Amphiphilic Comb Polymers As New Additives in Bicontinuous Microemulsions
nanomaterials Article Amphiphilic Comb Polymers as New Additives in Bicontinuous Microemulsions Debasish Saha 1 , Karthik R. Peddireddy 2 , Jürgen Allgaier 3 , Wei Zhang 3, Simona Maccarrone 4, Henrich Frielinghaus 4,* and Dieter Richter 3 1 Solid State Physics Division, Bhabha Atomic Research Centre, Mumbai 400085, India; debiitm@gmail.com 2 Department of Physics and Biophysics, University of San Diego, San Diego, CA 92110, USA; kpeddireddy@sandiego.edu 3 Jülich Centre for Neutron Science (JCNS-1) and Institute of Biological Information Processing (IBI-8) Forschungszentrum Jülich GmbH, 52425 Jülich, Germany; j.allgaier@fz-juelich.de (J.A.); w.zhang@fz-juelich.de (W.Z.); d.richter@fz-juelich.de (D.R.) 4 Jülich Centre for Neutron Science (JCNS), Forschungszentrum Jülich GmbH, Outstation at FRM II, Lichtenbergstr. 1, 85747 Garching, Germany; s.maccarrone@fz-juelich.de * Correspondence: h.frielinghaus@fz-juelich.de; Tel.: +49-89-289-10706 Received: 19 October 2020; Accepted: 29 November 2020; Published: 2 December 2020 Abstract: It has been shown that the thermodynamics of bicontinuous microemulsions can be tailored via the addition of various different amphiphilic polymers. In this manuscript, we now focus on comb-type polymers consisting of hydrophobic backbones and hydrophilic side chains. The distinct philicity of the backbone and side chains leads to a well-defined segregation into the oil and water domains respectively, as confirmed by contrast variation small-angle neutron scattering experiments. This polymer–microemulsion structure leads to well-described conformational entropies of the polymer fragments (backbone and side chains) that exert pressure on the membrane, which influences the thermodynamics of the overall microemulsion.
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