Electrical and Dielectric Properties of Uncoated and Coated Wood-Free Paper for Electrophotography
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Petri Sirviö | Electrical and Dielectric Properties of Uncoated and Coated Wood-Free Paper for Electrophotography | 2016 Electrophotography for Paper SirviöWood-Free Petri | Electrical and Dielectric and Coated of Uncoated Properties Petri Sirviö Electrical and Dielectric Properties of Uncoated and Coated Wood-Free Paper for Electrophotography 9 789521 234163 ISBN 978-952-12-3416-3 Electrical and Dielectric Properties of Uncoated and Coated Wood-Free Paper for Electrophotography Petri Sirviö Laboratory of Physical Chemistry Faculty of Science and Engineering Åbo Akademi University Åbo, Finland 2016 Supervised by Professor Jouko Peltonen, Professor Emeritus Jarl B. Rosenholm and Adjunct Professor Kaj Backfolk Laboratory of Physical Chemistry, Åbo Akademi University, Turku, Finland Reviewed by Professor Øyvind W. Gregersen Department of Chemical Engineering, Norwegian University of Science and Technology, Trondheim, Norway and Professor Arved C. Hübler Institute of Print and Media Technology, Chemnitz University of Technology, Chemnitz, Germany Dissertation opponent Professor Øyvind W. Gregersen Department of Chemical Engineering, Norwegian University of Science and Technology, Trondheim, Norway ISBN 978-952-12-3416-3 Painosalama Oy – Turku, Finland 2016 PREFACE The research summarized in this thesis has been conducted as a part of the research programs of Stora Enso Oyj to develop paper and board substrates for the electrophotographic printing processes in partnerships with several universities. The main part of the summarized research work has been done in Stora Enso’s R&D facilities and in cooperation with Åbo Akademi University and Vilnius University. I would like to thank the personnel involved in these institutions for their advice, expertise, and knowledge. In particular, I would like to thank professors Jarl B. Rosenholm and Jouko Peltonen from Åbo Akademi University, professor Kaj Backfolk from Lappeenranta University, and professors Jonas Sidaravicius and Robertas Maldzius from Vilnius University. The level of knowledge and experience accumulated into this group is indeed convincing and I am proud to have had the opportunity to work in such teams during the scientific part of my career. I would also like to thank all the authors and co- authors in the publications included in this thesis as well as those in the supporting publications. I am grateful for all the interesting work we have done, for all the interesting discussions, and for all that we have learned. Stora Enso Oyj is acknowledged for its vision of exploring new areas. The Finnish Funding Agency for Innovation TEKES is acknowledged for the financial support for this research. Finally, I would like to thank my wife Leena for her crucial support, which has made everything possible. I wish to dedicate this work to her. 3 CONTENTS ABSTRACT.............................................. ........................................................................................... 6 SVENSK SAMMANFATTNING ....................................................................................................... 7 LIST OF PUBLICATIONS ................................................................................................................. 8 SUPPORTING PUBLICATIONS ....................................................................................................... 9 1. INTRODUCTION ...................................................................................................................... 11 2. OBJECTIVES ............................................................................................................................. 12 3. LITERATURE REVIEW ........................................................................................................... 12 3.1 Effect of substrate topography on toner transfer ...................................................................... 12 3.2 Electrical resistivity and dielectric properties of paper and the effect of electric field on electrical resistivity......................................................................................................................... 13 3.3 Charging and charge decay of paper ........................................................................................ 15 3.4 Effect of coating ....................................................................................................................... 16 4. EXPERIMENTAL ...................................................................................................................... 17 4.1 Materials ................................................................................................................................... 17 4.1.1 Paper samples and coating formulations for determining the effect of roughness on toner transfer ........................................................................................................................................ 17 4.1.2 Paper samples for resistivity, charging, charge decay, and dielectric measurements ....... 18 4.2 Methods .................................................................................................................................... 19 4.2.1 Measurement of paper topography, roughness, print quality, and toner transfer .............. 19 4.2.2 Measurement of paper resistivity....................................................................................... 20 4.2.3 Measurement of charge acceptance and charge decay of paper ........................................ 20 4.2.4 Measurement of dielectric properties of paper .................................................................. 21 5. RESULTS AND DISCUSSION ................................................................................................. 22 5.1 Effects of substrate topography and moisture content on electrophotographic toner transfer . 22 5.2 Electrical resistivity/conductivity of paper............................................................................... 26 5.2.1 Dependency on electric field ............................................................................................. 26 5.2.2 Effect of NaCl and moisture content ................................................................................. 29 5.2.3 Effect of temperature ......................................................................................................... 31 5.2.4 Effects of coat weight and base paper on conductivity ..................................................... 33 5.3 Dielectric properties of paper ................................................................................................... 35 5.3.1 Influence of moisture and ion contents .............................................................................. 35 5.3.2 Influence of temperature .................................................................................................... 38 4 5.3.3 Influence of coating ........................................................................................................... 41 5.4 Charging and charge decay of paper ........................................................................................ 42 5.4.1 Charge acceptance ............................................................................................................. 42 5.4.2 Charge decay ..................................................................................................................... 43 5.4.3 Temperature vs. charging and charge decay ...................................................................... 45 6. CONCLUSIONS ........................................................................................................................ 48 7. REFERENCES ........................................................................................................................... 50 Publications I - VI 5 ABSTRACT The print substrate influences the print result in dry toner electrophotography, which is a widely used digital printing method. The influence of the substrate can be seen more easily in color printing, as that is a more complex process compared to monochrome printing. However, the print quality is also affected by the print substrate in grayscale printing. It is thus in the interests of both substrate producers and printing equipment manufacturers to understand the substrate properties that influence the quality of printed images in more detail. In dry toner electrophotography, the image is printed by transferring charged toner particles to the print substrate in the toner transfer nip, utilizing an electric field, in addition to the forces linked to the contact between toner particles and substrate in the nip. The toner transfer and the resulting image quality are thus influenced by the surface texture and the electrical and dielectric properties of the print substrate. In the investigation of the electrical and dielectric properties of the papers and the effects of substrate roughness, in addition to commercial papers, controlled sample sets were made on pilot paper machines and coating machines to exclude uncontrolled variables from the experiments. The electrical and dielectric properties of the papers investigated were electrical resistivity and conductivity, charge acceptance, charge decay, and the dielectric permittivity and losses at different frequencies, including the effect of temperature. The objective was to gain an understanding of how the electrical and dielectric properties are affected by normal variables in papermaking,