DOCSLIB.ORG

University of California Riverside

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
University of California Riverside UNIVERSITY OF CALIFORNIA RIVERSIDE Investigation of Photoelectric Effect in Transition Metal Dichalcogenides Field Effect Transistors A Thesis submitted in partial satisfaction of the requirements for the degree of Master of Science in Materials Science and Engineering by I-Hsi Daniel Lu September 2017 Thesis Committee: Dr. Ludwig Bartels, Chairperson Dr. Richard Wilson Dr. Sinisa Coh Copyright by I-Hsi Daniel Lu 2017 The Thesis of I-Hsi Daniel Lu is approved: Committee Chairperson University of California, Riverside Acknowledgements I would like to thank my principal investigator and advisor, Professor Ludwig Bartels, for his guidance over these past two years. I especially want to thank him for giving me many opportunities to learn and explore the semiconductor field. Over the last two years, I have had a chance to lead and support many projects from the group, collaborators, and national labs. I would like to thank Professor Bartels for sending me to different collaborators and conferences where I excel in developing new skills and presenting my work to the representatives from industries. I would like to thank Professor Richard Wilson and Professor Sinisa Coh for serving on my master thesis committees. I thank you for your time and support for my thesis defense in such short notice. I would like to thank all my published co-authorship works in ACS Nano, 2D Materials, Nano Letters, Nature Communications, ACS photonics, and Applied Physics Letters. I would like to thank the following professors for the publications: John Mann, Joshua C. H. Lui, Volker J. Sorger, Hubert J. Krenner, Velveth Klee, and Evan J. Reed. I would like to thank my family for always being supportive. I would also like to thank my colleagues in Bartels’ group, and in Sorger’s group. Thank you for making my graduate career fun and engaging. Lastly, I want to thank Cindy Merida for always being supportive and helpful during my career. iv Table of Contents Chapter 1: Introduction ................................................................ 1 Overview ..................................................................................................................................... 1 Introduction to TMDs................................................................................................................ 1 Instrumentation ......................................................................................................................... 1 Raman Spectroscopy ............................................................................................................. 2 Photoluminescence Spectroscopy ......................................................................................... 2 Chapter 2: Materials and Methods .............................................. 4 Chemical Vapor Deposition ...................................................................................................... 4 Chapter 3: Electrical contacts and Measurements on TMDs .... 7 Electron Beam Lithography ...................................................................................................... 7 MOSFET ..................................................................................................................................... 9 Electrical Probe Station ............................................................................................................. 9 Scanning Photocurrent Microscopy ....................................................................................... 10 Chapter 4: Composition-dependent photocurrent in CVD- grown Monolayer MoS2(1-x)Se2x Alloy Devices ........................... 14 Introduction .............................................................................................................................. 14 Methods ..................................................................................................................................... 15 Results and Discussion ............................................................................................................. 17 Conclusion ................................................................................................................................ 29 Chapter 5: Ferroelectric Control of 2D MoS2 ........................... 31 Introduction .............................................................................................................................. 31 Methods ..................................................................................................................................... 32 Results and Discussion ............................................................................................................. 33 Conclusion ................................................................................................................................ 43 Chapter 6: Hybrid Field-Effect and Acousto-Electric Devices 45 Introduction .............................................................................................................................. 45 Methods ..................................................................................................................................... 46 Results and Discussion ............................................................................................................. 48 v Conclusion ................................................................................................................................ 56 Figures ....................................................................................................................................... 58 Chapter 7: WS2 Band Structure ................................................. 62 Introduction .............................................................................................................................. 62 Methods ..................................................................................................................................... 63 Results and Discussion ............................................................................................................. 64 Figures ....................................................................................................................................... 69 Chapter 8: Tunable Properties of CVD Growth of Few-Layer MoTe2 ............................................................................................. 73 Introduction .............................................................................................................................. 73 Methods ..................................................................................................................................... 74 Results and Discussion ............................................................................................................. 74 Conclusion ................................................................................................................................ 78 Figures ....................................................................................................................................... 79 Chapter 9: Interlayer Breathing and Shear Modes in NbSe2 atomic layers ................................................................................. 82 Introduction .............................................................................................................................. 82 Methods ..................................................................................................................................... 83 Results and Discussion ............................................................................................................. 84 Conclusion ................................................................................................................................ 87 Figures ....................................................................................................................................... 89 Chapter 10: Efficacy of Light Emission Enhancement in Nanoscale Antenna ....................................................................... 92 Introduction .............................................................................................................................. 93 Methods ..................................................................................................................................... 93 Results and Discussion ............................................................................................................. 95 Conclusion ................................................................................................................................ 96 Figures ....................................................................................................................................... 98 References ................................................................................... 102 vi List of Figures Figure 1 ........................................................................................................................................... 4 Figure 2 ........................................................................................................................................... 5 Figure 3 ........................................................................................................................................... 8 Figure 4 ........................................................................................................................................
Load more

Recommended publications
  • The Photoelectric Effect in Photocells Suggested Level: High School Physics Or Chemistry Classes
    The Photoelectric Effect in Photocells Suggested Level: High School Physics or Chemistry Classes LEARNING OUTCOME After engaging in background reading on electromagnetic energy and exploring the frequencies of various colors of light, students realize that it is useful to think of light waves as streams of particles called quanta, and understand that the energy of each quantum depends on its frequency. LESSON OVERVIEW This lesson introduces students to the photoelectric effect (the basic physical phenomenon underlying the operation of photovoltaic cells) and the role of quanta of various frequencies of electromagnetic energy in producing it. The inadequacy of the wave theory of light in explaining photovoltaic effects is explored, as is the ionization energies for elements in the third row of the periodic table. MATERIALS • Student handout • Roll of masking tape • Ball of yarn • Scrap paper SAFETY • There are no safety precautions for this lesson. TEACHING THE LESSON Begin by explaining the structure and operation of photovoltaic cells, covering the information in the student handout and drawing from the background information below. Stake off an area of the classroom in which about two-thirds of your students can stand. It could, for example, be bounded by tape on the floor. This area is to represent a photovoltaic cell. Have half of your students form a line dividing the area in half. They represent the electrons lined up on the p-side of the p-n junction. Stretch yarn from the n-type semiconductor to one student chosen to represent a light bulb and from that student to the p-type semiconductor.
    [Show full text]
  • Introduction to Photovoltaic Technology WGJHM Van Sark, Utrecht University, Utrecht, the Netherlands
    1.02 Introduction to Photovoltaic Technology WGJHM van Sark, Utrecht University, Utrecht, The Netherlands © 2012 Elsevier Ltd. 1.02.1 Introduction 5 1.02.2 Guide to the Reader 6 1.02.2.1 Quick Guide 6 1.02.2.2 Detailed Guide 7 1.02.2.2.1 Part 1: Introduction 7 1.02.2.2.2 Part 2: Economics and environment 7 1.02.2.2.3 Part 3: Resource and potential 8 1.02.2.2.4 Part 4: Basics of PV 8 1.02.2.2.5 Part 5: Technology 8 1.02.2.2.6 Part 6: Applications 10 1.02.3 Conclusion 11 References 11 Glossary Photovoltaic system A number of PV modules combined Balance of system All components of a PV energy system in a system in arrays, ranging from a few watts capacity to except the photovoltaics (PV) modules. multimegawatts capacity. Grid parity The situation when the electricity generation Photovoltaic technology generations PV technologies cost of solar PV in dollar or Euro per kilowatt-hour equals can be classified as first-, second-, and third-generation the price a consumer is charged by the utility for power technologies. First-generation technologies are from the grid. Note, grid parity for retail markets is commercially available silicon wafer-based technologies, different from wholesale electricity markets. second-generation technologies are commercially Inverter Electronic device that converts direct electricity to available thin-film technologies, and third-generation alternating current electricity. technologies are those based on new concepts and Photovoltaic energy system A combination of a PV materials that are not (yet) commercialized.
    [Show full text]
  • The History of Solar
    Solar technology isn’t new. Its history spans from the 7th Century B.C. to today. We started out concentrating the sun’s heat with glass and mirrors to light fires. Today, we have everything from solar-powered buildings to solar- powered vehicles. Here you can learn more about the milestones in the Byron Stafford, historical development of solar technology, century by NREL / PIX10730 Byron Stafford, century, and year by year. You can also glimpse the future. NREL / PIX05370 This timeline lists the milestones in the historical development of solar technology from the 7th Century B.C. to the 1200s A.D. 7th Century B.C. Magnifying glass used to concentrate sun’s rays to make fire and to burn ants. 3rd Century B.C. Courtesy of Greeks and Romans use burning mirrors to light torches for religious purposes. New Vision Technologies, Inc./ Images ©2000 NVTech.com 2nd Century B.C. As early as 212 BC, the Greek scientist, Archimedes, used the reflective properties of bronze shields to focus sunlight and to set fire to wooden ships from the Roman Empire which were besieging Syracuse. (Although no proof of such a feat exists, the Greek navy recreated the experiment in 1973 and successfully set fire to a wooden boat at a distance of 50 meters.) 20 A.D. Chinese document use of burning mirrors to light torches for religious purposes. 1st to 4th Century A.D. The famous Roman bathhouses in the first to fourth centuries A.D. had large south facing windows to let in the sun’s warmth.
    [Show full text]
  • Polymeric Materials for Conversion of Electromagnetic Waves from the Sun to Electric Power
    polymers Review Polymeric Materials for Conversion of Electromagnetic Waves from the Sun to Electric Power SK Manirul Haque 1, Jorge Alfredo Ardila-Rey 2, Yunusa Umar 1 ID , Habibur Rahman 3, Abdullahi Abubakar Mas’ud 4,*, Firdaus Muhammad-Sukki 5 ID and Ricardo Albarracín 6 ID 1 Department of Chemical and Process Engineering Technology, Jubail Industrial College, P.O. Box 10099, Jubail 31961, Saudi Arabia; [email protected] (S.M.H.); [email protected] (Y.U.) 2 Department of Electrical Engineering, Universidad Técnica Federico Santa María, Santiago de Chile 8940000, Chile; [email protected] 3 Department of General Studies, Jubail Industrial College, P.O. Box 10099, Jubail 31961, Saudi Arabia; [email protected] 4 Department of Electrical and Electronics Engineering, Jubail Industrial College, P.O. Box 10099, Jubail 319261, Saudi Arabia 5 School of Engineering, Robert Gordon University, Garthdee Road, Aberdeen AB10 7QB, Scotland, UK; [email protected] 6 Departamento de Ingeniería Eléctrica, Electrónica, Automática y Física Aplicada, Escuela Técnica Superior de Ingeniería y Diseño Industrial, Universidad Politécnica de Madrid, Ronda de Valencia 3, 28012 Madrid, Spain; [email protected] * Correspondence: [email protected]; Tel.: +966-53-813-8814 Received: 10 February 2018; Accepted: 6 March 2018; Published: 12 March 2018 Abstract: Solar photoelectric energy converted into electricity requires large surface areas with incident light and flexible materials to capture these light emissions. Currently, sunlight rays are converted to electrical energy using silicon polymeric material with efficiency up to 22%. The majority of the energy is lost during conversion due to an energy gap between sunlight photons and polymer energy transformation.
    [Show full text]
  • Determination of the Main Parameters of the Photovoltaic Solar Module
    E3S Web of Conferences 191, 01004 (2020) https://doi.org/10.1051/e3sconf/202019101004 REEE 2020 Determination of the main parameters of the photovoltaic solar module Baydaulet A.Urmashev1, Murat Kunelbayev2*, Almas N.Temirbekov3, Syrym Kassenov4, Zhadra Zhaksylykova5, Farida Amenova6 1,3Department of Computer Science, Kazakh National University named after al-Farabi, Almaty, Republic of Kazakhstan 2Institute Information and Computational Technologies CS MES RK, Almaty, Republic of Kazakhstan 4Faculty of Mechanical Mathematics, al-Farabi Kazakh National University, Almaty, Kazakhstan 5Abay Kazakh National Pedagogical University, Almaty, Republic of Kazakhstan 6S. Amanzholov East Kazakhstan State University, Department of Mathematics, Faculty of Science and Technology Ust-Kamenogorsk, Republic of Kazakhstan Abstract. This article deals with the determination of the main operating parameters of a photovoltaic solar module. In laboratory tests, the study of the dependence of current, voltage and power on time and density of solar radiation, as well as monitoring of environmental parameters: temperature and humidity of the outside air. Analysis of the test results shows that a photoelectric module with an installed capacity of 800 W and a total battery capacity of 800 Ah provides the electric power industry with a daily consumption of 2.0 ... 2.2 kWh. The discharge time of the battery varies from 11.7 to 3.5 hours when the average electric load of the consumer changes from 300 to 1000 watts. homogeneous structure. The basis for the formation of cells that are suitable silicon-sized blocks. 1 Introduction They are cut into plates whose thickness is Solar cells in the production of electricity from about 0.3 mm.
    [Show full text]
  • WO 2018/222569 Al 06 December 2018 (06.12.2018) W !P O PCT
    (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2018/222569 Al 06 December 2018 (06.12.2018) W !P O PCT (51) International Patent Classification: KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, C01B 3/00 (2006.01) MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, (21) International Application Number: SC, SD, SE, SG, SK, SL, SM, ST, SV, SY,TH, TJ, TM, TN, PCT/US20 18/034842 TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (22) International Filing Date: (84) Designated States (unless otherwise indicated, for every 29 May 2018 (29.05.2018) kind of regional protection available): ARIPO (BW, GH, (25) Filing Language: English GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, (26) Publication Langi English TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, (30) Priority Data: EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, 62/5 13,284 31 May 2017 (3 1.05.2017) US MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, 62/5 13,324 31 May 2017 (3 1.05.2017) US TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, 62/524,307 23 June 2017 (23.06.2017) US KM, ML, MR, NE, SN, TD, TG).
    [Show full text]
  • DSSC) Lecture for ENG 230
    Dye Sensitized Solar Cell (DSSC) Lecture for ENG 230 May be 50 minutes of 3 hr lab.- would follow 30 minutes of cell assembly INTRODUCTION Economics Solar cells absorb some of the photons from sunlight and convert it to a useable amount of direct current electricity. The costs of solar power have been declining steadily and eventually will be competitive with traditional dirty sources of power which are currently contributing to climate change. The solar power falling on about one square mile is around 3 gigawatts, so a 30% efficient cell would produce 1 gigawatt per sq mile, the same as a nuclear plant. The cost of solar is not just in the cells but in the structure to hold the cells in all weathers, and in some cases to orient the cells to the sun. However, the cell cost is significant, and the DSSC combines the natural photovoltaic effect of pigments with nanotechnology to make it competitive with the silicon cells which are in production. The Photovoltaic Effect The photovoltaic effect is the creation of voltage in a material upon exposure to light. Though the photovoltaic effect is directly related to the photoelectric effect, they are different processes. In the photoelectric effect, electrons are ejected from a material's surface upon exposure to radiation. The photovoltaic effect differs in that electrons are transferred between different bands (i.e., from the valence to conduction bands) within the material, resulting in the buildup of voltage between two electrodes. Illuminating the material creates an electric current as excited electrons and the remaining holes are swept in different directions by the built-in electric field of the depletion region.
    [Show full text]
  • The Cavity QED Induced Thermophotovoltaic Effect
    Asian J. Energy Environ., Vol. 4, Issues 3-4, (2003), pp. 163-183 The Cavity QED Induced Thermophotovoltaic Effect T. V. Prevenslik 14B, Brilliance Court, Discovery Bay, Hong Kong Email: [email protected] (Received : 15 October 2003 – Accepted : 26 November 2003) Abstract : Thermophotovoltaic (TPV) devices comprise a heater separated from a photocell by a microscopic gap. As the gap is slowly reduced, the photocell current increases while the temperature drops suggesting an underlying thermal mechanism. Conversely, a non-thermal mechanism is indicated since the current remains in phase with rapid gap changes that are faster than the response time of the heater. Both slow and rapid TPV responses may be explained by a theory based on the modification of thermal blackbody (BB) radiation by the gap as a quantum electrodynamics (QED) cavity, the theory called the cavity QED induced TPV effect. By varying the gap, the electromagnetic (EM) resonance of the QED cavity may be adjusted from infrared (IR) to vacuum ultraviolet (VUV) frequencies. At typical heater temperature, the thermal kT energy of the atoms is emitted in the far IR, but the photocells are only sensitive over a small range of frequencies in the near Copyright © 2003 by the Joint Graduate School of Energy and Environment 163 T. V. Prevenslik IR. Thus, for large gaps having EM resonance beyond the far IR, the gap does not modify the BB spectrum, and therefore the photocell current is negligible because of the lack of near IR photons. But if the gap resonance is adjusted to the near IR, the far IR radiation undergoes a frequency up-conversion to produce near IR photons that dramatically increase the photocell current, the frequency up-conversion a consequence of conserving EM energy within cavity QED constraints.
    [Show full text]
  • A Potential Pathway to High Efficiency Concentrated Solar Power
    Energy & Environmental Science View Article Online PAPER View Journal | View Issue Thermophotovoltaics: a potential pathway to high efficiency concentrated solar power† Cite this: Energy Environ. Sci., 2016, 9,2654 Hamid Reza Seyf*a and Asegun Henryabc A high temperature thermophotovoltaic (TPV) system is modeled and its system level performance is assessed in the context of concentrated solar power (CSP) with thermal energy storage (TES). The model includes the treatment of the emitter and the heat transfer fluid that draws thermal energy from the TES, which then allows for the identification and prioritization of the most important TPV cell/ module level properties that should be optimized to achieve maximum performance. The upper limiting efficiency for an idealized system is then calculated, which shows that TPV with TES may one day have the potential to become competitive with combined cycle turbines, but could also offer other Received 12th May 2016, advantages that would give CSP an advantage over fossil based alternatives. The system concept is Accepted 4th July 2016 enabled by the usage of liquid metal as a high temperature heat transfer and TES fluid. The system DOI: 10.1039/c6ee01372d concept combines the great economic advantages of TES with the potential for low cost and high performance derived from TPV cells fabricated on reusable substrates, with a high reflectivity back www.rsc.org/ees reflector for photon recycling. Broader context Current approaches to concentrated solar power (CSP) rely on the same heat engines as fossil fuels, and thus the only way CSP can become cost competitiveisif the cost of collecting and storing high temperature heat from the sun can become less expensive than the heat delivered by fossil fuels.
    [Show full text]
  • Senior Project: Solar Bench
    1 Senior Project: Solar Bench Submitted by: Meshari Alharbi, Electrical Engineering Sponsored by University of Evansville Submitted to: DR. Christina Howe Project advisor: Dr. Mohsen Lotfalian Date and Place: March 25, 2017 2 Acknowledgements: I wish to express my gratitude to Dr. Lotfalian for advising my project, and Mr. Jeff Cron for his help with acquiring parts support, guidance and encouragement, without which this project wouldn’t have come forth. I would like also to express my gratitude to the staff of the Electrical Engineering Department for their support during the project. 3 Table of Contents: I. Introduction II. Problem Definition III. Design Approach . Main parts . IV. Safety and Environment V. Standards VI. Expected Result VII. References VIII. Appendix 4 Table of Figures: Figure 1: PV system Demo Figure 2: Arduino Nano layout Figure 3: MP1584EN Buck converter Figure 4: MP1584EN buck converter performance Figure 5: Schematics for the charge controller Figure 6: Final demo of the solar bench Table of tables: Table 1: Solar panels specification Table 2: Charge controller specifications Table 3: Charge controller parts coast 5 Solar Bench I. Introduction: In today’s technology, many products are being redesigned to be more efficient. As more products become more portable, the demand for portable power increases. Due to the limitations of fossil fuels, solar energy is becoming more popular as the renewable energy source that could change the future. The world depended on oil and gas as the main sources of energy, which damage the environment in many aspects. Some Engineers are trying to make energy without effecting the environment (renewable energy), for example oxygen, fresh water, solar, timber, and biomass energy.
    [Show full text]
  • The Photoelectric Effect
    PHOTOELECTRIC EFFECT The Photoelectric Effect In 1887 German physicist Heinrich Hertz discovered that electric charge is emitted from the surface of a metal body when illuminated with ultraviolet light. More careful investigation showed that electromagnetic radiation is able to release electrons from the surface of a metal. This phenomenon is now known as the photoelectric effect. Electron emission occurs only if the frequency of incident light exceeds the characteristic cut-off frequency of the particular metal. Importantly, the photoelectric effect cannot be explained in terms of classical physics with light modeled as a wave. Electric charge and discharge Here we explore the electric charging and discharging of an aluminium can, using ultraviolet light. Follow the steps and record your observations in the table below. Remove any dirt or build up of aluminium oxide on the can using the sandpaper provided. Place the aluminium can on the electroscope and transfer electric charge to the can using an ebonite rod. What type of electric charge is generated in this way? Illuminate the cleaned surface of the can with light from a torch. What do you notice? Using goggles, illuminate the same surface with ultraviolet (UV) light. What do you notice? Now use a glass rod to transfer electric charge to the aluminium can. What type of electric charge is generated in this way? Illuminate the cleaned surface of the can with light from a torch. What do you notice? Illuminate the same surface with ultraviolet light. What do you notice? Type of light Negative charge Positive charge Bright white light Dim white light Bright UV light Dim UV light Which particles of the metal do you think are being emitted as the can discharges? PAGE 1 / 8 PHOTOELECTRIC EFFECT An electric charge can be interpreted as an excess or a deficit of electrons.
    [Show full text]
  • T12. the Photoelectric Effect and Planck's Constant
    EXPERIMENT 12 THE PHOTOELECTRIC EFFECT AND PLANCK'S CONSTANT White light that is passed through various filters illuminates the photoelectric surface of a phototube causing photoelectrons to be emitted with energies dependent upon the energy of the light hitting the surface. The electrons then flow through the phototube to the collector and constitute a current flow. A voltage called the stopping voltage or stopping potential is applied to halt the flow of photoelectrons. If the frequencies or wavelengths of the incoming light and the corresponding stopping voltages are known, then the value of Planck's Constant can be found. THEORY When light strikes a metallic surface, electrons are emitted from the surface. This effect is called the photoelectric effect. The emitted electrons, called photoelectrons, have varying kinetic energies that are primarily dependent upon the frequency of the light that strikes the surface. (See Figure 1.) Figure 1. Light strikes a metallic surface and causes the emission of photoelectrons. In 1905 Albert Einstein was able to provide an explanation of the photoelectric effect. He proposed that light acts like a particle having energy equal to nf, where n is Planck's constant and f is the frequency of the incident light. These particles of light, called photons or quanta collide with and transfer energy to the electrons in the metal. The emitted electrons then use part of this energy to migrate to the surface of the metal and part to free themselves from the electrostatic attraction of the metallic surface; the remainder goes into the kinetic energy of the electrons. For those electrons at the surface of the metal, no energy is used by the electrons to migrate to the surface, and thus, these electrons end up with the maximum possible kinetic energy, Kmax.
    [Show full text]