Geology and Sulfide Mineralogy of the Number One Orebody, Ruby Creek Copper Deposit, Alaska

Total Page:16

File Type:pdf, Size:1020Kb

Geology and Sulfide Mineralogy of the Number One Orebody, Ruby Creek Copper Deposit, Alaska EconomicGeology Vol. 81, 1986, pp. 1675-1689 Geology and Sulfide Mineralogy of the Number One Orebody, Ruby Creek Copper Deposit, Alaska LAWRENCE R. BERNSTEIN* AND DENNIS P. COX U.S. GeologicalSurvey, 345 MiddlefieldRoad, Mail Stop984, MenloPark, California94025 Abstract The Number One orebodyis the largestand mostsulfide-rich ore zone (at least 200,000 tonscontaining 8.4 wt % Cu) at the Ruby Creek copperdeposit, in the southwesternBrooks Rangeof Alaska.Pyrite and copper-bearing sulfide minerals are concentratedwithin the matrix of a dolostonebreccia body, which is enclosedby phyllite andcalcic marble of Middle to Late Devonianage. The Number One orebodyhas three mineralogicalzones that gradeinto each other: (1) an outer zone,widest toward the hangingwall, containingmostly pyrite with minor amountsof chalcopyriteand traces of carrollitcand sphalerite;(2) an intermediatezone con- tainingmajor chalcopyriteand pyrite, minor tennantite-tetrahedrite,bornitc, carrollitc, and sphalerite,and tracesof galena;and (3) a core zone containingmajor bornitc, chalcopyrite, pyrite, and chalcocite,minor carrollitc, digenite, and sphalerite,and tracesof galena,covellite, and the germanium-bearingsulfides renierite and germanitc.Small clots of anthracitelike organicmaterial (anthraxolite) are foundthroughout the ore. Muchof the pyrite is fine grained andwas deposited before the othersulfides, being increasingly replaced by Cu-bearingsulfides from the outer zoneto the core. Someof thispyrite recrystallizedinto coarsergrains having cobaltiferousrims, and these grainswere generallynot replaced.The sulfideminerals are commonlypseudomorphous after lath-shaped crystals within the dolomiteclasts; no unreplaced exampleswere found,though the crystalsclosely resemble those of marcasite.The abundant fine-grained,porous pyrite alsomay represent replacement of marcasite.The originand timing of brecciationand ore depositionremain unknown, though dolomitization and ore deposition appearto have occurredin preexistingcarbonate breccia. Close mineralogicaland geologic similaritiesare noted with the Kipushi Cu-Zn-Pb depositin Zaire and with severalother carbonate-hostedcopper-rich organic-bearing deposits. The commonconcentration of the rare metalsCo, Ge, and Ga in thesestructurally and mineralogicallycomplex ores should increase their economic attractiveness. Introduction repeatedhere. Hitzman (1983, 1986) alsoprovided THE Ruby Creek copperdeposit, in the southwestern a reinterpretationof RunnelIs'sulfur isotopedata, BrooksRange of Alaska, consistsof sulfide-richdo- detailed analysesof anthraxoliteand other organic lostone breccia zones within Middle Devonian back- matter,an hypothesisconcerning the genesisof the reef faciescarbonate rocks. The ore consistspredom- deposit,and analogiesto other deposits. inantlyof copper-richsulfide minerals partly replac- Thisreport describes the geometry,internal struc- ing earlierfine-grained pyrite. Sulfides containing Zn, ture, and sulfidemineralogy of the largestand most Co, Pb, As, Sb, or Ge are presentin minor to trace sulfide-richorebody at RubyCreek, the NumberOne quantities.Anthracitelike organic material (anthrax- orebody.The surfaceexposure at the BergCamp area, olite)is foundsporadically distributed throughout the in the westernpart of the RubyCreek deposit, is also ore. Brecciation,apparently of more than one gen- described.The sequenceof crystallizationand im- erationand at scalesranging from millimetersto me- plicationsto the genesisof the ore arethen discussed. ters, greatly complicateszonal relationsof the min- Locationand Descriptionof Workings erals. The Ruby Creek depositis locatedabout 24 km The depositwas investigatedby Runnells(1963, 1969), who reportedthe resultsof geologic,miner- north of Kobuk village in the CosmosHills, Alaska alogical,and sulfurisotope studies. More recently, (67ø05'00"N, 156ø56'40"W), about350 km north- west of Fairbanks.Copper-bearing sulfide mineral- Hitzmanet al. (1982) andHitzman (1983, 1986) de- scribedthe geologyof the depositand surrounding izationcrops out at the originaldiscovery site at Berg areas in considerable detail; this material will not be Campand is also encountered in numerousdrill holes within an area of about1.5 kme (Fig. 1). In these sites, gradesof 1 to 3 wt percent Cu are common, * Present address:Center for Materials Research, Stanford with chalcopyritegenerally being the predominant University, Stanford, California 94305-4045. coppermineral. In a few drill holes,mainly within 0361-0128/86/609/1675-155•.50 1675 1676 L. R. BERNSTEINAND D. P. COX 4,780,000N Airstri ./•'-----•---- L --••_•e_• /Approximate limitof ( It 2 • 22 --'•x--'---'•/. diamonddrilling // F,gure2 /// 4,775,000N Coordinates in feet from Alaska StatePlane System, zone 6 0 250 500METERS 0 500 1000 1500 FEET FIG. ]. Locationmap of the Ruby Creek area. Shadedareas show the approximatesubsurface limits of bornite-chalcocitemineralization as indicated by diamonddrilling. the shadedareas shown in Figure 1, bornite-chalco- wt percentCu (C. T. Penney,unpub. Kennecott Corp. cite ore occursthat hashigher Cu grades. report, 1968). In 1965 the KennecottCorporation sank a shaftto Methods investigatea large high-gradeore zone encountered in the drill holes,which became known asthe Number Surfaceexposures at Ruby Creek, includingBerg One orebody.(In thisreport, we refer to thishigh- Camp, were examinedin 1979, 1980, and 1981. Un- gradezone as the "orebody"for simplicity.We do dergroundareas could not be examineddue to flood- notimply that this zone everywhere necessarily meets ing that occurredin 1967. Approximately12,000 ft any particulareconomic definition of ore.) A north- (3,700 m) of Ax diamonddrill core that penetrated trendingcrosscut at the 975-ft (300 m) level, aswell the Number One orebody and adjacent areas was asunderground drilling, servedto outlinethe dimen- loggedand sampled.From these data, crosssections sionsof the orebody.The orebodycontains a mini- were constructedthat were subsequentlyused to mum of 200,000 shorttons of chalcopyrite,bornitc, producegeologic plans at levels980, 1000, and 1020. andchalcocite ore with anaverage grade of about8.4 From the drill cores, 177 polishedsections were NUMBERONE OREBODY, RUBY CREEK DEPOSIT 1677 prepared.These sections were observedmicroscop- weatheringdolostone and less abundant dark gray, icallyin reflectedand transmitted light; minerals and fenestral, fossiliferousdolostone. These resemble textures were identified and recorded and the pro- Hitzman's(1983, 1986)hydrothermal and diagenetic portionsof the sulfideminerals were estimated.Ap- dolostones(A andB), respectively.The lightgray do- proximately20 polishedsections were examinedon lostoneis cutby numeroussparry dolomite veins that a CambridgeStereoscan scanning electron micro- terminateat the edgesof clasts(Fig. 3). Most clasts scope(SEM) equippedwith an energydispersive X- rangefrom 3 to 10 cm across,with clastslarger than ray elementalanalyzer at the U.S. GeologicalSurvey 50 cm acrossconstituting 18 percentof the mapped in Menlo Park, California. The latter work assistedin area. Calculationsshow that in any linear measure mineral identificationand in determiningthe distri- throughthe breccia,such as a diamonddrill core, bution of elementswithin mineral grains.Approxi- over50 percentof the sample would likely be in clasts mately15 polishedsections were analyzedon anARL- 1 to 3.3 m across. SEMQ electronmicroprobe at the U.S. Geological The matrix of the brecciaat Berg Camp is partly Surveyin Menlo Park; the operatingconditions and weathered,making its detailedcomposition difficult standardsare givenin Tables2 and3, below.Powder to determine.In the northwestpart of the exposure, X-ray diffractionwas used to identifyseveral minerals. the matrixis composedof fine-grainedto sparrydo- Semiquantitative emission spectroscopy was per- lomite that shows little contrast with the dolostone formedby ChrisHeropoulos of the U.S. Geological clasts.Within this area, breccia clastsare locally sur- Surveyin MenloPark on severalhand-picked sulfide, roundedby areasof red-brownsoil that is probably carbonate,and anthraxolitesamples of about 50 mg derivedfrom the weatheringof pyritic,iron-rich do- each.Additional types of datawere collectedon ren- lomitic matrix material. A continuous band of this soil ierite fromthis deposit; these are presented by Bern- lies between the breccia and the adjacentphyllite. stein (1986b). To the southeastand south,pyrite is increasingly abundantin the matrix,giving the brecciaa darker Geology color(Fig. 4). Chalcopyriteand borniteare alsoin- Copperdeposits at RubyCreek lie within the Bor- creasinglyabundant in the matrixto the southeast. nite Carbonatesequence of Hitzman(1983), a 1,000- Somewhite sparrydolomite veins cut the matrixin m-thick unit of Middle Devonianage composedof places. marble,dolostone, and minor graphiticto calcareous A gamma-rayscintillometer was used to measure phyllites. These rocks were metamorphosedto radioactivityin the areaof Figure2, to searchfor the greenschistfacies during the Cretaceous,with the presenceof pitchblendeor other uraniumminerals marbleand phyllite being penetrativelydeformed. notedby RunnelIs(1969). Radiationlevels of three The dolostoneacted competently during deformation to ten timesthe backgroundlevel were foundto cor- and blocksof dolostoneup to severalhundreds of respondto the areasof red-brownsoil notedabove. metersin size are now enclosedin marble and phyl- No correlationwas foundbetween radioactivityand lite. The origin of brecciain
Recommended publications
  • PHASE CHANGES in Cu 2 S AS a FUNCTION of TEMPERATURE 1. PREVIOUS WORK
    National Bureau of Standards Special Publication 364, Solid State Chemistry, Proceedings of 5th Materials Research Symposium, issued July 1972. PHASE CHANGES IN cu2s AS A FUNCTION OF TEMPERATURE William R. Cook, Jr. Gould Inc., Gould Laboratories Cleveland, Ohio 44108 and Case Western Reserve University Cleveland, Ohio 44106 The high-'copper phase boundary of Cu2s deviates from stoichiometry above 300 °C, first becoming copper deficient, then above - 1075 °C becoming copper rich. The maximum copper content occurs at the monotectic temperature of 1104 °C. The strong effect of oxygen on the hexagonal-cubic transition in Cu2S was confirmed; the transition was also found to be sensi­ tive to the type of pretreatment of the material. The high temperature tetragonal "Cu1 96s" phase is stable between Cu1.95S and Cu2s, at temperatures of - 90° to - 140 °C. The tr~nsi­ tion to the tetragonal phase is extremely sluggish. The true composition of djurleite has been shown to be approximately Cu1.93S. The phases near the chalcocite-digenite region of the diagram may be grouped into those with hexagonal close packing of sulfur atoms and those with cubic close packing of sulfurs. This is important in understanding rates of transformation among the various phases that occur in this area of the diagram. Key words: Chalcocite; cu2s; digenite; djurleite; nonstoichiometry; phase relations. 1. PREVIOUS WORK Fairly thorough explorations of the Cu-s phase diagram between cu2s and cu1• ,shave been made by a number of previous workers [1-8] 1 The resulting diagram may be seen in figure 1 taken largely from Roseboom [7] and Riu [8].
    [Show full text]
  • SAMPLING for COBALT at BORNITE, ALASKA Ry Jeffrey Y
    SAMPLING FOR COBALT AT BORNITE, ALASKA Ry Jeffrey Y. Foley %*9 * * * * * * * * * * * * * * * * * * * * * Field Report - January, l9R 11. S. nEPARTMENT OF THE INTERIOR James S. Watt, Secretary BuREAuA OF MINES TARLE OF CONTENTS Page Introduction ................................................ Economic Geoloqy............................................ Work by the Bureau.......................................... Recommendations............................................. References ................................................. SAMDLING FOR cnRALT AT RORNITE, ALASKA By Jeffrey Y. Foley 1 INTRODIICTION Carrollite (CuCo2S4), an ore mineral of cobalt, is known to occur in the Ruby Creek Cu-Zn deposit at Bornite (fig. 1), in northwest Alaska (5, q). 2 The events leading to mineralization of dolomite and argillite units and the distribution of these rocks in the Bornite district are among the topics covered in a PhD discertation by M. W. Hitzman of Stan- ford University (in progress). Hitzman has identified carkollite and cobaltiferous pyrite at numerous intersections in diamond drill core belonging to Rear Creek Mining Corporation, the present operator of the property. A brief visit to collect bulk samples was made by a Bureau geologist in July, 19R1, as part of the Alaska Critical Metals program. ECONOMIC GEOLOGY Hitzman summarizes the distribution of cobalt as occurring: 1) "...as late cobaltiferous pyrite rims on earlier formed pyrite grains in pyritiferous, ferroan dolo- mite with disseminated sphalerite and massive siderite" 2) "...as carrollite in high-grade hornite, chalcocite, chalcopyrite, and sphalerite ore at higher levels in the deposit." 1 Geologist, U.S. Rureau of Mines, Alaska Field Operations Center, Fairbanks. 2 Underlined numbers in parentheses refer to items in the list of references at the end oF this report. ; - > . ; - .>;. -1,; g n/ /- ; > @ ! - xi #."R-: 3 2 vl- t 7:'i "^.
    [Show full text]
  • DESCRIPTIVE MODEL of KIPUSHI Cu-Pb-Zn
    Model 32c DESCRIPTIVE MODEL OF KIPUSHI Cu-Pb-Zn By Dennis P. Cox and Lawrence R. Bernstein DESCRIPTION Massive base-metal sulfides and As-sulfosalts in dolomite breccias characterized by minor Co, Ge, Ga, U, and V. GEOLOGICAL ENVIRONMENT Rock Types Dolomite, shale. No rocks of unequivocal igneous origin are related to ore formation. [The pseudoaplite at Tsumeb is herein assumed to be a metasedimentary rock following H. D. LeRoex (1955, unpublished report).] Textures Fine-grained massive and carbonaceous, laminated, stromatolitic dolomites. Age Range Unknown; host rocks are Proterozoic in Africa, Devonian in Alaska, Pennsylvanian in Utah. Depositional Environment High fluid flow along tabular or pipe-like fault- or karst (?)-breccia zones. Tectonic Setting(s) Continental platform or shelf terrane with continental or passive margin rifting. Ore formation at Tsumeb and Ruby Creek predates folding. Associated Deposit Types Sedimentary copper, U-veins, barite veins. Sedimentary exhalative Pb-Zn may be a lateral facies. DEPOSIT DESCRIPTION Mineralogy Ruby Creek: pyrite, bornite, chalcocite, chalcopyrite, carrollite, sphalerite, tennantite. Tsumeb: galena, sphalerite, bornite, tennantite, enargite. Kipushi: sphalerite, bornite, chalcopyrite, carrollite, chalcocite, tennantite, pyrite. Less abundant minerals in these deposits are linnaeite, Co-pyrite, germanite, renierite, gallite, tungstenite, molybdenite, and native Bi. Bituminous matter in vugs. At Apex mine, marcasite. Texture/Structure Massive replacement, breccia filling, or stockwork. Replacement textures of pyrite after marcasite at Ruby Creek and Apex. Alteration Dolomitization, sideritization, and silicification may be related to mineralization. Early pyrite or arsenopyrite as breccia filling or dissemination. Ore Controls Abundant diagenetic pyrite or other source of S acts as precipitant of base metals in zones of high porosity and fluid flow.
    [Show full text]
  • Indium-Bearing Paragenesis from the Nueva Esperanza and Restauradora Veins, Capillitas Mine, Argentina
    Journal of Geosciences, 65 (2020), 97–109 DOI: 10.3190/jgeosci.304 Original paper Indium-bearing paragenesis from the Nueva Esperanza and Restauradora veins, Capillitas mine, Argentina María Florencia MÁRQUEZ-ZAVALÍA1,2*, Anna VYMAZALOVÁ3, Miguel Ángel GALLISKI1, Yasushi WATANABE4, Hiroyasu MURAKAMI5 1 IANIGLA, CCT-Mendoza (CONICET), Avda. A. Ruiz Leal s/n, Parque San Martin, CC330, (5500) Mendoza, Argentina; [email protected] 2 Mineralogía y Petrología, FAD, Universidad Nacional de Cuyo, Centro Universitario (5502) Mendoza, Argentina 3 Department of Rock Geochemistry, Czech Geological Survey, Geologická 6, 152 00 Prague 5, Czech Republic 4 Faculty of International Resource Sciences, Mining Museum of Akita University, 28-2 Osawa, Tegata, Akita, 010-8502 Japan 5 Coal Business Planning Group, Coal Business Office, Resources & Power Company, JXTG Nippon Oil & Energy Corporation, 1-2, Otemachi 1-chome, Chiyoda-ku, Tokyo 100-8162 Japan * Corresponding author The Nueva Esperanza and Restauradora are two of the twenty-three veins described at Capillitas mine, an epithermal precious- and base-metal vein deposit located in northern Argentina. Capillitas is genetically linked to other minera- lizations of the Farallón Negro Volcanic Complex, which hosts several deposits. These include two world-class (La Alumbrera and Agua Rica) and some smaller (e.g., Bajo El Durazno) porphyry deposits, and a few epithermal deposits (Farallón Negro, Alto de la Blenda, Cerro Atajo and Capillitas). The main hypogene minerals found at these two ve- ins include pyrite, sphalerite, galena, chalcopyrite, tennantite-(Zn) and tennantite-(Fe). Accessory minerals comprise hübnerite, gold, silver, stannite, stannoidite and mawsonite, and also diverse indium- and tellurium-bearing minerals.
    [Show full text]
  • Supergene Mineralisation of the Boyongan Porphyry Copper-Gold Deposit, Surigao Del Norte, Philippines
    Supergene Mineralisation of the Boyongan Porphyry Copper-Gold Deposit, Surigao del Norte, Philippines by Allan Maglaya Ignacio B.Sc. Geology, National Institute of Geological Sciences University of the Philippines Thesis submitted in partial fulfilment of the requirements of the Masters of Economic Geology Degree Centre for Ore Deposit Research, University of Tasmania December, 2005 DECLARATION OF ORIGINALITY This thesis contains no material which has been accepted for a degree of diploma by the University of Tasmania or any other institution, except by way of background information and duly acknowledged in the thesis, and contains no previous material previously pub- lished or written by another person except where due acknowledgement is given. Allan Maglaya Ignacio 01 December 2005 _________________________ STATEMENT OF AUTHORITY OF ACCESS This thesis may not to be made available for loan or copying for 1.5 years following the date this statement was signed. Following that time, the thesis may be available for loan and lim- ited copying in accordance with Copyright Act 1968. Allan Maglaya Ignacio 01 December 2005 _________________________ TABLE OF CONTENTS Page (s) LIST OF FIGURES …………………………………………………….. i - iii LIST OF APPENDICES ………………………………………………… iv ACKNOWLEDGMENTS ………………………………………………. v ABSTRACT ……………………………………………………………... vi - vii 1.0 INTRODUCTION ………………………………………………………. 1 - 8 1.1 Introduction …………………………………………………………. 1 1.2 Aims and Objectives ……………………………………………….. 1 1.3 Methods Employed …………………………………………………. 2 1.4 Location and Accessibility …………………………………………. 3 1.5 Climate ……………………………………………………………... 5 1.6 Previous Work ……………………………………………………… 5 2.0 GEOLOGICAL SETTING ………………………………………………. 9 - 37 2.1 Introduction ………………………………………………………. 9 2.2 Regional Tectonics …………….…………………………………. 9 2.3 Regional and Local Stratigraphy ………………………………... 11 2.3.1 Basement (Cretaceous-Paleogene) ………………………. 11 2.3.2 Bacuag Formation (Oliogocene-Miocene) .……………..
    [Show full text]
  • Cobalt Mineral Ecology
    American Mineralogist, Volume 102, pages 108–116, 2017 Cobalt mineral ecology ROBERT M. HAZEN1,*, GRETHE HYSTAD2, JOSHUA J. GOLDEN3, DANIEL R. HUMMER1, CHAO LIU1, ROBERT T. DOWNS3, SHAUNNA M. MORRISON3, JOLYON RALPH4, AND EDWARD S. GREW5 1Geophysical Laboratory, Carnegie Institution, 5251 Broad Branch Road NW, Washington, D.C. 20015, U.S.A. 2Department of Mathematics, Computer Science, and Statistics, Purdue University Northwest, Hammond, Indiana 46323, U.S.A. 3Department of Geosciences, University of Arizona, 1040 East 4th Street, Tucson, Arizona 85721-0077, U.S.A. 4Mindat.org, 128 Mullards Close, Mitcham, Surrey CR4 4FD, U.K. 5School of Earth and Climate Sciences, University of Maine, Orono, Maine 04469, U.S.A. ABSTRACT Minerals containing cobalt as an essential element display systematic trends in their diversity and distribution. We employ data for 66 approved Co mineral species (as tabulated by the official mineral list of the International Mineralogical Association, http://rruff.info/ima, as of 1 March 2016), represent- ing 3554 mineral species-locality pairs (www.mindat.org and other sources, as of 1 March 2016). We find that cobalt-containing mineral species, for which 20% are known at only one locality and more than half are known from five or fewer localities, conform to a Large Number of Rare Events (LNRE) distribution. Our model predicts that at least 81 Co minerals exist in Earth’s crust today, indicating that at least 15 species have yet to be discovered—a minimum estimate because it assumes that new minerals will be found only using the same methods as in the past. Numerous additional cobalt miner- als likely await discovery using micro-analytical methods.
    [Show full text]
  • Cobalt—For Strength and Color
    USGS Mineral Resources Program Cobalt—For Strength and Color Cobalt is a shiny, gray, brittle metal that is best known for creating an intense blue color in glass As part of a broad mission to and paints. It is frequently used in the manufacture of rechargeable batteries and to create alloys that conduct research and provide maintain their strength at high temperatures. It is also one of the essential trace elements (or “micro­ information on nonfuel mineral nutrients”) that humans and many other living creatures require for good health. Cobalt is an important resources, the U.S. Geological component in many aerospace, defense, and medical applications and is a key element in many clean Survey (USGS) supports science energy technologies. to understand The name cobalt comes from the German word kobold, meaning goblin. It was given this name by medieval miners who believed that troublesome goblins replaced the valuable metals in their ore with • How and where cobalt a substance that emitted poisonous fumes when smelted. The Swedish chemist Georg Brandt isolated resources form and metallic cobalt—the first new metal to be discovered since ancient times—in about 1735 and identified concentrate in the some of its valuable properties. Earth’s crust • How cobalt resources How Do We Use Cobalt? interact with the environment to affect human and Cobalt has been used to create vivid blue colors ecosystem health in glass and ceramics for thousands of years and it is still an important pigment. Many other uses for • Trends in the supply of cobalt have been developed during the past century.
    [Show full text]
  • MENDELSOHN (F.), Editor. the Geology of the Northern Rhodesian Copper- Belt
    996 BOOK REVIEWS instance 'pits', ' anisotropy', ' cellular texture', ' native iron', are fol- lowed by a 'text-card' with a more detailed description of the sections concerned in English and German. The price is DM 0.75 per photo-card, DM 0.45 per text-card. These prices are reduced by 10% for University departments and academic staff, by 15% for students. The great value of this unique publication is self-evident and does not need further appraisal. Ore-microscopists will welcome the card index as a high-quality source of reference, and university staff will find it a great help in teaching. Economic geologists and nfineralogists will appreciate the straightforward and clear approach, which provides an excellent introduction for research workers less well acquainted with the subject matter. Ore dressing workers and metallurgists will be able to Use the card index for the solution of their problems without having to go into details of ore mineralogy. The authors should be warmly con- gratulated on this first part of a very fine piece of work. A. F. H. MENDELSOHN (F.), editor. The Geology of the Northern Rhodesian Copper- belt. London (Macdonald & Co. Ltd.), 1961, xvi+523 pp., 185 figs. Price 8r Twenty-three authors have contributed to this comprehensive volume. Part 1 provides a general account of the physiography, stratigraphy, structure, metamorphism, and ore deposits of the Copperbelt together with a history of mineral exploration and an account of the methods employed. Part 2 gives detailed descriptions of the individual deposits. In addition to synthesizing the considerable volume of published work on the subject the authors draw extensively on material from unpublished company reports.
    [Show full text]
  • Article Benefited from Construc- Ering the Co Dominance Among the Non-Cu Metal Atoms, Tive Reviews by Jochen Schlüter and Taras Panikorovskii
    Eur. J. Mineral., 32, 637–644, 2020 https://doi.org/10.5194/ejm-32-637-2020 © Author(s) 2020. This work is distributed under the Creative Commons Attribution 4.0 License. Gobelinite, the Co analogue of ktenasite from Cap Garonne, France, and Eisenzecher Zug, Germany Stuart J. Mills1, Uwe Kolitsch2,3, Georges Favreau4, William D. Birch1, Valérie Galea-Clolus5, and Johannes Markus Henrich6 1Geosciences, Museums Victoria, GPO Box 666, Melbourne, Victoria 3001, Australia 2Mineralogisch-Petrographische Abt., Naturhistorisches Museum, Burgring 7, 1010 Vienna, Austria 3Institut für Mineralogie und Kristallographie, Universität Wien, Althanstraße 14, 1090 Vienna, Austria 4independent researcher: 421 Avenue Jean Monnet, 13090 Aix-en-Provence, France 5independent researcher: 10 rue Combe Noire, 83210 Solliès-Toucas, France 6independent researcher: Im Großen Garten 3, 57548 Kirchen (Sieg), Germany Correspondence: Stuart J. Mills ([email protected]) Received: 13 April 2020 – Revised: 30 October 2020 – Accepted: 9 November 2020 – Published: 25 November 2020 Abstract. The new mineral gobelinite, ideally CoCu4.SO4/2.OH/6 6H2O, is a new member of the ktenasite group and the Co analogue of ktenasite, ZnCu4.SO4/2.OH/6 6H2O.q It occurs at Cap Garonne (CG), Var, France (type locality), and Eisenzecher Zug (EZ), Siegerland, Northq Rhine-Westphalia, Germany (cotype lo- cality). The mineral forms pale green, bluish green or greyish green, blocky to thin, lath-like crystals. They are transparent and non-fluorescent, with a vitreous, sometimes also pearly, lustre and a white streak having a pale-green cast. Mohs hardness is about 2.5. The crystals are brittle with an irregular fracture; no cleav- age was observed.
    [Show full text]
  • Silver-Rich Central Idaho
    Silver-rich Disseminated Sulfides From a Tungsten-bearing Quartz Lode Big Creek District Central Idaho GEOLOGICAL SURVEY PROFESSIONAL PAPER 594-C Silver-rich Disseminated Sulfides From a Tungsten-bearing Quartz Lode Big Creek District Central Idaho By B. F. LEONARD, CYNTHIA W. MEAD, and NANCY CONKLIN SHORTER CONTRIBUTIONS TO GENERAL GEOLOGY GEOLOGICAL SURVEY PROFESSIONAL PAPER 594-C Study of a low-grade tungsten deposit whose associated suljide minerals, extracted as waste, are rich in silver and contain some gold UNITED STATES GOVERNMENT PRINTING OFFICE, WASHINGTON : 1968 UNITED STATES DEPARTMENT OF THE INTERIOR STEWART L. UDALL, Secretary GEOLOGICAL SURVEY William T. Pecora, Director For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.C. 20402 - Price 35 cents (paper cover) CONTENTS Page Page Abstract __________________________________________ _ C1 Mineralogy and paragenetic sequence-Continued Introduction ______________________________________ _ 1 Alteration products ____________________________ _ C15 Location and operation _____________________________ _ 4 Paragenetic sequence ___________________________ _ 16 Geology __________________________________________ _ 4 Geologic thermometry __________________________ _ 18 Ore deposit _______________________________________ _ 5 Classification and origin of hypogene mineralization ____ _ 19 Mineralogy and paragenetic sequence ________________ _ 6 Oxidation and enrichment ___ ------------------------ 20 Typical ore ___________________________________ _ 6 Economic considerations ____________________________ _ 21 Gangue indicated by mill products _______________ _ 7 Acknowledgments ___________________ .:. ______________ _ 23 Tungsten minerals _______ ,______________________ _ 8 References ________________________________________ _ 23 Sulfides and related minerals ____________________ _ 8 ILLUSTRATIONS [Plates follow page C24f - PLATE 1. Drawing and X-ray micrographs of acanthite and copper sulfides on galena. 2. Drawing and X-ray micrographs of electrum in pyrite. 3.
    [Show full text]
  • Unusual Mineral Diversity in a Hydrothermal Vein-Type Deposit: the Clara Mine, Sw Germany, As a Type Example
    427 The Canadian Mineralogist Vol. 57, pp. 427-456 (2019) DOI: 10.3749/canmin.1900003 UNUSUAL MINERAL DIVERSITY IN A HYDROTHERMAL VEIN-TYPE DEPOSIT: THE CLARA MINE, SW GERMANY, AS A TYPE EXAMPLE § GREGOR MARKL Universitat¨ Tubingen,¨ Fachbereich Geowissenschaften, Wilhelmstraße 56, D-72074 Tubingen,¨ Germany MAXIMILIAN F. KEIM Technische Universitat¨ Munchen,¨ Munich School of Engineering, Lichtenbergstraße 4a, 85748 Garching, Germany RICHARD BAYERL Ludwigstrasse 8, 70176 Stuttgart, Germany ABSTRACT The Clara baryte-fluorite-(Ag-Cu) mine exploits a polyphase, mainly Jurassic to Cretaceous, hydrothermal unconformity vein-type deposit in the Schwarzwald, SW Germany. It is the type locality for 13 minerals, and more than 400 different mineral species have been described from this occurrence, making it one of the top five localities for mineral diversity on Earth. The unusual mineral diversity is mainly related to the large number and diversity of secondary, supergene, and low- temperature hydrothermal phases formed from nine different primary ore-gangue associations observed over the last 40 years; these are: chert/quartz-hematite-pyrite-ferberite-scheelite with secondary W-bearing phases; fluorite-arsenide-selenide-uraninite- pyrite with secondary selenides and U-bearing phases (arsenates, oxides, vanadates, sulfates, and others); fluorite-sellaite with secondary Sr- and Mg-bearing phases; baryte-tennantite/tetrahedrite ss-chalcopyrite with secondary Cu arsenates, carbonates, and sulfates; baryte-tennantite/tetrahedrite ss-polybasite/pearceite-chalcopyrite, occasionally accompanied by Ag6Bi6Pb-bearing sulfides with secondary Sb oxides, Cu arsenates, carbonates, and sulfates; baryte-chalcopyrite with secondary Fe- and Cu- phosphates; baryte-pyrite-marcasite-chalcopyrite with secondary Fe- and Cu-sulfates; quartz-galena-gersdorffite-matildite with secondary Pb-, Bi-, Co-, and Ni-bearing phases; and siderite-dolomite-calcite-gypsum/anhydrite-quartz associations.
    [Show full text]
  • Sediment-Hosted Copper Deposits of the World: Deposit Models and Database
    Sediment-Hosted Copper Deposits of the World: Deposit Models and Database By Dennis P. Cox1, David A. Lindsey2 Donald A. Singer1, Barry C. Moring1, and Michael F. Diggles1 Including: Descriptive Model of Sediment-Hosted Cu 30b.1 by Dennis P. Cox1 Grade and Tonnage Model of Sediment-Hosted Cu by Dennis P. Cox1 and Donald A. Singer1 Descriptive Model of Reduced-Facies Cu 30b.2 By Dennis P. Cox1 Grade and Tonnage Model of Reduced Facies Cu by Dennis P. Cox1 and Donald A. Singer1 Descriptive Model of Redbed Cu 30b.3, by David A. Lindsey2 and Dennis P. Cox1 Grade and Tonnage Model of Redbed Cu by Dennis P. Cox1 and Donald A. Singer1 Descriptive Model of Revett Cu 30b.4, by Dennis P. Cox1 Grade and Tonnage Model of Revett Cu by Dennis P. Cox1 and Donald A. Singer1 Open-File Report 03-107 Version 1.3 2003, revised 2007 Available online at http://pubs.usgs.gov/of/2003/of03-107/ Any use of trade, product or firm names is for descriptive purposes only and does not imply endorsement by the U.S. Government. U.S. DEPARTMENT OF THE INTERIOR U.S. GEOLOGICAL SURVEY 1 345 Middlefield Road, Menlo Park, CA 94025 2 Box 25046, Denver Federal Center, Denver, CO 80225 Introduction This publication contains four descriptive models and four grade-tonnage models for sediment hosted copper deposits. Descriptive models are useful in exploration planning and resource assessment because they enable the user to identify deposits in the field and to identify areas on geologic and geophysical maps where deposits could occur.
    [Show full text]