Revision date: 21/08/2017 Supersedes date: 30/07/2015
SAFETY DATA SHEET NESTE LIPA 2
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier Product name NESTE LIPA 2
Product number ID 10748
Internal identification 7572
1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Solvent.
1.3. Details of the supplier of the safety data sheet Supplier Neste Markkinointi Oy Keilaranta 21, Espoo, PL 95, FIN-00095 NESTE, FINLAND Tel. +358 10 45811 [email protected]
1.4. Emergency telephone number National emergency telephone +358-9-471 977, +358-9-4711, Poison Information Centre number
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Flam. Liq. 2 - H225
Health hazards Eye Irrit. 2 - H319 STOT SE 3 - H336 Asp. Tox. 1 - H304
Environmental hazards Not Classified
2.2. Label elements
Pictogram
Signal word Danger
Hazard statements H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness.
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Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302+P352 IF ON SKIN: Wash with plenty of water.
Supplemental label EUH066 Repeated exposure may cause skin dryness or cracking. information
Contains Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% aromatics , propan-2-ol
2.3. Other hazards Other hazards Vapours may accumulate on the floor and in low-lying areas., Vapours may form explosive mixtures with air., May cause nausea, headache, dizziness and intoxication.
SECTION 3: Composition/information on ingredients
3.2. Mixtures
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% 70 - 80 % * aromatics CAS number: — REACH registration number: 01- 2119463258-33-XXXX
Classification Flam. Liq. 3 - H226 STOT SE 3 - H336 Asp. Tox. 1 - H304
propan-2-ol 20 - 30 % CAS number: 67-63-0 EC number: 200-661-7 REACH registration number: 01- 2119457558-25-XXXX
Classification Flam. Liq. 2 - H225 Eye Irrit. 2 - H319 STOT SE 3 - H336
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. Composition comments * Contains Benzene (CAS 71-43-2) < 0,1 %. n-hexane (CAS 110-54-3) < 1,0%. Total aromatics at maximum: < 0,5 %.
Other information Identity outside the EU (CAS number and name of the substance):, 64742-48-9, Naphtha (petroleum), hydrotreated heavy., Previous EC number:, 265-150-3.
SECTION 4: First aid measures
4.1. Description of first aid measures Inhalation Remove person to fresh air and keep comfortable for breathing. Get medical attention if symptoms are severe or persist.
Ingestion Do not induce vomiting. Get medical attention immediately.
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Skin contact Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing.
Eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation persists after washing.
4.2. Most important symptoms and effects, both acute and delayed General information Causes eye irritation. Aspiration hazard if swallowed. May cause nausea, headache, dizziness and intoxication. Repeated exposure may cause skin dryness or cracking.
4.3. Indication of any immediate medical attention and special treatment needed Notes for the doctor Treat symptomatically. Aspiration hazard if swallowed. Entry into the lungs following ingestion or vomiting may cause chemical pneumonitis.
SECTION 5: Firefighting measures
5.1. Extinguishing media Suitable extinguishing media Water spray, foam, dry powder or carbon dioxide.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media
5.2. Special hazards arising from the substance or mixture Specific hazards Flammable liquid and vapour. Containers can burst violently or explode when heated, due to excessive pressure build-up. Severe explosion hazard when vapours are exposed to flames.
Hazardous combustion Carbon dioxide (CO2). Carbon monoxide (CO). products
5.3. Advice for firefighters Protective actions during Cool containers exposed to heat with water spray and remove them from the fire area if it can firefighting be done without risk. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective for firefighters clothing.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Avoid inhalation of vapours and contact with skin and eyes. Wear adequate protective equipment at all operations.
For non-emergency personnel Keep upwind to avoid inhalation of gases, vapours, fumes and smoke.
For emergency responders Prevent unauthorized access. Vapours are heavier than air and may spread near ground and travel a considerable distance to a source of ignition and flash back. Use only in well- ventilated areas. Eliminate all ignition sources if safe to do so.
6.2. Environmental precautions Environmental precautions Avoid release to the environment. Stop leak if safe to do so. Avoid the spillage or runoff entering drains, sewers or watercourses. Inform the relevant authorities if environmental pollution occurs (sewers, waterways, soil or air). Risk of soil and ground water contamination.
6.3. Methods and material for containment and cleaning up
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Methods for cleaning up Immediately start clean-up of the liquid and contaminated soil. Large spills should be collected mechanically (remove by pumping) for disposal. Small Spillages: Absorb spillage with sand or other inert absorbent. Pay attention to the fire and health hazards caused by the product. Waste is classified as hazardous waste.
6.4. Reference to other sections Reference to other sections For personal protection, see Section 8.
SECTION 7: Handling and storage
7.1. Precautions for safe handling Usage precautions This material is a static accumulator. Avoid heat, flames and other sources of ignition. Take precautionary measures against static discharges. All handling should only take place in well- ventilated areas. Try to avoid product volatilization during handling and transferring. Avoid inhalation of vapours and contact with skin and eyes. Use personal protective equipment and/or local ventilation when needed. Do not eat, drink or smoke when using this product. Wash hands and any other contaminated areas of the body with soap and water before leaving the work site. During tank operations follow special instructions (risk of oxygen displacement and hydrocarbons).
7.2. Conditions for safe storage, including any incompatibilities Storage precautions Flammable liquid storage. Store in accordance with local regulations. Keep container tightly closed, in a cool, well ventilated place. Keep away from food, drink and animal feeding stuffs. Store in a demarcated bunded area to prevent release to drains and/or watercourses. Take precautions against leakage by constructing collecting pools and sewerage systems as well as by surfacing the loading and unloading stations.
7.3. Specific end use(s) Specific end use(s) Not known.
SECTION 8: Exposure Controls/personal protection
8.1. Control parameters Occupational exposure limits propan-2-ol Long-term exposure limit (8-hour TWA): 200 ppm 500 mg/m³ Short-term exposure limit (15-minute): 250 ppm 620 mg/m³ HTP 2016/FIN
Ingredient comments Solvent naphtha, group 1: 500 mg/m3 (8h), HTP 2016/FIN. The individual limit values can be applied for the hydrocarbons.
PNEC Not available.
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% aromatics
DNEL Workers - Inhalation; Long term systemic effects: 871 mg/m³ Workers - Dermal; Long term systemic effects: 208 mg/kg/day Consumer - Inhalation; Long term systemic effects: 185 mg/m³ Consumer - Dermal; Long term systemic effects: 125 mg/kg/day Consumer - Oral; Long term systemic effects: 125 mg/kg/day
8.2. Exposure controls
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Appropriate engineering All handling should only take place in well-ventilated areas. Use personal protective controls equipment and/or local ventilation when needed. Handle in accordance with good industrial hygiene and safety practice.
Eye/face protection Tight-fitting safety glasses. Face shield when needed.
Hand protection Wear protective gloves. It is recommended that gloves are made of the following material: Nitrile rubber. The selected gloves should have a breakthrough time of at least 4 hours. Protection class 5. Protective gloves according to standards EN 420 and EN 374. Change protective gloves regularly.
Other skin and body Protective clothing when needed. Wear anti-static protective clothing if there is a risk of protection ignition from static electricity.
Respiratory protection Filter device/half mask Gas filter, type A2. Filter device could be used maximum 2 hours at a time. Filter devices must not be used in conditions where the oxygen level is low (< 19 vol.-%). At high concentrations a breathing apparatus must be used (self-contained or fresh air hose breathing apparatus). Filter must be changed often enough. Respirators according to standards EN 140 and EN 141.
Environmental exposure Take precautions against leakage by constructing collecting pools and sewerage systems as controls well as by surfacing the loading and unloading stations.
SECTION 9: Physical and Chemical Properties
9.1. Information on basic physical and chemical properties Appearance Mobile liquid.
Colour Clear.
Odour Strong.
Odour threshold - pH -
Melting point -
Initial boiling point and range > 80°C
Flash point 14°C
Upper/lower flammability or Lower flammable/explosive limit: 2 % Estimated value. Upper flammable/explosive limit: 10 % explosive limits Estimated value.
Vapour pressure 2,6 kPa @ 20°C
Vapour density -
Relative density 0,78 @ 15°C
Solubility(ies) Slightly soluble in water.
Partition coefficient log Kow: 2...7 Hydrocarbons. log Kow: < 0,3 IPA
Auto-ignition temperature > 250°C
Decomposition Temperature -
Viscosity Kinematic viscosity < 7 mm2/s @ 40°C
Explosive properties -
Oxidising properties -
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9.2. Other information Other information -
SECTION 10: Stability and reactivity
10.1. Reactivity Reactivity There are no known reactivity hazards associated with this product.
10.2. Chemical stability Stability No data available.
10.3. Possibility of hazardous reactions Possibility of hazardous No potentially hazardous reactions known. reactions
10.4. Conditions to avoid Conditions to avoid Keep away from heat, sparks and open flame. Take precautionary measures against static discharges.
10.5. Incompatible materials Materials to avoid Strong acids. Oxidising agents.
10.6. Hazardous decomposition products Hazardous decomposition Does not decompose when used and stored as recommended. products
SECTION 11: Toxicological information
11.1. Information on toxicological effects Toxicological effects Based on available data the classification criteria are not met.
Skin corrosion/irritation Skin corrosion/irritation Repeated exposure may cause skin dryness or cracking., Based on available data the classification criteria are not met.
Serious eye damage/irritation Serious eye damage/irritation Causes serious eye irritation.
Skin sensitisation Skin sensitisation Based on available data the classification criteria are not met.
Germ cell mutagenicity Genotoxicity - in vitro Based on available data the classification criteria are not met.
Genotoxicity - in vivo Based on available data the classification criteria are not met.
Carcinogenicity Carcinogenicity Based on available data the classification criteria are not met.
Reproductive toxicity Reproductive toxicity - fertility Based on available data the classification criteria are not met.
Reproductive toxicity - Based on available data the classification criteria are not met. development
Specific target organ toxicity - single exposure STOT - single exposure May cause drowsiness or dizziness.
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Specific target organ toxicity - repeated exposure STOT - repeated exposure Based on available data the classification criteria are not met.
Aspiration hazard Aspiration hazard May be fatal if swallowed and enters airways. Entry into the lungs following ingestion or vomiting may cause chemical pneumonitis.
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% aromatics
Acute toxicity - oral
Notes (oral LD₅₀) LD₅₀ > 5000 mg/kg, Oral, Rat (OECD 401, 423)
Acute toxicity - dermal
Notes (dermal LD₅₀) LD₅₀ > 2000 mg/kg, Dermal, Rabbit (OECD 402)
Acute toxicity - inhalation
Notes (inhalation LC₅₀) LC₅₀ > 4,95 mg/l, Inhalation, Rat (4h) Air. (OECD 403)
SECTION 12: Ecological Information
12.1. Toxicity Toxicity Based on available data the classification criteria are not met.
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% aromatics
Acute toxicity - fish LL₅₀, 96 hours: > 1000 mg/l, LL0, 96 hours: 100 mg/l, (OECD 203)
Acute toxicity - aquatic EL50, 48 hours: > 1000 mg/l, invertebrates EL0, 48 hours: 1000 mg/l, (OECD 202)
Acute toxicity - aquatic EL50, 72 hours: > 1000 mg/l, Fish plants NOELR, 72 hours: 3 - 100 mg/l, Fish (OECD 201)
Chronic toxicity - fish early NOELR, 28 days: 0,13 mg/l, life stage (QSAR)
Chronic toxicity - aquatic NOELR, 21 days: 0,23 mg/l, invertebrates (QSAR)
12.2. Persistence and degradability Phototransformation The product contains volatile substances which may spread in the atmosphere. Can be photodegraded in the atmosphere.
Stability (hydrolysis) No significant reaction in water.
Biodegradation Expected to be readily biodegradable.
12.3. Bioaccumulative potential Bioaccumulative potential Hydrocarbons: Potentially bioaccumulating. IPA: The product is not bioaccumulating.
Partition coefficient log Kow: 2...7 Hydrocarbons. log Kow: < 0,3 IPA
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12.4. Mobility in soil Mobility Volatile. Volatilization is the fastest and most dominant elimination process in surface water and soil. Product can penetrate soil until reaching the surface of ground water. The product contains substances which are bound to particulate matter and are retained in soil.
12.5. Results of PBT and vPvB assessment Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB. assessment
12.6. Other adverse effects Other adverse effects Not known.
SECTION 13: Disposal considerations
13.1. Waste treatment methods General information Waste is classified as hazardous waste.
Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. When handling waste, the safety precautions applying to handling of the product should be considered. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Waste packaging should be collected for reuse or recycling.
SECTION 14: Transport information
14.1. UN number UN No. (ADR/RID) 1993
14.2. UN proper shipping name Proper shipping name UN 1993 FLAMMABLE LIQUID, N.O.S. (isopropanol, solvent naphtha) (ADR/RID)
14.3. Transport hazard class(es) ADR/RID class 3
14.4. Packing group ADR/RID packing group ll
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant No.
14.6. Special precautions for user Tunnel restriction code (D/E)
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code Transport in bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
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EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended). Commission Regulation (EU) No 2015/830 of 28 May 2015. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended).
15.2. Chemical safety assessment A chemical safety assessment has been carried out.
SECTION 16: Other information
Abbreviations and acronyms DNEL = Derived No-Effect Level used in the safety data sheet PNEC = Predicted No-Effect Concentration
Key literature references and Regulations, databases, literature, own research. sources for data
Revision comments Updated, sections: 8, 12 (new SDS software has been introduced)
Revision date 21/08/2017
Supersedes date 30/07/2015
SDS number 5870
Hazard statements in full H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness.
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