Herbicidal Composition and Method of Weed Control

Total Page:16

File Type:pdf, Size:1020Kb

Herbicidal Composition and Method of Weed Control Europäisches Patentamt *EP000888055B1* (19) European Patent Office Office européen des brevets (11) EP 0 888 055 B1 (12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) Int Cl.7: A01N 43/54 of the grant of the patent: 30.08.2000 Bulletin 2000/35 (86) International application number: PCT/EP97/01106 (21) Application number: 97908179.1 (87) International publication number: (22) Date of filing: 05.03.1997 WO 97/34484 (25.09.1997 Gazette 1997/41) (54) HERBICIDAL COMPOSITION AND METHOD OF WEED CONTROL HERBIZIDE ZUSAMMENSETZUNG UND DEREN VERWENDUNG ZUR UNKRAUTBEKÄMPFUNG COMPOSITION HERBICIDE ET PROCEDE DE LUTTE CONTRE LES MAUVAISES HERBES (84) Designated Contracting States: (72) Inventors: AT BE CH DE ES FR GB GR IT LI NL PT • HUDETZ, Manfred CH-4310 Rheinfelden (CH) (30) Priority: 15.03.1996 CH 69196 • NELGEN, Robert D-55270 Jugenheim (DE) (43) Date of publication of application: 07.01.1999 Bulletin 1999/01 (56) References cited: DE-A- 4 437 197 US-A- 5 183 492 (73) Proprietors: • Novartis AG 4058 Basel (CH) Designated Contracting States: BE CH DE ES FR GB GR IT LI NL PT • Novartis-Erfindungen Verwaltungsgesellschaft m.b.H. 1235 Wien (AT) Designated Contracting States: AT Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention). EP 0 888 055 B1 Printed by Jouve, 75001 PARIS (FR) EP 0 888 055 B1 Description [0001] The present invention relates to a novel herbicidal composition comprising a herbicidal active ingredient com- bination that is suitable for the selective control of weeds in crops of useful plants, such as cereals, maize, rice, sugar 5 cane, plantation crops, cotton, potatoes and soybean crops. [0002] The invention relates also to a method of controlling weeds in crops of useful plants and to the use of the novel composition for that purpose. [0003] Herbicidal compositions that comprise the compound of formula A 10 15 20 are described, for example, in US-A-5 183 492. [0004] It has now surprisingly been shown that a combination of variable proportions of the compound of formula A with one compound selected from glyphosate, terbuthylazine, atrazine, metolachlor, metolachlor (S-enantiomer), dimethenamid, glufosinate and paraquat exhibits a herbicidal activity that renders possible effective control, both pre- 25 emergence and post-emergence, of the majority of weeds that occur especially in crops of useful plants, without any significant damage being done to the useful plants. [0005] In accordance with the present invention there is therefore proposed a novel herbicidal composition for se- lective weed control that comprises, in admixture with one another, the compound of formula A 30 35 40 or an agrochemically acceptable salt thereof as active ingredient, and a synergistically effective amount of a compound selected from glyphosate, terbuthylazine, atrazine, metolachlor, metolachlor (S-enantiomer), dimethenamid, glufosinate and paraquat. 45 [0006] It is extremely surprising that the combination of the compound of formula A with a synergistically effective amount of a compound selected from glyphosate, terbuthylazine, atrazine, metolachlor, metolachlor (S-enantiomer), dimethenamid, glufosinate and paraquat exceeds the additive effect on the weeds to be controlled that is to be expected in principle, and thus broadens the range of activity of the two preparations especially in the following two respects: [0007] First, the rates of application of the individual compounds are reduced while the good action remains un- 50 changed. Secondly, the composition according to the invention achieves a high degree of weed control even where the individual substances have become no longer usable agronomically at low rates of application. The result is a substantial broadening of the weed spectrum and an additional increase in selectivity for the crops of useful plants, which is desirable and necessary should an unintentional overdose of active ingredient be applied. [0008] The herbicidal mixture according to the invention can be used against a large number of agronomically im- 55 portant weeds, such as Veronica, Galium, Papaver, Solanum, Chenopodium, Amaranthus, Xanthium, Abutilon, Am- brosia, Sagitaria, Setaria, Digitaria, Echinochloa, Ipomoea, Cassiastora, Datura stramonium, Sesbania exaltata and Sida spinosa in crops of useful plants. It has also been shown that after application of the compositions according to the invention the compound of formula A contained therein is broken down more rapidly in the useful plants treated, 2 EP 0 888 055 B1 especially maize, than metolachlor, which is an important advantage. [0009] The compositions according to the invention are suitable for all methods of application customary in agricul- ture, such as pre-emergence application, post-emergence application and seed dressing. [0010] The herbicidal mixture according to the invention is suitable especially for weed control in crops of useful 5 plants such as cereals, sugar cane, plantation crops (TVM), rice, cotton, soybeans, potatoes and, especially, maize, and also for dessication (drying out) or defoliation, for example for the purpose of facilitating harvesting, for example in cotton and potato crops. [0011] "Crops" is also to be understood as meaning crops that have been made tolerant to herbicides and classes of herbicides by conventional breeding or genetic engineering methods. 10 [0012] The active ingredient combination according to the invention comprises the compound of formula A and the compound selected from glyphosate, terbuthylazine, atrazine, metolachlor, metolachlor (S-enantiomer), dimethena- mid, glufosinate and paraquat in a synergistically effective ratio, but usually with an excess of one component over the other(s). Preferred mixing ratios of the compound of formula A with its mixing partners are generally from 100 : 1 to 1 : 100. 15 [0013] The above-mentioned active ingredient combinations are suitable especially for use in maize. [0014] The following active ingredient combinations may be used specifically for maize that is resistant to imida- zolinone herbicides: compound of formula A + glyphosate, compound of formula A + glufosinate. [0015] Other active ingredient combinations according to the invention may be used, for example in potato and cotton 20 crops, as dessicators or defoliants for the purpose of facilitating harvesting, for example compound of formula A + glufosinate or in no-till-maize and plantation crops (TVM), for example compound of formula A + glufosinate, compound of formula A + glyphosate, and compound of formula A + paraquat. [0016] The above-mentioned active ingredients are described and characterised in "The Pesticide Manual", Tenth Edition, 1994, Crop Protection Publications, and other customary agronomical technical literature. The compound of 25 formula A is described, for example, in US-A-5 183 492. [0017] The optical isomer (S-enantiomer) of metolachlor suitable in accordance with the invention is aRS,1'S(-)-N- (1'-methyl-2'-methoxyethyl)-N-chloroacetyl-2-ethyl-6-methylaniline of formula Va 30 35 and also its agrochemically acceptable salts, which are described, for example, in US-A-5 002 606. 40 [0018] The rate of application of the active ingredients may vary within wide limits and depends on the nature of the soil, the type of use (pre- or post-emergence; seed dressing; application to the seed furrow; no tillage application etc.), the crop plant, the weed to be controlled, the prevailing climatic conditions, and other factors determined by the type of use, time of use and target crop. Generally, the active ingredient mixture according to the invention can be applied at a rate of application of from 50 to 4000 g of active ingredient mixture/ha. 45 [0019] In the composition according to the invention, the component of formula A is present in a ratio by weight of from 1: 100 to 1 : 0.001 to a mixing partner selected from glyphosate, terbuthylazine, atrazine, metolachlor, metolachlor (S-enantiomer), dimethamid, glufosinate and paraquat. [0020] The compositions according to the invention may be used in unmodified form, that is to say as obtained in the synthesis, but they are preferably formulated in customary manner together with the adjuvants customarily em- 50 ployed in formulation technology, e.g. into emulsifiable concentrates, provided sulfonylureas are not present, directly sprayable or dilutable solutions, dilute emulsions, wettable powders, soluble powders, dusts, granules or microcap- sules. As with the nature of the compositions, the methods of application, such as spraying, atomising, dusting, wetting, scattering or pouring, are chosen in accordance with the intended objectives and the prevailing circumstances. [0021] The formulations, that is to say the compositions, preparations or mixtures comprising the compounds (active 55 ingredients) of formulae A the mixing partners and/or one or more solid or liquid formulation adjuvants, are prepared in a manner known per se, e.g. by homogeneously mixing and/or grinding the active ingredients with the formulation adjuvants, for example solvents or solid carriers. It is also possible in addition to use surface-active compounds (sur- factants) in the preparation of the formulations. 3 EP 0 888 055 B1
Recommended publications
  • 2,4-Dichlorophenoxyacetic Acid
    2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators.
    [Show full text]
  • Herbicide Mode of Action Table High Resistance Risk
    Herbicide Mode of Action Table High resistance risk Chemical family Active constituent (first registered trade name) GROUP 1 Inhibition of acetyl co-enzyme A carboxylase (ACC’ase inhibitors) clodinafop (Topik®), cyhalofop (Agixa®*, Barnstorm®), diclofop (Cheetah® Gold* Decision®*, Hoegrass®), Aryloxyphenoxy- fenoxaprop (Cheetah®, Gold*, Wildcat®), fluazifop propionates (FOPs) (Fusilade®), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) Cyclohexanediones (DIMs) butroxydim (Factor®*), clethodim (Select®), profoxydim (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) Phenylpyrazoles (DENs) pinoxaden (Axial®) GROUP 2 Inhibition of acetolactate synthase (ALS inhibitors), acetohydroxyacid synthase (AHAS) Imidazolinones (IMIs) imazamox (Intervix®*, Raptor®), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, Lightning®*, Midas®* OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) Pyrimidinyl–thio- bispyribac (Nominee®), pyrithiobac (Staple®) benzoates Sulfonylureas (SUs) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*, Trimac Plus®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron (Logran®, Logran® B-Power®*), tribenuron (Express®),
    [Show full text]
  • 40 CFR Ch. I (7–1–18 Edition) § 455.61
    § 455.61 40 CFR Ch. I (7–1–18 Edition) from: the operation of employee show- § 455.64 Effluent limitations guidelines ers and laundry facilities; the testing representing the degree of effluent of fire protection equipment; the test- reduction attainable by the applica- ing and emergency operation of safety tion of the best available tech- showers and eye washes; or storm nology economically achievable water. (BAT). (d) The provisions of this subpart do Except as provided in 40 CFR 125.30 not apply to wastewater discharges through 125.32, any existing point from the repackaging of microorga- source subject to this subpart must nisms or Group 1 Mixtures, as defined achieve effluent limitations rep- under § 455.10, or non-agricultural pes- resenting the degree of effluent reduc- ticide products. tion attainable by the application of the best available technology economi- § 455.61 Special definitions. cally achievable: There shall be no dis- Process wastewater, for this subpart, charge of process wastewater pollut- means all wastewater except for sani- ants. tary water and those wastewaters ex- § 455.65 New source performance cluded from the applicability of the standards (NSPS). rule in § 455.60. Any new source subject to this sub- § 455.62 Effluent limitations guidelines part which discharges process waste- representing the degree of effluent water pollutants must meet the fol- reduction attainable by the applica- lowing standards: There shall be no dis- tion of the best practicable pollut- charge of process wastewater pollut- ant control technology (BPT). ants. Except as provided in 40 CFR 125.30 through 125.32, any existing point § 455.66 Pretreatment standards for existing sources (PSES).
    [Show full text]
  • Dicamba Emissions Under Field Conditions As Affected by Surface
    Weed Technology Dicamba emissions under field conditions as www.cambridge.org/wet affected by surface condition Thomas C. Mueller1 and Lawrence E. Steckel2 1 2 Research Article Professor, Department of Plant Sciences, University of Tennessee, Knoxville, TN, USA and Professor, Department of Plant Sciences, University of Tennessee, Knoxville, TN, USA Cite this article: Mueller TC and Steckel LE (2021) Dicamba emissions under field Abstract conditions as affected by surface condition. Weed Technol. 35: 188–195. doi: 10.1017/ The evolution and widespread distribution of glyphosate-resistant broadleaf weed species cata- wet.2020.106 lyzed the introduction of dicamba-resistant crops that allow this herbicide to be applied POST to soybean and cotton. Applications of dicamba that are most cited for off-target movement Received: 15 June 2020 have occurred in June and July in many states when weeds are often in high densities and Revised: 13 July 2020 Accepted: 11 September 2020 at least 10 cm or taller at the time of application. For registration purposes, most field studies First published online: 17 September 2020 examining pesticide emissions are conducted using bare ground or very small plants. Research was conducted in Knoxville, TN, in the summer of 2017, 2018, and 2019 to examine the effect of Associate Editor: application surface (tilled soil, dead plants, green plants) on dicamba emissions under field con- Kevin Bradley, University of Missouri ditions. Dicamba emissions after application were affected by the treated surface in all years, Nomenclature: with the order from least to most emissions being dead plants < tilled soil < green plant Dicamba; cotton; Gossypium hirsutum l.; material.
    [Show full text]
  • Herbicidal Composition
    (19) TZZ ¥ ¥_T (11) EP 2 832 223 A1 (12) EUROPEAN PATENT APPLICATION published in accordance with Art. 153(4) EPC (43) Date of publication: (51) Int Cl.: 04.02.2015 Bulletin 2015/06 A01N 47/36 (2006.01) A01N 41/10 (2006.01) A01N 43/10 (2006.01) A01N 43/40 (2006.01) (2006.01) (2006.01) (21) Application number: 13769011.1 A01N 43/70 A01N 43/80 A01N 43/824 (2006.01) A01P 13/00 (2006.01) (22) Date of filing: 29.03.2013 (86) International application number: PCT/JP2013/059673 (87) International publication number: WO 2013/147225 (03.10.2013 Gazette 2013/40) (84) Designated Contracting States: • OKAMOTO, Hiroyuki AL AT BE BG CH CY CZ DE DK EE ES FI FR GB Kusatsu-shi GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO Shiga 525-0025 (JP) PL PT RO RS SE SI SK SM TR • TERADA, Takashi Designated Extension States: Kusatsu-shi BA ME Shiga 525-0025 (JP) (30) Priority: 30.03.2012 JP 2012079935 (74) Representative: Müller-Boré & Partner Patentanwälte PartG mbB (71) Applicant: Ishihara Sangyo Kaisha, Ltd. Friedenheimer Brücke 21 Osaka-shi, Osaka 550-0002 (JP) 80639 München (DE) (72) Inventors: • YAMADA, Ryu Kusatsu-shi Shiga 525-0025 (JP) (54) HERBICIDAL COMPOSITION (57) To provide a high active herbicidal composition at least one 4-hydroxyphenylpyruvate dioxygenase in- having a broad herbicidal spectrum. hibitor selected from the group consisting of sulcotrione, A herbicidal composition comprising, as active in- bicyclopyrone, mesotrione, topramezone and their salts; gredients, (a) nicosulfuron or its salt, (b) terbuthylazine and group C2 is at least one very long chain fatty acid or its salt and (c) compound C (compound C is at least biosynthesis inhibitor selected from the group consisting one herbicidal compound selected from the group con- of dimethenamid-P, flufenacet and their salts).
    [Show full text]
  • Coa F128821.Pdf
    page 1 of 4 Version 1 CERTIFIED REFERENCE MATERIAL Triazine & Urea Pesticide Mixture - 29 components; 100ug/ml each of Atrazine [CAS:1912-24-9] ; Atrazine-desethyl [CAS:6190-65-4] ; Atrazine-desisopropyl [CAS:1007-28-9] ; Metamitron [CAS:41394-05-2] ; Chloridazon [CAS:1698-60-8] ; Metoxuron [CAS:19937-59-8] ; Carbetamide [CAS:16118-49-3] ; Bromacil [CAS:314-40-9] ; Simazine [CAS:122-34-9] ; Cyanazine [CAS:21725-46-2] ; Terbuthylazine-desethyl [CAS:30125-63-4] ; Methabenzthiazuron [CAS:18691-97-9] ; Chlortoluron [CAS:15545-48-9] ; Monolinuron [CAS:1746-81-2] ; Diuron [CAS:330-54-1] ; Isoproturon [CAS:34123-59-6] ; Metobromuron [CAS:3060-89-7] ; Metazachlor [CAS:67129-08-2] ; Propazine [CAS:139-40-2] ; Dimefuron [CAS:34205-21-5] ; Terbuthylazine [CAS:5915-41-3] ; Linuron [CAS:330-55-2] ; Chloroxuron [CAS:1982-47-4] ; Prometryn [CAS:7287-19-6] ; Chlorpropham [CAS:101-21-3] ; Terbutryn [CAS:886-50-0] ; Metolachlor [CAS:51218-45-2] ; Ethofumesate [CAS:26225-79-6] ; Ethidimuron [CAS:30043-49-3] in Acetonitrile Lot N: XXXXXX Ref N: F128821 Certification Date:XXXXXX Barcode: XXXXXXXX Component Certified Value* CAS Chemical Formula and uncertainty [µg/ml] Atrazine 99.71 ± 1.19 1912-24-9 C8H14ClN5 Atrazine-desethyl 99.76 ± 1.88 6190-65-4 C6H10ClN5 Atrazine-desisopropyl 100.08 ± 2.34 1007-28-9 C5H8ClN5 Metamitron 99.93 ± 1.09 41394-05-2 C10H10N4O Chloridazon 99.57 ± 1.26 1698-60-8 C10H8ClN3O Metoxuron 100.01 ± 1.34 19937-59-8 C10H13ClN2O2 Carbetamide 100.00 ± 1.48 16118-49-3 C12H16N2O3 Bromacil 99.70 ± 1.17 314-40-9 C9H13BrN2O2 Simazine 100.09 ±
    [Show full text]
  • Redox Imbalance Caused by Pesticides: a Review of OPENTOX-Related Research
    Marjanović Čermak AM, et al. Redox imbalance caused by pesticides Arh Hig Rada Toksikol 2018;69:126-134 126 Review DOI: 10.2478/aiht-2018-69-3105 Redox imbalance caused by pesticides: a review of OPENTOX-related research Ana Marija Marjanović Čermak, Ivan Pavičić, and Davor Želježić Institute for Medical Research and Occupational Health, Zagreb, Croatia [Received in February 2018; Similarity Check in February 2018; Accepted in May 2018] Pesticides are a highly diverse group of compounds and the most important chemical stressors in the environment. Mechanisms that could explain pesticide toxicity are constantly being studied and their interactions at the cellular level are often observed in well-controlled in vitro studies. Several pesticide groups have been found to impair the redox balance in the cell, but the mechanisms leading to oxidative stress for certain pesticides are only partly understood. As our scientific project “Organic pollutants in environment – markers and biomarkers of toxicity (OPENTOX)” is dedicated to studying toxic effects of selected insecticides and herbicides, this review is focused on reporting the knowledge regarding oxidative stress-related phenomena at the cellular level. We wanted to single out the most important facts relevant to the evaluation of our own findings from studies conducted onin vitro cell models. KEY WORDS: antioxidants; apoptosis; glyphosate; in vitro; neonicotinoids; organophosphates; oxidative stress; pyrethroids; reactive oxygen species Over the years, population growth and changes in food (HrZZ), is dedicated to studying the toxic effects of two consumption patterns have challenged agricultural major pesticide classes with three subgroups each: (A) production to meet the demand for food and quality insecticides (organophosphates, neonicotinoids, and standards.
    [Show full text]
  • 12 Chemical Fact Sheets
    1212 ChemicalChemical factfact sheetssheets A conceptual framework for Introduction implementing the Guidelines (Chapter 1) (Chapter 2) he background docudocu-- ments referred to in FRAMEWORK FOR SAFE DRINKING-WATER SUPPORTING Tments referred to in INFORMATION thisthis chapterchapter (as the princi-princi- Health-based targets Public health context Microbial aspects pal reference for each fact (Chapter 3) and health outcome (Chapters 7 and 11) sheet) may be found on Water safety plans Chemical aspects (Chapter 4) (Chapters 8 and 12) thethe Water, Sanitation, HyHy-- System Management and Radiological Monitoring giene and Health web site assessment communication aspects at http://www.who.int/ (Chapter 9) Acceptability Surveillance water_sanitation_health/ aspects (Chapter 5) dwq/chemicals/en/indewater-quality/guidelines/x. (Chapter 10) htmlchemicals/en/. A complete. A complete list of rlist eferences of references cited citedin this in Application of the Guidelines in specic circumstances chapter,this chapter, including including the (Chapter 6) background documents Climate change, Emergencies, Rainwater harvesting, Desalination forfor each cchemical, hemical, is pro-pro- systems, Travellers, Planes and vided in Annex 22.. ships, etc. 12.1 Chemical contaminants in drinking-water Acrylamide Residual acrylamideacrylamide monomermonomer occursoccurs inin polyacrylamidepolyacrylamide coagulantscoagulants used used in in thethe treattreat-- ment of drinking-water. In general, thethe maximummaximum authorizedauthorized dosedose ofof polymerpolymer isis 11 mg/l. mg/l. At a monomer content of 0.05%, this corresponds to a maximum theoretical concen-- trationtration ofof 0.5 µg/l of the monomer in water.water. Practical concentrations maymay bebe lowerlower byby aa factor factor of 2–3. This applies applies to to thethe anionic anionic and and non-ionic non-ionic polyacrylamides, polyacrylamides, but but residual residual levelslevels fromfrom cationic polyacrylamides maymay bebe higher.higher.
    [Show full text]
  • List of Herbicide Groups
    List of herbicides Group Scientific name Trade name clodinafop (Topik®), cyhalofop (Barnstorm®), diclofop (Cheetah® Gold*, Decision®*, Hoegrass®), fenoxaprop (Cheetah® Gold* , Wildcat®), A Aryloxyphenoxypropionates fluazifop (Fusilade®, Fusion®*), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) butroxydim (Falcon®, Fusion®*), clethodim (Select®), profoxydim A Cyclohexanediones (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) A Phenylpyrazoles pinoxaden (Axial®) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, B Sulfonylureas Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron, (Logran®, Logran® B Power®*), tribenuron (Express®), trifloxysulfuron (Envoke®, Krismat®*) florasulam (Paradigm®*, Vortex®*, X-Pand®*), flumetsulam B Triazolopyrimidines (Broadstrike®), metosulam (Eclipse®), pyroxsulam (Crusader®Rexade®*) imazamox (Intervix®*, Raptor®,), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, B Imidazolinones Lightning®*, Midas®*, OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) B Pyrimidinylthiobenzoates bispyribac (Nominee®), pyrithiobac (Staple®) C Amides: propanil (Stam®) C Benzothiadiazinones: bentazone (Basagran®,
    [Show full text]
  • Journal of Plant Protection Research ISSN 1427-4345
    Journal of Plant Protection Research ISSN 1427-4345 ORIGINAL ARTICLE A study on Sorghum bicolor (L.) Moench response to split application of herbicides Sylwia Kaczmarek* Department of Weed Science and Plant Protection Techniques, Institute of Plant Protection – National Research Institute, Władysława Węgorka 20, 60-318 Poznań, Poland Vol. 57, No. 2: 152–157, 2017 Abstract DOI: 10.1515/jppr-2017-0021 Field experiments to evaluate the split application of mesotrione + s-metolachlor, mesot- rione + terbuthylazine, dicamba + prosulfuron, terbuthylazine + mesotrione + s-metol- Received: March 10, 2017 achlor, and sulcotrione in the cultivation of sorghum var. Rona 1 were carried out in 2012 Accepted: May 24, 2017 and 2013. Th e fi eld tests were conducted at the fi eld experimental station in Winna Góra, Poznań, Poland. Treatments with the herbicides were performed directly aft er sowing (PE) *Corresponding address: and at leaf stage 1–2 (AE1) or at leaf stage 3–4 (AE2) of sorghum. Th e treatments were car- [email protected] ried out in a laid randomized block design with 4 replications. Th e results showed that the tested herbicides applied at split doses were eff ective in weed control. Aft er the herbicide application weed density and weed biomass were signifi cantly reduced compared to the infested control. Th e best results were achieved aft er the application of mesotrione tank mixture with s-metolachlor and terbuthylazine. Application of split doses of herbicides was also correlated with the density, biomass, and height of sorghum. Key words: herbicides, mesotrione, s-metolachlor, sorghum, split doses, terbuthylazine, weed control Introduction Sorghum, the oldest cultivated crop in the world, is a total area of 390,000 ha.
    [Show full text]
  • (12) United States Patent (10) Patent No.: US 9.451,767 B2 Nolte Et Al
    US00945.1767B2 (12) United States Patent (10) Patent No.: US 9.451,767 B2 Nolte et al. (45) Date of Patent: Sep. 27, 2016 (54) AQUEOUS COMPOSITION COMPRISING (52) U.S. Cl. DCAMIBA AND A DRIFT CONTROL AGENT CPC ............... A0IN 33/04 (2013.01); A0IN 37/10 (2013.01); A0IN 37/40 (2013.01); A0IN (71) Applicant: BASF SE, Ludwigshafen (DE) 37/44 (2013.01) (58) Field of Classification Search (72) Inventors: Marc Nolte, Mannheim (DE); Wen Xu, CPC ...................................................... AO1N 37/44 Cary, NC (US); Steven Bowe, Apex, USPC .......................................................... 514/564 NC (US); Maarten Staal, Durham, NC See application file for complete search history. (US); Terrance M. Cannan, Raleigh, NC (US) (56) References Cited (73) Assignee: BASF SE, Ludwigshafen (DE) FOREIGN PATENT DOCUMENTS (*) Notice: Subject to any disclaimer, the term of this WO WO O2,34047 5, 2002 patent is extended or adjusted under 35 W. w838g 1239 U.S.C. 154(b) by 101 days. WO WO 2011/O19652 2, 2011 WO WO 2011/O102.11 9, 2011 (21) Appl. No.: 14/408,172 WO WO 2012/076567 6, 2012 (22) PCT Filed: Jun. 11, 2013 OTHER PUBLICATIONS International Search Report dated Jul. 12, 2013, prepared in Inter (86). PCT No.: PCT/EP2013/061962 national Application No. PCT/EP2013/061962. S 371 (c)(1), International Preliminary Report on Patentability dated Jun. 6. (2) Date: Dec. 15, 2014 2014, prepared in International Application No. PCT/EP2013/ O61962. (87) PCT Pub. No.: WO2013/189773 Primary Examiner — Raymond Henley, III PCT Pub. Date: Dec. 27, 2013 (74) Attorney, Agent, or Firm — Brinks Gilson & Lione (65) Prior Publication Data (57) ABSTRACT US 2015/O173354 A1 Jun.
    [Show full text]
  • PESTICIDES Criteria for a Recommended Standard
    CRITERIA FOR A RECOMMENDED STANDARD OCCUPATIONAL EXPOSURE DURING THE MANUFACTURE AND FORMULATION OF PESTICIDES criteria for a recommended standard... OCCUPATIONAL EXPOSURE DURING THE MANUFACTURE AND FORMULATION OF PESTICIDES * U.S. DEPARTMENT OF HEALTH, EDUCATION, AND WELFARE Public Health Service Center for Disease Control National Institute for Occupational Safety and Health July 1978 For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402 DISCLAIMER Mention of company names or products does not constitute endorsement by the National Institute for Occupational Safety and Health. DHEW (NIOSH) Publication No. 78-174 PREFACE The Occupational Safety and Health Act of 1970 emphasizes the need for standards to protect the health and provide for the safety of workers occupationally exposed to an ever-increasing number of potential hazards. The National Institute for Occupational Safety and Health (NIOSH) has implemented a formal system of research, with priorities determined on the basis of specified indices, to provide relevant data from which valid criteria for effective standards can be derived. Recommended standards for occupational exposure, which are the result of this work, are based on the effects of exposure on health. The Secretary of Labor will weigh these recommendations along with other considerations, such as feasibility and means of implementation, in developing regulatory standards. Successive reports will be presented as research and epideiriologic studies are completed and as sampling and analytical methods are developed. Criteria and standards will be reviewed periodically to ensure continuing protection of workers. The contributions to this document on pesticide manufacturing and formulating industries by NIOSH staff members, the review consultants, the reviewer selected by the American Conference of Governmental Industrial Hygienists (ACGIH), other Federal agencies, and by Robert B.
    [Show full text]