Safety Data Sheet Neste Lipa 2
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Revision date: 21/08/2017 Supersedes date: 30/07/2015 SAFETY DATA SHEET NESTE LIPA 2 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name NESTE LIPA 2 Product number ID 10748 Internal identification 7572 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Solvent. 1.3. Details of the supplier of the safety data sheet Supplier Neste Markkinointi Oy Keilaranta 21, Espoo, PL 95, FIN-00095 NESTE, FINLAND Tel. +358 10 45811 [email protected] 1.4. Emergency telephone number National emergency telephone +358-9-471 977, +358-9-4711, Poison Information Centre number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Flam. Liq. 2 - H225 Health hazards Eye Irrit. 2 - H319 STOT SE 3 - H336 Asp. Tox. 1 - H304 Environmental hazards Not Classified 2.2. Label elements Pictogram Signal word Danger Hazard statements H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. 1/9 Revision date: 21/08/2017 Supersedes date: 30/07/2015 NESTE LIPA 2 Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302+P352 IF ON SKIN: Wash with plenty of water. Supplemental label EUH066 Repeated exposure may cause skin dryness or cracking. information Contains Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% aromatics , propan-2-ol 2.3. Other hazards Other hazards Vapours may accumulate on the floor and in low-lying areas., Vapours may form explosive mixtures with air., May cause nausea, headache, dizziness and intoxication. SECTION 3: Composition/information on ingredients 3.2. Mixtures Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% 70 - 80 % * aromatics CAS number: — REACH registration number: 01- 2119463258-33-XXXX Classification Flam. Liq. 3 - H226 STOT SE 3 - H336 Asp. Tox. 1 - H304 propan-2-ol 20 - 30 % CAS number: 67-63-0 EC number: 200-661-7 REACH registration number: 01- 2119457558-25-XXXX Classification Flam. Liq. 2 - H225 Eye Irrit. 2 - H319 STOT SE 3 - H336 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. Composition comments * Contains Benzene (CAS 71-43-2) < 0,1 %. n-hexane (CAS 110-54-3) < 1,0%. Total aromatics at maximum: < 0,5 %. Other information Identity outside the EU (CAS number and name of the substance):, 64742-48-9, Naphtha (petroleum), hydrotreated heavy., Previous EC number:, 265-150-3. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air and keep comfortable for breathing. Get medical attention if symptoms are severe or persist. Ingestion Do not induce vomiting. Get medical attention immediately. 2/9 Revision date: 21/08/2017 Supersedes date: 30/07/2015 NESTE LIPA 2 Skin contact Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing. Eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation persists after washing. 4.2. Most important symptoms and effects, both acute and delayed General information Causes eye irritation. Aspiration hazard if swallowed. May cause nausea, headache, dizziness and intoxication. Repeated exposure may cause skin dryness or cracking. 4.3. Indication of any immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. Aspiration hazard if swallowed. Entry into the lungs following ingestion or vomiting may cause chemical pneumonitis. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray, foam, dry powder or carbon dioxide. Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media 5.2. Special hazards arising from the substance or mixture Specific hazards Flammable liquid and vapour. Containers can burst violently or explode when heated, due to excessive pressure build-up. Severe explosion hazard when vapours are exposed to flames. Hazardous combustion Carbon dioxide (CO2). Carbon monoxide (CO). products 5.3. Advice for firefighters Protective actions during Cool containers exposed to heat with water spray and remove them from the fire area if it can firefighting be done without risk. Prevent fire extinguishing water from contaminating surface water or the ground water system. Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective for firefighters clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Avoid inhalation of vapours and contact with skin and eyes. Wear adequate protective equipment at all operations. For non-emergency personnel Keep upwind to avoid inhalation of gases, vapours, fumes and smoke. For emergency responders Prevent unauthorized access. Vapours are heavier than air and may spread near ground and travel a considerable distance to a source of ignition and flash back. Use only in well- ventilated areas. Eliminate all ignition sources if safe to do so. 6.2. Environmental precautions Environmental precautions Avoid release to the environment. Stop leak if safe to do so. Avoid the spillage or runoff entering drains, sewers or watercourses. Inform the relevant authorities if environmental pollution occurs (sewers, waterways, soil or air). Risk of soil and ground water contamination. 6.3. Methods and material for containment and cleaning up 3/9 Revision date: 21/08/2017 Supersedes date: 30/07/2015 NESTE LIPA 2 Methods for cleaning up Immediately start clean-up of the liquid and contaminated soil. Large spills should be collected mechanically (remove by pumping) for disposal. Small Spillages: Absorb spillage with sand or other inert absorbent. Pay attention to the fire and health hazards caused by the product. Waste is classified as hazardous waste. 6.4. Reference to other sections Reference to other sections For personal protection, see Section 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions This material is a static accumulator. Avoid heat, flames and other sources of ignition. Take precautionary measures against static discharges. All handling should only take place in well- ventilated areas. Try to avoid product volatilization during handling and transferring. Avoid inhalation of vapours and contact with skin and eyes. Use personal protective equipment and/or local ventilation when needed. Do not eat, drink or smoke when using this product. Wash hands and any other contaminated areas of the body with soap and water before leaving the work site. During tank operations follow special instructions (risk of oxygen displacement and hydrocarbons). 7.2. Conditions for safe storage, including any incompatibilities Storage precautions Flammable liquid storage. Store in accordance with local regulations. Keep container tightly closed, in a cool, well ventilated place. Keep away from food, drink and animal feeding stuffs. Store in a demarcated bunded area to prevent release to drains and/or watercourses. Take precautions against leakage by constructing collecting pools and sewerage systems as well as by surfacing the loading and unloading stations. 7.3. Specific end use(s) Specific end use(s) Not known. SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Occupational exposure limits propan-2-ol Long-term exposure limit (8-hour TWA): 200 ppm 500 mg/m³ Short-term exposure limit (15-minute): 250 ppm 620 mg/m³ HTP 2016/FIN Ingredient comments Solvent naphtha, group 1: 500 mg/m3 (8h), HTP 2016/FIN. The individual limit values can be applied for the hydrocarbons. PNEC Not available. Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% aromatics DNEL Workers - Inhalation; Long term systemic effects: 871 mg/m³ Workers - Dermal; Long term systemic effects: 208 mg/kg/day Consumer - Inhalation; Long term systemic effects: 185 mg/m³ Consumer - Dermal; Long term systemic effects: 125 mg/kg/day Consumer - Oral; Long term systemic effects: 125 mg/kg/day 8.2. Exposure controls 4/9 Revision date: 21/08/2017 Supersedes date: 30/07/2015 NESTE LIPA 2 Appropriate engineering All handling should only take place in well-ventilated areas. Use personal protective controls equipment and/or local ventilation when needed. Handle in accordance with good industrial hygiene and safety practice. Eye/face protection Tight-fitting safety glasses. Face shield when needed. Hand protection Wear protective gloves. It is recommended that gloves are made of the following material: Nitrile rubber. The selected gloves should have a breakthrough time of at least 4 hours. Protection class 5. Protective gloves according to standards EN 420 and EN 374. Change protective gloves regularly. Other skin and body Protective clothing when needed. Wear anti-static protective clothing if there is a risk of protection