Replacement Technologies

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Replacement Technologies Working Group 2: Replacement Technologies Who we are & what we do IAEG Working Group 2, Replacement Technologies, works hard to ensure future alternatives in light of current or upcoming substance bans and limits rising out of environmental laws. Projects are suggested by member companies based on need, and if it has enough supporters, a data sharing collaboration activity is performed under a collaboration agreement in order to explore what project member companies use it for, and if they have any alternatives identified. This sharing of data better benefits member companies, and as a result the industry, allowing use of this information without needing to duplicate exploration studies performed by other members. If no viable alternatives are identified, then a technical exchange project can evolve into a research and development project. Through joint contribution of participating members, research is completed identifying affected components and required uses, and alternatives meeting industry requirements are then explored and tested. Current active projects include: cadmium replacement on industry standard parts, hard chrome plating, bond primers, corrosion inhibiting epoxy primers, chemical conversion coating, and anodize seal. Below we’ll explore a little of what some of the project’s aims are, and their most recent progress. Active Projects Cadmium Plating Objective: Demonstrate the availability of alternatives to cadmium plated industry standard parts to suppliers and users. Level: Research and development. Recent update: The team is currently engaging with standard bodies for the Aerospace industry that are responsible for design of relevant parts and suppliers of standard parts to understand what work has been done to date in this area. Hard Chrome Plating Objective: To produce hard chrome plating (HCP), chromic acid is used in the plating process, which is carcinogenic and heavily regulated by different regulations in countries worldwide. This projects investigates replacements to HCP which are not using hexavalent chromium. Level: Technology Exchange. Recent update: In the first part we focused on these existing technologies and put together the available data from all project members to come to a mapping where which replacement technology could be used. The report on this part is in work and should be available soon to the project members. In the second part we are looking for upcoming technologies (not yet industrialized) which are more close to a one-to-one replacement or show significant other advantages (e.g. less health and safety concerns, less cost). For this second part we have started the data collection. Corrosion inhibiting epoxy primers Objective: Joint approach to facilitate the identification of suitable alternatives to Chromate based corrosion inhibiting epoxy primers. These primers must protect metallic substrates against oxidation and/or galvanic corrosion under a wide range of operating and environmental and climatic exposure conditions. Due to chromates’ unique leaching and healing abilities, the industry has been struggling to find equivalent replacements with similar or superior corrosion inhibiting properties. This project seeks to map identified applications and their key requirements and develop a description of potential alternatives. Level: Technology Exchange. Recent update: Current ongoing tasks include collection of data for requirements gap analysis, of replacement candidate coating information, and of data from vendors. Chemical Conversion Coating Objective: To share participants' performance tests results of non-chromated Chemical Conversion Coating solutions available on the market. Level: Technology Exchange. Recent update: The best practices for the application process of the best performing products were shared, not only within the participants, but also with the manufacturers of those products. This way all the participants could benefit from very good technical exchange sessions, during which they could have some interesting discussions with the suppliers' technical staff. Each participating company now has more information to make their choice for a non-chromated Chemical Conversion Coating solution. Bond Primers Objective: Bond primer contain chromates for corrosion protection. At present, there are a number of alternatives but no direct replacement available. This project aims to find a suitable substitute given a number of considerations. Level: Technology Exchange. Recent update: Data is being aggregated on key applications and requirements, and candidates for replacements and their status. Anodize Seal Project Objective: Chromate applications in aerospace industry need replacement by environmentally- compliant alternatives. Joint approach to facilitate the identification of suitable alternatives to chromated Anodize Seals is needed. Anodize Seals are used to enhance corrosion protection while not affecting paint and sealant adhesion properties. This project will consist of a performance screening exercise of non-hex-chrome sealing solutions used for anodized aluminum, with and without paint coatings (chromated and non-chromated), either developed by the project members or proposed by the major suppliers identified by the project members. Level: Technology Exchange. Recent update: The Anodize Seal Project held their first meeting in July, and will begin discussing process requirements during their subsequent meetings. Thanks for reading! To follow future WG2 updates, watch out for updates in this newsletter, or further press releases or publications from our projects. For more information, contact WG2 Lead Jennifer Branton, at [email protected]. .
Recommended publications
  • Methods to Improve the Corrosion Performance of Microporous Nickel Deposits
    Methods to Improve The Corrosion Performance Of Microporous Nickel Deposits By Robert A. Tremmel During the last several years, nickel, which is essentially sulfur- microporous nickel-chromium free, plus a thinner layer of bright coatings have been critically nickel. Duplex nickel provides scrutinized by the automotive corrosion protection that is far industry. Today these coatings must superior to single layer systems. In be free of all surface defects, even these duplex systems, when corrosion after long-term exposure to acceler- occurs through a pore in the chro- ated tests and in real-life service. mium plate, the bright nickel is While proper control of all the rapidly penetrated until the semi- multi-layer nickel deposits is bright nickel is reached. Because the important, blemish-free surfaces electrochemical potential of the semi- Fig. 1—Corrosion mechanism of decorative nickel- can only be obtained when the chromium deposits. bright deposit is greater than that of microdiscontinuity and the activity the bright nickel deposit, thereby of the post-nickel strike are prop- making it more noble, the bright erly achieved and maintained. This also be free of surface defects1. nickel layer will corrode preferen- edited version of a paper presented Simply meeting porosity specifica- tially to the semi-bright nickel layer. at SUR/FIN® ’96—Cleveland shows tions is not enough. The size of the As the pit widens, however, some that research indicates that the pores is important, as well as the attack will eventually occur in the most important factor is the electrochemical potential of the semi-bright nickel layer and ulti- electrochemical potential of the microporous nickel strike.
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  • Analysis of Hard Chromium Coating Defects and Its Prevention Methods
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  • Plating on Aluminum
    JJW o NBSiR 80-2142 (Aluminum Association) on Aluminum AUG 5 1981 D. S. Lashmore Corrosion and Electrodeposition Group Chemical Stability and Corrosion Division National Measurement Laboratory U.S. Department of Commence National Bureau of Standards Washington, DC 20234 November 1980 Final Report Prepared for The Aiuminum Association The American Electropiaters Society 818 Connecticut Avenue, N.W. 1201 Louisiana Ave. Washington, DC 20006 Winter Park, FL 32789 NBSIR 80-2142 (Aluminum Association) PLATING ON ALUMINUM D. S. Lashmore Corrosion and Electrodeposition Group Chemical Stability and Corrosion Division National Measurement Laboratory U.S. Department of Commerce National Bureau of Standards Washington, DC 20234 November 1980 Final Report Prepared for The Aluminum Association The American Electroplaters Society 818 Connecticut Avenue, N.W. 1201 Louisiana Ave. Washington, DC 20006 Winter Park, FL 32789 U.S. DEPARTMENT OF COMMERCE, Philip M. Klutznick, Secretary Jordan J. Baruch, Assistant Secretary for Productivity, Technoiogy, and Innovation NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Director Table of Contents Page 1. Introduction 1 2. Program Summary 2 3. Phosphoric Acid Anodizing Prior to Plating 10 3.1. Adhesion Data 10 3.2. Microstructure of the Anodic Film 17 3.2.1. Microstructure of nickel plated onto the anodic 19 film 3.2.2. Initial Stages of Oxidation 25 3.3. Electrochemical Measurements 32 3.3.1. Current Density versus Applied Potential 32 3.3.2. Scanning Voltammetry 33 4. Immersion Deposition 37 4.1. Scanning Voltammetry 37 4.2. Dissolution Data 41 4.3. Discussion 44 5. Adhesion Theory 45 5.1. Adhesion of Metallic Coatings 45 5.2. Pre-existing Crack--Griffith Criterion 52 5.3.
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  • Electrodeposition of Nanocrystalline Cobalt Alloy Coatings As a Hard Chrome Alternative
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  • UK HITEA Project for Chromate Replacement.Pdf
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  • REACH Regulation: Replacement of Hard Chrome With
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  • An Evolution of Trivalent Chromate Technologies
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  • The Chrome Plating Industry PFAS TECHNICAL UPDATE
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  • Control Technology Assessment: Metal Plating and Cleaning Operations
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  • A Hybrid Predictive Approach for Chromium Layer Thickness in The
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  • Research on Chrome Plating of Steel Bars
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  • 19. the Galvanic (Electrochemical) Series
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