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Startex Denatured Alcohol Version 1.2 Revision Date: 03/20/2017

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Startex Denatured Alcohol Version 1.2 Revision Date: 03/20/2017 Safety Data Sheet Startex Denatured Alcohol Version 1.2 Revision Date: 03/20/2017 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Startex Denatured Alcohol Recommended use of the chemical and restrictions on use Recommended use : Alcohol solvent Manufacturer or supplier's details Company : Nexeo Solutions LLC - STARTEX™ Address 3 Waterway Square Place Suite 1000 The Woodlands, TX. 77380 United States of America Emergency telephone number: Health North America: 1-855-NEXEO4U (1-855-639-3648) Health International: 1-855-NEXEO4U (1-855-639-3648) Transport North America: CHEMTREC (1-800-424-9300) Additional Information: : Responsible Party: Product Safety Group E-Mail: [email protected] SDS Requests: 1-855-429-2661 SDS Requests Fax: 1-281-500-2370 Website: www.nexeosolutions.com SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 2 Acute toxicity (Oral) : Category 4 Acute toxicity (Inhalation) : Category 4 Acute toxicity (Dermal) : Category 4 Eye irritation : Category 2A Carcinogenicity : Category 2 Reproductive toxicity : Category 2 Specific target organ toxicity : Category 1 (Eyes, Central nervous system) - single exposure Specific target organ toxicity : Category 3 (Respiratory system) - single exposure GHS Label element SDS Number: 100000007369 1 / 16 Startex Denatured Alcohol Safety Data Sheet Startex Denatured Alcohol Version 1.2 Revision Date: 03/20/2017 Hazard pictograms : Signal word : Danger Hazard statements : H225 Highly flammable liquid and vapour. H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled H319 Causes serious eye irritation. H335 + H336 May cause respiratory irritation, and drowsiness or dizziness. H351 Suspected of causing cancer. H361 Suspected of damaging fertility or the unborn child. H371 May cause damage to organs. Precautionary statements : Prevention: P201 Obtain special instructions before use. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P242 Use only non-sparking tools. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P202 Do not handle until all safety precautions have been read and understood. P241 Use explosion-proof electrical/ ventilating/ lighting/ equip- ment. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P270 Do not eat, drink or smoke when using this product. P281 Use personal protective equipment as required. P280 Wear protective gloves/ eye protection/ face protection. Response: P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P307 + P311 IF exposed: Call a POISON CENTER or doctor/ physician. P370 + P378 In case of fire: Use dry sand, dry chemical or alco- hol-resistant foam for extinction. P363 Wash contaminated clothing before reuse. P332 + P313 If skin irritation occurs: Get medical advice/ atten- tion. SDS Number: 100000007369 2 / 16 Startex Denatured Alcohol Safety Data Sheet Startex Denatured Alcohol Version 1.2 Revision Date: 03/20/2017 P337 + P313 If eye irritation persists: Get medical advice/ atten- tion. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste dis- posal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components CAS-No. Chemical Name Weight % 64-17-5 Ethanol 70 - 90 67-56-1 Methanol 20 - 30 141-78-6 Ethyl acetate 1 - 5 64742-49-0 Naphtha (petroleum), hydrotreated light 0.1 - 1 64742-89-8 Solvent naphtha (pet), lt aliph. 0.1 - 1 142-82-5 Heptane 0.1 - 1 Any Concentration shown as a range is due to batch variation. SECTION 4. FIRST AID MEASURES General advice : Show this safety data sheet to the doctor in attendance. If inhaled : If symptoms persist, call a physician. In case of skin contact : If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact : Flush eyes with water as a precaution. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Take victim immediately to hospital. Do not induce vomiting without medical advice. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Alcohol-resistant foam Carbon dioxide (CO2) SDS Number: 100000007369 3 / 16 Startex Denatured Alcohol Safety Data Sheet Startex Denatured Alcohol Version 1.2 Revision Date: 03/20/2017 Dry chemical Unsuitable extinguishing : High volume water jet media Specific hazards during fire- : Do not allow run-off from fire fighting to enter drains or water fighting courses. Hazardous combustion prod- : Carbon oxides ucts Specific extinguishing meth- : Use a water spray to cool fully closed containers. ods Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored sepa- rately in closed containments. Special protective equipment : Wear self-contained breathing apparatus for firefighting if nec- for firefighters essary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- : Use personal protective equipment. tive equipment and emer- Ensure adequate ventilation. gency procedures Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentra- tions. Vapours can accumulate in low areas. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for : Contain spillage, and then collect with non-combustible ab- containment and cleaning up sorbent material, (e.g. sand, earth, diatomaceous earth, ver- miculite) and place in container for disposal according to local / national regulations (see section 13). SECTION 7. HANDLING AND STORAGE Advice on protection against : Do not spray on a naked flame or any incandescent material. fire and explosion Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Use only explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. Advice on safe handling : Avoid formation of aerosol. SDS Number: 100000007369 4 / 16 Startex Denatured Alcohol Safety Data Sheet Startex Denatured Alcohol Version 1.2 Revision Date: 03/20/2017 Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the ap- plication area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Container may be opened only under exhaust ventilation hood. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : No smoking. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters CAS-No. Components Value type Control parame- Basis (Form of ters / Permissible exposure) concentration 64-17-5 Ethanol TWA 1,000 ppm ACGIH TWA 1,000 ppm NIOSH REL 1,900 mg/m3 TWA 1,000 ppm OSHA Z-1 1,900 mg/m3 TWA 1,000 ppm OSHA P0 1,900 mg/m3 STEL 1,000 ppm ACGIH 67-56-1 Methanol TWA 200 ppm ACGIH STEL 250 ppm ACGIH TWA 200 ppm NIOSH REL 260 mg/m3 ST 250 ppm NIOSH REL 325 mg/m3 TWA 200 ppm OSHA Z-1 260 mg/m3 STEL 250 ppm OSHA P0 325 mg/m3 TWA 200 ppm OSHA P0 260 mg/m3 141-78-6 Ethyl acetate TWA 400 ppm ACGIH TWA 400 ppm NIOSH REL 1,400 mg/m3 SDS Number: 100000007369 5 / 16 Startex Denatured Alcohol Safety Data Sheet Startex Denatured Alcohol Version 1.2 Revision Date: 03/20/2017 TWA 400 ppm OSHA Z-1 1,400 mg/m3 TWA 400 ppm OSHA P0 1,400 mg/m3 64742-49-0 Naphtha (petroleum), hy- TWA 500 ppm OSHA Z-1 drotreated light 2,000 mg/m3 TWA 400 ppm OSHA P0 1,600 mg/m3 64742-89-8 Solvent naphtha (pet), lt aliph. TWA 500 ppm OSHA Z-1 2,000 mg/m3 TWA 400 ppm OSHA P0 1,600 mg/m3 142-82-5 Heptane TWA 85 ppm NIOSH REL 350 mg/m3 C 440 ppm NIOSH REL 1,800 mg/m3 TWA 500 ppm OSHA Z-1 2,000 mg/m3 TWA 400 ppm OSHA P0 1,600 mg/m3 STEL 500 ppm OSHA P0 2,000 mg/m3 Personal protective equipment Respiratory protection : In the case of vapour formation use a respirator with an ap- proved filter. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Skin and body protection : Impervious clothing Choose body protection according to the amount and concen- tration of the dangerous substance at the work place. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.
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