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Extrusive and Intrusive and Komatiitic , Peperites, and Genesis at the Dundonald Ni-Cu-(PGE) Deposit, Abitibi ,

M.G. Houlé1,2, P.C. Davis3, C.M. Lesher1,2, N.T. Arndt4 1Mineral Exploration Research Centre, Laurentian University, Sudbury, Ontario, Canada 2Ottawa-Carleton Geoscience Centre, University of Ottawa, Ottawa, Ontario, Canada 3Hucamp Mines Limited, Timmins, Ontario, Canada 4Université Joseph-Fournier, Grenoble, France email: [email protected].laurentian.ca

Introduction upwards. Each cycle comprises i) a lower member Following the recognition of the volcanic of thick differentiated komatiitic flows with of ultramafic rocks in the Barberton lower - cumulate zones and upper greenstone belt by Viljoen & Viljoen (1969), the acicular pyroxene spinifex-textured zones, ii) a existence of extrusive komatiites is now accepted central member of thick differentiated cumulate by most workers. Nevertheless, there are also flows with lower olivine cumulate zones numerous examples of komatiitic dikes, sills, and and upper olivine spinifex-textured zones, and iii) invasive flows (e.g., , 1979; Duke, 1986; an upper member of thick cumulate komatiite flows Arndt, 1994; Davis, 1997, 1999; Stone & Stone, with thick olivine mesocumulate to adcumulate 2000; Beresford & Cas, 2001; Lesher et al., lower zones and thin upper olivine spinifex- submitted; Lévesque, this volume). Here we textured zones. The first and second cycles are describe spectacularly preserved examples of exposed in the western part of Dundonald komatiitic sills and peperites in Dundonald (Fig. 1) and the second cycle and lowermost part of Township, Ontario, which are being studied as part the third cycle are exposed in the eastern part of the of a Ph.D. dissertation by M.G.H. same area (not shown). The third cycle hosts most of the Fe-Ni-Cu sulfide mineralization in the Dundonald Komatiitic Sequence Dundonald area, only parts of which are The volcanic sequence in Dundonald Township exposed in . comprises, from base to top (Davis, 1997, 1999): Ni-Cu-(PGE) mineralization in the komatiitic flows intercalated with to Dundonald South deposit occurs as i) stratiform volcanic flows, a thick layered tholeiitic mafic- contact disseminated/net-textured/massive sulfides, ultramafic (Dundonald Sill), felsic to ii) stratabound internal disseminated, blebby, and intermediate volcanic flows containing thin amygdaloidal sulfides, and iii) minor komatiitic dikes, and komatiitic volcanic flows metasediment-associated sulfides (Muir & Comba, intercalated with thin graphitic, sulfidic 1979; Eckstrand & Williamson, 1985; Barnes & argillaceous metasediments and rare high-Ti Naldrett, 1987). The are hosted by (or tholeiitic basalts. The sequence is exposed in associated with) olivine cumulate rocks that are glaciated throughout the township, but is discontinuous along strike and probably represent best exposed in the Dundonald South area, which channelized flows. The mineralization within was stripped by Falconbridge Ltd. in 1989 and by the metasedimentary rocks includes both primary Hucamp Mines in 2001, exposing 9000m2 of (peperitic) and secondary (metamorphically- glacially-polished outcrops known locally as mobilized) types. The sulfides are composed of Dundonald Beach. The -sedimentary pyrrhotite, , , millerite, package in this part of the area lies on the south- electrum, and PGE alloys (Muir & Comba, 1979; facing limb of a regional fold, strikes roughly east- M.E. Fleet, pers. comm. to P.C.D., 1993). Massive west, and dips steeply to the south. The ores contain, on average, ~47.5% Ni, 0.35% Cu, metasediments are locally sheared subparallel to and 19 g/t ∑PGE in 100% sulfides, whereas bedding, but most of the volcanic rocks and disseminated ores contain, on average, ~38.1% Ni, peperites are not penetratively deformed. 0.88% Cu, and 24 g/t PGE (Barnes & Naldrett, The upper komatiitic sequence in the 1987; Davis, 2001). Grab samples of massive Dundonald South area comprises three cycles that sulfides in the first cycle at Dundonald Beach exhibit an overall decrease in MgO content with contain 20-34% Ni, 4.4-45 g/t Pt+Pd, 1.8 g/t increasing stratigraphic height. However, the MgO Os+Ir+Rh, and 2.4 g/t Ru. The very high metal contents of the rocks within each cycle increase tenors imply very high R (mass ratio of to sulfide ) and very reducing conditions, but the accumulated substantial amounts of this differences between ore types suggest higher R in prior to ponding (Davis, 1997). disseminated ores than in massive ores. Some komatiitic basalts in the first cycle form sills with thin (1-2 cm) symmetric upper and lower Intrusive, Invasive, and Extrusive Komatiites chilled margins that cross-cut previous komatiitic and Komatiitic Basalts basalt flows and invade the graphitic argillaceous The komatiites and komatiitic basalts sediments, forming peperites and graphite “egg- exposed at Dundonald Beach (Davis, 1997) and in shell ” (Davis, 1997, 1999). Several thin drill core (Muir & Comba, 1979) range in thickness (~5-10 cm) spinifex-textured dikes occur in the from 1m to >150m and display all of the textures underlying felsic volcanic rocks (Davis, 1997, typical of komatiites: glassy and rubbly flow-top 1999). The sills may be subdivided into two types. breccias, fine-grained random olivine spinifex Type I sills are relatively thick (~4 m), are textures, coarse-grained platy olivine or acicular composed of fine- to medium grained komatiitic pyroxene spinifex textures, and a wide variety of basalt, and have straight contacts with thin (~2-3 crescumulate, orthocumulate, mesocumulate, and cm) very fine-grained lower and upper chilled adcumulate textures. Some of the thicker flows margins. They do not appear to have interacted (e.g., “Empire flow”) are well differentiated with extensively with wall rocks. Type II sills are thinner lower meso- to adcumulate zones and upper (<50 cm), are composed of fine-grained komatiitic gabbroic zones, suggesting that differentiation basalt with local globular textures (Fig. 2B) occurred after the flow had ponded (Vicker, 1991), indicative of contamination, and have wavy, but most of the thicker flows contains an excess irregular contacts (Fig. 2A) with very thin (<1 cm) component of olivine and therefore appear to have chilled margins. They appear to have interacted extensively with wall rocks.

Figure 1. Simplified geological map of the western part of the Dundonald Beach area (modified from Davis, 1999). Rocks young to the south.

Figure 2. A) Type II komatiitic basalt sill showing globular textures wavy and irregular contact with the host unit (hammer for scale). B) Close up of the figure 2A showing globular texture (coin for scale).

Peperites are produced when hot containing rounded clasts of komatiitic basalt in a intrudes unconsolidated or poorly consolidated metasedimentary (Fig. 3B). Peperites sediments (e.g., White et al., 2000). This interaction containing clasts of komatiite surrounded by appears to have occurred between unconsolidated metasediment occur on larger scales (meters) than graphitic argillaceous sediments and the komatiitic peperites containing clasts of sediments surrounded magma in the Dundonald Beach area, producing by komatiites (centimeters), but both textures blocky peperites, containing angular clasts of generally occur close to one other. desiccated sediment in a komatiitic basaltic matrix (“egg-shell breccias: Fig. 3B) and fluidal peperites,

Figure 3. A) Detailed map showing relationship between graphitic argillaceous metasediments and komatiitic basalts at Dundonald Beach. B) Peperite comprising clasts of desiccated graphitic, argillaceous metasediment in a matrix of bleached (contaminated?) komatiitic basalt. C) Peperite comprising clasts of bleached (contaminated?) komatiitic basalt in a matrix of graphitic, argillaceous metasediment. Conclusions Dundonald and Munro Townships and Although the peperites and contaminated genesis of associated nickel and copper- komatiitic basalt sills described here contain only zinc volcanogenic massive sulfide minor Ni-Cu-(PGE) mineralization, the very high deposits, , Ontario, metal tenors of the mineralization in the lava Canada: Unpublished M.Sc. thesis, Uni- channels and the contaminated geochemical versity of Alabama, Tuscaloosa, 201 pp. signatures of the komatiites (Davis, 1997) provide Duke, J.M., 1986, and economic geology indirect evidence for interaction between those of the Dumont Sill; an intrusion komatiites and sulfidic, graphitic sediments to of komatiitic affinity in northwestern generate the magmatic Ni-Cu-(PGE) ores. Thus, the Quebec: Economic Geology Report, peperites and sills exposed on Dundonald Beach Geological Survey of Canada, v. 35, 56 pp. probably represent a less dynamic end-member in a Eckstrand, O.R, & Williamson, B.L., 1985, larger system of lava channels, sills, and dikes. Vesicles in the Dundonald komatiites: Geological Association of Canada – Acknowledgements Mineralogical Association of Canada We are very grateful to Falconbridge Ltd. Annual Meeting, Program and Abstracts, and Hucamp Mines Ltd. for providing access to v. 10, p A-16. field exposures, drill cores, and geological data. Lesher, C.M., Williams, D.A., Osmond R, Watts, This research has been supported by a Ontario T., Green, A.H., Dupras, N., and Geological Survey partnership grant and a Natural Lévesque, M., submitted, Sciences and Engineering Research Council of komatiitic invasive lava Canada operating grant to CML and a Fonds pour channels (sinuous rilles) in the Cape Smith la Formation de Chercheurs et l’Aide à la Belt, New Québec: Geology. Recherche fellowship to MGH. We would like to Lévesque, M., this volume, of the thank Kevin Montgomery of Hucamp Mines Ltd. Raglan Formation in the Zone 3, Zone 2, for assistance during the field work. and Katinniq areas, Cape Smith Belt, Nouveau-Québec. References Muir, J. E., & Comba, C. D. A., 1979, The Arndt, N.T., 1994, Archean komatiites. Chapter 1 Dundonald deposit; an example of volcan- in Condie K.C. (Ed), Archean crustal ic-type nickel-sulfide mineralization: evolution, Developments in Canadian Mineralogist, v. 17, p. 351-359. Geology, v. 11, p. 11-44. Stone, M.S., & Stone, W.E., 2000, A crustally Barnes, S.-J., & Naldrett, A.J., 1987, Fractionation contaminated komatiitic dyke-sill-lava of the -Group Elements and complex, Abitibi greenstone belt, Ontario: in some komatiites of the Abitibi Precambrian Research, v.102, p.21-46. Greenstone Belt, Northern Ontario: Vicker, P.A., 1991, Petrographic and geochemical Economic Geol., v. 82, p. 165-183. examination of the Empire Komatiite Beresford, S.W., & Cas, R.A.F., 2001, Komatiitic Flow, Dundonald Township, Northern invasive lava flows, Kambalda, Western Ontario: Unpublished B.Sc. thesis, Australia: Canadian Mineralogist, v. 39, University of Western Ontario, London, p.505-524. Ontario, 82 pp. Davis, P.C., 2001, Komatiite associated PGM Viljoen, M.J., & Viljoen, R.P., 1969, Evidence for mineralization on Hucamp Mines Limited the existence of a mobile extrusive exploration properties, Ontario: PGE peridotitic magma from the Komati Exploration Workshop, Sudbury, p. 14. Formation of the Onverwacht group: Davis, P.C., 1999, Physical of Geological Society of South , komatiites flows at Dundonald Beach and Special, Publication 2, Upper Alexo Mine, Dundonald and Clergue Project, p.87-112. Townships, Kidd-Munro Assemblage, Williams, D.A.C., 1979, The association of some Ontario portion and the Abitibi Greenstone nickel sulfide deposits with komatiitic Belt. Day 2: Guidebook Series, v.1, in Rhodesia: Canadian Mineral Exploration Research Centre, Mineralogist, v. 17, p. 337-349. Laurentian University, p. 27-44. White, J.D.L., McPhie, J., & Skilling, I., 2000, Davis, P.C., 1997, Volcanic stratigraphy of the late Peperite: a useful genetic term: Bull. of Archean Kidd-Munro assemblage in Volcanology, v. 62, p. 65-66.