PUBLICATIONS Journal of Geophysical Research: Atmospheres RESEARCH ARTICLE Emission of Methane and Heavier Alkanes From 10.1002/2017JD027675 the La Brea Tar Pits Seepage Area, Los Angeles Key Points: G. Etiope1 , L. A. Doezema2 , and C. Pacheco2 • Considerable methane emission from the La Brea park in Los Angeles 1Istituto Nazionale di Geofisica e Vulcanologia, Sezione Roma 2, Roma, Italy, and Faculty of Environmental Science and • Molecular alteration during seepage 2 must be considered in atmospheric Engineering, Babes-Bolyai University, Cluj-Napoca, Romania, Chemistry and Biochemistry, Loyola Marymount University, hydrocarbon emission modeling Los Angeles, CA, USA • A fault seems to act as a main pathway of gas migration from the Salt Lake oil reservoir to the surface Abstract Natural hydrocarbon (oil and gas) seeps are widespread in Los Angeles, California, due to gas migration, along faults, from numerous subsurface petroleum fields. These seeps may represent important Supporting Information: natural contributors of methane (CH4) and heavier alkanes (C2-C4) to the atmosphere, in addition to • Supporting Information S1 anthropogenic fossil fuel and biogenic sources. We measured the CH4 flux by closed-chamber method from the La Brea Tar Pits park (0.1 km2), one of the largest seepage sites in Los Angeles. The gas seepage occurs Correspondence to: throughout the park, not only from visible oil-asphalt seeps but also diffusely from the soil, affecting grass G. Etiope, À1
[email protected] physiology. About 500 kg CH4 d is emitted from the park, especially along a belt of enhanced degassing that corresponds to the 6th Street Fault. Additional emissions are from bubble plumes in the lake within À the park (order of 102–103 kg d 1) and at the intersection of Wilshire Boulevard and Curson Avenue Citation: > À1 fl Etiope, G., Doezema, L.