evaluation of the Propensity of Niobium to Absorb Hydrogen During Fabrication of Superconducting Radio Frequency Accelerator Cavities Richard E. Ricker Materials Performance Group Metallurgy Division Materials Science and Engineering Laboratory National Institute of Standards and Technology US Department of Commerce Gaithersburg, MD 20899-8553 ABSTRACT During the fabrication of niobium superconducting radio frequency (SRF) particle accelerator cavities procedures are used that chemically or mechanically remove the passivating surface film of niobium pentoxide (Nb2O5). Removal of this film will expose the underlying niobium metal and allow it to react with the processing environment. If these reactions produce hydrogen at sufficient concentrations and rates, then hydrogen will be absorbed and diffuse into the metal. High hydrogen activities could result in supersaturation and the nucleation of hydride phases. If the metal repassivates at the conclusion of the processing step and the passive film blocks hydrogen egress, then the absorbed hydrogen or hydrides could be retained and alter the performance of the metal during subsequent processing steps or in-service. This report examines the feasibility of this hypothesis by identifying the postulated events, conditions, and reactions and determining if each is consistent with accepted scientific principles, literature, and data. Established precedent for similar events in other systems was found in the scientific literature and thermodynamic analysis found that the postulated reactions were not only energetically favorable, but produced large driving forces. The hydrogen activity or fugacity required for the reactions to be at equilibrium was determined used to indicate the propensity for hydrogen evolution, absorption, and hydride nucleation. The influence of processing conditions and kinetics on the proximity of hydrogen surface coverage to these theoretical values is discussed. -
Formation of Niobium Oxides by Electrolysis from Acidic Aqueous Solutions on Glassy Carbon
Macedonian Journal of Chemistry and Chemical Engineering, Vol. 38, No. 1, pp. 39–48 (2019) MJCCA9 – 767 ISSN 1857-5552 e-ISSN 1857-5625 Received: November 13, 2018 DOI: 10.20450/mjcce.2019.1623 Accepted: February 1, 2019 Original scientific paper FORMATION OF NIOBIUM OXIDES BY ELECTROLYSIS FROM ACIDIC AQUEOUS SOLUTIONS ON GLASSY CARBON Nataša M. Vukićević1*, Vesna S. Cvetković1, Ljiljana S. Jovanović2, Miroslav M. Pavlović1, Jovan N. Jovićević1 1Institute of Chemistry, Technology and Metallurgy, National Institute, Department of Electrochemistry, University of Belgrade, Njegoševa 12, Serbia 2Faculty of Science, Department of Chemistry, Biochemistry and Environmental Protection, University of Novi Sad, Trg Dositeja Obradovića 3, Serbia [email protected] In this study niobium oxide films were formed without peroxo-precursors from three different mixed acidic aqueous solutions on glassy carbon. Linear sweep voltammetry and potential step were techniques used for electrochemical experiments. The simultaneous and consecutive electrochemical re- duction of water, nitrate and sulphate ions provided an alkaline environment with oxygen in the near vi- cinity of the working cathode, which in combination with the present niobium ions, produced niobium oxides and/or oxyhydroxides on the glassy carbon substrate. The formed deposits were analyzed using scanning electron microscopy and energy dispersive spectroscopy and appear to consist of NbO, NbO2 and Nb2O5. Both the niobium and acid concentration of the electrolytes used influenced the morphology and particle size of the deposits. The formation of niobium-fluoride and hydrogen-niobiumoxide com- plexes is addressed. Key words: electrochemical deposition; niobium oxides; acidic solution; glassy carbon ФОРМИРАЊЕ НА ФИЛМОВИ ОД ОКСИДИ НА НИОБИУМ СО ЕЛЕКТРОЛИЗА ОД КИСЕЛИ РАСТВОРИ НА СТАКЛЕСТА ГРАФИТНА ЕЛЕКТРОДА Во овој труд е изучувано формирањето на филмови на оксиди од ниобиум што се одвива без пероксидни медијатори од три различни водни раствори со различни рН вредности на стаклеста графитна електрода. -
Inorganic Chemistry
INORGANIC CHEMISTRY Saito Inorganic Chemistry Saito This text is disseminated via the Open Education Resource (OER) LibreTexts Project (https://LibreTexts.org) and like the hundreds of other texts available within this powerful platform, it freely available for reading, printing and "consuming." Most, but not all, pages in the library have licenses that may allow individuals to make changes, save, and print this book. Carefully consult the applicable license(s) before pursuing such effects. Instructors can adopt existing LibreTexts texts or Remix them to quickly build course-specific resources to meet the needs of their students. Unlike traditional textbooks, LibreTexts’ web based origins allow powerful integration of advanced features and new technologies to support learning. The LibreTexts mission is to unite students, faculty and scholars in a cooperative effort to develop an easy-to-use online platform for the construction, customization, and dissemination of OER content to reduce the burdens of unreasonable textbook costs to our students and society. The LibreTexts project is a multi-institutional collaborative venture to develop the next generation of open-access texts to improve postsecondary education at all levels of higher learning by developing an Open Access Resource environment. The project currently consists of 13 independently operating and interconnected libraries that are constantly being optimized by students, faculty, and outside experts to supplant conventional paper-based books. These free textbook alternatives are organized within a central environment that is both vertically (from advance to basic level) and horizontally (across different fields) integrated. The LibreTexts libraries are Powered by MindTouch® and are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. -
Ternary and Quaternary Phases in the Alkali-Earth - Rhenium - Oxygen System
Ternary and quaternary phases in the alkali-earth - rhenium - oxygen system Vom Fachbereich Material- und Geowissenschaften der Technischen Universität Darmstadt zur Erlangung des akademischen Grades eines Doktor rer. nat. genehmigte Dissertation angefertigt von Dipl.-Chem. Kirill G. Bramnik Berichterstatter: Prof. Dr. H. Fuess Mitberichterstatter: Prof. Dr. J. Galy Prof. Dr. H.M. Ortner Tag der Einreichung: 09.05.2001 Tag der mündlichen Prüfung: 07.06.2001 Darmstadt 2001 D 17 2 Моим родителям 3 1 INTRODUCTION ............................................................................................. 5 2 LITERATURE SURVEY.................................................................................. 7 2.1 STRUCTURAL CHEMISTRY OF TERNARY RHENIUM OXIDES................................. 7 2.2 SYNTHETIC PROBLEMS.................................................................................... 24 2.3 MAGNETIC AND ELECTRICAL PROPERTIES OF COMPLEX RHENIUM OXIDES ...... 26 3 EXPERIMENTAL........................................................................................... 30 3.1 POWDER DIFFRACTION.................................................................................... 30 3.1.1 X-ray powder diffraction...............................................................................................30 3.1.2 Neutron powder diffraction...........................................................................................30 3.2 ELECTRON DIFFRACTION................................................................................