minerals Article Potentially Toxic Elements (PTEs) in Cultivated Soils from Lombardy (Northern Italy): Spatial Distribution, Origin, and Management Implications Elisa Sacchi 1,*, Stefano Brenna 2, Stefania Fornelli Genot 1, Alessandra Leoni 2, Vanna Maria Sale 2 and Massimo Setti 1 1 Department of Earth and Environmental Sciences, University of Pavia, 27100 Pavia, Italy;
[email protected] (S.F.G.);
[email protected] (M.S.) 2 ERSAF, Regional Agency for Agriculture and Forests of Lombardy, 20124 Milano, Italy;
[email protected] (S.B.);
[email protected] (A.L.);
[email protected] (V.M.S.) * Correspondence:
[email protected]; Tel.: +39-0382985880 Received: 31 January 2020; Accepted: 23 March 2020; Published: 27 March 2020 Abstract: This work aims to quantify the contribution of agricultural practices to diffuse pollution in cultivated soils. Two samples (the first from the top layer and the second from a depth of about 100 cm) were retrieved from about 1000 soil profiles and analyzed for their potentially toxic elements (PTEs) content (Cd, Cu, Ni, Pb, Zn, Mn). In addition, we collected dedicated soil profiles for three specific types of land use and agronomic practice, namely vine-, cereal- and rice-growing areas. Baseline concentrations and distribution maps were produced. Statistical data treatment, coupled with the results of the dedicated soil profiles, enabled the identification of precise pollution sources and processes. In cultivated soils, PTEs contents prove to be generally well below the Italian regulatory limits, with the exception of Cu in vineyard soils, due to the long-lasting use of Cu-based pesticides.