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Kennecott Uranium Company 42 Miles NW of Rawlins P.O. Box 1500 Rawlins, WY 82301-1500 USA T +1 (307) 328 1476 F +1 (307) 324 4925

November 2, 2020

WYPDES Permits Section Department of Environmental Quality/WDQ 200 W. 17th Street, 4th Floor Cheyenne, WY 82002

Attention: Kathy Shreve

Subject: Re-submittal Renewal Application, WYPDES Permit: WY0026689

Enclosed please find Kennecott Uranium Company’s application to renew the Wyoming Pollutant Discharge Elimination System (WYPDES) Permit WY0026689. Please note that this is Kennecott's second time submitting this renewal application. The first application was submitted on 7/28/2020. The application that is attached address questions that Ms. Kathy Shreve had. The following applies to this renewal application:

• This is an application for renewal of an existing permit (WY0026689). • Kennecott Uranium Company is sending this letter to notify your office that we do intend to renew WYPDES Permit WY0026689 and ask that the permit not be canceled on the 7/31/2020 permit expiration date. • Unfortunately, the previous site supervisor retired at the beginning of 2020 and contact information was not changed so the notification was not received by our new supervisor in order for the application to be completed with enough time for it to be reviewed and accepted/issued by WY DEQ before the 7/31/2020 permit expiration date. No discharge under this permit has occurred since spring 1983 (a period of over thirty-seven (37) years) following cessation of mining operations at the Sweetwater Uranium Project following a drop in uranium prices and loss of a uranium supply contract.

If you have any questions please do not hesitate to contact me.

Sincerely yours,

Stephen Bourn General Manager cc: Leland Roberts Karl Kronfuss Official Use only Wyoming Pollutant Discharge Elimination System (WYPDES) Date Received:

Department of Environmental Quality Application for Permit to Discharge Wastewater for:

Industrial operations, Form G

 Please print or type. Submission of illegible materials will result in return of the application to the applicant.  All items must be completed accurately and in their entirety or the application will be deemed incomplete and the processing will be delayed or application returned.

 An original signature of the applicant is required. Faxes cannot be accepted.

1. Check the box corresponding to the type of application being applied for:

New x Renewal

Major modification Permit number ______WY0026689 Expiration Date: ______07/31/2020

2. General Facility Location: Township(s) ______24 North Range(s) ______93 West 3. Facility Street address if applicable: ______2938 Minerals X Road (42 miles Northwest of Rawlins) 4. Receiving Waters ______Unnamed playa lake on Battles Springs Flat 5. Name of the facility producing the discharge

______Kennecott Uranium Company

6. Standard Industrial Classification code (SIC Code) ______1094 and primary industrial category, per Table I, Appendix B (If Applicable): ______.Uranium ores mining and/or beneficiating

7. Permittee and Consultant (if applicable) Contact Information:

Permittee Contact Name Consultant Contact Name Karl Kronfuss Company Name Company Name Kennecott Uranium Company Mailing Address Mailing Address PO Box 1500 City, State, and Zip Code City, State, and Zip Code Rawlins, Wy 82301-1500 Telephone Number Telephone Number 307-328-1478 E-Mail Address E-Mail Address [email protected] Preference for contact: Preference for contact: E-Mail 8. Status of applicant: Federal State x private public Other ______

9. Status of applicant (check more than one): x Owner x Operator

10. Please include a brief description of the nature of the business conducted at this facility and principal products or services provided by the facility. ______This facility is a uranium mine (WYDEQ ______Permit to Mine #481) with an associated conventional uranium mill licensed by the Nuclear ______Regulatory Commission (NRC), Source Materials License #WYSUA-1350______

11. Please describe each type of process, operation or production area that contributes wastewater to the effluent for each outfall and the average flow which each process contributes. ______Mineral dewatering is the process contributing wastewater______to each outfall at a total rate of 5.0 mg. ______12. Please include a brief description of the wastewater treatment at the facility, including the ultimate disposal of any solid or liquid wastes other than by discharge.

______The treatment facility would add to the waste water stream. The barium chloride would precipitate the in ______settling ponds. These settling ponds would at the end of operations be covered with an earthen cover and the ground surface reclaimed ______13. For new facilities, the expected date of commencement of discharge. ______N/A this is a renewal For existing facilities, provide actual flow data from each outfall within the last six months

Will discharge be x continuous or intermittent?

If the discharge is to be intermittent the following information for each outfall shall be provided: (I) Number of times per year the discharge is to occur. (II) Anticipated duration of each discharge. (III) Anticipated flow of each discharge. (IV) Months in which discharge is expected to occur.

14. If requesting modification of existing permit, describe modification requests: ______N/A ______

b. For each change or improvement, provided projected dates, as accurately as possible, for completion of each step listed below:

1. Begin Construction: ______N/A 2. End Construction: ______N/A 3. Begin Discharge: ______N/A 4. Operational Level Attained:______N/A

Page 2 of 20 Landowner or lessee’s contact information (additional spaces may be added as necessary): Landowner #1 Name Landowner #2 Name U. S. Department of the Interior, Bureau of Land Management Mailing Address Mailing Address 1300 Third Street City, State, and Zip Code City, State, and Zip Code Rawlins, Wy 82301

b. Access Route: As part of the application, the applicant shall certify under penalty of perjury that the applicant has secured and shall maintain permission for Department of Environmental Quality personnel and their invitees to access the permitted facility, including (i) permission to access the land where the permitted facility is located, (ii) permission to collect resource data as defined by Wyoming Statute § 6-3-414, and (iii) permission to enter and cross all properties necessary to access the permitted facility if the facility cannot be directly accessed from a public road. A map of access route(s) to the facility shall accompany the application.

15. Facility Flow Diagram:

Please provide a schematic line drawing showing the water flow and water balance through the facility. The water balance must show approximate average flows at intake and discharge points and between units, including treatment units. If a water balance cannot be determined, a pictorial description of the nature and amount of any sources of water and any collection and treatment measures may be provided. Note the following example:

.

16. Outfall location: Complete the attached Appendix A, Table 1.

Page 3 of 20 17. Outfall Characterization: Complete the attached Appendix A, Table 2. See application instructions for details. a. Will any flocculants (settling agents or chemical additives) be used to treat water prior to discharge?

x YES NO If yes, list here the chemical name, manufacture, and purpose. Include MSDS sheets._Barium chloride / Solvay Chemicals and others / radium precipitation______

18. Please complete Appendix A, Tables 2 and 3 for each outfall. 19. Complete Appendix A, Table 4 only if you are required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operations of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application.

20. Facility map: Attach a description and a clear, legible, detailed topographic map of the discharging facility that extending one mile beyond the property boundaries of the source. Include the following: a. A legend b. Well locations where fluids from the facility are injected underground c. Retention Ponds d. Each intake sites e. Discharge points (outfalls) f. Monitoring and/or compliance points g. Hazardous waste treatment, storage, or disposal facilities h. Immediate receiving streams i. Section, Township, and Range information j. Wells, springs, other surface water bodies, drinking water wells, and surface water intake structures listed in public records, or otherwise known to the applicant in the map area. k. Location of treatment facilities l. Access Routes

21. Describe the control measures that will be implemented to prevent significant damage to or erosion of the receiving water channel at the outfall(s)_ Riprap will be used as erosion control at the outfall outlets if they are ever used for discharge.____

22. Production: a. Does an effluent guideline limitation or standard apply to your facility (e.g. metal finishing, fertilizer manufacturing, etc) as stated under Section 306 of the Clean Water Act? (Contact Wyoming DEQ with questions)

YES (complete item 21B below) x NO b. Are the limitations in the applicable effluent guideline express in terms of production or other measure of operation? (In Wyoming, primarily petroleum refining and cheese production)

YES (complete table below) x NO

Affected outfalls Quantity per day* Units of Measure Specify Operation, Product, or Materials N/A

*For new facilities and outfalls, please provide a reasonable measure of expected production. For existing facilities or outfalls, please provide a measure of actual production.

23. If applicable, provide a list of any toxic pollutants which the applicant currently uses or manufactures as an intermediate or final product or byproduct.

Page 4 of 20 24. Effluent Characterization All water quality samples shall be taken as grab samples and analyzed in accordance with 40 CRF Part 136 unless use of another method is required for the pollutant under 40 CFR Subparts N and O.

All applicants must analyze and submit the results for the constituents listed below (see Table 1, Appendix B). Biochemical Oxygen Demand (BOD5) Ammonia (as N) Chemical Oxygen Demand Temperature Total Organic pH Total Suspended Solids Color of Discharge

Primary Industries: A primary industry is any industry listed under the Primary Industrial Category in Appendix B, Table II.

If you are a primary industry (refer to Appendix B, Table II), samples must be collected for all fractions identified in Appendix B, Table I. For Appendix B, Tables IIA – III, mark “X” in the Required Testing column for each fraction related to your industry and provide the sample result. Sample results must be provided for each outfall that has the potential to discharge process wastewater.

For Appendix B, Table IV, mark “X” in column “Believed Present” for each pollutant you know or have reason to believe is present. Mark “X” in column “Believed Absent” for each pollutant you believe is absent. If an applicable federal effluent limitations guideline limits the pollutant through permit effluent limitations, the applicant must report quantitative data. For every pollutant discharged which is not so limited in an effluent limitations guideline, the applicant must either report quantitative data or briefly describe the reasons the pollutant is expected to be discharged.

For Appendix B, Table V, circle the pollutants you know or have reason to believe are present. For every pollutant from Table V expected to be discharged, from each outfall, provide a brief description of the reasons the pollutant is expected to be discharged, and report any quantitative data you may have.

Base your determination of whether a pollutant will be present in your discharge on your knowledge of the facility’s raw materials, maintenance chemicals, intermediate and final products, byproducts, and any analyses of your effluent or of any similar effluent. You may also provide the determination and the estimates based on available in-house or contractor’s engineering reports or any other studies performed on the facilities.

Secondary Industries: A secondary industry is an industry that is not listed under the primary Industrial Category in Appendix B, Table II.

For Appendix B, Tables IIA – III, mark “X” in column “Believed Present” for each pollutant you know or have reason to believe is present. Mark “X” in column “Believed Absent” for each pollutant you believe is absent. If you mark column “Believed Present” for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column “Believed Present” for acrolein, acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4, 6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column “Believed Present”, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.

For Appendix B, Table IV, mark “X” in column “Believed Present” for each pollutant you know or have reason to believe is present. Mark “X” in column “Believed Absent” for each pollutant you believe is absent. If an applicable federal effluent limitations guideline limits the pollutant through permit effluent limitations, the applicant must report quantitative data. For every pollutant discharged which is not so limited in an effluent limitations guideline, the applicant must either report quantitative data or briefly describe the reasons the pollutant is expected to be discharged.

For Appendix B, Table V, circle the pollutants you know or have reason to believe are present. For every pollutant from Table V expected to be discharged, from each outfall, provide a brief description of the reasons the pollutant is expected to be discharged, and report any quantitative data you may have.

Base your determination of whether a pollutant will be present in your discharge on your knowledge of the facility’s raw materials, maintenance chemicals, intermediate and final products, byproducts, and any analyses of your effluent or of any similar effluent. You may also provide the determination and the estimates based on available in-house or contractor’s engineering reports or any other studies performed on the facilities.

Page 5 of 20 For New Industrial Facilities: For Appendix B, Tables IIA – IV, mark “X” in column “Believed Present” for each pollutant you know or have reason to believe is present. Mark “X” in column “Believed Absent” for each pollutant you believe is absent. For each pollutant marked as “Believed Present” provide an estimated daily maximum concentration in the “Water Sample Results” column. For Appendix B, Table V, circle the pollutants you know or have reason to believe are present (no estimated daily maximum concentrations are required).

Base your determination of whether a pollutant will be present in your discharge on your knowledge of the facility’s raw materials, maintenance chemicals, intermediate and final products, byproducts, and any analyses of your effluent or of any similar effluent. You may also provide the determination and the estimates based on available in-house or contractor’s engineering reports or any other studies performed on the facilities.

Each applicant must report the existence of any technical evaluation concerning the wastewater treatment that will be utilized, along with the name and location of similar plants, if information is available.

25. Use Appendix B, Table VI to list any of the pollutants, for which you are not required to submit a water quality analysis, listed in Appendix B, Tables II – V below which you know or have reason to believe is discharged or may be discharged from any outfall. For every pollutant you list, briefly describe the reasons you believe to be present and report any analytical data in your possession. 26. Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on receiving water in relation to your discharge within the last three years?

YES x NO

If yes, identify the tests and describe their purpose below: ______

27. Dioxin testing: Each applicant for existing facilities must report qualitative data, generated using a screening procedure not calibrated with analytical standards for 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) if it :

i. Used or manufactures 2,4,5-trichlorophenoxy acetic acid (2,4,5,-T), 2-(2,4,5-trichlorophenoxy) propanoic acid (Silvex, 2,4,5,- TP); 2-(2,4,5-tricholorophenoxy) ethyl 2,2-dichloropropionate (Erbon); 0,0-dimethyl 0-(2,4,5-trichlorophenyl) phosphorothioate; 2,4,5-trichlorophenol (TCP); or hexachlorophene (HCP); or ii. Knows or has reason to believe that TCDD is or may be present in an effluent. iii. Applicants for new facilities must report if 2,3,7,8 Tetrachlorodibenzo-P-Dioxin (TCDD) may be discharged if any of the pollutants defined in 31.i above are used or manufactured or if there is reason to believe that TCDD will or may be present in the effluent.

28. For applications for existing facilities, has the facility ever exceeded permit limits or water quality standards?

x YES Many years ago NO If yes, a. Which constituents? Total Suspended Solids (TSS) / Radium-226 Oil and Grease

b. Has the exceedance been addressed? Yes, at the time. Facility is no longer dicharging.

c. Describe how the exceedance was addressed.Treatment testing using coagulants was done in April 1982 to address TSS. Radium-226 exceedances were addressed via increasing barium chloride addition rates. The Oil and Grease exceedances occurred when discharge commenced and were believed to be due to contamination related to the construction of the settling ponds. d. If the facility has never discharged or has not yet been constructed, please indicate below.

YES x NO Report the existence of any technical evaluation concerning the applicant’s wastewater treatment, along with the name and location of similar plants. ______A similar plant was operated at the Big Eagle Mine, permitted under permit WY0025950 and planned for the Jackpot Mine under permit WY0033952

Page 6 of 20 29. Other information: Any optional information the permittee wishes to have considered: ______

30. Signature

Authorized signatories for this application are the following: For corporations: A principal executive officer of at least the level of vice president, or the manager of one or more manufacturing, production, or operating facilities, provided the manager is authorized to make management decisions which govern the overall operation of the facility from which the discharge originates. For partnerships: A general partner. For a sole proprietorship: The proprietor. For a municipal, state, Either a principal executive officer or ranking elected official. federal or other public facility: I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is to the best of my knowledge and belief, true, accurate, and complete. Additionally, I certify that I have secured and shall maintain permission for Department of Environmental Quality personnel and their invitees to access the permitted facility, including (i) permission to access the land where the facility is located, (ii) permission to collect resource data as defined by Wyoming Statute § 6-3-414, and (iii) permission to enter and cross all properties necessary to access the facility if the facility cannot be directly accessed from a public road. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations.

______Stephen Bourn General Manager Printed Name of Person Signing Title

______Signature of Applicant Date

______867-445-5456 Telephone Fax

Section 35-11-901 of Wyoming Statutes provides that: *All permit applications must be signed in accordance with 40 CFR Part 122.22, “for” or “by” signatures are not acceptable. Section 35-11-901 of Wyoming Statutes provides that: Any person who knowingly makes any false statement, representation, or certification in any application ... shall upon conviction be fined not more than $10,000 or imprisoned for not more than one year, or both.

Wyoming Statute 35-11-312 was revised to require discharge permit fees be paid prior to permit issuance. Therefore, payment of permit fees must be accompanied with the application. Any application received without proper fee payment will be returned.

Individual permits are issued for a period of five years. A check for $500 per permit must be included with all applications for new permits and renewals for individual For Agency Use Only WYPDES permits. Date Check Received ______

I have enclosed a check for $______Check Amount ______Check Number ______Permit Term ______

Approval ______

Page 7 of 20 Appendix A, Outfall Characterization

TABLE 1: Outfall Location Information Latitude (NAD Longitude (NAD 83, decimal 83, decimal Discharge degrees Immediate Quarter/ degrees accurate Mainstem (closest Point Section Township Range accurate to a Receiving County Quarter to a minimum of 5 perennial water) (Outfall) # minimum of 5 Stream decimal places) decimal places) West North 24N Unnamed playa lake on 001 SW/NW 21 93W 42.04177 107.93056 Battle Spring Draw Battle Springs flat. Sweetwater Unnamed playa lake on 002 SW/NE 19 24N 93W 42.03944 107.95806 Battle Spring Draw Battle Springs flat. Sweetwater 19 93W 107.95472 Unnamed playa lake on 003 NE/NE 24N 42.04278 Battle Spring Draw Battle Springs flat. Sweetwater 93W Unnamed playa lake on 004 SE/SE 34 24N 42.00500 108.00750 Battle Spring Draw Battle Springs flat. Sweetwater 005

Page 8 of 20 Appendix A, Narrative Outfall Descriptions

Table 2, Narrative Outfall Descriptions

Indicate if outfall discharge is: Treatment (Description A. Continuous or List codes from Outfall B. Intermittent “Wastewater Treatment Final Treatment Water Source #1 Water Source #2 Water Source #3 number Unit C. Seasonal Codes”, Next Page) D. No Discharge (indicate one for each outfall)

(example) Bottom Ash Metal Cleaning 001 Bottom Ash Runoff Floor Drain Runoff Continuous 1-U, 4-A Settling Pond Wastewater 001 Mine dewatering A - Continuous 2-C Barium Chloride addition for radium removal 002 2-C Barium Chloride addition Mine dewatering A - Continuous for radium removal 2-C Barium Chloride 003 A - Continuous Mine dewatering addition for radium removal 004 2-C Barium Chloride addition Mine dewatering A - Continuous for radium removal 005

006

007

Additional spaces/tables may be included as necessary. Use the format provided.

Page 9 of 20 Wastewater Treatment Codes PHYSICAL TREATMENT PROCESSES 1–A...... Ammonia Stripping 1–M ...... Grit Removal 1–B ...... Dialysis 1–N ...... Microstraining 1–C ...... Diatomaceous Earth Filtration 1–O ...... Mixing 1–D ...... Distillation 1–P ...... Moving Bed Filters 1–E ...... Electrodialysis 1–Q...... Multimedia Filtration 1–F ...... Evaporation 1–R ...... Rapid Sand Filtration 1–G ...... Flocculation 1–S ...... Reverse Osmosis (Hyperfiltration) 1–H ...... Flotation 1–T ...... Screening 1–I ...... Foam Fractionation 1–U ...... Sedimentation (Settling) 1–J ...... Freezing 1–V ...... Slow Sand Filtration 1–K ...... Gas–Phase Separation 1–W ...... Solvent Extraction 1–L ...... Grinding (Comminutors) 1–X ...... Sorption

CHEMICAL TREATMENT PROCESSES 2–A ...... Carbon Adsorption 2–G ...... Disinfection (Ozone) 2–B ...... Chemical Oxidation 2–H ...... Disinfection (Other) 2–C ...... Chemical Precipitation 2–I ...... Electrochemical Treatment 2–D ...... Coagulation 2–J ...... Exchange 2–E ...... Dechlorination 2–K ...... Neutralization 2–F ...... Disinfection (Chlorine) 2–L ...... Reduction

BIOLOGICAL TREATMENT PROCESSES 3–A ...... Activated Sludge 3–E ...... Pre-Aeration 3–B ...... Aerated Lagoons 3–F ...... Spray Irrigation/Land Application 3–C ...... Anaerobic Treatment 3–G ...... Stabilization Ponds 3–D ...... Nitrification–Denitrification 3–H ...... Trickling Filtration

OTHER PROCESSES 4–A ...... Discharge to Surface Water 4–C ...... Reuse/Recycle of Treated Effluent 4–B ...... Ocean Discharge Through Outfall 4-D ...... Underground Injection

SLUDGE TREATMENT AND DISPOSAL PROCESSES 5–A ...... Aerobic Digestion 5–M ...... Heat Drying 5–B ...... Anaerobic Digestion 5–N ...... Heat Treatment 5–C...... Belt Filtration 5–O ...... Incineration 5–D...... Centrifugation 5–P ...... Land Application 5–E ...... Chemical Conditioning 5–Q ...... Landfill 5–F ...... Chlorine Treatment 5–R ...... Pressure Filtration 5–G ...... Composting 5–S ...... Pyrolysis 5–H ...... Drying Beds 5–T ...... Sludge Lagoons 5–I...... Elutriation 5–U ...... Vacuum Filtration 5–J ...... Flotation Thickening 5–V ...... Vibration 5–K ...... Freezing 5–W ...... Wet Oxidation 5–L ...... Gravity Thickening

Page 10 of 20 Appendix A, Discharge Rates

Table 3, Discharge Rates

For Continuously For Non-Continuous Discharging Outfalls Discharging outfalls

Outfall Average Daily Number of times per Anticipated duration of Anticipated flow of each Months in which discharge is Number # Discharge (MGD) year the discharge is each discharge discharge (MGD) expected to occur. to occur

001 .25

002 .25

003 .25

004 .25

Page 11 of 20 Appendix A, Improvements

TABLE 4: Improvements Are you now required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operations of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and grant or loan conditions.

1. Affected outfalls 2. Identification of condition, 4. Final Compliance Date agreement, etc. 3. Brief description of project Outfall Source of discharge A. Required B. Projected

001 N/A

002 N/A

003 N/A

004 N/A

005

Page 12 of 20 Appendix B, Table I

Table I: Effluent Characteristics per outfall You must provide the results of at least one analysis for every pollutant in this table for each outfall.

Maximum 30-day value Long term average value Outfall #______Maximum Daily Value (if available) (if available) Number of Analyses

Parameter Mass Concentration Mass Concentration Mass Concentration Biochemical Oxygen Demand (BOD) Total Suspended Solids (TSS)

Total Organic Carbon (TOC)

Chemical Oxygen Demand (COD)

Ammonia (as N)

Flow, discharge, MGD Value Value Value pH (range) S.U. Max Min Max Min Not Applicable Temperature (Winter) °C Value Value Value

Temperature (Summer) °C Value Value Value

Color of Discharge

* Consistent with the 2015 renewal application no discharge was conducted so this table was not completed. As this facility has not discharged since 1983, and the facility does not have water quality data available for many of the constituents that are currently limited by Wyoming Water Quality Rules and Regulations, Chapter 1 because such data collection was not required before the facility ceased discharge.

Page 13 of 20 Appendix B, Table II

Table II--Testing Requirements for Toxic Pollutants by PRIMARY INDUSTRIAL CATEGORY Organic Toxic Pollutants Other Toxic GS/MS Fraction (listed in Table IIA-Table IID) Pollutants (Listed in Table III) PRIMARY INDUSTRIAL CATEGORY Volatile Acid Base/Neutral Pesticides (Metals and Cyanide) and Total See Table IIA See Table IIB See Table IIC See Table IID Phenols Adhesives and Sealants...... X X X NR X Aluminum Forming...... X X X NR X Auto and Other Laundries...... X X X X X Battery Manufacturing...... X NR X NR X Coal Mining...... NR NR NR NR X Coil Coating...... X X X NR X Copper Forming...... X X X NR X Electric and Electronic Components X X X X X Electroplating...... X X X NR X Explosives Manufacturing...... NR X X NR X Foundries...... X X X NR X Gum and Wood Chemicals1...... X X X1 NR X Inorganic Chemicals Manufacturing X X X NR X Iron and Steel Manufacturing..... X X X NR X Leather Tanning and Finishing.... X X X NR X Mechanical Products Manufacturing X X X NR X Nonferrous Metals Manufacturing.. X X X X X Ore Mining2...... X X2 X X X Organic Chemicals Manufacturing.. X X X X X Paint and Ink Formulation...... X X X NR X Pesticides...... X X X X X Petroleum Refining...... X NR NR NR X Pharmaceutical Preparations...... X X X NR X Photographic Equipment and Supplies...... X X X NR X Plastic and Synthetic Materials Manufacturing...... X X X X X Plastic Processing...... X NR NR NR X Porcelain Enameling...... NR NR NR NR X Printing and Publishing...... X X X X X Pulp and Paper Mills...... (see individual subcategories) X X X X X Rubber Processing...... X X X NR X Soap and Detergent Manufacturing. X X X NR X Steam Electric Power Plants...... X X NR NR X Textile Mills...... (SubPart C Greige Mills exempt) X X X NR X Timber Products Processing...... X X X X X X = testing is required NR =testing is not required unless believed to be present. 1’Base/neutral’ constituents only required for ‘tall oil rosin’ and ‘rosin-based derivatives’ subcategories (subparts D and F). 2Subpart B, Base and Precious Metals Subcategory only required to test for ‘Acid’ constituents. Appendix B, Table IIA Table IIA VOLATILE COMPOUNDS (Complete table and include lab reports if applicable) Organic Toxic Pollutants GS/MS Fraction Pollutant Mark with “X” Water Sample Required Believed Believed Result (if Testing Absent Present required) 1 V acrolein X 2 V acrylonitrile X 3 V benzene X 5 V bromoform X 6 V carbon tetrachloride X 7 V chlorobenzene X 8 V chlorodibromomethane X 9 V chloroethane X 10 V 2-chloroethylvinyl ether X 11 V chloroform X 12 V dichlorobromomethane X 14 V 1,1-dichloroethane X 15 V 1,2-dichloroethane X 16 V 1,1-dichloroethylene X 17 V 1,2-dichloropropane X 18 V 1,3-dichloropropylene X 19 V ethylbenzene X 20 V methyl bromide X 21 V methyl chloride X 22 V methylene chloride X 23 V 1,1,2,2-tetrachloroethane X 24 V tetrachloroethylene X 25 V toluene X 26 V 1,2-trans-dichloroethylene X 27 V 1,1,1-trichloroethane X 28 V 1,1,2-trichloroethane X 29 V X 31 V vinyl chloride X Appendix B, Table IIB

Table IIB ACID COMPOUNDS (Complete table and include lab reports if applicable) Organic Toxic Pollutants GS/MS Fraction Mark with “X” Water Quality Pollutant Required Believed Believed Results Testing Absent Present 1A 2-chlorophenol X 2A 2,4-dichlorophenol X 3A 2,4-dimethylphenol X 4A 4,6-dinitro-o-cresol X 5A 2,4-dinitrophenol X 6A 2-nitrophenol X 7A 4-nitrophenol X 8A p-chloro-m-cresol X 9A pentachlorophenol X 10A phenol X 11A 2,4,6-trichlorophenol X

Appendix B, Table IIC

Table IIC-BASE/NEUTRAL COMPOUNDS (Complete table and include lab reports if applicable) Organic Toxic Pollutants GS/MS Fraction Pollutant Mark with “X” Water Sample Required Believed Believed Results(if Testing Absent Present required) 1 B acenaphthene X 2 B acenaphthylene X 3 B anthracene X 4 B benzidine X 5 B benzo(a)anthracene X 6 B benzo(a)pyrene X 7 B 3,4-benzofluoranthene X 8 B benzo(ghi)perylene X 9 B benzo(k)fluoranthene X 10B. Bis (2-Chloroethoxy) Methane X 11 B bis(2-chloroethyl)ether X 12 B bis(2-chloroisopropyl)ether X 13 B bis (2-ethylhexyl)phthalate X 14 B 4-bromophenyl phenyl ether X 15 B butylbenzyl phthalate X 16 B 2-chloronaphthalene X 17 B 4-chlorophenyl phenyl ether X 18 B chrysene X 19 B dibenzo(a,h)anthracene X 20 B 1,2-dichlorobenzene X 21 B 1,3-dichlorobenzene X 22 B 1,4-dichlorobenzene X 23 B 3,3'-dichlorobenzidine X 24 B diethyl phthalate X 25 B dimethyl phthalate X 26 B di-n-butyl phthalate X 27 B 2,4-dinitrotoluene X 28 B 2,6-dinitrotoluene X 29 B di-n-octyl phthalate X Page 16 of 20 Table IIC-BASE/NEUTRAL COMPOUNDS (Complete table and include lab reports if applicable) Organic Toxic Pollutants GS/MS Fraction Pollutant Mark with “X” Water Sample Required Believed Believed Results(if Testing Absent Present required) 30B. 1,2-Diphenylhydrazine (as Azobenzene) X 31B. Fluoranthene (206 X 32B. Fluorene X 33B. Hexachlorobenzene X 34B. Hexachlorobutadiene X 35B. Hexachlorocyclopentadiene X 36B Hexachloroethane X 37B. Indeno X 38B. Isophorone X 39B. Naphthalene X 40B. Nitrobenzene X 41B. N-Nitrosodimethylamine X 42B. N-Nitrosodi-N-Propylamine X 43B. N-Nitrosodiphenylamine X 44B. Phenanthrene X 45B. Pyrene X 46B.1,2,4-Tri-Chlorobenzene X

Appendix B, Table IID Table IID-PESTICIDE COMPOUNDS (Complete table and include lab reports if applicable) Pollutant Mark with “X” Water Sample Results Required Believed Believed Testing Absent Present 1P aldrin X 2P alpha-BHC X 3P beta-BHC X 4P gamma-BHC X 5P delta-BHC X 6P chlordane X 7P 4,4'-DDT X 8P 4,4'-DDE X 9P 4,4'-DDD X 10P dieldrin X 11P alpha-endosulfan X 12P beta-endosulfan X 13P endosulfan X 14P endrin X 15P endrin aldehyde X 16P heptachlor X 17P heptachlor epoxide X 18P PCB-1242 X 19P PCB-1254 X 20P PCB-1221 X 21P PCB-1232 X 22P PCB-1248 X 23P PCB-1260 X 24P PCB-1016 X 25P toxaphene X

Page 17 of 20 Appendix B, Table III

Table III—Metals(Total Recoverable), Cyanide, Total Phenols, and Hardness Pollutant Mark with “X” Water Sample Results Required Believed Believed Testing Absent Present Antimony, Total Recoverable X Arsenic, Dissolved X 0-0.002 mg/L Beryllium, Total Recoverable X Cadmium, Dissolved X Chromium, Dissolved X Copper, Dissolved X Cyanide, Dissolved X Hardness (as CaCO3), Total X 81.7-95.7 mg/L Lead, Dissolved X Mercury, Dissolved X Nickel, Dissolved X Phenols, Total Recoverable X Selenium, Total Recoverable X Silver, Dissolved X 0-0.01 mg/L Thallium, Total Recoverable X Zinc, Dissolved X 0.05-0.19mg/L DIOXIN 2,3,7,8-Tetra-Chlorodibenzo-P-Bioxin X As this facility has not discharged since 1983, and the facility does not have water quality data available for many of the constituents that are currently limited by Wyoming Water Quality Rules and Regulations, Chapter 1 because such data collection was not required before the facility ceased discharge.

Page 18 of 20 Appendix B, Table IV

TABLE IV: Conventional and Nonconventional Pollutants: Pollutant Mark with “X” Water Sample Results Believed Absent Believed Present Bromide X Chlorine, Total Residual X E. coli X Fluoride X 0.12-017 mg/L Nitrate-Nitrite X 0.0-0.18 mg/L Nitrogen, Total Organic X Oil and Grease X Phosphorus X Radioactivity Alpha, Total X 0.0-2.8 pCi/L Beta, Total X Radium, Total Recoverable X 0.0-2.0 pCi/L Radium 226, Total Recoverble X 0.0-2.0 pCi/L Sulfate X 39.8-57.8 mg/L Sulfide X Sulfite X Surfactants X Aluminum, Dissolved X 0.0-0.12 mg/L Barium, Total Recoverable X Boron X Cobalt X Iron, Dissolved X 0.0-0.28 mg/L , Dissolved X 0.0-0.20 mg/L Molybdenum X 0.0-0.01 mg/L Manganese, Dissolved X 0.0-0.02 mg/L Tin X Titanium X

As this facility has not discharged since 1983, and the facility does not have water quality data available for many of the constituents that are currently limited by Wyoming Water Quality Rules and Regulations, Chapter 1 because such data collection was not required before the facility ceased discharge.

Page 19 of 20 Appendix B, Table V

TOXIC POLLUTANTS AND HAZARDOUS SUBSTANCES Circle any constituent(s) below you believe to be present in the discharge TABLE V TOXIC POLLUTANT Asbestos HAZARDOUS SUBSTANCES Acetaldehyde Diethyl amine Napthenic acid Monomethyl amine Allyl alcohol Dintrobenzene Naled Allyl chloride Diquat Nitrotoluene Amyl acetate Disulfoton Parathion Aniline Diuron Phenolsulfonate Asbestos Epichlorohydrin Phosgene Benzonitrile Ethion Propargite Benzyl chloride Ethylene diamine Propylene oxide Butyl acetate Ethylene dibromide Pyrethrins Butylamine Formaldehyde Quinoline Captan Furfural Resorcinol Carbaryl Guthion Strontium Carbofuran Dimethyl amine Strychnine Carbon disulfide Isoprene Styrene Chlorpyrifos Isopropanolamine TDE (Tetrachlorodiphenyl ethane) Coumaphos Kelthane Trichlorofon Cresol Kepone 2,4,5-T (2,4,5-Trichlorophenoxyacetic acid) Crotonaldehyde Malathion 2,4,5-TP [2-(2,4,5-Trichlorophenoxy) propanoic acid] Cyclohexane Mercaptodimethur Triethanolamine Diazinon Methoxychlor Triethylamine Dicamba Methyl mercaptan Trimethylamine Dichlobenil Methyl methacrylate Uranium Dichlone Methyl parathion Vanadium 2,4-D (2,4-Dichlorophenoxyacetic acid) Mevinphos Vinyl acetate 2,2-Dichloropropionic acid Mexacarbate Xylene Dichlorvos Monoethyl amine Xylenol

Appendix B, Table VI

Below:

Page 20 of 21 TABLE VI Use the space below to list any of the pollutants in the above tables (II-VI) which you are not required to submit a water quality sample and you know or have reason to believe is discharged or may be discharged from any outfall. For every pollutant you list, briefly describe the reasons you believe to be present and report any analytical data in your possession. 1. Pollutant 2. Source 1. Pollutant 2. Source Arsenic Dewatering wells – Zinc Dewatering wells – present at low present at low concentrations (0.0 – concentrations (0.05 – 0.002 mg/L) based on 0.19 mg/L) based on analyses of dewatering analyses of dewatering wells. wells. Hardness Dewatering wells – Fluoride Dewatering wells – present at low present at low concentrations (81.7 – concentrations (0.12 – 95.7 mg/L) based on 0.17 mg/L) based on analyses of dewatering analyses of dewatering wells. wells. Sulfate Dewatering wells – Nitrate-Nitrite Dewatering wells – present at low present at low concentrations (39.8 – concentrations (0.0 – 0.18 57.8 mg/L) based on mg/L) based on analyses analyses of dewatering of dewatering wells. wells. Alpha, Total Dewatering wells – Radium, Total Dewatering wells – present at low Recoverable present at low concentrations (0.0 – 2.8 concentrations (0.0 – 2.0 pCi/L) based on analyses pCi/L) based on analyses of dewatering wells. of dewatering wells. Radium-226, Total Dewatering wells – Aluminum Dewatering wells – Recoverable present at low present at low concentrations (0.0 – 2.0 concentrations (0.0 – 0.12 pCi/L) based on analyses mg/L) based on analyses of dewatering wells. of dewatering wells. Iron – Dissolved Dewatering wells – Magnesium – Dissolved Dewatering wells – present at low present at low concentrations (0.0 – 0.28 concentrations (0.0 – 0.20 mg/L) based on analyses mg/L) based on analyses of dewatering wells. of dewatering wells. Molybdenum Dewatering wells – Manganese – Dissolved Dewatering wells – present at low present at low concentrations (0.0 – 0.01 concentrations (0.0 – 0.02 mg/L) based on analyses mg/L) based on analyses of dewatering wells. of dewatering wells. Uranium Dewatering wells – Silver Dewatering wells – present at low present at low concentrations (0.0 – concentrations (0.0 – 0.01 0.064 mg/L) based on mg/L) based on analyses analyses of dewatering of dewatering wells. wells.

Page 21 of 21

Barium Chloride, Dihydrate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Date of issue: 04/16/2014 Revision date: 03/13/2019 Supersedes: 10/28/2016 Version: 1.2

SECTION 1: Identification

1.1. Identification Product form : Substance Substance name : Barium Chloride, Dihydrate CAS-No. : 10326-27-9 Product code : LC11560 Formula : BaCl2.2H2O Synonyms : barium dichloride, dihydrate / muriate of barium, dihydrate

1.2. Recommended use and restrictions on use Use of the substance/mixture : Chemical intermediate Insecticide

1.3. Supplier LabChem, Inc. Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647

1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 or +1-703-741-5970

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture GHS-US classification Acute toxicity (oral) H301 Toxic if swallowed Category 3 Hazardous to the aquatic H402 Harmful to aquatic life environment - Acute Hazard Category 3

Full text of H statements : see section 16

2.2. GHS Label elements, including precautionary statements GHS US labeling Hazard pictograms (GHS US) :

GHS06 Signal word (GHS US) : Danger Hazard statements (GHS US) : H301 - Toxic if swallowed H402 - Harmful to aquatic life Precautionary statements (GHS US) : P264 - Wash exposed skin thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P273 - Avoid release to the environment. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P330 - If swallowed, rinse mouth P405 - Store locked up. P501 - Dispose of contents/container to comply with local, state and federal regulations

2.3. Other hazards which do not result in classification Other hazards not contributing to the : None under normal conditions. classification 2.4. Unknown acute toxicity (GHS US) Not applicable

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SECTION 3: Composition/Information on ingredients

3.1. Substances Substance type : Mono-constituent

Name Product identifier % GHS-US classification Barium Chloride, Dihydrate (CAS-No.) 10326-27-9 100 Acute Tox. 3 (Oral), H301 (Main constituent) Aquatic Acute 3, H402

Full text of hazard classes and H-statements : see section 16

3.2. Mixtures Not applicable SECTION 4: First-aid measures

4.1. Description of first aid measures First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with labored breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. First-aid measures after skin contact : Rinse with water. Soap may be used. Do not apply (chemical) neutralizing agents. Take victim to a doctor if irritation persists. First-aid measures after eye contact : Rinse with water. Remove contact lenses, if present and easy to do. Continue rinsing. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists. First-aid measures after ingestion : Rinse mouth with water. Give nothing to drink. Victim is fully conscious: immediately induce vomiting. Induce vomiting by giving a 0.9 % saline solution. Immediately consult a doctor/medical service. Call Poison Information Centre (www.big.be/antigif.htm). Take the container/vomit to the doctor/hospital. Ingestion of large quantities: immediately to hospital. Doctor: administration of chemical antidote. Doctor: gastric lavage.

4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Dry/sore throat. Coughing. Symptoms/effects after eye contact : Redness of the eye tissue. Symptoms/effects after ingestion : Vomiting. Nausea. Abdominal pain. Blood in stool. Bleeding of the gastrointestinal tract. Increased salivation. Myasthenia. Cramps/uncontrolled muscular contractions. Paralysis. Disturbances of heart rate. High arterial pressure.

4.3. Immediate medical attention and special treatment, if necessary Obtain medical assistance. SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Adapt extinguishing media to the environment for surrounding fires.

5.2. Specific hazards arising from the chemical Fire hazard : DIRECT FIRE HAZARD. Non combustible. Reactivity : Reacts with (strong) oxidizers.

5.3. Special protective equipment and precautions for fire-fighters Precautionary measures fire : Exposure to fire/heat: keep upwind. Exposure to fire/heat: consider evacuation. Exposure to fire/heat: have neighbourhood close doors and windows. Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Dilute toxic gases with water spray. Take account of toxic fire-fighting water. Use water moderately and if possible collect or contain it. Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective clothing. Dust cloud production: compressed air/oxygen apparatus. Reactivity hazard: compressed air/oxygen apparatus. Reactivity hazard: gas-tight suit.

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Emergency procedures : Mark the danger area. Prevent dust cloud formation. No naked flames. Wash contaminated clothes. In case of hazardous reactions: keep upwind. In case of reactivity hazard: consider evacuation. Measures in case of dust release : In case of dust production: keep upwind. In case of dust production: consider evacuation. Dust production: have neighbourhood close doors and windows.

6.1.2. For emergency responders Protective equipment : Do not breathe dust. Equip cleanup crew with proper protection. Emergency procedures : Stop release. Ventilate area. If a major spill occurs, all personnel should be immediately evacuated and the area ventilated.

6.2. Environmental precautions Prevent soil and water pollution. Prevent spreading in sewers.

6.3. Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Dam up the solid spill. Knock down/dilute dust cloud with water spray. If reacting: dilute toxic gas/vapour with water spray. Take account of toxic/corrosive precipitation water. Methods for cleaning up : Stop dust cloud by covering with sand/earth. Scoop solid spill into closing containers. Carefully collect the spill/leftovers. Clean contaminated surfaces with an excess of water and soap solution. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.

6.4. Reference to other sections No additional information available SECTION 7: Handling and storage

7.1. Precautions for safe handling Additional hazards when processed : Pulverization rapidly increases toxic concentration. Precautions for safe handling : Avoid raising dust. Keep away from naked flames/heat. Measure the concentration in the air regularly. Carry operations in the open/under local exhaust/ventilation or with respiratory protection. Comply with the legal requirements. Clean contaminated clothing. Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Keep container tightly closed. Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

7.2. Conditions for safe storage, including any incompatibilities Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources. Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. strong acids. Storage area : Store in a dry area. Keep container in a well-ventilated place. Keep locked up. Unauthorized persons are not admitted. Meet the legal requirements. Special rules on packaging : SPECIAL REQUIREMENTS: closing. clean. correctly labelled. meet the legal requirements. Secure fragile packagings in solid containers. Packaging materials : SUITABLE MATERIAL: steel. stainless steel. paper with plastic inner lining. cardboard. synthetic material. MATERIAL TO AVOID: aluminium.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters Barium Chloride, Dihydrate (10326-27-9) ACGIH ACGIH TWA (mg/m³) 0.5 mg/m³ NIOSH NIOSH REL (TWA) (mg/m³) 0.5 mg/m³

8.2. Appropriate engineering controls Appropriate engineering controls : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation.

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Barium Chloride, Dihydrate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

8.3. Individual protection measures/Personal protective equipment Personal protective equipment: Safety glasses. Gloves. Protective clothing. Dust production: dust mask with filter type P3.

Materials for protective clothing: GIVE GOOD RESISTANCE: butyl rubber. chloroprene rubber. chlorinated polyethylene. neoprene. PVC. viton

Hand protection: Gloves

Eye protection: Safety glasses. In case of dust production: protective goggles

Skin and body protection: Protective clothing

Respiratory protection: Dust production: dust mask with filter type P3. High dust production: self-contained breathing apparatus

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties Physical state : Solid

Appearance : Crystalline solid. Powder. Crystalline powder. Grains. : Colourless to white

: Odorless

Odor threshold : No data available

pH : 5 - 8 (5 %)

Melting point : 963 °C

Freezing point : No data available

Boiling point : 1560 °C

Flash point : Not applicable

Relative evaporation rate (butyl acetate=1) : No data available

Flammability (solid, gas) : No data available

Vapor pressure : < 0.1 hPa (20 °C)

Relative vapor density at 20 °C : Not applicable

Relative density : 3.1

Specific gravity / density : 3100 kg/m³ Molecular mass : 244.28 g/mol : Soluble in water. Water: 36 g/100ml

Log Pow : No data available

Auto-ignition temperature : No data available

Decomposition temperature : No data available

Viscosity, kinematic : No data available

Viscosity, dynamic : No data available

Explosion limits : No data available

Explosive properties : No data available

Oxidizing properties : No data available

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Barium Chloride, Dihydrate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

9.2. Other information VOC content : 0 %

SECTION 10: Stability and reactivity

10.1. Reactivity Reacts with (strong) oxidizers.

10.2. Chemical stability Stable under normal conditions.

10.3. Possibility of hazardous reactions Not established.

10.4. Conditions to avoid Incompatible materials. Moisture.

10.5. Incompatible materials Strong oxidizers.

10.6. Hazardous decomposition products . barium. SECTION 11: Toxicological information

11.1. Information on toxicological effects

Likely routes of exposure : Inhalation; Skin and eye contact

Acute toxicity : Not classified

Barium Chloride, Dihydrate (10326-27-9) LD50 oral rat 118 mg/kg (Rat, Oral) ATE US (oral) 118 mg/kg body weight

Skin corrosion/irritation : Not classified pH: 5 - 8 (5 %) Serious eye damage/irritation : Not classified pH: 5 - 8 (5 %) Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified

Reproductive toxicity : Not classified Specific target organ toxicity – single exposure : Not classified

Specific target organ toxicity – repeated : Not classified exposure

Aspiration hazard : Not classified

Potential Adverse human health effects and : Toxic if swallowed. Harmful if inhaled. symptoms Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Dry/sore throat. Coughing. Symptoms/effects after eye contact : Redness of the eye tissue. Symptoms/effects after ingestion : Vomiting. Nausea. Abdominal pain. Blood in stool. Bleeding of the gastrointestinal tract. Increased salivation. Myasthenia. Cramps/uncontrolled muscular contractions. Paralysis. Disturbances of heart rate. High arterial pressure.

SECTION 12: Ecological information

12.1. Toxicity Ecology - general : Not classified as dangerous for the environment according to the criteria of Regulation (EC) No 1272/2008. Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). Ecology - water : Harmful to crustacea. Slightly harmful to fishes. Harmful to aquatic plants. Groundwater pollutant. Mild water pollutant (surface water). Not harmful to bacteria.

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Barium Chloride, Dihydrate (10326-27-9) LC50 fish 1 870 mg/l (Leuciscus idus) EC50 Daphnia 1 21.9 mg/l (48 h, Daphnia magna, Anhydrous form)

12.2. Persistence and degradability Barium Chloride, Dihydrate (10326-27-9) Persistence and degradability Biodegradability: not applicable. Chemical oxygen demand (COD) Not applicable

ThOD Not applicable BOD (% of ThOD) Not applicable

12.3. Bioaccumulative potential Barium Chloride, Dihydrate (10326-27-9) Bioaccumulative potential No bioaccumulation data available.

12.4. Mobility in soil No additional information available

12.5. Other adverse effects No additional information available

SECTION 13: Disposal considerations

13.1. Disposal methods Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Remove to an authorized dump (Class I). Detoxicate. Additional information : Hazardous waste according to Directive 2008/98/EC, as amended by Regulation (EU) No 1357/2014 and Regulation (EU) No 2017/997.

SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : UN1564 Barium compounds, n.o.s., 6.1, III

UN-No.(DOT) : UN1564 Proper Shipping Name (DOT) : Barium compounds, n.o.s. Transport hazard class(es) (DOT) : 6.1 - Class 6.1 - Poisonous materials 49 CFR 173.132 Packing group (DOT) : III - Minor Danger Hazard labels (DOT) : 6.1 - Poison

DOT Packaging Non Bulk (49 CFR 173.xxx) : 213 DOT Packaging Bulk (49 CFR 173.xxx) : 240 DOT Symbols : G - Identifies PSN requiring a technical name

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DOT Special Provisions (49 CFR 172.102) : IB8 - Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). IP3 - Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. T1 - 1.5 178.274(d)(2) Normal...... 178.275(d)(2) TP33 - The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter. DOT Packaging Exceptions (49 CFR 173.xxx) : 153 DOT Quantity Limitations Passenger aircraft/rail : 100 kg (49 CFR 173.27) DOT Quantity Limitations Cargo aircraft only (49 : 200 kg CFR 175.75) DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel. Other information : No supplementary information available.

Transportation of Dangerous Goods Transport document description : UN1564 BARIUM COMPOUND, N.O.S. (Barium Chloride), 6.1, III UN-No. (TDG) : UN1564 Proper Shipping Name (Transportation of : BARIUM COMPOUND, N.O.S. Dangerous Goods) TDG Primary Hazard Classes : 6.1 - Class 6.1 - Toxic Substances Packing group : III - Minor Danger TDG Special Provisions : 16 - (1) The technical name of at least one of the most dangerous substances that predominantly contributes to the hazard or hazards posed by the dangerous goods must be shown, in parentheses, on the shipping document following the shipping name in accordance with clause 3.5(1)(c)(ii)(A) of Part 3 (Documentation). The technical name must also be shown, in parentheses, on a small means of containment or on a tag following the shipping name in accordance with subsections 4.11(2) and (3) of Part 4 (Dangerous Goods Safety Marks). (2) Despite subsection (1), the technical name for the following dangerous goods is not required to be shown on a shipping document or on a small means of containment when Canadian law for domestic transport or an international convention for international transport prohibits the disclosure of the technical name: (a)UN1544, ALKALOID SALTS, SOLID, N.O.S. or ALKALOIDS, SOLID, N.O.S; (b)UN1851, MEDICINE, LIQUID, TOXIC, N.O.S; (c)UN3140, ALKALOID SALTS, LIQUID, N.O.S. or ALKALOIDS, LIQUID, N.O.S; (d)UN3248, MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S; or (e)UN3249, MEDICINE, SOLID, TOXIC, N.O.S. An example in Canada is the “Food and Drugs Act”. (3) Despite subsection (1), the technical name for the following dangerous goods is not required to be shown on a small means of containment: (a)UN2814, INFECTIOUS SUBSTANCE, AFFECTING HUMANS; or (b)UN2900, INFECTIOUS SUBSTANCE, AFFECTING ANIMALS. SOR/2014-306 Explosive Limit and Limited Quantity Index : 5 kg Passenger Carrying Road Vehicle or Passenger : 100 kg Carrying Railway Vehicle Index

Transport by sea Transport document description (IMDG) : UN 1564 barium compound, n.o.s. (Barium Chloride), 6.1, III UN-No. (IMDG) : 1564 Proper Shipping Name (IMDG) : barium compound, n.o.s. Class (IMDG) : 6.1 - Toxic substances Packing group (IMDG) : III - substances presenting low danger EmS-No. (1) : F-A EmS-No. (2) : S-A

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Air transport Transport document description (IATA) : UN 1564 Barium compound, n.o.s. (Barium Chloride), 6.1, III UN-No. (IATA) : 1564 Proper Shipping Name (IATA) : Barium compound, n.o.s. Class (IATA) : 6.1 - Toxic Substances Packing group (IATA) : III - Minor Danger

SECTION 15: Regulatory information

15.1. US Federal regulations Barium Chloride, Dihydrate (10326-27-9) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Health hazard - Acute toxicity (any route of exposure)

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory

15.2. International regulations CANADA Barium Chloride, Dihydrate (10326-27-9) Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations No additional information available

National regulations

Barium Chloride, Dihydrate (10326-27-9) Listed on the Canadian IDL (Ingredient Disclosure List)

15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm

SECTION 16: Other information

Revision date : 03/13/2019

Full text of H-phrases: see section 16: --- H301 Toxic if swallowed ------H402 Harmful to aquatic life ---

NFPA health hazard : 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury. NFPA fire hazard : 0 - Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. NFPA reactivity : 0 - Material that in themselves are normally stable, even under fire conditions.

Hazard Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 0 Minimal Hazard - Materials that will not burn Physical : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. Personal protection : E E - Safety glasses, Gloves, Dust respirator

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Barium Chloride, Dihydrate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations SDS US LabChem

Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application.

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