Chemistry Publications Chemistry 6-4-2019 Reshaping, Intermixing, and Coarsening for Metallic Nanocrystals: Nonequilibrium Statistical Mechanical and Coarse-Grained Modeling King C. Lai Iowa State University and Ames Laboratory,
[email protected] Yong Han Iowa State University and Ames Laboratory,
[email protected] Peter M. Spurgeon Iowa State University,
[email protected] Wenyu Huang Iowa State University,
[email protected] Patricia A. Thiel IFoowlalo Swta tthie Usn iaverndsit ay ddandit Aionmeals L waborkoratso rayt, :pthiehttps://
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[email protected]. Reshaping, Intermixing, and Coarsening for Metallic Nanocrystals: Nonequilibrium Statistical Mechanical and Coarse-Grained Modeling Abstract Self-assembly of supported 2D or 3D nanocrystals (NCs) by vacuum deposition and of 3D NCs by solution- phase synthesis (with possible subsequent transfer to a support) produces intrinsically nonequilibrium systems. Individual NCs can have far-from-equilibrium shapes and composition profiles. The free energy of NC ensembles is lowered by coarsening which can involve Ostwald ripening or Smoluchowski ripening (NC diffusion and coalescence).