Smouldering Natural Fires: Comparison of Burning Dynamics in Boreal Peat and Mediterranean Humus
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Module III – Fire Analysis Fire Fundamentals: Definitions
Module III – Fire Analysis Fire Fundamentals: Definitions Joint EPRI/NRC-RES Fire PRA Workshop August 21-25, 2017 A Collaboration of the Electric Power Research Institute (EPRI) & U.S. NRC Office of Nuclear Regulatory Research (RES) What is a Fire? .Fire: – destructive burning as manifested by any or all of the following: light, flame, heat, smoke (ASTM E176) – the rapid oxidation of a material in the chemical process of combustion, releasing heat, light, and various reaction products. (National Wildfire Coordinating Group) – the phenomenon of combustion manifested in light, flame, and heat (Merriam-Webster) – Combustion is an exothermic, self-sustaining reaction involving a solid, liquid, and/or gas-phase fuel (NFPA FP Handbook) 2 What is a Fire? . Fire Triangle – hasn’t change much… . Fire requires presence of: – Material that can burn (fuel) – Oxygen (generally from air) – Energy (initial ignition source and sustaining thermal feedback) . Ignition source can be a spark, short in an electrical device, welder’s torch, cutting slag, hot pipe, hot manifold, cigarette, … 3 Materials that May Burn .Materials that can burn are generally categorized by: – Ease of ignition (ignition temperature or flash point) . Flammable materials are relatively easy to ignite, lower flash point (e.g., gasoline) . Combustible materials burn but are more difficult to ignite, higher flash point, more energy needed(e.g., wood, diesel fuel) . Non-Combustible materials will not burn under normal conditions (e.g., granite, silica…) – State of the fuel . Solid (wood, electrical cable insulation) . Liquid (diesel fuel) . Gaseous (hydrogen) 4 Combustion Process .Combustion process involves . – An ignition source comes into contact and heats up the material – Material vaporizes and mixes up with the oxygen in the air and ignites – Exothermic reaction generates additional energy that heats the material, that vaporizes more, that reacts with the air, etc. -
Safety Data Sheet
Coghlan’s Magnesium Fire Starter #7870 SAFETY DATA SHEET This Safety Data Sheet complies with the Canadian Hazardous Product Regulations, the United States Occupational Safety and Health Administration (OSHA) Hazard Communication Standard, 29 CFR 1910 (OSHA HCS), and the European Union Directives. 1. Product and Supplier Identification 1.1 Product: Magnesium Fire Starter 1.2 Other Means of Identification: Coghlan’s #7870 1.3 Product Use: Fire starter 1.4 Restrictions on Use: None known 1.5 Producer: Coghlan’s Ltd., 121 Irene Street, Winnipeg, Manitoba Canada, R3T 4C7 Telephone: +1(204) 284-9550 Facsimile: +1(204) 475-4127 Email: [email protected] Supplier: As above 1.6 Emergencies: +1(877) 264-4526 2. Hazards Identification 2.1 Classification of product or mixture This product is an untested preparation. GHS classification for this preparation is based upon its use as a fire starter by making shavings and small particulate from the metal block. As shipped in mass form, this preparation is not considered to be a hazardous product and is not classifiable under the requirements of GHS. GHS Classification: Flammable Solids, Category 1 2.2 GHS Label Elements, including precautionary statements Pictogram: Signal Word: Danger Page 1 of 11 October 18, 2016 Coghlan’s Magnesium Fire Starter #7870 GHS Hazard Statements: H228: Flammable Solid GHS Precautionary Statements: Prevention: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280: Wear protective gloves, eye and face protection Response: P370+P378: In case of fire use water as first choice. Sand, earth, dry chemical, foam or CO2 may be used to extinguish. -
Operating and Maintaining a Wood Heater
OPERATING AND MAINTAINING A WOODHEATER FIREWOOD ASSOCIATION THE FIREWOODOF AUSTRALIA ASSOCIATION INC. OF AUSTRALIA INC. Building a wood fire Maintaining a wood heater For any fire to start and keep going three things are needed, Even in correctly operated wood heaters and fireplaces, some fuel, oxygen and heat. In wood fires the fuel is provided by the of the combustion gases will condense on the inside of the wood, the oxygen comes from the air, and the initial heat comes flue or chimney as a black tar-like substance called creosote. from burning paper or a fire lighter. In a going fire the heat is If this substance is allowed to build up it will restrict the air flow provided by the already burning wood. Without fuel, heat and in the heater or fireplace, reducing its efficiency. Eventually oxygen the fire will go out. When the important role of oxygen a build up of creosote can completely block the flue, making is understood, it is easy to see why you need plenty of air space around each piece of kindling when setting up the fire. the fire impossible to operate. One sign of a blocked flue is smoke coming into the room when you open the heater door. Kindling catches fire easily because it has a large surface Creosote appearing on the glass door is another indication area and small mass, which allows it to reach combustion that your heater is not working properly. Because creosote temperature quickly. The surface of a large piece of wood is flammable, if the chimney or flue gets hot enough the will not catch fire until it has been brought up to combustion creosote can catch alight, causing a dangerous chimney fire. -
Smoke Alarms in US Home Fires Marty Ahrens February 2021
Smoke Alarms in US Home Fires Marty Ahrens February 2021 Copyright © 2021 National Fire Protection Association® (NFPA®) Key Findings Smoke alarms were present in three-quarters (74 percent) of the injuries from fires in homes with smoke alarms occurred in properties reported homei fires in 2014–2018. Almost three out of five home with battery-powered alarms. When present, hardwired smoke alarms fire deathsii were caused by fires in properties with no smoke alarms operated in 94 percent of the fires considered large enough to trigger a (41 percent) or smoke alarms that failed to operate (16 percent). smoke alarm. Battery-powered alarms operated 82 percent of the time. Missing or non-functional power sources, including missing or The death rate per 1,000 home structure fires is 55 percent lower in disconnected batteries, dead batteries, and disconnected hardwired homes with working smoke alarms than in homes with no alarms or alarms or other AC power issues, were the most common factors alarms that fail to operate. when smoke alarms failed to operate. Of the fire fatalities that occurred in homes with working smoke Compared to reported home fires with no smoke alarms or automatic alarms, 22 percent of those killed were alerted by the device but extinguishing systems (AES) present, the death rate per 1,000 reported failed to respond, while 11 percent were not alerted by the operating fires was as follows: alarm. • 35 percent lower when battery-powered smoke alarms were People who were fatally injured in home fires with working smoke present, but AES was not, alarms were more likely to have been in the area of origin and • 51 percent lower when smoke alarms with any power source involved in the ignition, to have a disability, to be at least 65 years were present but AES was not, old, to have acted irrationally, or to have tried to fight the fire themselves. -
Learn the Facts: Fuel Consumption and CO2
Auto$mart Learn the facts: Fuel consumption and CO2 What is the issue? For an internal combustion engine to move a vehicle down the road, it must convert the energy stored in the fuel into mechanical energy to drive the wheels. This process produces carbon dioxide (CO2). What do I need to know? Burning 1 L of gasoline produces approximately 2.3 kg of CO2. This means that the average Canadian vehicle, which burns 2 000 L of gasoline every year, releases about 4 600 kg of CO2 into the atmosphere. But how can 1 L of gasoline, which weighs only 0.75 kg, produce 2.3 kg of CO2? The answer lies in the chemistry! Î The short answer: Gasoline contains carbon and hydrogen atoms. During combustion, the carbon (C) from the fuel combines with oxygen (O2) from the air to produce carbon dioxide (CO2). The additional weight comes from the oxygen. The longer answer: Î So it’s the oxygen from the air that makes the exhaust Gasoline is composed of hydrocarbons, which are hydrogen products heavier. (H) and carbon (C) atoms that are bonded to form hydrocarbon molecules (C H ). Air is primarily composed of X Y Now let’s look specifically at the CO2 reaction. This reaction nitrogen (N) and oxygen (O2). may be expressed as follows: A simplified equation for the combustion of a hydrocarbon C + O2 g CO2 fuel may be expressed as follows: Carbon has an atomic weight of 12, oxygen has an atomic Fuel (C H ) + oxygen (O ) + spark g water (H O) + X Y 2 2 weight of 16 and CO2 has a molecular weight of 44 carbon dioxide (CO2) + heat (1 carbon atom [12] + 2 oxygen atoms [2 x 16 = 32]). -
Combustion Chemistry William H
Combustion Chemistry William H. Green MIT Dept. of Chemical Engineering 2014 Princeton-CEFRC Summer School on Combustion Course Length: 15 hrs June 2014 Copyright ©2014 by William H. Green This material is not to be sold, reproduced or distributed without prior written permission of the owner, William H. Green. 1 Combustion Chemistry William H. Green Combustion Summer School June 2014 2 Acknowledgements • Thanks to the following people for allowing me to show some of their figures or slides: • Mike Pilling, Leeds University • Hai Wang, Stanford University • Tim Wallington, Ford Motor Company • Charlie Westbrook (formerly of LLNL) • Stephen J. Klippenstein (Argonne) …and many of my hard-working students and postdocs from MIT 3 Overview Part 1: Big picture & Motivation Part 2: Intro to Kinetics, Combustion Chem Part 3: Thermochemistry Part 4: Kinetics & Mechanism Part 5: Computational Kinetics Be Prepared: There will be some Quizzes and Homework 4 Part 1: The Big Picture on Fuels and Combustion Chemistry 5 What is a Fuel? • Fuel is a material that carries energy in chemical form. • When the fuel is reacted (e.g. through combustion), most of the energy is released as heat • Though sometimes e.g. in fuel cells or flow batteries it can be released as electric power • Fuels have much higher energy densities than other ways of carrying energy. Very convenient for transportation. • The energy is released via chemical reactions. Each fuel undergoes different reactions, with different rates. Chemical details matter. 6 Transportation Fuel: Big Issues •People want, economy depends on transportation • Cars (growing rapidly in Asia) • Trucks (critical for economy everywhere) • Airplanes (growing rapidly everywhere) • Demand for Fuel is “Inelastic”: once they have invested in a vehicle, people will pay to fuel it even if price is high •Liquid Fuels are Best • Liquids Flow (solids are hard to handle!) • High volumetric and mass energy density • Easy to store, distribute. -
Fire Service Features of Buildings and Fire Protection Systems
Fire Service Features of Buildings and Fire Protection Systems OSHA 3256-09R 2015 Occupational Safety and Health Act of 1970 “To assure safe and healthful working conditions for working men and women; by authorizing enforcement of the standards developed under the Act; by assisting and encouraging the States in their efforts to assure safe and healthful working conditions; by providing for research, information, education, and training in the field of occupational safety and health.” This publication provides a general overview of a particular standards- related topic. This publication does not alter or determine compliance responsibilities which are set forth in OSHA standards and the Occupational Safety and Health Act. Moreover, because interpretations and enforcement policy may change over time, for additional guidance on OSHA compliance requirements the reader should consult current administrative interpretations and decisions by the Occupational Safety and Health Review Commission and the courts. Material contained in this publication is in the public domain and may be reproduced, fully or partially, without permission. Source credit is requested but not required. This information will be made available to sensory-impaired individuals upon request. Voice phone: (202) 693-1999; teletypewriter (TTY) number: 1-877-889-5627. This guidance document is not a standard or regulation, and it creates no new legal obligations. It contains recommendations as well as descriptions of mandatory safety and health standards. The recommendations are advisory in nature, informational in content, and are intended to assist employers in providing a safe and healthful workplace. The Occupational Safety and Health Act requires employers to comply with safety and health standards and regulations promulgated by OSHA or by a state with an OSHA-approved state plan. -
Wildland Fire Incident Management Field Guide
A publication of the National Wildfire Coordinating Group Wildland Fire Incident Management Field Guide PMS 210 April 2013 Wildland Fire Incident Management Field Guide April 2013 PMS 210 Sponsored for NWCG publication by the NWCG Operations and Workforce Development Committee. Comments regarding the content of this product should be directed to the Operations and Workforce Development Committee, contact and other information about this committee is located on the NWCG Web site at http://www.nwcg.gov. Questions and comments may also be emailed to [email protected]. This product is available electronically from the NWCG Web site at http://www.nwcg.gov. Previous editions: this product replaces PMS 410-1, Fireline Handbook, NWCG Handbook 3, March 2004. The National Wildfire Coordinating Group (NWCG) has approved the contents of this product for the guidance of its member agencies and is not responsible for the interpretation or use of this information by anyone else. NWCG’s intent is to specifically identify all copyrighted content used in NWCG products. All other NWCG information is in the public domain. Use of public domain information, including copying, is permitted. Use of NWCG information within another document is permitted, if NWCG information is accurately credited to the NWCG. The NWCG logo may not be used except on NWCG-authorized information. “National Wildfire Coordinating Group,” “NWCG,” and the NWCG logo are trademarks of the National Wildfire Coordinating Group. The use of trade, firm, or corporation names or trademarks in this product is for the information and convenience of the reader and does not constitute an endorsement by the National Wildfire Coordinating Group or its member agencies of any product or service to the exclusion of others that may be suitable. -
Fundamentals of Applied Smouldering Combustion
Western University Scholarship@Western Electronic Thesis and Dissertation Repository 6-20-2018 10:00 AM Fundamentals of Applied Smouldering Combustion Marco Zanoni The University of Western Ontario Supervisor Gerhard, Jason I. The University of Western Ontario Co-Supervisor Torero, Jose L. The University of Western Ontario Graduate Program in Civil and Environmental Engineering A thesis submitted in partial fulfillment of the equirr ements for the degree in Doctor of Philosophy © Marco Zanoni 2018 Follow this and additional works at: https://ir.lib.uwo.ca/etd Part of the Environmental Engineering Commons, and the Heat Transfer, Combustion Commons Recommended Citation Zanoni, Marco, "Fundamentals of Applied Smouldering Combustion" (2018). Electronic Thesis and Dissertation Repository. 5410. https://ir.lib.uwo.ca/etd/5410 This Dissertation/Thesis is brought to you for free and open access by Scholarship@Western. It has been accepted for inclusion in Electronic Thesis and Dissertation Repository by an authorized administrator of Scholarship@Western. For more information, please contact [email protected]. Abstract Smouldering combustion is defined as a flameless oxidation reaction occurring on the surface of the condensed phase (i.e., solid or liquid). Traditional research on smouldering was related to economic damages, fire risk, and death, due to the release of toxic gases and slow propagation rates. Recently, smouldering has been applied as an intentional, engineering technology (e.g., waste and contaminant destruction). Smouldering involves the transport of heat, mass, and momentum in the solid and fluid phases along with different chemical reactions. Therefore, numerical models are essential for the fundamental understanding of the process. Smouldering models either neglected heat transfer between phases (i.e., assumed local thermal equilibrium) or employed heat transfer correlations (i.e., under local thermal non- equilibrium conditions) not appropriate for smouldering. -
EMPLOYEE FIRE and LIFE SAFETY: Developing a Preparedness Plan and Conducting Emergency Evacuation Drills
EMPLOYEE FIRE AND LIFE SAFETY: Developing a Preparedness Plan and Conducting Emergency Evacuation Drills The following excerpts are taken from the book Introduction to Employee Fire and Life Safety, edited by Guy Colonna, © 2001 National Fire Protection Association. EXCERPTS FROM CHAPTER 3: Quick Tip Developing a Preparedness Plan To protect employees from fire and other emergencies and to prevent Jerry L. Ball property loss, whether large or small, companies use preparedness plans Fire is only one type of emergency that happens at work. Large and (also called pre-fire plans or pre- small workplaces alike experience fires, explosions, medical emergen- incident plans). cies, chemical spills, toxic releases, and a variety of other incidents. To protect employees from fire and other emergencies and to prevent property loss, whether large or small, companies use preparedness plans (also called pre-fire plans or pre-incident plans). The two essential components of a fire preparedness plan are the following: 1. An emergency action plan, which details what to do when a fire occurs 2. A fire prevention plan, which describes what to do to prevent a fire from occurring Of course, these two components of an overall preparedness plan are inseparable and overlap each other. For the purposes of this discus- sion, however, this chapter subdivides these two components into even smaller, more manageable subtopics. OSHA REGULATIONS uick ip Emergency planning and training directly influence the outcome of an Q T emergency situation. Facilities with well-prepared employees and Emergency planning and training directly influence the outcome of an well-developed preparedness plans are likely to incur less structural emergency situation. -
Recent Development in Fire Suppression Systems
Proceedings, 5th AOSFST, Newcastle, Australia, 2001 Editors: M.A. Delichatsios, B.Z. Dlugogorski and E.M. Kennedy RECENT DEVELOPMENT IN FIRE SUPPRESSION SYSTEMS A. Kim Institute for Research in Construction National Research Council Canada CANADA ABSTRACT With halon phase-out, there has been a major thrust to find new advanced fire suppression systems in recent years. Some of the newly developed fire suppression systems include halocarbon and inert gaseous agents, water mist systems, compressed-air-foam systems, and aerosol and gas generators. This paper gives a brief description of the newly developed fire suppression systems, and provides technical information on the fire suppression performance of each system as well as the limitations or concerns related to using the new suppression systems. INTRODUCTION The traditional means of providing fire suppression in buildings is a sprinkler system. However, water is not a suitable suppression medium for all types of fires. Water, when sprayed in coarse droplets such as in sprinkler spray, is not effective in suppressing liquid fuel fires. Also, in some cases, water damage is a concern because of the large amount of water used for sprinkler systems. In the 1940’s, an effort was made to develop more effective fire suppression agents. The first systematic search for effective gaseous fire suppressants can be traced to the late 1940s when the Purdue Research Foundation conducted an extensive study of more than 60 chemical compounds for the U.S. army1. This study led to the development of halon chemicals as a superior performing suppression agent. Halon is a chemical agent, which combines hydrogen, carbon, chlorine and bromine atoms. -
Wildfire Prevention Strategies Guide
A Publication of the National Wildfire Coordinating Group Wildfire Prevention Sponsored by United States Department of Agriculture Strategies United States Department of the Interior National Association of State Foresters PMS 455 March 1998 NFES 1572 Wildfire Prevention Strategies i - WILDFIRE PREVENTION STRATEGIES Preface This Wildfire Prevention Guide is a project of the National Wildfire Coordinating Group. This is one in a series designed to provide information and guidance for personnel who have interests and/or responsibilities in fire prevention. Each guide in the series addresses an individual component of a fire prevention program. In addition to providing insight and useful information, each guide suggests implementation strategies and examples for utilizing this information. Each Wildfire Prevention Guide has been developed by Fire Prevention Specialists and subject matter experts in the appropriate area. The goal of this series is to improve and enhance wildfire prevention programs and to facilitate the achievement of NWCG program goals. NWCG Wildfire Prevention Guide development: • Conducting School Programs (1996) • Event Management (1996) • Wildfire Prevention Marketing (1996) • Wildfire Prevention and the Media (1998) • Wildfire Prevention Strategies • Effective Wildfire Prevention Patrol • Recreation Areas • Exhibits and Displays • Equipment, Industrial and Construction Operations • Show Me Trips and Tours WILDFIRE PREVENTION STRATEGIES Preface - ii iii - WILDFIRE PREVENTION STRATEGIES Contents 1.0 Introduction ...........................................................................1