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Contents Part a Nanocarbons
Contents Foreword by Claes-Goran Granqvist V Foreword by Neal Lane VII List of Abbreviations XXIX 1 Science and Engineering of Nanomaterials Robert Vajtai 1 1.1 History and Definition of Nanomaterials 2 1.2 Formation of Nanomaterials 6 1.3 Properties of Nanomaterials 10 1.k Typical Applications of Nanomaterials 22 1.5 Concluding Remarks 31 1.6 About the Contents of the Handbook 31 References 31 Part A NanoCarbons 2 Graphene - Properties and Characterization Aravind Vijayaraghavan 39 2.1 Methods of Production k2 2.2 Properties 50 2.3 Characterization 58 2.k Applications 69 2.5 Conclusions and Outlook 1W References 74 3 Fullerenes and Beyond: Complexity, Morphology, and Functionality in Closed Carbon Nanostructures Humberto Terrones 83 3.1 Geometry and Structural Features of Fullerenes 85 3.2 Methods of Synthesis of Fullerenes and Proposed Growth Models.... 88 3.3 Physicochemical Properties of Fullerenes 90 3.4 Applications of Fullerenes and Beyond 92 3.5 Conclusions 99 References 99 k Single-Walled Carbon Nanotubes Sebastien Nanot, Nicholas A. Thompson, Ji-Hee Kim, Xucin Wang, William D. Rice, Erik H. Haroz, Yogeeswaran Ganesan, Cary L. Pint, Junichiro Kono 105 4.1 History 106 4.2 Crystallographic and Electronic Structure 106 http://d-nb.info/1012138798 4.3 Synthesis Ill 4.4 Optical Properties 115 4.5 Transport Properties 123 4.6 Thermal and Mechanical Properties 128 4.7 Concluding Remarks 135 References 135 5 Multi-Walled Carbon Nanotubes Akos Kukovecz, Gabor Kozma, Zoltan Kdnya 147 5.1 Synthesis 148 5.2 Chemistry of MWCNTs 153 5.3 Properties 157 5.4 Selected Applications 163 References 169 6 Modified Carbon Nanotubes Aaron Morelos-Gomez, Ferdinando Tristan Lopez, Rodolfo Cruz-Silva, Sofia M. -
Nanomedicine and Medical Nanorobotics - Robert A
BIOTECHNOLOGY– Vol .XII – Nanomedicine and Medical nanorobotics - Robert A. Freitas Jr. NANOMEDICINE AND MEDICAL NANOROBOTICS Robert A. Freitas Jr. Institute for Molecular Manufacturing, Palo Alto, California, USA Keywords: Assembly, Nanomaterials, Nanomedicine, Nanorobot, Nanorobotics, Nanotechnology Contents 1. Nanotechnology and Nanomedicine 2. Medical Nanomaterials and Nanodevices 2.1. Nanopores 2.2. Artificial Binding Sites and Molecular Imprinting 2.3. Quantum Dots and Nanocrystals 2.4. Fullerenes and Nanotubes 2.5. Nanoshells and Magnetic Nanoprobes 2.6. Targeted Nanoparticles and Smart Drugs 2.7. Dendrimers and Dendrimer-Based Devices 2.8. Radio-Controlled Biomolecules 3. Microscale Biological Robots 4. Medical Nanorobotics 4.1. Early Thinking in Medical Nanorobotics 4.2. Nanorobot Parts and Components 4.3. Self-Assembly and Directed Parts Assembly 4.4. Positional Assembly and Molecular Manufacturing 4.5. Medical Nanorobot Designs and Scaling Studies Acknowledgments Bibliography Biographical Sketch Summary Nanomedicine is the process of diagnosing, treating, and preventing disease and traumatic injury, of relieving pain, and of preserving and improving human health, using molecular tools and molecular knowledge of the human body. UNESCO – EOLSS In the relatively near term, nanomedicine can address many important medical problems by using nanoscale-structured materials and simple nanodevices that can be manufactured SAMPLEtoday, including the interaction CHAPTERS of nanostructured materials with biological systems. In the mid-term, biotechnology will make possible even more remarkable advances in molecular medicine and biobotics, including microbiological biorobots or engineered organisms. In the longer term, perhaps 10-20 years from today, the earliest molecular machine systems and nanorobots may join the medical armamentarium, finally giving physicians the most potent tools imaginable to conquer human disease, ill-health, and aging. -
Computational Investigations of Molecular Transport
COMPUTATIONAL INVESTIGATIONS OF MOLECULAR TRANSPORT PROCESSES IN NANOTUBULAR AND NANOCOMPOSITE MATERIALS A Dissertation Presented to The Academic Faculty by Suchitra Konduri In Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy in Chemical Engineering in the School of Chemical & Biomolecular Engineering Georgia Institute of Technology May 2009 COMPUTATIONAL INVESTIGATIONS OF MOLECULAR TRANSPORT PROCESSES IN NANOTUBULAR AND NANOCOMPOSITE MATERIALS Approved by: Dr. Sankar Nair, Advisor Dr. Carson J. Meredith School of Chemical & Biomolecular School of School of Chemical & Engineering Biomolecular Engineering Georgia Institute of Technology Georgia Institute of Technology Dr. William J. Koros Dr. Yonathan S. Thio School of Chemical & Biomolecular School of Polymer, Textile & Fiber Engineering Engineering Georgia Institute of Technology Georgia Institute of Technology Dr. Peter J. Ludovice Dr. Min Zhou School of Chemical & Biomolecular School of Mechanical Engineering Engineering Georgia Institute of Technology Georgia Institute of Technology Date Approved: Februay 05, 2009 ACKNOWLEDGEMENTS This thesis is the result of not just my efforts, but is influenced directly or indirectly by a number of people, whom I would like to acknowledge here. Firstly, I express my sincere thanks to my advisor, Prof. Sankar Nair, for providing me an opportunity to work with him, and for extending his unwavering support, guidance and commitment to help me develop my scientific skills and become a better researcher that I believe I am now. His trust and help in times of need are greatly appreciated. I am grateful to my committee members Prof. William J. Koros, Prof. Peter J. Ludovice, Prof. Carson J. Meredith, Prof. Yonathan S. Thio, and Prof. Min Zhou for providing valuable suggestions and for their critical reading of this thesis. -
Nanocomposite Membranes for Liquid and Gas Separations from the Perspective of Nanostructure Dimensions
membranes Review Nanocomposite Membranes for Liquid and Gas Separations from the Perspective of Nanostructure Dimensions Pei Sean Goh *, Kar Chun Wong and Ahmad Fauzi Ismail Advanced Membrane Technology Research Centre (AMTEC), School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, Johor Bahru 81310, Malaysia; [email protected] (K.C.W.); [email protected] (A.F.I.) * Correspondence: [email protected]; Tel.: +60-7-553-5812 Received: 26 September 2020; Accepted: 19 October 2020; Published: 21 October 2020 Abstract: One of the critical aspects in the design of nanocomposite membrane is the selection of a well-matched pair of nanomaterials and a polymer matrix that suits their intended application. By making use of the fascinating flexibility of nanoscale materials, the functionalities of the resultant nanocomposite membranes can be tailored. The unique features demonstrated by nanomaterials are closely related to their dimensions, hence a greater attention is deserved for this critical aspect. Recognizing the impressive research efforts devoted to fine-tuning the nanocomposite membranes for a broad range of applications including gas and liquid separation, this review intends to discuss the selection criteria of nanostructured materials from the perspective of their dimensions for the production of high-performing nanocomposite membranes. Based on their dimension classifications, an overview of the characteristics of nanomaterials used for the development of nanocomposite membranes is presented. The advantages and roles of these nanomaterials in advancing the performance of the resultant nanocomposite membranes for gas and liquid separation are reviewed. By highlighting the importance of dimensions of nanomaterials that account for their intriguing structural and physical properties, the potential of these nanomaterials in the development of nanocomposite membranes can be fully harnessed. -
Nanotechnology and Green Nanotechnology: a Road Map for Sustainable Development, Cleaner Energy and Greener World
Volume 3, Issue 1, January – 2018 International Journal of Innovative Science and Research Technology ISSN No:-2456 –2165 Nanotechnology and Green Nanotechnology: A Road Map for Sustainable Development, Cleaner Energy and Greener World Palak K. Lakhani1, Neelam Jain2 1Faculty of Natural Sciences II-Chemistry and Physics, Martin Luther University, Halle-Wittenberg, Saxony Anhalt, Germany 2Department of Biotechnology, Amity University, Jaipur, Rajasthan, India Abstract:-Imagine the chips embedded in the human compare the nanoworld to an orange, it would the same as body reporting every body movement and just waiting to comparing the same orange to earth. The concept of strike at those nasty bacterial invaders, clothing smart nanoscale can be easily observed in figure 1. By working at enough to monitor out health and save us from this tiny, microscopic scale, researchers are learning how to environmental hazards, huge buildings and machines manipulate matter like never before. In this brave new having the capability to repair and adjust themselves to science of nanotechnology, the increased surface area upon the vagaries of the environment, or a regular wristwatch which to work is exponential and that opens up possibilities doubling up as a supercomputer. Thanks to unimaginable until now. nanotechnology, all of these wonders, and many more, are possible. Scientific discoveries and inventions have in fact propelled man to challenge new frontiers. And with his superior brain, man has been able to deliver most of these goodies. Nanotechnology is one such technological wonders that we are experiencing now. Scientists and engineers are working round the clock to achieve breakthroughs that could possibly be the answer to human misery. -
Scaling the Mass Transport Enhancement Through Carbon Nanotube Membranes Seul Youn, Jakob Buchheim, Mahesh Lokesh, Hyung Park
Scaling the Mass Transport Enhancement through Carbon Nanotube Membranes Seul Youn, Jakob Buchheim, Mahesh Lokesh, Hyung Park To cite this version: Seul Youn, Jakob Buchheim, Mahesh Lokesh, Hyung Park. Scaling the Mass Transport Enhancement through Carbon Nanotube Membranes. 2018. hal-01890716 HAL Id: hal-01890716 https://hal.archives-ouvertes.fr/hal-01890716 Preprint submitted on 8 Oct 2018 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Scaling the Mass Transport Enhancement through Carbon Nanotube Membranes Seul Ki Youn, Jakob Buchheim, Mahesh Lokesh, Hyung Gyu Park* Nanoscience for Energy Technology and Sustainability, Department of Mechanical and Process Engineering, Swiss Federal Institute of Technology (ETH) Zurich, Tannenstrasse 3, Zurich CH-8092, Switzerland *Corresponding author: [email protected] ABSTRACT Measuring and controlling enhanced mass transport in carbon nanotube (CNT) and membranes thereof have been of great interest and importance in fundamental studies of nanofluidics as well as practical applications including desalination and gas separation. Experiments and simulations have claimed nearly frictionless transport and attributed it to tight graphitic confinement. Nevertheless, rare and scattered experimental data are obscuring the transport efficiency limit and the mechanistic understanding of fluid transport through CNTs. -
Greenwashing: a Tale of Precaution
GREENWASHING: A TALE OF PRECAUTION DAVID M. BERUBE PROFESSOR SCITECH COM Faucibus ergo sum & ENV SCIENCE ego DIR. PCOST, NCSU I shop, therefore I RISK COM ADV COMM, FDA am MANAGE, CET LLC CORPORATE MARKETING OF SCIENCE MARKETING NANOSCIENCE The marketing and sale of scientific products is evolving as the result of several factors including (1) the uncertain economy, (2) unprecedented levels of competition, (3) new geographical and user markets, and (4) an explosion of content and media channels. In this environment, many companies are assessing new strategies, technologies, and new media channels to develop new types of relationships with their customers, provide targeted and valuable content in their marketing materials, and leverage new technologies to promote closer collaboration between the marketing and sales organizations. GOVERNMENT MARKETING OF NANO AS “NEXT INDUSTRIAL REVOLUTION” There seems to be an arms race going on among nanotechnology investment and consulting firms as to who can come up with the highest figure for the size of the "nanotechnology market". The current record stands at $2.95 trillion by 2015. The granddaddy of the trillion-dollar forecasts of course is the National Science Foundation’s (NSF) "$1 trillion by 2015", which inevitably gets quoted in many articles, business plans and funding applications. The problem with these forecasts is that they are based on a highly inflationary data collection and compilation methodology. The result is that the headline figures - $1 trillion!, $2 trillion!, $3 trillion! - are more reminiscent of supermarket tabloids than serious market research. Some would call it pure hype. This type of market size forecast leads to misguided expectations because few people read the entire report and in the end only the misleading trillion-dollar headline figure gets quoted out of context, even by people who should now better, and finally achieves a life by itself. -
An Integral Part of Sustainable Nano
Green Synthesis and Green Nanotechnology: An Integral Part of Sustainable Nano Barbara Karn, PhD National Science Foundation Santa Barbara November 3, 2013 Green Nano Green nanotechnology is about doing things right in the first place— About making green nano-products and using nano-products in support of sustainability. Green Nanotechnology Framework 1. Production/Processes Making nanomaterials and their products cause no harm Making NanoX “greenly” Right Green e.g., Green chemistry, Green engineering, DfE, Smart business practices Using NanoX to “green” up production e.g., Nanomembranes, nanoscaled catalysts Light Green Pollution Prevention Emphasis 2. Products Using nanomaterials and their products help the environment Direct Environmental Applications e.g., environmental remediation, sensors Deep Green Indirect Environmental Applications e.g., saved energy, reduced waste, Anticipating full life cycle of nanomaterials and nanoproducts NEXT STEPS: Policies that offer incentives for developing green nanoproducts and manufacturing techniques Nano “Greening” Production – Light Green Nano Membranes Separate out metals and byproducts Clean process solvents Product separations Nano Catalysts Increased efficiency and selectivity Process Energy More Efficient Lower use Other names: Clean production, P2, clean tech, environmentally benign manufacturing Indirect Applications – Light Green Dematerialization Energy Savings--Light Weight nanocomposites Spun carbon nanotubes or other nanomaterials to replace copper wiring Increased miniaturization -
Developments in the Application of Nanomaterials for Water Treatment and Their Impact on the Environment
nanomaterials Review Developments in the Application of Nanomaterials for Water Treatment and Their Impact on the Environment Haleema Saleem and Syed Javaid Zaidi * Center for Advanced Materials (CAM), Qatar University, P.O. Box 2713 Doha, Qatar; [email protected] * Correspondence: [email protected] or [email protected]; Tel.: +974-44037723 Received: 5 August 2020; Accepted: 1 September 2020; Published: 7 September 2020 Abstract: Nanotechnology is an uppermost priority area of research in several nations presently because of its enormous capability and financial impact. One of the most promising environmental utilizations of nanotechnology has been in water treatment and remediation where various nanomaterials can purify water by means of several mechanisms inclusive of the adsorption of dyes, heavy metals, and other pollutants, inactivation and removal of pathogens, and conversion of harmful materials into less harmful compounds. To achieve this, nanomaterials have been generated in several shapes, integrated to form different composites and functionalized with active components. Additionally, the nanomaterials have been added to membranes that can assist to improve the water treatment efficiency. In this paper, we have discussed the advantages of nanomaterials in applications such as adsorbents (removal of dyes, heavy metals, pharmaceuticals, and organic contaminants from water), membrane materials, catalytic utilization, and microbial decontamination. We discuss the different carbon-based nanomaterials (carbon nanotubes, graphene, -
Opportunities and Challenges of Nanotechnology in the Green Economy Ivo Iavicoli1*, Veruscka Leso1, Walter Ricciardi1, Laura L Hodson2 and Mark D Hoover3
Iavicoli et al. Environmental Health 2014, 13:78 http://www.ehjournal.net/content/13/1/78 REVIEW Open Access Opportunities and challenges of nanotechnology in the green economy Ivo Iavicoli1*, Veruscka Leso1, Walter Ricciardi1, Laura L Hodson2 and Mark D Hoover3 Abstract In a world of finite resources and ecosystem capacity, the prevailing model of economic growth, founded on ever-increasing consumption of resources and emission pollutants, cannot be sustained any longer. In this context, the “green economy” concept has offered the opportunity to change the way that society manages the interaction of the environmental and economic domains. To enable society to build and sustain a green economy, the associated concept of “green nanotechnology” aims to exploit nano-innovations in materials science and engineering to generate products and processes that are energy efficient as well as economically and environmentally sustainable. These applications are expected to impact a large range of economic sectors, such as energy production and storage, clean up-technologies, as well as construction and related infrastructure industries. These solutions may offer the opportunities to reduce pressure on raw materials trading on renewable energy, to improve power delivery systems to be more reliable, efficient and safe as well as to use unconventional water sources or nano-enabled construction products therefore providing better ecosystem and livelihood conditions. However, the benefits of incorporating nanomaterials in green products and processes may bring challenges with them for environmental, health and safety risks, ethical and social issues, as well as uncertainty concerning market and consumer acceptance. Therefore, our aim is to examine the relationships among guiding principles for a green economy and opportunities for introducing nano-applications in this field as well as to critically analyze their practical challenges, especially related to the impact that they may have on the health and safety of workers involved in this innovative sector. -
Carbon Nanotubes (Cnts): a Potential Nanomaterial for Water Purification
Review ReviewCarbon Nanotubes (CNTs): A Potential CarbonNanomaterial Nanotubes for Water (CNTs): Purification A Potential Nanomaterial forBharti WaterArora 1,* and Purification Pankaj Attri 2,* Bharti1 Department Arora 1, *of and Applied Pankaj Sciences, Attri The2,* NorthCap University, Sector-23-A, Gurugram, Haryana-122017, 1 IndiaDepartment of Applied Sciences, The NorthCap University, Sector-23-A, Gurugram, Haryana 122017, India 2 2 CenterCenter of of Plasma Plasma Nano-Interface Nano-Interface Engineer Engineering,ing, Kyushu Kyushu University, University, Fukuoka Fukuoka 819-0395, 819-0395, Japan Japan ** Correspondence:Correspondence: [email protected] [email protected] (B.A.); (B.A.); [email protected] [email protected] (P.A.) (P.A.) Received: 23 July 2020; Accepted: 3 Sept Septemberember 2020; Published: 10 10 September September 2020 Abstract: Nanomaterials such as carbon nanotubes (CNTs) have been used as an excellent material for catalysis, separation, separation, adsorption adsorption and and disinfecti disinfectionon processes. processes. CNTs CNTs have have grabbed grabbed the the attention attention of ofthe the scientific scientific community community and and they they have have the potentia the potentiall to adsorb to adsorb most most of the of organic the organic compounds compounds from fromwater. water. Unlike, Unlike, reverse reverse osmosis osmosis (RO), nanofiltration (RO), nanofiltration (NF) and (NF) ultrafiltration and ultrafiltration (UF) membranes (UF) membranes aligned alignedCNT membranes CNT membranes can act canas high-flow act as high-flow desalination desalination membranes. membranes. CNTs CNTsprovide provide a relatively a relatively safer saferelectrode electrode solution solution for biosensors. for biosensors. The Thearticle article is of is ofthe the utmost utmost importance importance for for the the scientists scientists and technologists working in water purification purification technologies to eliminate the the water water crisis crisis in in the the future. -
Ecotoxicology and Environmental Safety 154 (2018) 237–244
Ecotoxicology and Environmental Safety 154 (2018) 237–244 Contents lists available at ScienceDirect Ecotoxicology and Environmental Safety journal homepage: www.elsevier.com/locate/ecoenv Ecofriendly nanotechnologies and nanomaterials for environmental T applications: Key issue and consensus recommendations for sustainable and ecosafe nanoremediation ⁎ I. Corsia, ,1, M. Winther-Nielsenb, R. Sethic, C. Puntad, C. Della Torree, G. Libralatof, G. Lofranog, ⁎ L. Sabatinih, M. Aielloi, L. Fiordii, F. Cinuzzij, A. Caneschik, D. Pellegrinil, I. Buttinol, ,1 a Department of Physical, Earth and Environmental Sciences, University of Siena, via Mattioli, 4-53100 Siena, Italy b Department of Environment and Toxicology, DHI, Agern Allé 5, 2970 Hoersholm, Denmark c Department of Environment, Land and Infrastructure Engineering (DIATI), Politecnico di Torino, Italy d Department of Chemistry, Materials, and Chemical Engineering “G. Natta”, Politecnico di Milano and RU INSTM, Via Mancinelli 7, 20131 Milano, Italy e Department of Bioscience, University of Milano, via Celoria 26, 20133 Milano, Italy f Department of Biology, University of Naples Federico II, via Cinthia ed. 7, 80126 Naples, Italy g Department of Chemical and Biology “A. Zambelli”, University of Salerno, via Giovanni Paolo II 132, 84084 Fisciano, SA, Italy h Regional Technological District for Advanced Materials, c/o ASEV SpA (management entity), via delle Fiascaie 12, 50053 Empoli, FI, Italy i Acque Industriali SRL, Via Molise, 1, 56025 Pontedera, PI, Italy j LABROMARE SRL, Via dell'Artigianato