Lead Poisoning in the Smelting and Refining of Lead
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
Some Problems and Potentials of the Study of Cupellation
Some problems and potentials of the study of cupellation remains: the case of post-medieval Montbéliard, France Marcos Martinon-Torres, Nicolas Thomas, Thilo Rehren, Aude Mongiatti To cite this version: Marcos Martinon-Torres, Nicolas Thomas, Thilo Rehren, Aude Mongiatti. Some problems and po- tentials of the study of cupellation remains: the case of post-medieval Montbéliard, France. Archeo- sciences, revue d’Archéométrie, G.M.P.C.A./Presses universitaires de Rennes, 2008, pp.59-70. halshs- 00599974 HAL Id: halshs-00599974 https://halshs.archives-ouvertes.fr/halshs-00599974 Submitted on 19 Jun 2011 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Some problems and potentials of the study of cupellation remains: the case of early modern Montbéliard, France Problèmes et perspectives à partir de l’étude des vestiges archéologiques issus de la coupellation : l’exemple du site de Montbéliard (France) Marcos Martinón-Torres*, Nicolas Thomas**, Thilo Rehren*, and Aude Mongiatti* Abstract: Bone-ash cupels are increasingly identified in medieval and later archaeological contexts related to the refining of noble metals in alchemy, assaying, jewellery or coin minting. These small finds may provide information on metal refining activities, the technical knowledge of different craftspeople, and the versatility of laboratory practices, which often differed from the standard protocols recorded in metallurgical treatises. -
Effects of Varied Process Parameters on Froth Flotation Efficiency: a Case Study of Itakpe Iron Ore
Nigerian Journal of Technology (NIJOTECH) Vol. 39, No. 3, July 2020, pp. 807 – 815 Copyright© Faculty of Engineering, University of Nigeria, Nsukka, Print ISSN: 0331-8443, Electronic ISSN: 2467-8821 www.nijotech.com http://dx.doi.org/10.4314/njt.v39i3.21 EFFECTS OF VARIED PROCESS PARAMETERS ON FROTH FLOTATION EFFICIENCY: A CASE STUDY OF ITAKPE IRON ORE S. Akande1, E. O. Ajaka2, O. O. Alabi3 and T. A. Olatunji4,* 1, 2, DEPARTMENT OF MINING ENGINEERING, FEDERAL UNIV. OF TECHNOLOGY, AKURE, ONDO STATE, NIGERIA 3, 4, DEPT. OF MET. & MATERIALS ENGINEERING, FEDERAL UNIV. OF TECHNOLOGY, AKURE, ONDO STATE, NIGERIA Email addresses: 1 [email protected], 2 [email protected], 3 [email protected], 4 [email protected] ABSTRACT The dire need for Itakpe iron ore concentrates of appreciable iron content meets for smelting operation necessitated this study. Core samples of the iron ore sourced from Itakpe, Kogi State, Nigeria were prepared for petrological analysis followed by chemical and particle size analyses. Froth flotation was done using different collectors at varying particle sizes and pH values. Characterization studies carried out revealed that Itakpe iron ore is a lean ore assaying 36.18% Fe2O3 and contains predominantly quartz, sillimanite, and haematite. Its liberation size lies favourably at 75 µm. Processing the ore by froth flotation yielded appreciable enrichment. Optimal recovery (~92%) was achieved using potassium amyl xanthate (PAX) at pH 11 for fine feed sizes (<125 µm) yielding iron concentrate assaying 67.66% Fe2O3. Thus, processing at this set-of- conditions is recommended for the industrial production of more enriched Itakpe iron ore concentrates. -
Principles of Extractive Metallurgy Lectures Note
PRINCIPLES OF EXTRACTIVE METALLURGY B.TECH, 3RD SEMESTER LECTURES NOTE BY SAGAR NAYAK DR. KALI CHARAN SABAT DEPARTMENT OF METALLURGICAL AND MATERIALS ENGINEERING PARALA MAHARAJA ENGINEERING COLLEGE, BERHAMPUR DISCLAIMER This document does not claim any originality and cannot be used as a substitute for prescribed textbooks. The information presented here is merely a collection by the author for their respective teaching assignments as an additional tool for the teaching-learning process. Various sources as mentioned at the reference of the document as well as freely available material from internet were consulted for preparing this document. The ownership of the information lies with the respective author or institutions. Further, this document is not intended to be used for commercial purpose and the faculty is not accountable for any issues, legal or otherwise, arising out of use of this document. The committee faculty members make no representations or warranties with respect to the accuracy or completeness of the contents of this document and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose. BPUT SYLLABUS PRINCIPLES OF EXTRACTIVE METALLURGY (3-1-0) MODULE I (14 HOURS) Unit processes in Pyro metallurgy: Calcination and roasting, sintering, smelting, converting, reduction, smelting-reduction, Metallothermic and hydrogen reduction; distillation and other physical and chemical refining methods: Fire refining, Zone refining, Liquation and Cupellation. Small problems related to pyro metallurgy. MODULE II (14 HOURS) Unit processes in Hydrometallurgy: Leaching practice: In situ leaching, Dump and heap leaching, Percolation leaching, Agitation leaching, Purification of leach liquor, Kinetics of Leaching; Bio- leaching: Recovery of metals from Leach liquor by Solvent Extraction, Ion exchange , Precipitation and Cementation process. -
Corrosion of Refractories in Lead Smelting Reactors
CORROSION OF REFRACTORIES IN LEAD SMELTING REACTORS By LINGXUAN WEI B.Sc, Wuhan University of Science & Technology, China 1986 M.Sc, University of Science & Technology Beijing, China 1997 A THESIS SUBMITTED IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF APPLIED SCIENCE in THE FACULTY OF GRADUATE STUDIES DEPARTMENT OF METALS AND MATERIALS ENGINEERING We accept this thesis as conforming to the required standard THE UNIVERSITY OF BRITISH .UMB1A DECEMBER 2000 ©Lingxuan Wei, ZO0O UBC Special Collections - Thesis Authorisation Form http://www.library.ubc.ca/spcoll/thesauth.html In presenting this thesis in partial fulfilment of the requirements for an advanced degree at the University of British Columbia, I agree that the Library shall make it freely available for reference and study. I further agree that permission for extensive copying of this thesis for scholarly purposes may be granted by the head of my department or by his or her representatives. It is understood that copying or publication of this thesis for financial gain shall not be allowed without my written permission. v 3 The University of British Columbia Vancouver, Canada Date lof 1 3/19/01 2:36 PM ABSTRACT Corrosion of refractories by slag is a complex phenomenon which, depending on the particular system, involves many processes, such as chemical wear (corrosion) and physical or mechanical wear (erosion), which may act synergistically. No single model can explain all cases of corrosion nor can it explain all corrosion mechanisms of a particular refractory in different environments, but the knowledge of the microstructure combined with the chemistry of the systems are necessary to understand the corrosion mechanism of a refractory material. -
Chapter 11: Beneficiation
CHAPTER 11 Beneficiation – Comminution Sponsored by: SPONSOR PROFILE Through pioneering the introduction of modern process • project controls and reporting plants and associated technologies to remote and logistically • contract management challenging locations, Lycopodium Minerals Pty Ltd has • procurement and logistics management developed a successful track record in developing and • inspection and expediting commissioning major resource projects worldwide. • quality assurance/quality control Since its establishment in 1992, Lycopodium has become a • financial evaluations leading international engineering and project management • client representation. consultancy, with an enviable reputation for providing Engineering technically innovative and cost-effective engineering solutions. They are focused on the evaluation and development of projects • Conceptual through to detailed design in the fields of minerals processing, materials handling and • across all disciplines: earthworks, civil infrastructure. • structural, mechanical, piping • electrical, instrumentation, control Lycopodium Minerals has undertaken studies and projects across a broad range of commodities including gold (free, • systems, automation and infrastructure. gravity, refractory, preg robbing), base metals (concentrators, Process hydrometallurgy), iron ore, uranium, rare earths and industrial minerals. Their resume of projects reflects diversity in not • Metallurgical test work design only commodity, but client background, technology, scale of • management and interpretation -
Table of Contents
Table of Contents Preface ........................................... xi Chapter 1. Physical Extraction Operations .................... 1 1.1. Solid-solid and solid-fluid separation operations .............. 1 1.1.1. Flotation ................................... 1 1.1.2. Settling under gravity ........................... 3 1.1.3. Centrifugation ................................ 3 1.1.4. Filtration ................................... 4 1.2. Separation operations of the components of a fluid phase ........ 5 1.2.1. Condensation ................................ 5 1.2.2. Vacuum distillation ............................. 5 1.2.3. Liquation ................................... 6 1.2.4. Distillation .................................. 8 1.2.5. Extractive distillation ........................... 11 1.3. Bibliography ................................... 12 Chapter 2. Hydrometallurgical Operations .................... 15 2.1. Leaching and precipitation operations .................... 15 2.1.1. Leaching and precipitation reactors ................... 15 2.1.2. Continuous stirred tank reactor (CSTR) ................ 18 2.1.3. Models of leaching and precipitation operations ........... 20 2.1.4. Particle-size distribution (PSD) functions ............... 21 2.2. Reactor models based on particle residence time distribution functions ........................................ 24 2.2.1. Performance equations for a single CSTR ............... 24 2.2.2. Performance equations for multistage CSTRs ............. 28 2.3. Reactor models based on the population balance -
Sand, Gravel, and Crushed Stone On-The-Job Training Modules
SAND, GRAVEL, AND CRUSHED STONE ON-THE-JOB TRAINING MODULES Module 17 - “Primary Crushing Operation” UNITED STATES DEPARTMENT OF LABOR ELAINE L. CHAO SECRETARY MINE SAFETY AND HEALTH ADMINISTRATION DAVE D. LAURISKI ASSISTANT SECRETARY Originally Published AUGUST 2000 INSTRUCTION GUIDE SERIES MSHA IG 40 MODULE NUMBER 17 OF INSTRUCTION GUIDE NUMBER 40 ON-THE-JOB TRAINING FOR THE SAND, GRAVEL, AND CRUSHED STONE INDUSTRY PRIMARY CRUSHING OPERATION This module describes basic job steps, potential hazards and accidents, and recommended safe job procedures for primary crushing operations. This job is normally done by the crusher operator, but may be done by other occupations. Crusher operators must protect themselves, and other people in the area, from accidents and injuries resulting from operation of the crusher and associated equipment. There are several different types of primary crushers, however, there are many similarities in the job clxii procedures followed by crusher operators. Crushing is the first step in converting shot rock into usable products. Essentially, crushing is no more than taking large rocks and reducing them to small pieces. Crushing is sometimes continued until only fines remain. At some operations, all the crushing is accomplished in one step, by a primary crusher. At other operations, crushing is done in two or three steps, with a primary crusher that is followed by a secondary crusher, and sometimes a tertiary crusher. Raw material, of various sizes, is brought to the primary crusher by rear-dump haul units, or carried by a wheel front-end loader. Primary crushing reduces this run-of-mine rock to a more manageable size. -
Effect of Comminution Method on Particle Damage and Breakage Energy
EFFECT OF COMMINUTION METHOD ON PARTICLE DAMAGE AND BREAKAGE ENERGY Michael Moats, Jan Miller, Chen-Lun Lin and Raj Rajamani Department of Metallurgical Engineering University of Utah Outline • Our Department • High Pressure Grinding • Particle Damage Characterization • Breakage Energy • Application to Simulant Development Department of Metallurgical Engineering • University of Utah is located in Salt Lake City along the Wasatch Mtns. • Only stand alone Metallurgical Engineering department remaining in the U.S. • Traditional curriculum with critical mass of professors – Mineral Processing – Chemical Metallurgy – Physical Metallurgy High Pressure Grinding Rolls (HPGR) HPGR consists of a pair of counter rotating rolls, one fixed and the other floating. The feed is introduced to the gap in between the rolls and they compress the bed of particles. The grinding force applied to the crushing zone is controlled by a hydro-pneumatic spring on the floating roll. Speeds of the rolls are also adjustable to obtain optimum grinding conditions. Comparison of HPGR and AG/SAG Mills Aspect HPGR AG/SAG Mill Grinding Mechanism Inter-particle compression Impact, attrition and compression Residence Time Low-single pass High (feed migrates through length of mill) Wet/Dry Grinding Dry-Low moisture Predominantly wet milling Availability >90% -2-4 change outs pa >90% -1-2 change outs pa Size regulated feed Required Yes-strongly affects stud breakage AG-No, SAG-Sometimes Critical material size Not required Required Product particle Yes (beneficial for downstream Negligible micro-cracking processes Maximum Throughput 2000tph 4000tph Footprint Small Large Specific power 1-5kWh/t 5-12kWh/t Operating cost Overall plant 20% lower Overall plant 20% higher Capital Cost 25% lower 25% higher Delivery time Substantially faster Substantially longer Variation in feed hardness Single parameter variable High losses •Reference: Koenig, R.L. -
Evaluation of Scale-Up Model for Flotation with Kristineberg Ore
Evaluation of Scale-up Model for Flotation with Kristineberg Ore Adam Isaksson Chemical Engineering, master's level 2018 Luleå University of Technology Department of Civil, Environmental and Natural Resources Engineering Evaluation of Scale-up Model for Flotation with Kristineberg Ore Adam Isaksson 2018 For degree of MASTER OF SCIENCE Luleå University of Technology Department of Civil, Environmental and Natural Resources Engineering Division of Minerals and Metallurgical Engineering Printed by Luleå University of Technology, Graphic Production 2018 Luleå 2018 www.ltu.se Preface As you may have figured out by now, this thesis is all about mineral processing and the extraction of metals. It was written as part of my studies at Luleå University of Technology, for a master’s degree in Chemical Engineering with specialisation Mineral and Metal Winning. There are many people I would like to thank for helping me out during all these years. First of all, my thanks go to supervisors Bertil Pålsson and Lisa Malm for the guidance in this project. Iris Wunderlich had a paramount role during sampling and has kindly delivered me data to this report, which would not have been finished without her support. I would also like to thank Boliden Mineral AB as a company. Partly for giving me the chance to write this thesis in the first place, but also for supporting us students during our years at LTU. Speaking of which, thanks to Olle Bertilsson for reading the report and giving me feedback. The people at the TMP laboratory deserves another mention. I am also very grateful for the financial support and generous scholarships from Jernkontoret these five years. -
Emission Estimation Technique Manual
1DWLRQDO3ROOXWDQW,QYHQWRU\ Emission Estimation Technique Manual for Lead Concentrating, Smelting and Refining First published in December 1999 EMISSION ESTIMATION TECHNIQUES FOR LEAD CONCENTRATING, SMELTING AND REFINING TABLE OF CONTENTS 1.0 INTRODUCTION 1 1.1 Context of this Manual 1 1.2 EETs Should be Considered as “Points of Reference” 2 1.3 Hierarchical Approach Recommended in Applying EETs 3 1.4 NPI Emissions in the Environmental Context 3 1.5 NPI Reporting Requirements 3 1.6 Use of this Manual 4 2.0 PROCESS DESCRIPTION 5 2.1 General 5 2.2 Lead Processing 6 2.2.1 Lead Concentrating 6 2.2.2 Smelting Process 8 2.3 Secondary Lead Processing 11 3.0 ANCILLARY ACTIVITIES AND ASSOCIATED FACILITIES 13 3.1 Ancillary Activities 13 3.1.1 Acid Plant 13 3.1.2 Selenium Removal Process 13 3.1.3 Zinc Recovery 15 3.1.4 Cadmium Plant 15 3.2 Associated Facilities 15 3.2.1 Fuel and Organic Liquid Storage 15 3.2.2 Fossil Fuel Electric Generation 16 3.2.3 Combustion Engines 16 3.3 Maintenance Activities 16 4.0 POSSIBLE EMISSIONS 17 4.1 Reporting Thresholds 19 4.2 Reporting Requirements 21 5.0 EMISSION ESTIMATION 22 5.1 Emission Estimation Techniques 22 5.1.1 Direct Measurement 32 5.1.2 Engineering Calculations 33 5.1.3 Mass Balance 33 5.1.4 Emission Factors 35 5.2 Acceptable Reliability and Uncertainty 36 5.2.1 Direct Measurement 36 5.2.2 Mass Balance 36 5.2.3 Engineering Calculations 37 5.2.4 Emission Factors 37 5.3 NPI Reporting Steps 38 Lead Concentrating, Smelting, and Refining i LEAD CONCENTRATING, SMELTING AND REFINING TABLE OF CONTENTS CONT’ 6.0 -
ENVIRONMENTAL CODE of PRACTICE Base Metals Smelters and Refineries
ENVIRONMENTAL CODE OF PRACTICE C ANADIAN E NVIRONMENTAL P ROTECTION A CT , 1999 First Edition Base Metals Smelters and Refineries March 2006 EPS 1/MM/11 E Metals Section Natural Resource Sectors Pollution Prevention Directorate Environmental Stewardship Branch Environment Canada Library and Archives Canada Cataloguing in Publication Main entry under title: Environmental Code of Practice for Base Metals Smelters and Refineries: Code of Practice, Canadian Environmental Protection Act, 1999. Issued also in French under title: Code de pratiques écologiques pour les fonderies et affineries de métaux communs : Code de pratique de la Loi canadienne sur la protection de l’environnement (1999). “First Edition”. Available also on the Internet. Includes bibliographical references. ISBN 0-662-42221-X Cat. no.: En84-34/2005E EPS 1/MM/11 E 1. Non-ferrous metal industries – Waste disposal – Canada. 2. Non-ferrous metals – Metallurgy – Environmental aspects – Canada. 3. Non-ferrous metals – Refining – Environmental aspects – Canada. 4. Smelting – Environmental aspects – Canada. 5. Best management practices (Pollution prevention) – Canada. i. Canada. Pollution Prevention Directorate. Metals Section. ii. Canada. Environment Canada. TD195.F6E58 2005 669'.028'6 C2005-980316-9 READERS’ COMMENTS Inquiries and comments on this Code of Practice, as well as requests for additional copies of the Code, should be directed to: Metals Section Natural Resources Sectors Division Pollution Prevention Directorate Environmental Stewardship Branch Environment Canada Place Vincent Massey 351 St. Joseph Blvd. Gatineau, Quebec K1A 0H3 Fax (819) 953-5053 Note: Website addresses mentioned in this document may have changed or references cited may have been removed from websites since the publication of the document. -
In the United States District Court for the Southern District of Indiana
Case 1:15-cv-00433-TWP-TAB Document 1 Filed 03/16/15 Page 1 of 20 PageID #: 1 IN THE UNITED STATES DISTRICT COURT FOR THE SOUTHERN DISTRICT OF INDIANA UNITED STATES OF AMERICA ) and the ) STATE OF INDIANA, ) ) Plaintiffs, ) ) ) Civil Action No. 15-cv-433 v. ) ) ) EXIDE TECHNOLOGIES ) (d/b/a EXIDE TECHNOLOGIES, INC.), ) ) ) ) Defendant. ) ) COMPLAINT The United States of America, by the authority of the Attorney General of the United States acting at the request of the Administrator of the United States Environmental Protection Agency (“EPA”), and the State of Indiana (“Indiana”), by the authority of the Indiana Attorney General, acting at the request of the Indiana Department of Environmental Management (“IDEM”), hereby file this Complaint and allege as follows: NATURE OF ACTION 1. This is a civil action brought against Exide Technologies (referred to herein as “Exide” or the “Defendant”) pursuant to the Clean Air Act, 42 U.S.C. § 7401 et seq. and the laws of Indiana. This action seeks civil penalties and injunctive relief for violation of certain requirements under the Clean Air Act and its implementing regulations, as well as corresponding requirements of Indiana law, at a secondary lead smelting facility that Exide owns and operates at 2601 West Mount Pleasant Boulevard, Muncie, Indiana (the “Facility”). Indiana’s authority to Case 1:15-cv-00433-TWP-TAB Document 1 Filed 03/16/15 Page 2 of 20 PageID #: 2 seek injunctive relief and civil fines with respect to the Facility derives not only from the Clean Air Act, but also Indiana Code (“Ind.