Interaction of Quantum Vortex Beams with Matter
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Interaction of Quantum Vortex Beams with Matter by Maria Solyanik-Gorgone B.S. in Physics, May 2009, Karazin Kharkiv National University, Kharkiv, Ukraine M.S. in Theoretical Physics, May 2010, Karazin Kharkiv National University, Kharkiv, Ukraine A Dissertation submitted to The Faculty of The Columbian College of Arts and Sciences of The George Washington University in partial satisfaction of the requirements for the degree of Doctor of Philosophy August 31, 2019 Dissertation directed by Andrei Afanasev Associate Professor of Physics The Columbian College of Arts and Sciences of The George Washington University certifies that Maria Solyanik-Gorgone has passed the Final Examination for the degree of Doctor of Philosophy as of May 10, 2019. This is the final and approved form of the dissertation. Interaction of Quantum Vortex Beams with Matter Maria Solyanik-Gorgone Dissertation Research Committee: Andrei Afanasev, Associate Professor of Physics, Dissertation Director Helmut Haberzettl, Professor of Physics, Committee Member Alexander van der Horst, Assistant Professor of Physics, Committee Member ii c Copyright 2019 by Maria Solyanik-Gorgone All rights reserved iii Dedication To my beloved parents for believing in me unconditionally and loving me selflessly. iv Acknowledgments I would like to express my deepest appreciation and gratitude to my research advisor, Professor Andrei Afanasev, for sharing his diverse expertise, for his continuous support of my research, patience and encouragement. This work would not be possible without his guidance. I especially thank my collaborators: Professor C. E. Carlson, Professor C. T. Schmiegelow, Professor F. Schmidt-Kaler and Professor V. G. Serbo for a supportive and friendly environ- ment, productive work, stimulating discussions, insightful comments and hard questions throughout the whole time of us working together on projects. I would also like to ac- knowledge the contribution of Professor C. W. Clark on the early stages of my project. His discussions and lectures during my summer internship in 2016 provided the necessary foundation for future theoretical work in Atomic Physics and Spectroscopy. The experience and skills I obtained while working with this group of scientists is unique and irreplaceable in my future endeavors. My sincere thanks go to my readers, Professor H. Haberzettl and Professor A. van der Horst for the valuable comments, insightful questions and kind corrections. I would like to express my deepest gratitude to the department professors and staff for supporting friendly, nurturing but also stimulating and challenging environment for students to develop, mature as specialists and form their scientific identity. Also, I am grateful for financial support that has come from the department funds towards completion of my project. Special thanks go to my graduate student mentor, Professor E. J. Downie. Her great example as a scientist, teacher and leader helped me grow into who I am today and, I am sure, will continue inspiring me in the future. Very special words of thanks go to my dear husband, life mentor and friend, Nicholas M. Gorgone, for his kind support and advice. Thank you for sheltering me when it is tough and sharing happiness in the moments of delight. v Abstract Interaction of Quantum Vortex Beams with Matter The excitations in atomic, nuclear and semiconductor structures with orbital angular momentum carrying photons are analyzed. The violations of the conventional set of an- gular momentum selection rules are derived and discussed in detail for all three types of structures. In the case of atoms and ions, fine and hyperfine coupling are accounted for by means of the multipole expansion of partial transition amplitudes. The theory is devel- oped for arbitrary beam polarization, alignment of the beam’s optical axis with respect to the target’s quantization axis, and transition multipolarity. The approach is extrapolated to semiconductor structures using the Luttinger formalism. Spin polarization anomalies for electrons photo-excited by twisted light in G-point in zinc-blende GaAs are revealed. Unusual sensitivity to the twisted beam polarization content, and radial and axial positioning of the target in the beam profile, are identified and studied in detail. The phenomenon of circular dichroism due to twisted beam topology during propagation in isotropic matter is predicted and analyzed. Three families of modes are considered and analyzed: Bessel, Bessel-Gauss and Laguerre-Gauss. The results are applicable in a wide range of studies: spectroscopy, metrology, quantum computing and communications, cybersecurity and more. vi Statement of Originality Herein I certify that the content of this thesis is my own work with the exceptions, listed below. Any resemblance to the results elsewhere, that are not mentioned in this statement and/or throughout this thesis, is accidental. Chapter 1: The overview of the general trends and fundamental breakthroughs in Singular Optics and Photonics, that paved the foundation for modern study of twisted light and matter beams is provided. Chapter 2: The overview of the necessary concepts in Laser Optics and Photonics, and systematic description of the Quantum Mechanical formalism for twisted mode quantization, established in the field, is provided. Chapter 3: Professor C. E. Carlson made a substantial integrated contribution in developing the theoretical model for the data in Section 3.5. The data in Chapter 3 is the product of work done by Professor C. T. Schmiegelow, as a part of an experimental collaboration under the supervision of Professor F. Schmidt-Kaler. Chapter 4: The theoretical analysis and main predictions were done by Professor A. Afanasev and Professor C. E. Carlson for the spin-less case. Chapter 5: The formalism and analysis for mesoscopic proton targets for the np-capture discussed here was done by Professor A. Afanasev and Professor V. G. Serbo. Chapter 6: The atomic-like approximation in the eqn. (6.13) was done by Professor A. Afanasev. In the process of the completion of this work, many Mathematica code prototypes with key ideas and plots were shared with me by Professor A. Afanasev before the corresponding theoretical background was developed. vii Table of Contents Dedication ............................. iv Acknowledgments ..........................v Abstract .............................. vi Statement of Originality........................ vii List of Figures ............................ ix List of Tables ............................x List of Abbreviations ......................... xi List of Symbols ........................... xii Chapter 1: Introduction........................1 1.1 History.......................2 1.2 Thesis Outline....................6 Chapter 2: OAM Photon States.....................9 2.1 Review of Necessary Fundamentals in Optics........9 2.2 Vortex Beams.................... 13 2.2.1 Orbital Angular Momentum and Spin of Light....... 16 2.3 Orbital Angular Momentum Modes............ 17 2.3.1 Bessel Beams.................... 18 2.3.2 Bessel-Gauss Beams.................. 23 2.3.3 Laguerre-Gauss Beams................. 24 2.4 Orbital Angular Momentum Beams and Polarization States.. 26 viii Chapter 3: Quantum Mechanical Transition Matrix for Twisted Light - Atom Inter- actions.......................... 29 3.1 Plane-wave Transition Amplitude............. 30 3.2 Photo-Excitation by Twisted Beams in Total Angular Momen- tum Basis...................... 32 3.3 Twisted Photo-Excitation in Atoms: Hyperfine Structure... 35 3.4 Photo-Excitation with Twisted Light in Cooled Trapped Ions.. 37 3.4.1 40Ca Ion in Parallel Configuration Irradiated by Circularly Po- larized Light..................... 37 3.4.2 40Ca Ion in 45◦-Configuration and More.......... 46 3.4.3 Ion photo-excitations in Radially and Azimuthally Polarized Orbital Angular Momentum Beams............ 56 3.5 Recoil from Orbital Angular Momentum Photons in Trapped Ions........................ 58 Chapter 4: Chirality, Chirooptics and Circular Dichroism in Orbital Angular Mo- mentum Photon-Matter Interactions............... 62 4.1 Chirality in Light................... 62 4.2 Optical Activity and Twisted Photon Beams........ 66 Chapter 5: Electromagnetic Interactions and Neutron-Proton Systems...... 68 5.1 Deuteron Photodisintegration and np-Capture with Orbital An- gular Momentum Beam States.............. 69 Chapter 6: Photo-Induced Processes in Semiconductor Materials and Quantum Dots........................... 75 6.1 Twisted Photon Interaction with Bulk GaAs........ 76 6.2 Twisted Photon Interaction with Semiconductor Quantum Dots. 86 Chapter 7: Conclusions........................ 91 Bibliography............................. 94 ix Chapter A: List of Useful Formulas.................... 105 Chapter B: Spherical Wave Decomposition of Twisted Modes......... 108 x List of Figures Figure 2.1. The generic phase profile of the OAM-carrying beam with a screw-like dislocation at the beam center, propagating in the z-direction. ····· 14 Figure 2.2. LG (rows 1 and 2), Bessel (row 3) and BG (row 4) modes’ intensity profiles for different values of OAM `g , p nodal number, and TAM mg . All the axes are in arbitrary units and the columns correspond to topological charge `g for LG, and TAM quantum number mg for BB and BG. ·························· 19 Figure 2.3. Schematic picture of the twisted beam geometry from the prospective of the local observer P’ versus the coordinate system P attached to the beam axis. The red arrow specifies the overall direction of the