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SAFETY DATA SHEET C450 Scratch Resistant Rapid Repair Clear

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SAFETY DATA SHEET C450 Scratch Resistant Rapid Repair Clear Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 SAFETY DATA SHEET C450 Scratch Resistant Rapid Repair Clear SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier Product name : C450 Scratch Resistant Rapid Repair Clear Product type : Liquid. Other means of : Not available. identification 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses Use in coatings - Clearcoat 1.3 Details of the supplier of the safety data sheet Valspar b.v. Zuiveringweg 89 8243 PE Lelystad The Netherlands tel: +31 (0)320 292200 fax: +31 (0)320 292201 e-mail address of person : [email protected] responsible for this SDS 1.4 Emergency telephone number National advisory body/Poison Centre Telephone number : UK: 0-800-014-8126 CALL: +(44)-870-8200418 (Hours of operation - 24 hours) Ireland: +353 1 8092566 Beaumont Hospital - National Poisons Information Centre CALL: +(353)-19014670 (Hours of operation - 24 hours) Supplier Telephone number : Call: +31 (0)320 292200 (8:30AM - 5PM) SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition : Mixture Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Flam. Liq. 2, H225 Eye Irrit. 2, H319 Skin Sens. 1, H317 STOT SE 3, H336 Aquatic Chronic 3, H412 The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended. See Section 16 for the full text of the H statements declared above. See Section 11 for more detailed information on health effects and symptoms. 2.2 Label elements Date of issue/Date of revision : 12/8/2020 Date of previous issue : 12/7/2020 Version : 1 1/24 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 C450 Scratch Resistant Rapid Repair Clear SECTION 2: Hazards identification Hazard pictograms : Signal word : Danger Hazard statements : Highly flammable liquid and vapour. May cause an allergic skin reaction. Causes serious eye irritation. May cause drowsiness or dizziness. Harmful to aquatic life with long lasting effects. Precautionary statements Prevention : Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid release to the environment. Response : IF INHALED: Call a POISON CENTER or doctor if you feel unwell. Storage : Store in a well-ventilated place. Keep container tightly closed. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazardous ingredients : acetone 4-chloro-α,α,α-trifluorotoluene Poly(oxy-1,2-ethanediyl), α- [3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropyl]-ω-hydroxy- Hydroxyphenyl-benzotriazole derivate II bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate Supplemental label : Not applicable. elements Annex XVII - Restrictions : Not applicable. on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles Special packaging requirements Containers to be fitted : Not applicable. with child-resistant fastenings Tactile warning of danger : Not applicable. 2.3 Other hazards Other hazards which do : None known. not result in classification SECTION 3: Composition/information on ingredients 3.2 Mixtures : Mixture Date of issue/Date of revision : 12/8/2020 Date of previous issue : 12/7/2020 Version : 1 2/24 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 C450 Scratch Resistant Rapid Repair Clear SECTION 3: Composition/information on ingredients Product/ingredient name Identifiers % Regulation (EC) No. Type 1272/2008 [CLP] acetone REACH #: ≥10 - ≤25 Flam. Liq. 2, H225 [1] [2] 01-2119471330-49 Eye Irrit. 2, H319 EC: 200-662-2 STOT SE 3, H336 CAS: 67-64-1 EUH066 Index: 606-001-00-8 n-butyl acetate REACH #: ≥10 - ≤25 Flam. Liq. 3, H226 [1] [2] 01-2119485493-29 STOT SE 3, H336 EC: 204-658-1 EUH066 CAS: 123-86-4 Index: 607-025-00-1 4-chloro-α,α,α-trifluorotoluene REACH #: ≥10 - ≤17 Flam. Liq. 3, H226 [1] 01-2119857280-40 Skin Sens. 1B, H317 EC: 202-681-1 Aquatic Chronic 2, CAS: 98-56-6 H411 heptan-2-one REACH #: ≥10 - ≤25 Flam. Liq. 3, H226 [1] [2] 01-2119902391-49 Acute Tox. 4, H302 EC: 203-767-1 Acute Tox. 4, H332 CAS: 110-43-0 STOT SE 3, H336 Index: 606-024-00-3 4-methylpentan-2-one REACH #: ≤3 Flam. Liq. 2, H225 [1] [2] 01-2119473980-30 Acute Tox. 4, H332 EC: 203-550-1 Eye Irrit. 2, H319 CAS: 108-10-1 STOT SE 3, H335 Index: 606-004-00-4 EUH066 2-methoxy-1-methylethyl acetate REACH #: ≤3 Flam. Liq. 3, H226 [1] [2] 01-2119475791-29 STOT SE 3, H336 EC: 203-603-9 CAS: 108-65-6 Index: 607-195-00-7 Poly(oxy-1,2-ethanediyl), α- REACH #: <1 Skin Sens. 1A, H317 [1] [3-[3-(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropyl]-ω-hydroxy- 01-0000015075-76 Aquatic Chronic 2, CAS: 104810-48-2 H411 Hydroxyphenyl-benzotriazole REACH #: <1 Skin Sens. 1A, H317 [1] derivate II 01-0000015075-76 Aquatic Chronic 2, CAS: 104810-47-1 H411 bis(1,2,2,6,6-pentamethyl- REACH #: ≤0.56 Skin Sens. 1A, H317 [1] 4-piperidyl) sebacate 01-2119537297-32 Aquatic Acute 1, H400 EC: 255-437-1 (M=1) CAS: 41556-26-7 Aquatic Chronic 1, H410 (M=1) 1-methoxy-2-propanol REACH #: ≤0.3 Flam. Liq. 3, H226 [1] [2] 01-2119457435-35 STOT SE 3, H336 EC: 203-539-1 CAS: 107-98-2 Index: 603-064-00-3 dioctyltin dilaurate REACH #: ≤0.3 STOT SE 2, H371 [1] [2] 01-2119979527-19 (oral) EC: 222-883-3 CAS: 3648-18-8 methyl 1,2,2,6,6-pentamethyl- EC: 280-060-4 ≤0.18 Skin Sens. 1A, H317 [1] 4-piperidyl sebacate CAS: 82919-37-7 Aquatic Acute 1, H400 (M=1) Aquatic Chronic 1, H410 (M=1) 2-butoxyethanol REACH #: ≤0.1 Acute Tox. 4, H302 [1] [2] 01-2119475108-36 Acute Tox. 4, H312 EC: 203-905-0 Acute Tox. 4, H332 CAS: 111-76-2 Skin Irrit. 2, H315 Index: 603-014-00-0 Eye Irrit. 2, H319 Date of issue/Date of revision : 12/8/2020 Date of previous issue : 12/7/2020 Version : 1 3/24 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU) 2015/830 C450 Scratch Resistant Rapid Repair Clear SECTION 3: Composition/information on ingredients See Section 16 for the full text of the H statements declared above. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section. Type [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII [5] Substance of equivalent concern [6] Additional disclosure due to company policy Occupational exposure limits, if available, are listed in Section 8. SECTION 4: First aid measures 4.1 Description of first aid measures General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and seek medical advice. Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10 minutes and seek immediate medical advice. Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners. Ingestion : If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do NOT induce vomiting. Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. 4.2 Most important symptoms and effects, both acute and delayed There are no data available on the mixture itself. The mixture has been assessed following the conventional method of the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2 and 3 for details. Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through the skin.
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