Chapter 38 Liquefied Petroleum Gases
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Combustion and Heat Release Characteristics of Biogas Under Hydrogen- and Oxygen-Enriched Condition
energies Article Combustion and Heat Release Characteristics of Biogas under Hydrogen- and Oxygen-Enriched Condition Jun Li 1, Hongyu Huang 2,*, Huhetaoli 2, Yugo Osaka 3, Yu Bai 2, Noriyuki Kobayashi 1,* and Yong Chen 2 1 Department of Chemical Engineering, Nagoya University, Nagoya, Aichi 464-8603, Japan; [email protected] 2 Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China; [email protected] (H.); [email protected] (Y.B.); [email protected] (Y.C.) 3 Faculty of Mechanical Engineering, Kanazawa University, Kakuma, Kanazawa, Ishikawa 920-1192, Japan; [email protected] * Correspondence: [email protected] (H.H.); [email protected] (N.K.); Tel.: +86-20-870-48394 (H.H.); +81-52-789-5428 (N.K.) Received: 10 May 2017; Accepted: 20 July 2017; Published: 13 August 2017 Abstract: Combustion and heat release characteristics of biogas non-premixed flames under various hydrogen-enriched and oxygen-enriched conditions were investigated through chemical kinetics simulation using detailed chemical mechanisms. The heat release rates, chemical reaction rates, and molar fraction of all species of biogas at various methane contents (35.3–58.7%, mass fraction), hydrogen addition ratios (10–50%), and oxygen enrichment levels (21–35%) were calculated considering the GRI 3.0 mechanism and P1 radiation model. Results showed that the net reaction rate of biogas increases with increasing hydrogen addition ratio and oxygen levels, leading to a higher net heat release rate of biogas flame. Meanwhile, flame length was shortened with the increase in hydrogen addition ratio and oxygen levels. -
New Federal Law Addresses Excise Tax on LNG, LPG, And
Multistate Tax EXTERNAL ALERT New federal law addresses excise tax on LNG, LPG, and CNG August 13, 2015 Overview President Obama recently signed into law the Surface Transportation and Veterans Health Care Choice Improvement Act of 2015 (H.R. 3236).1 Effective January 1, 2016, the new law equalizes the federal excise tax treatment of liquefied natural gas (LNG) and liquefied petroleum gas (LPG) and provides further guidance applicable to the taxation of compressed natural gas (CNG). This Tax Alert summarizes these federal excise tax law changes. The federal excise tax on alternative fuels Currently, under Internal Revenue Code (I.R.C.) §4041, the federal excise tax on “alternative fuels” is imposed when such fuels are sold for use or used as a fuel in a motor vehicle or motorboat.2 The term “alternative fuels” includes, but is not limited to, LNG, CNG, and LPG.3 LNG is currently subject to tax at the federal diesel fuel tax rate of 24.3 cents per gallon.4 However, LNG contains a lower energy content than diesel. According to the Oak Ridge National Laboratory, LNG has an energy content of 74,700 Btu per gallon (lower heating value), while diesel has an energy content of 128,450 Btu per gallon (lower heating value).5 Therefore, one gallon of LNG has the energy equivalency of 58 percent of one gallon of diesel fuel, although LNG is currently taxed as having the energy equivalency of 100 percent of one gallon of diesel fuel.6 Similarly, LPG is currently subject to tax at the federal gasoline tax rate of 18.3 cents per gallon.7 However, LPG contains a lower energy content than gasoline. -
Final Report Study on the Potential of Increased Use of LPG for Cooking in Developing Countries
Final Report Study on the Potential of Increased Use of LPG for Cooking in Developing Countries September 2020 TABLE OF CONTENTS Executive Summary ....................................................................................................................................................................... 2 List of Abbreviations ...................................................................................................................................................................... 6 Preface .......................................................................................................................................................................................... 7 1 Introduction.......................................................................................................................................................................... 8 1.1 General ................................................................................................................................................................................. 8 1.2 Background ........................................................................................................................................................................... 8 2 Purpose and Scope of the Study ............................................................................................................................................ 9 2.1 Purpose of the Study ........................................................................................................................................................... -
Liquefied Petroleum Gas (LPG)
Liquefied Petroleum Gas (LPG) Demand, Supply and Future Perspectives for Sudan Synthesis report of a workshop held in Khartoum, 12-13 December 2010 The workshop was funded by UKaid from the Department for International Development Cover image: © UNAMID / Albert Gonzalez Farran This report is available online at: www.unep.org/sudan Disclaimer The material in this report does not necessarily represent the views of any of the organisations involved in the preparation and hosting of the workshop. It must be noted that some time has passed between the workshop and the dissemination of this report, during which some important changes have taken place, not least of which is the independence of South Sudan, a fact which greatly affects the national energy context. Critically, following the independence, the rate of deforestation in the Republic of Sudan has risen from 0.7% per year to 2.2% per year, making many of the discussions within this document all the more relevant. Whilst not directly affecting the production of LPG, which is largely derived from oil supplies north of the border with South Sudan, the wider context of the economics of the energy sector, and the economy as a whole, have changed. These changes are not reflected in this document. This being said, it is strongly asserted that this document still represents a useful contribution to the energy sector, particularly given its contribution to charting the breadth of perspectives on LPG in the Republic of Sudan. Liquefied Petroleum Gas (LPG) Demand, Supply and Future Perspectives for Sudan Synthesis report of a workshop held in Khartoum, 12-13 December 2010 A joint publication by: Ministry of Environment, Forestry and Physical Development – Sudan, Ministry of Petroleum – Sudan, United Kingdom Department for International Development, United Nations Development Programme and United Nations Environment Programme Table of contents Acronyms and abbreviations . -
Energy and the Hydrogen Economy
Energy and the Hydrogen Economy Ulf Bossel Fuel Cell Consultant Morgenacherstrasse 2F CH-5452 Oberrohrdorf / Switzerland +41-56-496-7292 and Baldur Eliasson ABB Switzerland Ltd. Corporate Research CH-5405 Baden-Dättwil / Switzerland Abstract Between production and use any commercial product is subject to the following processes: packaging, transportation, storage and transfer. The same is true for hydrogen in a “Hydrogen Economy”. Hydrogen has to be packaged by compression or liquefaction, it has to be transported by surface vehicles or pipelines, it has to be stored and transferred. Generated by electrolysis or chemistry, the fuel gas has to go through theses market procedures before it can be used by the customer, even if it is produced locally at filling stations. As there are no environmental or energetic advantages in producing hydrogen from natural gas or other hydrocarbons, we do not consider this option, although hydrogen can be chemically synthesized at relative low cost. In the past, hydrogen production and hydrogen use have been addressed by many, assuming that hydrogen gas is just another gaseous energy carrier and that it can be handled much like natural gas in today’s energy economy. With this study we present an analysis of the energy required to operate a pure hydrogen economy. High-grade electricity from renewable or nuclear sources is needed not only to generate hydrogen, but also for all other essential steps of a hydrogen economy. But because of the molecular structure of hydrogen, a hydrogen infrastructure is much more energy-intensive than a natural gas economy. In this study, the energy consumed by each stage is related to the energy content (higher heating value HHV) of the delivered hydrogen itself. -
Influence of the Use of Liquefied Petroleum Gas (LPG) Systems In
energies Article Influence of the Use of Liquefied Petroleum Gas (LPG) Systems in Woodchippers Powered by Small Engines on Exhaust Emissions and Operating Costs Łukasz Warguła 1,* , Mateusz Kukla 1 , Piotr Lijewski 2, Michał Dobrzy ´nski 2 and Filip Markiewicz 2 1 Institute of Machine Design, Faculty of Mechanical Engineering, Poznan University of Technology, Piotrowo 3, PL-60965 Poznan, Poland; [email protected] 2 Institute of Internal Combustion Engines and Drives, Faculty of Civil Engineering and Transport, Poznan University of Technology, Piotrowo 3, PL-60965 Poznan, Poland; [email protected] (P.L.); [email protected] (M.D.); fi[email protected] (F.M.) * Correspondence: [email protected]; Tel.: +48-(61)-665-20-42 Received: 12 August 2020; Accepted: 3 November 2020; Published: 4 November 2020 Abstract: The use of alternative fuels is a contemporary trend in science aimed at the protection of non-renewable resources, reducing the negative impact on people and reducing the negative impact on the natural environment. Liquefied petroleum gas (LPG) is an alternative fuel within the meaning of the European Union Directive (2014/94/UE), as it is an alternative for energy sources derived from crude oil. The use of LPG fuel in low-power internal combustion engines is one of the currently developed scientific research directions. It results from the possibility of limiting air pollutant emissions compared to the commonly used gasoline and the lower cost of this fuel in many countries. By “gasoline 95” the Authors mean non-lead petrol as a flammable liquid that is used primarily as a fuel in most spark-ignited internal combustion engines, whereas 95 is an octane rating (octane number). -
2002-00201-01-E.Pdf (Pdf)
report no. 2/95 alternative fuels in the automotive market Prepared for the CONCAWE Automotive Emissions Management Group by its Technical Coordinator, R.C. Hutcheson Reproduction permitted with due acknowledgement Ó CONCAWE Brussels October 1995 I report no. 2/95 ABSTRACT A review of the advantages and disadvantages of alternative fuels for road transport has been conducted. Based on numerous literature sources and in-house data, CONCAWE concludes that: · Alternatives to conventional automotive transport fuels are unlikely to make a significant impact in the foreseeable future for either economic or environmental reasons. · Gaseous fuels have some advantages and some growth can be expected. More specifically, compressed natural gas (CNG) and liquefied petroleum gas (LPG) may be employed as an alternative to diesel fuel in urban fleet applications. · Bio-fuels remain marginal products and their use can only be justified if societal and/or agricultural policy outweigh market forces. · Methanol has a number of disadvantages in terms of its acute toxicity and the emissions of “air toxics”, notably formaldehyde. In addition, recent estimates suggest that methanol will remain uneconomic when compared with conventional fuels. KEYWORDS Gasoline, diesel fuel, natural gas, liquefied petroleum gas, CNG, LNG, Methanol, LPG, bio-fuels, ethanol, rape seed methyl ester, RSME, carbon dioxide, CO2, emissions. ACKNOWLEDGEMENTS This literature review is fully referenced (see Section 12). However, CONCAWE is grateful to the following for their permission to quote in detail from their publications: · SAE Paper No. 932778 ã1993 - reprinted with permission from the Society of Automotive Engineers, Inc. (15) · “Road vehicles - Efficiency and emissions” - Dr. Walter Ospelt, AVL LIST GmbH. -
Material Safety Data Sheet
SAFETY DATA SHEET EFFECTIVE JUNE 2016 SECTION 1 – PRODUCT & COMPANY IDENTIFICATION Product Name: Commercial Odorized Propane Chemical Name: Propane (C3H8) Chemical Family: Petroleum Hydrocarbon Common Names: Liquefied Petroleum Gas, LP-Gas, LPG, Bottle Gas Intended Use: Propane is a liquid fuel Distributor: Campora Propane Service, PO Box 31717 Stockton, CA 95213 Emergency Response: CHEMTREC (800) 424-9300 General Information: (209) 941-2994 SECTION 2 – CHEMICAL HAZARD CLASSIFICATION & WARNING INFORMATION Fire Hazard NFPA CLASSES: 1-Slight 2-Moderate 3-Serious Health Hazard Reactivity 4-Severe Physical hazards Flammable gases Category 1 Gases under pressure Liquefied gas Health hazards Acute toxicity, inhalation Category 4 Germ cell mutagenicity Category 1B Carcinogenicity Category 1A Reproductive toxicity Category 1A Specific target organ toxicity, repeated Category 2 exposure OSHA defined hazards Not classified. Label Elements Signal Word Danger Hazard Statement Propane (also called LPG-Liquefied Petroleum Gas or LP-Gas) is a liquid fuel stored under pressure. In most systems, propane is vaporized to a gas before it leaves the tank. Propane is highly flammable when mixed with air (oxygen) and can be ignited by many sources, including open flames, smoking materials, electrical sparks, and static electricity. Severe “freeze burn” or frostbite can result if propane liquid comes in contact with your skin. Extremely flammable gas. Harmful if inhaled. May cause genetic defects. May cause cancer. May damage fertility or the unborn child. May cause damage to Blood through prolonged or repeated exposure. May cause cryogenic burns or injury. Propane is a simple asphyxiant. Precautionary statement General Read and follow all Safety Data Sheets (SDS’S) before use. -
Producing Fuel and Electricity from Coal with Low Carbon Dioxide Emissions
Producing Fuel and Electricity from Coal with Low Carbon Dioxide Emissions K. Blok, C.A. Hendriks, W.C. Turkenburg Depanrnent of Science,Technology and Society University of Utrecht Oudegracht320, NL-351 1 PL Utrecht, The Netherlands R.H. Williams Center for Energy and Environmental Studies Princeton University Princeton, New Jersey08544, USA June 1991 Abstract. New energy technologies are needed to limit CO2 emissions and the detrimental effects of global warming. In this article we describe a process which produces a low-carbon gaseousfuel from coal. Synthesis gas from a coal gasifier is shifted to a gas mixture consisting mainly of H2 and CO2. The CO2 is isolated by a physical absorption process, compressed,and transported by pipeline to a depleted natural gas field where it is injected. What remains is a gaseousfuel consisting mainly of hydrogen. We describe two applications of this fuel. The first involves a combined cycle power plant integrated with the coal gasifier, the shift reactor and the CO2 recovery units. CO2 recovery and storage will increase the electricity production cost by one third. The secondprovides hydrogen or a hydrogen-rich fuel gas for distributed applications, including transportation; it is shown that the fuel can be produced at a cost comparable to projected costs for gasoline. A preliminary analysis reveals that all components of the process described here are in such a phase of development that the proposed technology is ready for demonstration. ~'> --. ~'"' .,.,""~ 0\ ~ 0\0 ;.., ::::. ~ ~ -.., 01) §~ .5~ c0 ~.., ~'> '" .~ ~ ..::. ~ ~ "'~'" '" 0\00--. ~~ ""00 Q....~~ '- ~~ --. ~.., ~ ~ ""~ 0000 .00 t¥") $ ~ .9 ~~~ .- ..~ c ~ ~ ~ .~ O"Oe) """1;3 .0 .-> ...~ 0 ~ ,9 u u "0 ...~ --. -
Scale Gas-‐To-‐Methanol Conversion by Engine Reformers
System Model of Small-Scale Gas-to-Methanol Conversion by Engine Reformers By Angela J. Acocella B.S., Mechanical Engineering Rensselaer Polytechnic Institute, 2012 Submitted to the Engineering Systems Division in partial fulfillment of the requirements for the degree of Master of Science in Technology & Policy at the Massachusetts Institute of Technology June 2015 © 2015 Massachusetts Institute of Technology, All rights reserved Signature of Author............................................................................................................. Technology & Policy Program; Engineering Systems Division May 8, 2015 Certified by.............................................................................................................................. Daniel R. Cohn Research Scientist, MIT Energy Initiative Thesis Supervisor Accepted by............................................................................................................................. Dava J. Newman Professor of Aeronautics and Astronautics and Engineering Systems Director, Technology and Policy Program 2 System Model of Small-Scale Gas-to-Methanol Conversion by Engine Reformers by Angela J. Acocella Submitted to the Engineering Systems Division On May 8, 2015 in partial fulfillment of the requirements for the degree of Master of Science in Technology & Policy ABSTRACT As global energy demands grow and environmental concerns over resource extraction methods intensify, high impact solutions are becoming increasingly essential. Venting and flaring of associated -
Liquefied Petroleum Gas Specifications and Test Methods
GPA Standard 2140-97 Liquefied Petroleum Gas Specifications and Test Methods Adopted as Recommended Procedures 1931 Revised 1940-1947-1948-1951-1955-1957-1959-1960-1962-1968 1970-1973-1975-1977-1980-1984-1986-1988-1990-1992-1996-1997 Reprinted 1998 Gas Processors Association 6526 East 60th Street Tulsa, Oklahoma 74145 TABLE OF CONTENTS Disclaimer ........................................................................................ ii Foreword ......................................................................................... ii GPA Specifications for Liquefied Petroleum Gases ....................................................... 1 ASTM D-1265-92: Sampling Liquefied Petroleum Gases .................................................. 2 ASTM D-1267-95: Vapor Pressure of Liquefied Petroleum Gases ........................................... 5 ASTM D-1657-89: Density or Relative Density of Light Hydrocarbons by Pressure Hydrometer ............................................................ 10 ASTM D-1837-94: Volatility of Liquefied Petroleum Gases ............................................... 14 ASTM D-1838-91: Copper Strip Corrosion by Liquefied Petroleum Gases .................................................................. 17 ASTM D-2158-92: Residues in Liquefied Petroleum Gases ................................................ 20 ASTM D-2163-91: Analysis of Liquefied Petroleum (LP) Gases and Propylene Concentrates by Gas Chromatography ........................................ 24 ASTM D-2713-91: Dryness of Propane (Valve Freeze -
Chapter 38 Liquefied Petroleum Gases
Color profile: Generic CMYK printer profile Composite Default screen CHAPTER 38 LIQUEFIED PETROLEUM GASES SECTION 3801 3803.2.1.2 Construction and temporary heating. Por- GENERAL table containers are allowed to be used in buildings or 3801.1 Scope. Storage, handling and transportation of lique- areas of buildings undergoing construction or for tempo- fied petroleum gas (LP-gas) and the installation of LP-gas rary heating as set forth in Sections 6.17.4, 6.17.5 and equipment pertinent to systems for such uses shall comply with 6.17.8 of NFPA 58. this chapter and NFPA 58. Properties of LP-gases shall be 3803.2.1.3 Group F occupancies. In Group F occupan- determined in accordance with Appendix B of NFPA 58. cies, portable LP-gas containers are allowed to be used to 3801.2 Permits. Permits shall be required as set forth in Sec- supply quantities necessary for processing, research or tions 105.6 and 105.7. experimentation. Where manifolded, the aggregate Distributors shall not fill an LP-gas container for which a water capacity of such containers shall not exceed 735 permit is required unless a permit for installation has been pounds (334 kg) per manifold. Where multiple mani- issued for that location by the fire code official. folds of such containers are present in the same room, each manifold shall be separated from other manifolds 3801.3 Construction documents. Where a single container is by a distance of not less than 20 feet (6096 mm). more than 2,000 gallons (7570 L) in water capacity or the aggregate capacity of containers is more than 4,000 gallons (15 3803.2.1.4 Group E and I occupancies.