Notice of Receipt of Requests to Voluntarily Cancel Certain Pesticide Registrations and Amend Registrations to Terminate Certain
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Propoxur United States Environmental Protection Agency
United States Prevention, Pesticides EPA738-R-97-009 Environmental Protection And Toxic Substances August 1997 Agency (7508W) Reregistration Eligibility Decision (RED) PROPOXUR UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 OFFICE OF PREVENTION, PESTICIDES AND TOXIC SUBSTANCES CERTIFIED MAIL Dear Registrant: I am pleased to announce that the Environmental Protection Agency has completed its reregistration eligibility review and decisions on the pesticide chemical case propoxur. The enclosed Reregistration Eligibility Decision (RED) contains the Agency's evaluation of the data base of this chemical, its conclusions of the potential human health and environmental risks of the current product uses, and its decisions and conditions under which these uses and products will be eligible for reregistration. The RED includes the data and labeling requirements for products for reregistration. It may also include requirements for additional data (generic) on the active ingredient to confirm the risk assessments. To assist you with a proper response, read the enclosed document entitled "Summary of Instructions for Responding to the RED." This summary also refers to other enclosed documents which include further instructions. You must follow all instructions and submit complete and timely responses. The first set of required responses is due 90 days from the receipt of this letter. The second set of required responses is due 8 months from the date of receipt of this letter. Complete and timely responses will avoid the Agency taking the enforcement action of suspension against your products. If you have questions on the product specific data requirements or wish to meet with the Agency, please contact the Special Review and Reregistration Division representative Bonnie Adler (703) 308-8523. -
2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
Herbicide Mode of Action Table High Resistance Risk
Herbicide Mode of Action Table High resistance risk Chemical family Active constituent (first registered trade name) GROUP 1 Inhibition of acetyl co-enzyme A carboxylase (ACC’ase inhibitors) clodinafop (Topik®), cyhalofop (Agixa®*, Barnstorm®), diclofop (Cheetah® Gold* Decision®*, Hoegrass®), Aryloxyphenoxy- fenoxaprop (Cheetah®, Gold*, Wildcat®), fluazifop propionates (FOPs) (Fusilade®), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) Cyclohexanediones (DIMs) butroxydim (Factor®*), clethodim (Select®), profoxydim (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) Phenylpyrazoles (DENs) pinoxaden (Axial®) GROUP 2 Inhibition of acetolactate synthase (ALS inhibitors), acetohydroxyacid synthase (AHAS) Imidazolinones (IMIs) imazamox (Intervix®*, Raptor®), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, Lightning®*, Midas®* OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) Pyrimidinyl–thio- bispyribac (Nominee®), pyrithiobac (Staple®) benzoates Sulfonylureas (SUs) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*, Trimac Plus®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron (Logran®, Logran® B-Power®*), tribenuron (Express®), -
Organophosphate Poisoning : a Review
120 Sinha and Sharma Med J Indones Organophosphate poisoning : A review Parmod K. Sinha, Ashok Sharma Abstrak Pestisida organofosfat digunakan secara luas di seluruh dunia. Keracunan oleh bahan ini merupakan masalah kesehatan masyarakat, terutama di negara berkembang. Zat neurotoksik organofosfat merupakan bahan yang dianggap mengancam dalam bidang militer dan terorisme. Mekanisme toksisitas bahan ini adalah dengan cara menghambat asetilkolinesterase yang mengakibatkan menumpuknya neurotransmitor asetilkolin dan terjadi rangsangan terus-menerus pada reseptor asetilkolin pada sistem saraf sentral maupun perifer. Selain krisis kolinergik, organofosfat dapat menimbulkan berbagai sindrom neurologis, baik akut maupun kronik. Sedangkan gejala peralihan ( intermediate) terjadi 1-4 hari setelah krisis kolinergik teratasi. Pengobatan standar terdiri dari reaktivasi asetilkolinesterase dengan antidot golongan oksim (prolidoksim, oksidoksime, HI-6 dan HLo7), dan pengendalian efek biokimia asetilkolin dengan menggunakan atropin. Golongan oksim yang baru HI-6 dan Hlo7 merupakan reaktivator asetilkolinesterase yang lebih cocok dan efektif untuk keracunan akut dan berat dibandingkan dengan prolidoksim dan obidoksim. Penderita yang mendapat pengobatan segera, biasanya dapat sembuh dari toksisitas akut, namun gejala neurologis ikutan dapat saja terjadi. (Med J Indones 2003; 12: 120-6) Abstract Organophosphate pesticides are used extensively worldwide, and poisoning by these agents, particularly in developing nations is a public health problem. Organophosphorous -
Monitoring for Resistance to Organophosphorus and Pyrethroid Insecticides in Varroa Mite Populations
INSECTICIDE RESISTANCE AND RESISTANCE MANAGEMENT Monitoring for Resistance to Organophosphorus and Pyrethroid Insecticides in Varroa Mite Populations 1,2 3 1 4 LAMBERT H. B. KANGA, JOHN ADAMCZYK, KEITH MARSHALL, AND ROBERT COX J. Econ. Entomol. 103(5): 1797Ð1802 (2010); DOI: 10.1603/EC10064 ABSTRACT The occurrence of resistance in Varroa mite populations is a serious threat to the beekeeping industry and to crops that rely on the honey bee for pollination. Integrated pest management strategies for control of this pest include the judicious use of insecticides. To monitor Þeld populations of Varroa mite for insecticide resistance, a glass vial bioassay procedure was developed to use in the development of a resistance management strategy. Diagnostic concen- trations needed to separate susceptible genotypes from resistant individuals were determined for cypermethrin (0.1 g per vial), ßuvalinate (5.0 g per vial), malathion (0.01 g per vial), coumaphos (10.0 g per vial), diazinon (5.0 g per vial), methomyl (0.5 g per vial), propoxur (0.1 g per vial), and endosulfan (2.5 g per vial). Resistance to organophosphorus insecticides (malathion, coumaphos) and pyrethroids (cypermetrhrin, ßuvalinate) was widespread in both La Media Ranch, TX, and Wewahitchka, FL, from 2007 to 2009. There was no resistance to endosulfan, diazinon, methomyl, and propoxur in Þeld populations of Varroa mite in the two locations where resistance was monitored. The seasonal patterns of resistance in Wewahitchka were different from those of La Media Ranch. In the former location, the frequency of resistance to all insecticides tested decreased signiÞcantly from 2007 to 2009, whereas it increased in the latter location. -
Quaternary Ammonium Compounds
Phenoxy Alkanoic Acids in Milk Using Modified QuEChERS Method Version 1 (last update: 10.04.14) Compound details The group of Phenoxy herbicides is subdivided in Phenoxyacetic herbicides (e.g. 4-CPA, 2,4-D, MCPA, 2,4,5-T) Phenoxybutyric herbicides (e.g. 2,4-DB, MCPB) Phenoxypropionic herbicides (e.g. dichlorprop, fenoprop, mecoprop) Aryloxyphenoxypropionic herbicides (e.g. diclofop, fluazifop, haloxyfop, quizalofop) altogether 49 different compounds [4]. As representatives of the group the following four herbicides were validated for milk. 2,4-D Haloxyfop O N O F OH Cl O OH Cl O F F O Cl Dichlorprop Fluazifop O N O F OH Cl O OH O F F O Cl Residue definition (commodity group AO): 2,4-D (sum of 2,4-D and its esters expressed as 2,4-D) Dichlorprop: sum of dichlorprop (including dichlorprop-P) and its conjugates, expressed as dichlorprop Fluazifop-P-butyl (fluazifop acid (free and conjugate)) Haloxyfop including Haloxyfop-R: Haloxyfop-R and conjugates of haloxyfop-R expressed as haloxyfop-R EU Reference Laboratory for Pesticides Requiring Single Residue Methods Page 1 CVUA Stuttgart, Schaflandstr. 3/2, 70736 Fellbach, Germany [email protected] Extraction method: Analysis is performed applying QuEChERS extraction: Weigh 10 g milk, add 10 mL acetoni- trile, shake 15 min. (GenoGrinder), add citrat-salt mix, shake 1 min. (GenoGrinder), centri- fuge --> raw extract, As expected, the acidic phenoxy alkanoic acids show reduced recoveries when a PSA clean- up is performed: Mean recovery in % (0.1ppm) Compound after PSA-cleanup 2.4-D 47 2.4-DP (Dichlorprop) -
How Herbicides Work: Biology to Application (Agdex 606-2)
How Herbicides Work Biology to Application Linda Hall Agriculture Research Division Alberta Agriculture and Rural Development Hugh Beckie Thomas M. Wolf Saskatoon Research Centre Saskatoon Research Centre Agriculture and Agri-Food Canada Agriculture and Agri-Food Canada Disclaimer While every effort has been made to ensure accuracy, Alberta Agriculture and Rural Development does not accept responsibility for errors or ommissions. It remains the responsibility of the readers to follow product information contained on the product label or package insert. The publisher, editor and all contributors to this publication cannot be held responsible for publication errors or any consequence resulting from the use of this publication. Published by: Alberta Agriculture and Rural Development Information Management 7000 - 113 Street Edmonton, Alberta Canada T6H 5T6 Editors: Chris Kaulbars and Gerard Vaillancourt Graphic Designer: John Gillmore Electronic Composition: Sherrill Strauss and J.A. Serafinchon Photographs: Beth Hoar – Alberta Agriculture and Rural Development David Wall – Agriculture and Agri-Food Canada Tom Wolf – Agriculture and Agri-Food Canada Dow AgroSciences Copyright © 1999. All rights reserved by Her Majesty the Queen in the right of Alberta. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical photocopying, recording, or otherwise without written permission from Information Management, Alberta Agriculture and Rural Development. Tables/chemical -
Herbicide Strategies for Managing Glyphosate-Resistant and Susceptible Kochia (Bassia Scoparia) in Spring Wheat
Canadian Journal of Plant Science Herbicide strategies for managing glyphosate-resistant and susceptible kochia (Bassia scoparia) in spring wheat Journal: Canadian Journal of Plant Science Manuscript ID CJPS-2020-0303.R1 Manuscript Type:ForArticle Review Only Date Submitted by the 17-Jan-2021 Author: Complete List of Authors: Torbiak, Alysha; Hamman Ag Research Inc. Blackshaw, Robert; Agriculture and Agri-Food Canada Brandt, Randall; Development Centre, Agriculture and Agri-Food Canada Hamman, Bill; Hamman Ag Research Inc. Geddes, Charles; Lethbridge Research and Development Centre, Agriculture and Agri-Food Canada glyphosate resistance, herbicide resistance, herbicide stewardship, Keywords: <i>Bassia scoparia</i>, <i>Kochia scoparia</i> Is the invited manuscript for consideration in a Special Not applicable (regular submission) Issue?: © The Author(s) or their Institution(s) Page 1 of 34 Canadian Journal of Plant Science Herbicide strategies for managing glyphosate-resistant and susceptible kochia (Bassia scoparia) in spring wheat Alysha T. Torbiak, Robert E. Blackshaw, Randall N. Brandt, Bill Hamman, and Charles M. Geddes* Charles M. Geddes, Randall N. Brandt, and Robert E. Blackshaw. Agriculture and Agri- Food Canada, LethbridgeFor Research Review and Development Centre,Only 5403 1st Avenue South, Lethbridge, AB T1J 4B1, Canada. Alysha T. Torbiak, and Bill Hamman. Hamman Ag Research Inc. 347 Squamish Court West, Lethbridge, AB T1K 7R8, Canada. *Corresponding author: Charles M. Geddes (email: [email protected]) ORCID iD: Charles M. Geddes https://orcid.org/0000-0001-8088-224X 1 © The Author(s) or their Institution(s) Canadian Journal of Plant Science Page 2 of 34 Abstract Kochia [Bassia scoparia (L.) A.J. Scott] is a summer-annual tumbleweed that is tolerant of heat, drought and salinity, and capable of causing large yield losses in spring wheat (Triticum aestivum L). -
Table II. EPCRA Section 313 Chemical List for Reporting Year 2017 (Including Toxic Chemical Categories)
Table II. EPCRA Section 313 Chemical List For Reporting Year 2017 (including Toxic Chemical Categories) Individually listed EPCRA Section 313 chemicals with CAS numbers are arranged alphabetically starting on page II-3. Following the alphabetical list, the EPCRA Section 313 chemicals are arranged in CAS number order. Covered chemical categories follow. Note: Chemicals may be added to or deleted from the list. The Emergency Planning and Community Right-to-Know Call Center or the TRI-Listed Chemicals website will provide up-to-date information on the status of these changes. See section B.3.c of the instructions for more information on the de minimis % limits listed below. There are no de minimis levels for PBT chemicals since the de minimis exemption is not available for these chemicals (an asterisk appears where a de minimis limit would otherwise appear in Table II). However, for purposes of the supplier notification requirement only, such limits are provided in Appendix C. Chemical Qualifiers Certain EPCRA Section 313 chemicals listed in Table II have parenthetic “qualifiers.” These qualifiers indicate that these EPCRA Section 313 chemicals are subject to the section 313 reporting requirements if manufactured, processed, or otherwise used in a specific form or when a certain activity is performed. An EPCRA Section 313 chemical that is listed without a qualifier is subject to reporting in all forms in which it is manufactured, processed, and otherwise used. The following chemicals are reportable only if they are manufactured, processed, or otherwise used in the specific form(s) listed below: Chemical/ Chemical Category CAS Number Qualifier Aluminum (fume or dust) 7429-90-5 Only if it is a fume or dust form. -
Effects of Six Insecticides on Emergence of Some Parasites and Predators from Southern Pine Beetle Infested Trees
Stephen F. Austin State University SFA ScholarWorks Faculty Publications Forestry 1976 Effects of Six Insecticides on Emergence of Some Parasites and Predators from Southern Pine Beetle Infested Trees Jack E. Coster I. R. Ragenovich Follow this and additional works at: https://scholarworks.sfasu.edu/forestry Part of the Forest Sciences Commons Tell us how this article helped you. Repository Citation Coster, Jack E. and Ragenovich, I. R., "Effects of Six Insecticides on Emergence of Some Parasites and Predators from Southern Pine Beetle Infested Trees" (1976). Faculty Publications. 317. https://scholarworks.sfasu.edu/forestry/317 This Article is brought to you for free and open access by the Forestry at SFA ScholarWorks. It has been accepted for inclusion in Faculty Publications by an authorized administrator of SFA ScholarWorks. For more information, please contact [email protected]. Effects of Six Insecticides on Emergence of Some Parasites and Predators from Southern Pine Beetle' Infested Trees2 JACK E. COSTER AND IRAL R. RAGENOVICHB School of Forestry, Stephen F. Austin State University, Nacogdoches, TX 75961 ABSTRACT Six insecticides (lindane, phosmet, diazinon, acephate, propoxur, and carbaryl) were tested to determine effects on predators and parasites associated with southern pine beetle, Dendroctonus frontalis Zimmerman, in eastern Texas. Eleven species of parasites and predators emerged from insecticide-treated pine bolts. The most prevalent species was Coeloides pissodis followed by Medetera lJistriata, Roptrocerus xylophagorum, Corticeus glaber, and Thanasimus dulJius. In terms of emergence from treated pines, only diazinon significantly reduced the total number of associated insects. They were 65% fewer in number following diazinon treatment. The insecticides differed in their effects on the 11 associates. -
List of Herbicide Groups
List of herbicides Group Scientific name Trade name clodinafop (Topik®), cyhalofop (Barnstorm®), diclofop (Cheetah® Gold*, Decision®*, Hoegrass®), fenoxaprop (Cheetah® Gold* , Wildcat®), A Aryloxyphenoxypropionates fluazifop (Fusilade®, Fusion®*), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) butroxydim (Falcon®, Fusion®*), clethodim (Select®), profoxydim A Cyclohexanediones (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) A Phenylpyrazoles pinoxaden (Axial®) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, B Sulfonylureas Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron, (Logran®, Logran® B Power®*), tribenuron (Express®), trifloxysulfuron (Envoke®, Krismat®*) florasulam (Paradigm®*, Vortex®*, X-Pand®*), flumetsulam B Triazolopyrimidines (Broadstrike®), metosulam (Eclipse®), pyroxsulam (Crusader®Rexade®*) imazamox (Intervix®*, Raptor®,), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, B Imidazolinones Lightning®*, Midas®*, OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) B Pyrimidinylthiobenzoates bispyribac (Nominee®), pyrithiobac (Staple®) C Amides: propanil (Stam®) C Benzothiadiazinones: bentazone (Basagran®, -
Environmental Health Criteria 63 ORGANOPHOSPHORUS
Environmental Health Criteria 63 ORGANOPHOSPHORUS INSECTICIDES: A GENERAL INTRODUCTION Please note that the layout and pagination of this web version are not identical with the printed version. Organophophorus insecticides: a general introduction (EHC 63, 1986) INTERNATIONAL PROGRAMME ON CHEMICAL SAFETY ENVIRONMENTAL HEALTH CRITERIA 63 ORGANOPHOSPHORUS INSECTICIDES: A GENERAL INTRODUCTION This report contains the collective views of an international group of experts and does not necessarily represent the decisions or the stated policy of the United Nations Environment Programme, the International Labour Organisation, or the World Health Organization. Published under the joint sponsorship of the United Nations Environment Programme, the International Labour Organisation, and the World Health Organization World Health Orgnization Geneva, 1986 The International Programme on Chemical Safety (IPCS) is a joint venture of the United Nations Environment Programme, the International Labour Organisation, and the World Health Organization. The main objective of the IPCS is to carry out and disseminate evaluations of the effects of chemicals on human health and the quality of the environment. Supporting activities include the development of epidemiological, experimental laboratory, and risk-assessment methods that could produce internationally comparable results, and the development of manpower in the field of toxicology. Other activities carried out by the IPCS include the development of know-how for coping with chemical accidents, coordination