Perturbative Analysis of Two-Qubit Gates on Transmon Qubits
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An Introduction to Quantum Field Theory
AN INTRODUCTION TO QUANTUM FIELD THEORY By Dr M Dasgupta University of Manchester Lecture presented at the School for Experimental High Energy Physics Students Somerville College, Oxford, September 2009 - 1 - - 2 - Contents 0 Prologue....................................................................................................... 5 1 Introduction ................................................................................................ 6 1.1 Lagrangian formalism in classical mechanics......................................... 6 1.2 Quantum mechanics................................................................................... 8 1.3 The Schrödinger picture........................................................................... 10 1.4 The Heisenberg picture............................................................................ 11 1.5 The quantum mechanical harmonic oscillator ..................................... 12 Problems .............................................................................................................. 13 2 Classical Field Theory............................................................................. 14 2.1 From N-point mechanics to field theory ............................................... 14 2.2 Relativistic field theory ............................................................................ 15 2.3 Action for a scalar field ............................................................................ 15 2.4 Plane wave solution to the Klein-Gordon equation ........................... -
Unit 1 Old Quantum Theory
UNIT 1 OLD QUANTUM THEORY Structure Introduction Objectives li;,:overy of Sub-atomic Particles Earlier Atom Models Light as clectromagnetic Wave Failures of Classical Physics Black Body Radiation '1 Heat Capacity Variation Photoelectric Effect Atomic Spectra Planck's Quantum Theory, Black Body ~diation. and Heat Capacity Variation Einstein's Theory of Photoelectric Effect Bohr Atom Model Calculation of Radius of Orbits Energy of an Electron in an Orbit Atomic Spectra and Bohr's Theory Critical Analysis of Bohr's Theory Refinements in the Atomic Spectra The61-y Summary Terminal Questions Answers 1.1 INTRODUCTION The ideas of classical mechanics developed by Galileo, Kepler and Newton, when applied to atomic and molecular systems were found to be inadequate. Need was felt for a theory to describe, correlate and predict the behaviour of the sub-atomic particles. The quantum theory, proposed by Max Planck and applied by Einstein and Bohr to explain different aspects of behaviour of matter, is an important milestone in the formulation of the modern concept of atom. In this unit, we will study how black body radiation, heat capacity variation, photoelectric effect and atomic spectra of hydrogen can be explained on the basis of theories proposed by Max Planck, Einstein and Bohr. They based their theories on the postulate that all interactions between matter and radiation occur in terms of definite packets of energy, known as quanta. Their ideas, when extended further, led to the evolution of wave mechanics, which shows the dual nature of matter -
Quantum Theory of the Hydrogen Atom
Quantum Theory of the Hydrogen Atom Chemistry 35 Fall 2000 Balmer and the Hydrogen Spectrum n 1885: Johann Balmer, a Swiss schoolteacher, empirically deduced a formula which predicted the wavelengths of emission for Hydrogen: l (in Å) = 3645.6 x n2 for n = 3, 4, 5, 6 n2 -4 •Predicts the wavelengths of the 4 visible emission lines from Hydrogen (which are called the Balmer Series) •Implies that there is some underlying order in the atom that results in this deceptively simple equation. 2 1 The Bohr Atom n 1913: Niels Bohr uses quantum theory to explain the origin of the line spectrum of hydrogen 1. The electron in a hydrogen atom can exist only in discrete orbits 2. The orbits are circular paths about the nucleus at varying radii 3. Each orbit corresponds to a particular energy 4. Orbit energies increase with increasing radii 5. The lowest energy orbit is called the ground state 6. After absorbing energy, the e- jumps to a higher energy orbit (an excited state) 7. When the e- drops down to a lower energy orbit, the energy lost can be given off as a quantum of light 8. The energy of the photon emitted is equal to the difference in energies of the two orbits involved 3 Mohr Bohr n Mathematically, Bohr equated the two forces acting on the orbiting electron: coulombic attraction = centrifugal accelleration 2 2 2 -(Z/4peo)(e /r ) = m(v /r) n Rearranging and making the wild assumption: mvr = n(h/2p) n e- angular momentum can only have certain quantified values in whole multiples of h/2p 4 2 Hydrogen Energy Levels n Based on this model, Bohr arrived at a simple equation to calculate the electron energy levels in hydrogen: 2 En = -RH(1/n ) for n = 1, 2, 3, 4, . -
Vibrational Quantum Number
Fundamentals in Biophotonics Quantum nature of atoms, molecules – matter Aleksandra Radenovic [email protected] EPFL – Ecole Polytechnique Federale de Lausanne Bioengineering Institute IBI 26. 03. 2018. Quantum numbers •The four quantum numbers-are discrete sets of integers or half- integers. –n: Principal quantum number-The first describes the electron shell, or energy level, of an atom –ℓ : Orbital angular momentum quantum number-as the angular quantum number or orbital quantum number) describes the subshell, and gives the magnitude of the orbital angular momentum through the relation Ll2 ( 1) –mℓ:Magnetic (azimuthal) quantum number (refers, to the direction of the angular momentum vector. The magnetic quantum number m does not affect the electron's energy, but it does affect the probability cloud)- magnetic quantum number determines the energy shift of an atomic orbital due to an external magnetic field-Zeeman effect -s spin- intrinsic angular momentum Spin "up" and "down" allows two electrons for each set of spatial quantum numbers. The restrictions for the quantum numbers: – n = 1, 2, 3, 4, . – ℓ = 0, 1, 2, 3, . , n − 1 – mℓ = − ℓ, − ℓ + 1, . , 0, 1, . , ℓ − 1, ℓ – –Equivalently: n > 0 The energy levels are: ℓ < n |m | ≤ ℓ ℓ E E 0 n n2 Stern-Gerlach experiment If the particles were classical spinning objects, one would expect the distribution of their spin angular momentum vectors to be random and continuous. Each particle would be deflected by a different amount, producing some density distribution on the detector screen. Instead, the particles passing through the Stern–Gerlach apparatus are deflected either up or down by a specific amount. -
Lecture 3: Particle in a 1D Box
Lecture 3: Particle in a 1D Box First we will consider a free particle moving in 1D so V (x) = 0. The TDSE now reads ~2 d2ψ(x) = Eψ(x) −2m dx2 which is solved by the function ψ = Aeikx where √2mE k = ± ~ A general solution of this equation is ψ(x) = Aeikx + Be−ikx where A and B are arbitrary constants. It can also be written in terms of sines and cosines as ψ(x) = C sin(kx) + D cos(kx) The constants appearing in the solution are determined by the boundary conditions. For a free particle that can be anywhere, there is no boundary conditions, so k and thus E = ~2k2/2m can take any values. The solution of the form eikx corresponds to a wave travelling in the +x direction and similarly e−ikx corresponds to a wave travelling in the -x direction. These are eigenfunctions of the momentum operator. Since the particle is free, it is equally likely to be anywhere so ψ∗(x)ψ(x) is independent of x. Incidently, it cannot be normalized because the particle can be found anywhere with equal probability. 1 Now, let us confine the particle to a region between x = 0 and x = L. To do this, we choose our interaction potential V (x) as follows V (x) = 0 for 0 x L ≤ ≤ = otherwise ∞ It is always a good idea to plot the potential energy, when it is a function of a single variable, as shown in Fig.1. The TISE is now given by V(x) V=infinity V=0 V=infinity x 0 L ~2 d2ψ(x) + V (x)ψ(x) = Eψ(x) −2m dx2 First consider the region outside the box where V (x) = . -
The Quantum Mechanical Model of the Atom
The Quantum Mechanical Model of the Atom Quantum Numbers In order to describe the probable location of electrons, they are assigned four numbers called quantum numbers. The quantum numbers of an electron are kind of like the electron’s “address”. No two electrons can be described by the exact same four quantum numbers. This is called The Pauli Exclusion Principle. • Principle quantum number: The principle quantum number describes which orbit the electron is in and therefore how much energy the electron has. - it is symbolized by the letter n. - positive whole numbers are assigned (not including 0): n=1, n=2, n=3 , etc - the higher the number, the further the orbit from the nucleus - the higher the number, the more energy the electron has (this is sort of like Bohr’s energy levels) - the orbits (energy levels) are also called shells • Angular momentum (azimuthal) quantum number: The azimuthal quantum number describes the sublevels (subshells) that occur in each of the levels (shells) described above. - it is symbolized by the letter l - positive whole number values including 0 are assigned: l = 0, l = 1, l = 2, etc. - each number represents the shape of a subshell: l = 0, represents an s subshell l = 1, represents a p subshell l = 2, represents a d subshell l = 3, represents an f subshell - the higher the number, the more complex the shape of the subshell. The picture below shows the shape of the s and p subshells: (notice the electron clouds) • Magnetic quantum number: All of the subshells described above (except s) have more than one orientation. -
Appendix: the Interaction Picture
Appendix: The Interaction Picture The technique of expressing operators and quantum states in the so-called interaction picture is of great importance in treating quantum-mechanical problems in a perturbative fashion. It plays an important role, for example, in the derivation of the Born–Markov master equation for decoherence detailed in Sect. 4.2.2. We shall review the basics of the interaction-picture approach in the following. We begin by considering a Hamiltonian of the form Hˆ = Hˆ0 + V.ˆ (A.1) Here Hˆ0 denotes the part of the Hamiltonian that describes the free (un- perturbed) evolution of a system S, whereas Vˆ is some added external per- turbation. In applications of the interaction-picture formalism, Vˆ is typically assumed to be weak in comparison with Hˆ0, and the idea is then to deter- mine the approximate dynamics of the system given this assumption. In the following, however, we shall proceed with exact calculations only and make no assumption about the relative strengths of the two components Hˆ0 and Vˆ . From standard quantum theory, we know that the expectation value of an operator observable Aˆ(t) is given by the trace rule [see (2.17)], & ' & ' ˆ ˆ Aˆ(t) =Tr Aˆ(t)ˆρ(t) =Tr Aˆ(t)e−iHtρˆ(0)eiHt . (A.2) For reasons that will immediately become obvious, let us rewrite this expres- sion as & ' ˆ ˆ ˆ ˆ ˆ ˆ Aˆ(t) =Tr eiH0tAˆ(t)e−iH0t eiH0te−iHtρˆ(0)eiHte−iH0t . (A.3) ˆ In inserting the time-evolution operators e±iH0t at the beginning and the end of the expression in square brackets, we have made use of the fact that the trace is cyclic under permutations of the arguments, i.e., that Tr AˆBˆCˆ ··· =Tr BˆCˆ ···Aˆ , etc. -
Quantum Field Theory II
Quantum Field Theory II T. Nguyen PHY 391 Independent Study Term Paper Prof. S.G. Rajeev University of Rochester April 20, 2018 1 Introduction The purpose of this independent study is to familiarize ourselves with the fundamental concepts of quantum field theory. In this paper, I discuss how the theory incorporates the interactions between quantum systems. With the success of the free Klein-Gordon field theory, ultimately we want to introduce the field interactions into our picture. Any interaction will modify the Klein-Gordon equation and thus its Lagrange density. Consider, for example, when the field interacts with an external source J(x). The Klein-Gordon equation and its Lagrange density are µ 2 (@µ@ + m )φ(x) = J(x); 1 m2 L = @ φ∂µφ − φ2 + Jφ. 2 µ 2 In a relativistic quantum field theory, we want to describe the self-interaction of the field and the interaction with other dynamical fields. This paper is based on my lecture for the Kapitza Society. The second section will discuss the concept of symmetry and conservation. The third section will discuss the self-interacting φ4 theory. Lastly, in the fourth section, I will briefly introduce the interaction (Dirac) picture and solve for the time evolution operator. 2 Noether's Theorem 2.1 Symmetries and Conservation Laws In 1918, the mathematician Emmy Noether published what is now known as the first Noether's Theorem. The theorem informally states that for every continuous symmetry there exists a corresponding conservation law. For example, the conservation of energy is a result of a time symmetry, the conservation of linear momentum is a result of a plane symmetry, and the conservation of angular momentum is a result of a spherical symmetry. -
Introduction to Quantum Information Theory
Introduction to Quantum Information Theory Carlos Palazuelos Instituto de Ciencias Matemáticas (ICMAT) [email protected] Madrid, Spain March 2013 Contents Chapter 1. A comment on these notes 3 Chapter 2. Postulates of quantum mechanics 5 1. Postulate I and Postulate II 5 2. Postulate III 7 3. Postulate IV 9 Chapter 3. Some basic results 13 1. No-cloning theorem 13 2. Quantum teleportation 14 3. Superdense coding 15 Chapter 4. The density operators formalism 17 1. Postulates of quantum mechanics: The density operators formalism 17 2. Partial trace 19 3. The Schmidt decomposition and purifications 20 4. Definition of quantum channel and its classical capacity 21 Chapter 5. Quantum nonlocality 25 1. Bell’s result: Correlations in EPR 25 2. Tsirelson’s theorem and Grothendieck’s theorem 27 Chapter 6. Some notions about classical information theory 33 1. Shannon’s noiseless channel coding theorem 33 2. Conditional entropy and Fano’s inequality 35 3. Shannon’s noisy channel coding theorem: Random coding 38 Chapter 7. Quantum Shannon Theory 45 1. Von Neumann entropy 45 2. Schumacher’s compression theorem 48 3. Accessible Information and Holevo bound 55 4. Classical capacity of a quantum channel 58 5. A final comment about the regularization 61 Bibliography 63 1 CHAPTER 1 A comment on these notes These notes were elaborated during the first semester of 2013, while I was preparing a course on quantum information theory as a subject for the PhD programme: Investigación Matemática at Universidad Complutense de Madrid. The aim of this work is to present an accessible introduction to some topics in the field of quantum information theory for those people who do not have any background on the field. -
Interaction Representation
Interaction Representation So far we have discussed two ways of handling time dependence. The most familiar is the Schr¨odingerrepresentation, where operators are constant, and states move in time. The Heisenberg representation does just the opposite; states are constant in time and operators move. The answer for any given physical quantity is of course independent of which is used. Here we discuss a third way of describing the time dependence, introduced by Dirac, known as the interaction representation, although it could equally well be called the Dirac representation. In this representation, both operators and states move in time. The interaction representation is particularly useful in problems involving time dependent external forces or potentials acting on a system. It also provides a route to the whole apparatus of quantum field theory and Feynman diagrams. This approach to field theory was pioneered by Dyson in the the 1950's. Here we will study the interaction representation in quantum mechanics, but develop the formalism in enough detail that the road to field theory can be followed. We consider an ordinary non-relativistic system where the Hamiltonian is broken up into two parts. It is almost always true that one of these two parts is going to be handled in perturbation theory, that is order by order. Writing our Hamiltonian we have H = H0 + V (1) Here H0 is the part of the Hamiltonian we have under control. It may not be particularly simple. For example it could be the full Hamiltonian of an atom or molecule. Neverthe- less, we assume we know all we need to know about the eigenstates of H0: The V term in H is the part we do not have control over. -
A Relativistic Electron in a Coulomb Potential
A Relativistic Electron in a Coulomb Potential Alfred Whitehead Physics 518, Fall 2009 The Problem Solve the Dirac Equation for an electron in a Coulomb potential. Identify the conserved quantum numbers. Specify the degeneracies. Compare with solutions of the Schrödinger equation including relativistic and spin corrections. Approach My approach follows that taken by Dirac in [1] closely. A few modifications taken from [2] and [3] are included, particularly in regards to the final quantum numbers chosen. The general strategy is to first find a set of transformations which turn the Hamiltonian for the system into a form that depends only on the radial variables r and pr. Once this form is found, I solve it to find the energy eigenvalues and then discuss the energy spectrum. The Radial Dirac Equation We begin with the electromagnetic Hamiltonian q H = p − cρ ~σ · ~p − A~ + ρ mc2 (1) 0 1 c 3 with 2 0 0 1 0 3 6 0 0 0 1 7 ρ1 = 6 7 (2) 4 1 0 0 0 5 0 1 0 0 2 1 0 0 0 3 6 0 1 0 0 7 ρ3 = 6 7 (3) 4 0 0 −1 0 5 0 0 0 −1 1 2 0 1 0 0 3 2 0 −i 0 0 3 2 1 0 0 0 3 6 1 0 0 0 7 6 i 0 0 0 7 6 0 −1 0 0 7 ~σ = 6 7 ; 6 7 ; 6 7 (4) 4 0 0 0 1 5 4 0 0 0 −i 5 4 0 0 1 0 5 0 0 1 0 0 0 i 0 0 0 0 −1 We note that, for the Coulomb potential, we can set (using cgs units): Ze2 p = −eΦ = − o r A~ = 0 This leads us to this form for the Hamiltonian: −Ze2 H = − − cρ ~σ · ~p + ρ mc2 (5) r 1 3 We need to get equation 5 into a form which depends not on ~p, but only on the radial variables r and pr. -
Advanced Quantum Theory AMATH473/673, PHYS454
Advanced Quantum Theory AMATH473/673, PHYS454 Achim Kempf Department of Applied Mathematics University of Waterloo Canada c Achim Kempf, September 2017 (Please do not copy: textbook in progress) 2 Contents 1 A brief history of quantum theory 9 1.1 The classical period . 9 1.2 Planck and the \Ultraviolet Catastrophe" . 9 1.3 Discovery of h ................................ 10 1.4 Mounting evidence for the fundamental importance of h . 11 1.5 The discovery of quantum theory . 11 1.6 Relativistic quantum mechanics . 13 1.7 Quantum field theory . 14 1.8 Beyond quantum field theory? . 16 1.9 Experiment and theory . 18 2 Classical mechanics in Hamiltonian form 21 2.1 Newton's laws for classical mechanics cannot be upgraded . 21 2.2 Levels of abstraction . 22 2.3 Classical mechanics in Hamiltonian formulation . 23 2.3.1 The energy function H contains all information . 23 2.3.2 The Poisson bracket . 25 2.3.3 The Hamilton equations . 27 2.3.4 Symmetries and Conservation laws . 29 2.3.5 A representation of the Poisson bracket . 31 2.4 Summary: The laws of classical mechanics . 32 2.5 Classical field theory . 33 3 Quantum mechanics in Hamiltonian form 35 3.1 Reconsidering the nature of observables . 36 3.2 The canonical commutation relations . 37 3.3 From the Hamiltonian to the equations of motion . 40 3.4 From the Hamiltonian to predictions of numbers . 44 3.4.1 Linear maps . 44 3.4.2 Choices of representation . 45 3.4.3 A matrix representation . 46 3 4 CONTENTS 3.4.4 Example: Solving the equations of motion for a free particle with matrix-valued functions .