<<

ILSEPT 2017 | Oral Program

Oral Program Sunday 8 January 2017 17:00-19:00 Registration | Room: Ballroom Foyer 18:00-19:00 Welcome Drinks Reception | Room: Ballroom B Monday 9 January 2017 08:30-08:45 Opening Remarks | Room: Ballroom A Session Chair: Martin Atkins, Queen's University Belfast, UK

Room: Ballroom A [PL01] Cecilia Devi Wilfred 08:50–09:35 CO2 removal using tailor made ionic liquids C.D. Wilfred, Universiti Teknologi PETRONAS, Malaysia

Session 1: Application of ionic liquids in CO2 Session 2: Application of ionic liquids in capture biotechnology and biorefining 09:40–11:00 Session Chair: Mohamed Ibrahim Abdul Mutalib, Session Chair: Tom Welton, Imperial College , Universiti Teknologi PETRONAS, Malaysia UK Room: Ballroom A Room: Function room 5 & 6 [O02.1] Development of a single-step extraction process based in aqueous solutions of ionic liquids to recover phycobiliproteins from red seaweeds 09:40–10:00 [KN01] Development of an ionic liquids aspen 1 1 1 2 S.P.M. Ventura* , M. Martins , F.A. Vieira , A. Rego , database and its use for the design of selective 2 1 1 M.H. Abreu , J.A.P. Coutinho , University of Aveiro, co capture processes from biogas streams 2 2 Portugal, ALGAplus, Portugal J. Jacquemin*1, P. García-Gutierrez2, C. McCrellis2, 2 2 ,3 2 ,3 [O02.2] Novel SO3H-functionalized dicationic ionic I. Dimitriou , S.F.R Taylor , C. Hardacre , R.W.K. 2 1 2 liquids - A comparative study for esterification Allen , Queen’s University Belfast, UK, University 3 reaction by ultrasound cavitation and mechanical 10:00–10:20 of Sheffield, UK, University of Manchester, UK stirring for biodiesel production A.N. Masri*, J.M. Leveque, M.I. Abdul Mutalib, Universiti Teknologi PETRONAS, Malaysia [O02.3] Extraction of polyphenols from a real [O01.1] Modelling the solubility of CO and H S in 2 2 aqueous effluent from the paper industry 10:20–10:40 ionic liquids using PC-SAFT equation of state J.P. Magnin, N. Papaiconomou*, T. Eyraud, I. H. Al-fnaish*, L. Lue, University of Strathclyde, UK Billard, LEPMI, France [O02.4] Influence of imidazolium-based ILs as co- surfactant in aqueous micellar two-phase systems to [O01.2] A study on carbon dioxide removal by extract natural colorants from fermented broth of blending the in membrane synthesis Talaromyces amestolkiae 10:40–11:00 D.F. Mohshim*, H. Mukhtar, Z. Man, Universiti F.A.E. Torres, A.C.A. Francisco, J.F.B. Pereira, V.C. Teknologi PETRONAS, Malaysia Santos-Ebinuma*, Department of Bioprocess and Biotechnology, School of Pharmaceutical Sciences, UNESP-Univ. Estadual Paulista, Brazil 11:00–11:20 Coffee Break | Room: Ballroom B Session1 Continues: Application of ionic liquids Session 2: Application of ionic liquids in in CO2 capture Continues… biotechnology and biorefining Continues… 11:20–13:00 Session Chair: Mohamed Ibrahim Abdul Mutalib, Session Chair: Tom Welton, , Universiti Teknologi PETRONAS, Malaysia UK Room: Ballroom A Room: Function room 5 & 6 [O04.1] and nanocellulose dissolution and synthesis via ionic liquids 11:20–11:40 G. Reyes*, N. Flores, M. Soto, V. Vargas, S. Cardenas, J. Romero, A. Matus, University of Bío-Bío, Chile

[KN02] Protic ionic liquids for co2 separation [O04.2] Effect of salt-based additive on the partition D. MacFarlane*, R. Vijayaraghavan, Monash behaviour of protein in aqueous two-phase system University, Australia composed on green ionic liquid 11:40–12:00 S. Cher Pin1, R. Ramakrishnan Nagasundara1, V. R.2, M. Douglas R.2, C. Eng-Seng1, O. Chien- Wei*1, 1Monash University, Malaysia, 2Monash University, Australia [O03.1] Chemically tunable ionic liquid-amine [O04.3] Enzymatic production of biodiesel from solutions for CO2 capture waste oil using different ionic liquids as a reaction 12:00–12:20 F.A. Chowdhury*, T. Kato, Research Institute of medium Innovative Technology for the Earth (RITE), Japan H. Taher*1, S. Al-Zuhair1, E. Nashef1, N. ILSEPT 2017 | Oral Program

Anvar1, 1Masdar Institute, United Arab Emirates, 2UAE University, United Arab Emirates [O04.4] Downstream processing of Saccharina japonica to obtain bioactive compounds using ionic [O03.2] Ionic liquids for CO2 capture and liquids pooled with compressed fluids: a holistic transformation 12:20–12:40 approach B. Iliev*, T.J.S. Schubert, F.M. Stiemke, Iolitec P.S. Saravana*, A. Tilahun, C. Gereniu, V.D. Tri, Y.J. Ionic Liquids Technologies GmbH, Germany Cho, H.C. Woo, B.S. Chun, Pukyong National University, Republic of Korea [O03.3] Sustainable catalytic transformation of [O04.5] Separation of bioactive compounds using CO and epoxide into cyclic carbonate using ionic 2 nanostructured ionic liquids and poly(ionic liquid)s 12:40–13:00 liquids functionalized activated carbon W. Jin, X. Liu, Y. Xie, X. Suo, Q. Yang, Q. Ren, H. A.H. Jadhav*, J.G. Seo, Myongji University, Xing*, Zhejiang University, China Republic of Korea 13:00–14:00 Lunch | Room: Dynasty Restaurant Session Chair: Martin Atkins, Queen's University Belfast, UK

Room: Ballroom A [PL02] Syed Salim Bin Saled New ionic liquid process for the purification and refining of crude palm oil – Controlling free fatty acids 14:10–14:55 (FFA) and impurities S.S.B. Saled, FGV, Malaysia Session 3: Application of ionic liquids in Session 2: Application of ionic liquids in biotechnology and biorefining biotechnology and biorefining Continues… 15:00–16:00 Session Chair: Cecilia Devi Wilfred, Universiti Session Chair: Douglas MacFarlane, Monash Teknologi PETRONAS, Malaysia University, Australia Room: Ballroom A Room: Function room 5 & 6 [O06.1] Eutectic mixtures as ionic liquid analogues in liquid-liquid chromatography separations of natural compounds 15:00–15:20 F. Bezold, S. Roehrer, M. Minceva*, Technical [KN03] Advances in cellulose processing with University of Munich, Germany ionic liquids

A.W.T. King*, A.J. Holding, K.J. Helminen, T. [O06.2] Separation of mandelic acid enantiomers Laaksonen, I. Kilpeläinen, University of Helsink, using chiral ionic liquids-based aqueous biphasic Finland systems 15:20–15:40 F.A. e Silva, T.E. Sintra, S.N. Rocha, C. Monteiro, S.P.M. Ventura*, J.A.P. Coutinho, University of Aveiro, Portugal [O05.1] Rubisco separation using biocompatible- aqueous two phase systems [O06.3] Ionic liquid screening for solvent design of C.A. Suarez Ruiz*1, C. van den Berg1, R.H. Wijffels1 herbal phytochemical extraction 15:40–16:00 ,2, M.H. Eppink1 ,3, 1Wageningen University, The N.R. Abd Rahman*, A.A. Mustaffa, N.A. Netherlands, 2Nord University, Norway, 3Synthon Yunus, Universiti Teknologi, Malaysia Biopharmaceuticals B.V, The Netherlands 16:00–18:00 Coffee Break + Poster Session | Room: Ballroom B Tuesday 10 January 2017 Session Chair: Martin Atkins, Queen's University Belfast, UK

Room: Ballroom A [PL03] Kuah Yong Cheun HycapureTM hg: Providing the silver lining 08:30–09:15 K.Y. Cheun*, N.A. Manan, A. Hassan, A.A. Rahman, M. Abai, M.A. Ishak, S.M. Shariff, PETRONAS Research Sdn Bhd, Malaysia Session 4: Ionic liquids as advanced materials in Session 5: Laboratory to commercialisation separations and extractions Session Chair: João A. P. Coutinho, University of 09:20–11:00 Session Chair: Margarida Costa Gomes, Aveiro, Portugal CNRS/Université Blaise Pascal, France Room: Function room 5 & 6 Room: Ballroom A [O07.1] Low-viscosity ionic liquid media for [KN04] Chris Hamer carbon monoxide/nitrogen separation by Ionic liquids – the beginning of the end or the end of 09:20–09:40 reactive absorption the beginning? A look at the life of ionic liquids G. Zarca*, I. Ortiz, A. Urtiaga, Universidad de through patent claims Cantabria, Spain C.K. Hamer, Mathys & Squire LLP, UK ILSEPT 2017 | Oral Program

[O07.2] Nanosheet-coating on a highly gas permeable membrane with aromatic polymers containing imidazolium group or oligo(ethylene 09:40–10:00 oxide) to improve the CO2 selectivity Y. Nagase*, C. Umeda, B. Suleimenova, K. Ando, T. Suzuki, T. Oda, S. Koguchi, Y. Okamura, Tokai University, Japan [O08.1] Volatile fatty acid recovery from fermented [O07.3] Solvent extraction of Nd(III) from wastewater utilizing an ionic liquid aqueous solution of NdCl3 by [T66614][BA] ionic 10:00–10:20 E. Reyhanitash*, C. Edelijn, B. Zaalberg, S.R.A. liquid Kersten, B. Schuur, University of Twente, The M. Panigrahi, Bulent Ecevit University, Turkey Netherlands [O07.4] Solvent extraction of uranium by using ionic liquid media: effects of aggregation [O08.2] Ionic liquids in (bio)refineries - opportunities T. Sukhbaatar*, S. Dourdain, S. Pellet-Rostaing, G. and threats 10:20–10:40 Arrachart, S. Chapron, ICSM/CEA Marcoule, B. Schuur*, X. Li, E. Reyhanitash, M. France Blahusiak, University of Twente, The Netherlands

[O07.5] Liquid-liquid extraction of recombinant green fluorescent protein using aqueous biphasic systems composed of polymers and cholinium- [O08.3] Assessment of the structure-ecotoxicity based ionic liquids relationship of cholinium-based ionic liquids N.V. dos Santos1, C. Lopes1, S.R. Valentini1, V.C. 10:40–11:00 S.P.M. Ventura*, J.I. Santos, A.M.M. Gonçalves, J.L. Santos-Ebinuma1, S.P.M. Ventura2, J.A.P. Pereira, A.F. e Silva, J.A.P. Coutinho, F. Coutinho2, J.F.B. Pereira*1, 1School of Gonçalves, University of Aveiro, Portugal Pharmaceutical Sciences, UNESP – Univ Estadual Paulista, Brazil, 2CICECO - Aveiro Institute of Materials, University of Aveiro, Portugal 11:00–11:20 Coffee Break | Room: Ballroom B Session 4: Ionic liquids as advanced materials in Session 5: Laboratory to commercialisation separations and extractions Continues… Continues… 11:20–13:00 Session Chair: Andre de Haan, Delft University of Session Chair: João A. P. Coutinho, University of Technology, The Netherlands Aveiro, Portugal Room: Ballroom A Room: Function room 5 & 6 [O10.1] Hydrodynamics of two-phase ionic liquid solvent systems in countercurrent chromatography 11:20–11:40 [KN05] Margarida Costa Gomes 1 1 2 1 V. Lange* , P. Angeli , L. Brown , University College Can mixtures of ionic liquids improve gas 2 London, UK, AECS-QuikPrep Ltd., UK separations? 1 1 ,2 1 [O10.2] Techno-economical assessment of the M.C Gomes* , L.F. Lepre , J. Szala-Bilnik , R. 2 1 1 process performance of ionic liquids for carbon Ando , A.A.H. Pádua , CNRS/Université Blaise 11:40–12:00 2 capture Pascal, France, Universidade de São Paulo, Brazil M.T. Mota-Martinez*, S.B.M. Loqman, N. Mac Dowell, J.P. Hallett, Imperial College London, UK [O09.1] Thallium extraction from HCl media [O10.3] Zebrafish (Danio rerio) for studying ionic using ionic liquids for a future investigation of liquid toxicity;correlation between cytotoxicity and element 113 chemistry ionic liquid aggregation 12:00–12:20 M. Volia*1, E. Tereshatov1, M. Boltoeva2, K. Tran3, S-K. Ruokonen*1, C. Sanwald2, A.W.T. King1, P. C. Folden, III1, 1Texas A&M University, USA, Panula1, S.K. Wiedmer1, 1University of Helsinki, 2Institut Pluridisciplinaire Hubert Curien (IPHC), Finland, 2University of Tübingen, Germany France, 3Eastern Kentucky University, USA [O09.2] Selective separation of Co(II) from NI(II) [O10.4] What are the lever arms for liquid-liquid in HCl acidic medium by Cyphos IL 101 diluted in extraction and separation of metal ions from kerosene aqueous acidic phases towards pure ionic liquids? C. Reynoso-Rojas1, D. Cholico-Gonzalez2, L. 12:20–12:40 I. Billard1, C. Bonnaud2, E. Chainet1, L. Duclos1, M. Hernandez-Perales1, P. Gonzalez-Muñoz1, M. Gras2, N. Papaiconomou*2 ,3, L. Svecova4, F. Avila-Rodriguez*1, 1Universidad de Guanajuato, Tedjar1, 1CNRS, France, 2UGA, France, 3Un. Savoie Mexico, 2CONACYT- Universidad Michoacana de Mont Blanc, France, 4INP, France San Nicolás de Hidalgo, Mexico

ILSEPT 2017 | Oral Program

[O09.3] Performances and mechanistic investigations of ionic liquids for strategic metal extraction [O10.5] Separation of acetylene/ethylene with G. Arrachart*1, R. Turgis1, D. Virieux2, S. Legeai3, 12:40–13:00 ionicmaterials M. Draye4, S. Pellet-Rostaing1, 1ICSM - UMR 5257, H. Xing, Zhejiang University, China France, 2ICGM - UMR 5253, France, 3IJL - UMR CNRS 7198, France, 4Université de Savoie Mont Blanc, France 13:00–14:00 Lunch | Room: Dynasty Restaurant Session Chair: Martin Atkins, Queen's University Belfast, UK

Room: Ballroom A [PL04] Andre de Haan 14:10–14:55 Ionic liquids in biobased chemicals processing A.B. de Haan, Delft University of Technology, The Netherlands Session 4: Ionic liquids as advanced materials in Session 6: Process modelling & fundamental studies separations and extractions Continues… Session Chair: Johan Jacquemin, Queen’s University 15:00–16:00 Session Chair: Jorge F. B. Pereira, UNESP – Univ Belfast, UK Estadual Paulista, Brazil Room: Function room 5 & 6 Room: Ballroom A [O11.1] Metal selective deprotection-mediated palladium(II) extraction by task-specific ionic liquids with THP-protected thiol moieties 15:00–15:20 K. Kanie*1, K. Funaki1, S. Kawamura1, A. Miyazaki1, S. Ma1, A. Sugie2, A. Mori2, A. [KN06] Mohamed Ibrahim Abdul Mutalib Muramatsu1, 1Tohoku University, Japan, 2Kobe Development of predictive methods for ILs eco- University, Japan toxicity using QSAR/QSPR: Progress and Challenges [O11.2] Recovery of cynaropicrin from Cynara M.I.A. Mutalib, Universiti Teknologi PETRONAS, cardunculus L. using aqueous solutions of Malaysia surface-active ionic liquids 15:20–15:40 E.L.P. Faria*, M.V. Gomes, R.S. Carmo, J.A.P. Coutinho, C.S.R. Freire, A.J.D. Silvestre, M.G. Freire, University of Aveiro, Portugal [O11.3] Organosilicas from silylated ionic liquids precursors: functional materials for adsorption / [O12.1] Ionic liquids from the perspective of a separation of anionic pollutants computational chemist 15:40–16:00 B. Prelot*1, P. Hesemann1, U.D. Thach1, R. A. Klamt*1 ,2, M. Diedenhofen1, 1COSMOlogic, Bouchal1, S. Le Caer2, S. Pellet-Rostaing3, 1ICGM- Germany, 2University of Regensburg, Germany CNRS-University Montpellier, France, 2LIONS, France, 3ICSM, France 16:00–16:20 Coffee Break | Room: Ballroom B Session 4: Ionic liquids as advanced materials in Session 6: Process modelling & fundamental studies separations and extractions Continues… Continues… 16:20–17:20 Session Chair: Jorge F. B. Pereira, UNESP – Univ Session Chair: Johan Jacquemin, Queen’s University Estadual Paulista, Brazil Belfast, UK Room: Ballroom A Room: Function room 5 & 6 [O14.1] Modelling mercury removal using ionic liquids 16:20–16:40 M. Khalifa*, L. Lue, H. Al-fnaish, Strathclyde [KN07] Tom Welton University, UK Ionic liquids: Solvents for sustainable chemistry [O14.2] A Computer-aided ionic liquid design for T. Welton, Imperial College London, UK separation processes based on molecular group 16:40–17:00 descriptor and multi-scale simulations Z.W. Qi, East China University of Science and Technology, China [O14.3] A comparison between using ionic liquids and deep eutectic solvents as extracting solvents in [O13.1] 1 Innovative biphasic systems containing the conceptual design of extractive denitrogenation non-perfluorinated hydrophobic ionic liquids units of simulated diesel 17:00–17:20 L. Moura*, J.D. Holbrey, Queen's University of H.F. Hizaddin*1, M.K.O. Hadj-kali2, M.I. Mohamad Belfast, UK Nor1, M.A. Hashim1, 1University of Malaya, Malaysia, 2King Saud University, Saudi Arabia

ILSEPT 2017 | Oral Program

Session Chair: Martin Atkins, Queen's University Belfast, UK

Room: Ballroom A [PL05] Suojiang Zhang 17:20–18:05 Ionic liquid-based gas separation: from molecule to engineering S. Zhang, Chinese Academy of Sciences, China Wednesday 11 January 2017 Session Chair: Martin Atkins, Queen's University Belfast, UK

Room: Ballroom A [PL06] Kenneth R. Seddon 08:30–09:15 Ionic Liquid–Liquid Chromatography (ILLC™) M.J. Earle, M.A. Gîlea, N.V. Plechkova and K.R. Seddon*, Queen’s University Belfast, UK Session 7: Application of ionic liquids in Session 8: Ionic liquids as advanced materials in chemicals and petrochemicals purification 09:20–11:00 Session Chair: Andreas Klamt, COSMOlogic, Session Chair: Boelo Schuur, University of Twente, Germany The Netherlands Room: Ballroom A Room: Function room 5 & 6 [O15.1] The effect of alkyl chain length on extractive desulfurization of diesel fuels using ester functionalized ionic liquids 09:20–09:40 J. Joshua Raj*, M. Pranesh, M. Sivapragasam, C.D. [KN08] Valentine Ananikov Wilfred, K.C. Lethesh, M.I. Abdul Influence of water effect and structured domains on Mutalib, Universiti Teknologi Petronas, Malaysia biomass conversion and extraction processes in [O15.2] CO capture performances of 2 ionic liquids [Emim][Gly] ionic liquid confined into porous V.P. Ananikov, Russian Academy of Sciences, Russia sorbents for post-combustion applications 09:40–10:00 M. Balsamo*, A. Erto, A. Lancia, F. Montagnaro, G. Totarella, R. Turco, Università degli Studi di Napoli Federico II, Italy [O16.1] Phycobiliproteins purification by applying [O15.3] Detachment studies between high- mixed aqueous micellar two-phase systems using density crude oil and sand particles in ionic liquid 10:00–10:20 ionic liquids as co-surfactants S.J. Dhuny, E.V. Lau*, Monash University F.A. Vicente, I.S. Cardoso, J.A.P. Coutinho*, S.P.M. Malaysia, Malaysia Ventura, University of Aveiro, Portugal [O16.2] An association extraction process for vitamin E recovery from the methylated oil [O15.4] Design and Synthesis of a Reusable Ionic deodorizer distillate by in-situ formation of deep 10:20–10:40 Liquid Supported-IBX eutectic solvent A. Mihoya*, S. Koguchi, Tokaiuniversity, Japan H. Cheng*, L. Qin, L. Chen, Z. Qi, East China University of Science and Technology, China [O16.3] Novel electrolyte for dye sensitized solar [O15.5] Chemical reactions in ionic liquid with an cells using recrystallized quinolinium ionic liquids epoxy group 10:40–11:00 G. Selvaraj*1, C.D. Wilfred1, W.Z.N. Yahya1, K.E. T. Tsuda*, K. Iwasaki, K. Kumagai, S. Neo2, 1Universiti Teknologi PETRONAS, Malaysia, Kuwabata, Osaka University, Japan 2Universiti Tunku Abdul Rahman, Malaysia 11:00–11:20 Coffee Break | Room: Ballroom B Session 8: Ionic liquids as advanced materials in Session Chair: Martin Atkins, Queen's University purification Continues… 11:20–12:40 Belfast, UK Session Chair: Boelo Schuur, University of Twente, Room: Ballroom A The Netherlands Room: Function room 5 & 6 [O18.1] Purification of the recombinant green fluorescent protein produced by Escherichia coli using ionic liquid-based aqueous biphasic systems 11:20–11:40 [KN09] Peter Licence 1 2 1 M. Martins , J.F.B. Pereira* , J.A.P. Coutinho , S.P.M. Probing interfacial phenomena of advanced 1 1 2 Ventura , University of Aveiro, Portugal, UNESP – fluids by XPS Univ Estadual Paulista, Brazil R.K. Blundell, C.J. Clarke, E.F. Smith, P. [O18.2] Highly efficient separation of nitrogen- Licence*, The University of Nottingham, UK containing compounds by deep eutectic solvents 11:40–12:00 Q. Yang*, M. Ali, Y. Li, Q. Ren, Zhejiang University, China 12:00–12:15 Closing Remarks | Room: Ballroom A