Ati 316™, Ati 316L™, Ati 317™, Ati 317L™
Total Page:16
File Type:pdf, Size:1020Kb
ATI 316™, ATI 316L™, ATI 317™, ATI 317L™ Technical Data Sheet ATI 316™, ATI 316L™, ATI 317™, ATI 317L™ Stainless Steel: Austenitic (UNS S31600, S31603, S31700, S31703) INTRODUCTION ATI 316™ (UNS S31600), ATI 316L™ (S31603), ATI 317™ (S31700) and ATI 317L™ (S31703) alloys are molybdenum-bearing austenitic stainless steels which are more resistant to general corrosion and pitting/crevice corrosion than the conventional chromium-nickel austenitic stainless steels such as ATI 304. These alloys also offer higher creep, stress-to-rupture and tensile strength at elevated temperature. ATI 317™ and ATI 317L™ alloys containing 3 to 4% molybdenum are preferred to ATI 316™ or ATI 316L™ alloys which contain 2 to 3% molybdenum in applications requiring enhanced pitting and general corrosion resistance. ATI 316LM™ alloy (W.Nr. 1.4404), a 2.5% minimum Mo version of ATI 316L™ stainless steel, is available only by special order. Austenitic stainless steels with higher molybdenum or molybdenum plus nitrogen content which provide even greater resistance to pitting, crevice corrosion and general corrosion are also available in flat-rolled products. These include ATI 316LN™ (UNS S31653), ATI 317LX™ (UNS S31725, 4-5% Mo), ATI 317LXN™ (S31726, 4-5% Mo and 0.1-0.2% N), and AL-6XN® (N08367, 6-7% Mo and 0.18-0.25% N) alloys. Properties of these alloys are described in separate ATI technical data publications available. In addition to excellent corrosion resistance and strength properties, the ATI 316™, ATI 316L™, ATI 317™ and ATI 317L™ Cr- Ni-Mo alloys also provide excellent fabricability and formability which are typical of the austenitic stainless steels. PRODUCT FORMS ATI 316™, ATI 316L™, ATI 317™ and ATI 317L™ stainless steels are available in the form of sheet, strip and plate to ASTM A240 and ASME SA-240 and other pertinent specifications from ATI. Data are typical, are provided for informational purposes, and should not be construed as maximum or minimum values for specification Allegheny Technologies Incorporated or for final design, or for a particular use or application. The data may be revised anytime without notice. We make no representation or 1000 Six PPG Place warranty as to its accuracy and assume no duty to update. Actual data on any particular product or material may vary from those shown Pittsburgh, PA 15222-5479 U.S.A. herein. TM is trademark of and ® is registered trademark of ATI Properties, Inc. or its affiliated companies. ® The starburst logo is a www.ATImetals.com registered trademark of ATI Properties, Inc. © 2014 ATI. All rights reserved. VERSION 1 (2/18/2014): PAGE 1 of 15 ATI 316™, ATI 316L™, ATI 317™, ATI 317L™ Technical Data Sheet Percentage by Weight (maximum unless range is specified) Element ATI 316™ ATI 316L™ ATI 317™ ATI 317L™ Carbon 0.08 0.030 0.08 0.030 Manganese 2.00 2.00 2.00 2.00 Silicon 0.75 0.75 0.75 0.75 Chromium 16.00 16.00 18.00 18.00 18.00 18.00 20.00 20.00 Nickel 10.00 10.00 11.00 11.00 14.00 14.00 15.00 15.00 Molybdenum 2.00 2.00 3.00 3.00 3.00 3.00 4.00 4.00 Phosphorus 0.045 0.045 0.045 0.045 Sulfur 0.030 0.030 0.030 0.030 Nitrogen 0.10 0.10 0.10 0.10 Iron Bal. Bal. Bal. Bal. SPECIFICATIONS & CERTIFICATES Because of the extensive use of ATI 316™, ATI 316L™, ATI 317™ and ATI 317L™ austenitic stainless steels and their broad specification coverage, the following list of specifications is representative, but not complete. ATI 316™, ATI 316L™, ATI 317™ and ATI 317L™ stainless steel product forms are assigned allowable stresses in Section II, Part D of the ASME Boiler and Pressure Vessel Code. For the ATI 316™ and ATI 317™ alloys, the maximum use temperature is 1500°F (816°C), whereas for ATI 316L™ and ATI 317L™ alloys the limit is 850°F (454°C) for Section VIII, Division 1 applications. All of the grades are accepted for use in food preparation and storage by the National Sanitation Foundation and for contact with dairy products by the Dairy and Food Industries Supply Association-Sanitary Standards Committee. ATI 316™ and ATI 316L™, in particular, are standard materials used in each industry. These also find many uses in the brewery and other beverage industries, pharmaceutical and bioprocessing industries. Data are typical, are provided for informational purposes, and should not be construed as maximum or minimum values for specification Allegheny Technologies Incorporated or for final design, or for a particular use or application. The data may be revised anytime without notice. We make no representation or 1000 Six PPG Place warranty as to its accuracy and assume no duty to update. Actual data on any particular product or material may vary from those shown Pittsburgh, PA 15222-5479 U.S.A. herein. TM is trademark of and ® is registered trademark of ATI Properties, Inc. or its affiliated companies. ® The starburst logo is a www.ATImetals.com registered trademark of ATI Properties, Inc. © 2014 ATI. All rights reserved. VERSION 1 (2/18/2014): PAGE 2 of 15 ATI 316™, ATI 316L™, ATI 317™, ATI 317L™ Technical Data Sheet Specification Product Form ASTM ASME Plate, Sheet and Strip A 240 SA-240 Seamless and/or A 249/A 249M SA-249/SA-249M Welded Tubing (316, 316L, 317 (316, 316L, 317 only). A 554 only) A 312/A 312M, A SA-312/SA-312M, Seamless and/or 409/A 409M (316, SA-409/SA-409M Welded Pipe 316L, 317 only) (316, 316L, 317 only) A 276 (316, Bar, Wire 316L, 317 only). SA-479/SA-479M A478, (316, (316, 316L, 317 316L, 317 only). only) A479/A 479M, (316, 316L, 317 only). A 314 (316, Billet, Forgings 316L, 317 only). A473 (316, 316L, 317 only). Flanges, A 182/A 182M, A SA-182/SA-182M, Fittings 403/A 403M SA-403/SA-403M TYPICAL COMPOSITION Chemical composition as represented by ASTM A240 and ASME SA-240 specifications are indicated in the table below. CORROSION RESISTANCE General Corrosion ATI 316™, ATI 316L™, ATI 317™ and ATI 317L™ alloys are more resistant to atmospheric and other mild types of corrosion than the 18-8 stainless steels. In general, media that do not corrode 18-8 stainless steels will not attack these molybdenum-containing grades. One known exception is highly oxidizing acids such as nitric acid to which the molybdenum-bearing stainless steels are less resistant. ATI 316™ and ATI 317™ alloys are considerably more resistant than any of the other chromium-nickel types to solutions of sulfuric acid. At temperatures as high as 120°F (49°C), ATI 316™ and ATI 317™ alloys are resistant to concentrations of this acid up to 5 percent. At temperatures under 100°F (38°C), both types have excellent resistance to higher concentrations. Service tests are usually desirable as operating conditions and acid contaminants may significantly affect corrosion rate. Where condensation of sulfur-bearing gases occurs, these alloys are much more resistant than other types of stainless steels. In such applications, however, the acid concentration has a marked influence on the rate of attack and should be carefully determined. The molybdenum-bearing ATI 316™ and ATI 317™ stainless steels also provide resistance to a wide variety of other environments. As shown by the laboratory corrosion data below, these alloys offer excellent resistance to boiling 20% phosphoric acid. They are also widely used in handling hot organic and fatty acids. This is a factor in the manufacture and handling of certain food and pharmaceutical products where the molybdenum-containing stainless steels are often required in order to minimize metallic contamination. Data are typical, are provided for informational purposes, and should not be construed as maximum or minimum values for specification Allegheny Technologies Incorporated or for final design, or for a particular use or application. The data may be revised anytime without notice. We make no representation or 1000 Six PPG Place warranty as to its accuracy and assume no duty to update. Actual data on any particular product or material may vary from those shown Pittsburgh, PA 15222-5479 U.S.A. herein. TM is trademark of and ® is registered trademark of ATI Properties, Inc. or its affiliated companies. ® The starburst logo is a www.ATImetals.com registered trademark of ATI Properties, Inc. © 2014 ATI. All rights reserved. VERSION 1 (2/18/2014): PAGE 3 of 15 ATI 316™, ATI 316L™, ATI 317™, ATI 317L™ Technical Data Sheet Generally, the ATI 316™ and ATI 316L™ stainless grades can be considered to perform equally well for a given environment. The same is true for ATI 317™ and ATI 317L™ alloys. A notable exception is in environments sufficiently corrosive to cause intergranular corrosion of welds and heat-affected zones on susceptible alloys. In such media, the ATI 316L™ and ATI 317L™ alloys are preferred over ATI 316™ and ATI 317™ alloys, respectively, for the welded condition since low carbon levels enhance resistance to intergranular corrosion. General Corrosion in Boiling Solutions Corrosion Rate, Mils/Yr (mm/a) Boiling ATI 316L™ ATI 317L™ Test Solution Base Metal Welded Base Metal Welded 20% Acetic Acid* 0.12 (<0.01) 0.12 (<0.01) 0.48 (0.01) 0.36 (0.01) 45% Formic Acid 23.4 (0.59) 20.9 (0.53) 18.3 (0.46) 24.2 (0.62) 1% Hydrochloric Acid* 226 (5.74) 300 (7.62) 54.2 (1.38) 51.4 (1.31) 10% Oxalic Acid 48.2 (1.22) 44.5 (1.13) 44.9 (1.14) 43.1 (1.09) 20% Phosphoric Acid* 0.20 (<0.01) 0.20 (<0.01) 0.72 (0.02) 0.60 (0.02) 10% Sulfamic Acid 124 (3.16) 119 (3.03) 94.2 (2.39) 97.9 (2.49) 10% Sulfuric Acid 635 (16.1) 658 (16.7) 298 (7.57) 356 (9.05) 10% Sodium Bisulfate 71.5 (1.82) 56.2 (1.43) 55.9 (1.42) 66.4 (1.69) 50% Sodium Hydroxide 77.6 (1.97) 85.4 (2.17) 32.8 (0.83) 31.9 (0.81) * Samples activated Pitting/Crevice Corrosion Resistance of austenitic stainless steels to pitting and/ or crevice corrosion in the presence of chloride or other halide ions is enhanced by higher chromium (Cr), molybdenum (Mo), and nitrogen (N) content.