IIS: Determinación De Arsénico Y Otros Parámetros En Aguas Subterráneas En La Edwin Astorga Sub Cuenca Titicaca (Época De Lluvia) (Parte II)

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IIS: Determinación De Arsénico Y Otros Parámetros En Aguas Subterráneas En La Edwin Astorga Sub Cuenca Titicaca (Época De Lluvia) (Parte II) !!" !#$%&%'%()*+)!#,+#&+-./ "/#&%/-&/)0)123&+#%/4 !"#$%&'()"(*+,"+$"-.'(/'+$&'-$'(0(123$"+&'4 5'674&')()"(*+,"+$"-.' !"#$ !"#$"%$&'( )("%*(&%(+,+ -./%$"*(0 %&'()#*+,- ./#0/1#2#3)4(5(/ Universidad Mayor de San Andrés Ingeniería Sanitaria y Ambiental REVISTA N° 3 Junio 2016 La Paz – Bolivia Edición Principal: Oscar Paz - Instituto de Ingeniería Sanitaria y Ambiental – UMSA Colaboradores en este número: Evelin Humerez Contenido Carlos España Carla Elias Hernán Coriza Graciela Espinoza Prólogo ....................................................................................................... 5 Gregorio Carvajal Eufemia Briancon Estudio de la calidad del agua en la cuenca del Río Condoriri en los Grover Rivera Andes ......................................................................................................7 Edwin Astorga Oscar Paz Estudio de ecotoxicidad en el Río Choqueyapu .......................................15 Dirección a.i. del IIS: Determinación de arsénico y otros parámetros en aguas subterráneas en la Edwin Astorga sub cuenca Titicaca (época de lluvia) (parte II) ........................................23 Gregorio Carvajal Reducción de la DQO mediante coagulante ecológico de cáscara del Revisión: limón ....................................................................................................32 José Díaz B. 0HWRGRORJtDSDUDXQDFODVL¿FDFLyQGHODFDOLGDGGHFXHUSRVGHDJXD ....39 Colaboración especial: Personal técnico - administrativo del IIS Referencias: Al citar este documento debe señalar como: Revista de Ingeniería Sanitaria y Ambiental, UMSA, N°3. Facultad de Ingeniería N° 3-2016; La Paz, 2016. Los artículos de la revista son plena responsabilidad de cada uno de sus autores. del Instituto de Ingeniería Sanitaria Depósito legal: 4-3-58-15 P.O. N° 3 © 2016 IIS - UMSA Revista 3 Contactos: http//:iis.umsa.edu.bo Av. Villazón 1995, telf. 591-2 2441519, Fax 591-2 2440121 La Paz, Bolivia PRÓLOGO El tercer número de la revista Ingeniería Sanitaria y Ambiental del Instituto de Ingeniería Sanitaria y Ambiental de la UMSA, pone a consideración del mundo aca- démico, de las instituciones nacionales y subnacionales ligadas a la temática y de la sociedad civil en general, una serie de artículos de investigación y de actualidad que aportan al entendimiento de factores relacionados con la calidad de los cuerpos de agua desde diferentes ópticas. Un estudio sobre la calidad de las aguas de la cuenca del río Condoriri preten- de indagar sobre cómo el cambio climático, que está afectando a las zonas glaciares, a su vez está impactando sobre la calidad del agua de la cuenca. De la misma ma- nera se comparte una investigación más sistemática de la ecotoxicidad de la cuenca del río Choqueyapu. También se presenta la segunda parte de un estudio sobre la presencia de arsénico en aguas subterráneas de la sub-cuenca Titicaca, así como la presencia de otros químicos y de bacterias del grupo Coliforme en estas aguas. Un estudio muy amplio para determinar los índices de calidad de los cuerpos de agua y su aplicación en la cuenca del río La Paz y del río Katari es desarrollado y SUHWHQGHDSRUWDUFRQQXHYRVPRGHORVSDUDODFODVL¿FDFLyQGHFXHUSRVGHDJXDHQHO país. Finalmente, en el campo de las tecnologías alternativas se presenta un análisis de tratamiento de aguas residuales utilizando productos naturales. Esperamos, una vez más, que de esta manera la sociedad en su conjunto conozca del trabajo del IIS, su aporte al conocimiento, que es acompañado de la for- mación de nuevos profesionales para el país y que se complementa con los servicios que otorga en materia de calidad de agua, saneamiento y medio ambiente. del Instituto de Ingeniería Sanitaria El Editor N° 3 Revista 5 ESTUDIO DE LA CALIDAD DEL AGUA EN LA CUENCA DEL RÍO CONDORIRI EN LOS ANDES AUTORES:AUTORES Evelin Susana Humerez Espinoza1 Carlos David España Vásquez2 Makoto Umeda3 SUMMARY 7KLVUHVHDUFKLQYHVWLJDWHVWKHHϑHFWVRIWKHSK\VLFRFKHPLFDOSDUDPHWHUVPDMRULRQVDQGQX- trients over water quality formation and submerged aquatic plants. The principal aims of this VWXG\DUHWRGHWHUPLQHWKHLQÀXHQFHRIWKHZHDWKHULQJRIURFNVDQGWRLGHQWLI\WKHSULQFLSDO source of nutrients for the macrophyte growth in the dry season. Field measurements were done in the Condoriri River watershed in Bolivia. Water samples had pH averages of 7.42 ± 0.51 and 6.64 ± 0.46 in May 2013 and May 2014, respectively. Fluctuating variations of water temperature, electric conductivity, dissolved oxygen, nutrients, and ions were observed in WKHULYHU7KHZHDWKHULQJRIVLOLFDWHVFDUERQDWHVDQGVXOSKDWHVZDVLGHQWL¿HGDVWKHSULQFLSDO source of major ions. Macrophyte biomass exhibited a correlation with positive gradient with total nitrogen (R2 7KHZHDWKHULQJRIURFNVDQGWKHSUHVHQFHRIPDFURSK\WHVLQÀXHQ- ced the water quality of the Condoriri River through chemical and metabolic reactions in this ecosystem. 123 RESUMEN En este estudio se investiga el efecto de los parámetros físico químicos, los iones mayores y los nutrientes sobre la calidad del agua y las plantas acuáticas sumergidas. Los objetivos FODYHVVRQGHWHUPLQDUODLQÀXHQFLDGHODPHWHRUL]DFLyQGHODVURFDVHLGHQWL¿FDUODSULQFLSDO IXHQWHGHQXWULHQWHVSDUDHOFUHFLPLHQWRGHODVPDFUy¿WDVHQODpSRFDGHHVWLDMH/DVPHGL- ciones de campo fueron realizadas en la cuenca del río Condoriri en Bolivia. Las muestras de agua tuvieron valores promedio de pH de 7.42 ± 0.51 y 6.64 ± 0.46 para mayo 2013 y mayo UHVSHFWLYDPHQWH6HREVHUYDURQÀXFWXDQWHVYDULDFLRQHVGHWHPSHUDWXUDGHODJXDFRQ- ductividad eléctrica, oxígeno disuelto, nutrientes e iones a lo largo del río. La meteorización de ORVVLOLFDWRVFDUERQDWRV\VXOIDWRVIXHLGHQWL¿FDGDFRPRODSULQFLSDOIXHQWHGHORVLRQHVPD\R- UHV/DELRPDVDGHODVPDFUy¿WDVH[KLELyXQDUHODFLyQFRQJUDGLHQWHSRVLWLYRFRQHOQLWUyJHQR del Instituto de Ingeniería Sanitaria total (R2 /DPHWHRUL]DFLyQGHODVURFDV\ODSUHVHQFLDGHODVPDFUy¿WDVLQÀX\HURQHQ la calidad del agua del río Condoriri a través de las reacciones químicas y metabólicas en este N° 3 ecosistema. Revista Palabras Claves: &DOLGDGGHODJXD*ODFLDU&RQGRULULPDFUy¿WDVQXWULHQWHV 7 1 Docente Investigadora invitada IIS - UMSA 2 Docente Investigador IIS – UMSA 'RFHQWH,QYHVWLJDGRU+\GUDXOLFVDQG+\GURGLQDPLF/DERUDWRU\±7RKRNX8QLYHUVLW\ 1. Introducción (Q ORV $QGHV FHQWUDOHV HO GHO DJXD VH riri está conformada por una corriente princi- te la época seca (Mayo-Agosto). En base a las origina en las montañas, sirviendo a ecosiste- pal, un sistema de humedales localizados en observaciones efectuadas desde Septiembre de El cambio climático está afectando a todos los mas y poblaciones circundantes (Vuille et al., la parte central y tres lagunas (Khellual Kho- 2011 a Agosto de 2012, la precipitación total ecosistemas en el mundo, especialmente a los 0XFKDV FLXGDGHV VLWXDGDV VREUH ORV ta, Chiar Khota y Kallan Khota), ubicadas en para las épocas de lluvias y de estiaje fue de glaciares tropicales. El retroceso de los gla- 2500 m.s.n.m. dependen casi por completo de ORVNLOyPHWURV\UHVSHFWLYDPHQWH$O 624 mm y 19 mm, respectivamente. La vegeta- ciares afecta a la calidad y disponibilidad del las reservas de agua de los glaciares (Brad- pie de los glaciares en la parte superior de la ción acuática en el río Condoriri está compuesta agua, particularmente, en las regiones mon- ley et al., 2006). El río en cual se enfoca este cuenca, la composición geológica de las rocas SULQFLSDOPHQWHSRUPDFUy¿WDV\EDMDVFRQFHQ- tañosas en Los Andes. Los glaciares tropicales WUDEDMRSURYHHHOGHODJXDSRWDEOHDODV controla la geoquímica del río como en muchas WUDFLRQHVGHSHUL¿WRQ\¿WRSODQFWRQORVHFRVLV- están sufriendo un rápido retroceso y algunos ciudades de La Paz y El Alto que representan de las montañas en los Andes. Las rocas es- temas acuáticos en los Andes presentan una de ellos ya han desaparecido, tal es el caso del DSUR[LPDGDPHQWHHOGHODSREODFLyQGHO tán compuestas por cuarzo, siderita, hemati- composición similar (Jacobsen et al., 2001). glaciar Chacaltaya en Bolivia (Ramírez et al., país, sus aguas son utilizadas para el consumo ta, apatita, monacita, plagioclasa, portlandita, 2001). humano, la agricultura, la generación de ener- calcita, yeso, moscovita y hauynita. gía eléctrica y mantienen la biodiversidad, por 4. Materiales y métodos La calidad del agua en ríos Ha sido ampliamente esta razón las investigaciones en ecosistemas Figura 1 Cuenca del río Condoriri y puntos de muestreo estudiada, la composición química del acuáticos de glaciar son altamente requeridas En la Fig.1 se exhibe el mapa con los puntos DJXD HVWi LQÀXHQFLDGD SRU YDULRV IDFWRUHV para un mayor entendimiento de las condicio- de muestreo y en la Fig.2 se observa a la la- relacionados a los procesos Hidroquímicos y los nes presentes de los ríos y lagos de glaciares y guna Chiar Khota que se encuentra en la par- nutrientes. La vegetación acuática desempeña el manejo de los recursos hídricos en el futuro. te central de la cuenca. Diecisiete puntos de un rol determinante en el metabolismo y el muestreo fueron establecidos en el río Condo- mantenimiento de la biodiversidad en mucHos riri y las lagunas Khellual Khota, Chiar Khota y ecosistemas acuáticos (Rodríguez et al., 2. Objetivo Kallan Khota (CD1-CD17) y un punto adicional /DLQÀXHQFLDGHODFDUJDGHQXWULHQWHV HQHOÀXMRODWHUDO &'/ FRPRVHPXHVWUDHQOD y la composición química del agua Han sido Objetivo general Fig. 1. 3DUiPHWURV¿VLFRTXtPLFRVFRPRHOS+ evaluadas en importantes ríos del mundo la temperatura del agua, la conductividad eléc- 0H\EHFN Los objetivos claves son evaluar la calidad del trica (CE) y el oxígeno disuelto fueron medidos agua y el crecimiento de las plantas acuáticas in situ utilizando un
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