Tribology Wear Analysis
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Lubrication Chemistry Viewed from DFT-Based Concepts and Electronic Structural Principles
Int. J. Mol. Sci. 2004, 5, 13-34 International Journal of Molecular Sciences ISSN 1422-0067 © 2004 by MDPI www.mdpi.org/ijms/ Lubrication Chemistry Viewed from DFT-Based Concepts and Electronic Structural Principles Li Shenghua*, Yang He and Jin Yuansheng State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, P.R. China Tel.: +86 (10) 62772509, Fax: +86 (10) 62784691, E-mail: [email protected] URL: http://www.pim.tsinghua.edu.cn/sklt/sklt.html *Author to whom correspondence should be addressed. Received: 16 April 2003 / Accepted: 16 October 2003 / Published: 26 December 2003 Abstract: Fundamental molecular issues in lubrication chemistry were reviewed under categories of solution chemistry, contact chemistry and tribochemistry. By introducing the Density Functional Theory(DFT)-derived chemical reactivity parameters (chemical potential, electronegativity, hardness, softness and Fukui function) and related electronic structural principles (electronegativity equalization principle, hard-soft acid-base principle, and maximum hardness principle), their relevancy to lubrication chemistry was explored. It was suggested that DFT, theoretical, conceptual and computational, represents a useful enabling tool to understand lubrication chemistry issues prior to experimentation and the approach may form a key step in the rational design of lubrication chemistry via computational methods. It can also be optimistically anticipated that these considerations will gestate unique DFT-based strategies to understand sophisticated tribology themes, such as origin of friction, essence of wear, adhesion in MEMS/NEMS, chemical mechanical polishing in wafer manufacturing, stress corrosion, chemical control of friction and wear, and construction of designer tribochemical systems. Keywords: Lubrication chemistry, DFT, chemical reactivity indices, electronic structural principle, tribochemistry, mechanochemistry. -
Tech Spotlight
impact.qxd 3/12/04 11:25 AM Page 1 TECH SPOTLIGHT Impact Testing notched side by the moving striker by the metrology of the parts that are Wayne Hayward pendulum, and the energy needed to subject to the most wear and tear, and Tinius Olsen Testing Machine Co. break off the free end is the measure some machines were manufactured Horsham, Pennsylvania of the impact strength. This article before strict adherence to the specifi- discusses the equipment, calibration, cations in ASTM E23 was deemed to and procedures for Charpy testing. be critical. Accurate results are not pos- he purpose of impact testing is to sible if the equipment is not operating Tdetermine the toughness of a ma- Impact testing equipment according to the specification; there- terial by measuring the amount of en- Instruments for impact testing of fore, it is strongly recommended that ergy absorbed by a specimen as it frac- metals have been manufactured com- the impact tester be calibrated and/or tures while being struck by a striker mercially since the 1900’s, and several verified by an accredited calibration pendulum moving at high speed. The manufacturers of testing equipment service at regular intervals. impact strength is defined as the max- meet the requirements of ASTM E23, imum amount of energy that can be “Standard Test Methods for Notched Instrument calibration absorbed by the specimen without Bar Impact Testing of Metallic Mate- A calibration swing is performed to fracture. rials.” The standard provides dimen- ensure that energy losses due to In the Charpy impact test, a notch sion and tolerance requirements for windage and friction in the bearings is placed in the specimen. -
The Use of Artificial Intelligence in Tribology—A Perspective
lubricants Perspective The Use of Artificial Intelligence in Tribology—A Perspective Andreas Rosenkranz 1,*, Max Marian 2,* , Francisco J. Profito 3, Nathan Aragon 4 and Raj Shah 4 1 Department of Chemical Engineering, Biotechnology and Materials, University of Chile, Santiago 7820436, Chile 2 Engineering Design, Friedrich-Alexander-University Erlangen-Nuremberg (FAU), 91058 Erlangen, Germany 3 Department of Mechanical Engineering, Polytechnic School, University of São Paulo, São Paulo 17033360, Brazil; fprofi[email protected] 4 Koehler Instrument Company, Holtsville, NY 11742, USA; [email protected] (N.A.); [email protected] (R.S.) * Correspondence: [email protected] (A.R.); [email protected] (M.M.) Abstract: Artificial intelligence and, in particular, machine learning methods have gained notable attention in the tribological community due to their ability to predict tribologically relevant pa- rameters such as, for instance, the coefficient of friction or the oil film thickness. This perspective aims at highlighting some of the recent advances achieved by implementing artificial intelligence, specifically artificial neutral networks, towards tribological research. The presentation and discussion of successful case studies using these approaches in a tribological context clearly demonstrates their ability to accurately and efficiently predict these tribological characteristics. Regarding future research directions and trends, we emphasis on the extended use of artificial intelligence and machine learning concepts in the field of tribology including the characterization of the resulting surface topography and the design of lubricated systems. Keywords: artificial intelligence; machine learning; artificial neural networks; tribology 1. Introduction and Background Citation: Rosenkranz, A.; Marian, M.; There have been very recent advances in applying methods of deep or machine Profito, F.J.; Aragon, N.; Shah, R. -
TRIBOLOGY Lecture 3: FRICTION
Video Course on Tribology Prof. Dr Harish Hirani Department of Mechanical Engineering Indian institute of Technology, Delhi Lecture No. # 03 Friction Welcome to the third lecture of video course on Tribology. Topic of this lecture is friction. It is interesting. We experience friction in day to day life when you walk we experience friction, when we cycle we experience friction, when we drive we experience friction. This is very common mode which we experience every day. TRIBOLOGY Lecture 3: FRICTION And often when you go to mall, we find this kind of signal or warning that slippery when the floor is wet. So, you need to be careful when you walk resending the water place as lubricant layer. Some Typical Values of Coefficient of Friction for Metals sliding on themselves Metals Sliding on themselves µ Aluminum 1.5 Copper 1.5 Copper((oxide film not penetrated) 0.5 Gold 2.5 Iron 1.2 Platinum 3 Silver 1.5 Steel(mild steel) 0.8 Steel(tool steel) 0.4 Observations: 1. μ > 1.0 2. Mild steel vs Tool steel 3. μ depends on environment. And it reduces the friction. So, we need to walk with more force. So, the overall the friction force turn out to be same. I have gone through number of books and found number of variation in coefficient of friction. So, I am just showing on the first slide of this course that typical value of coefficient friction which is often quoted in books. We say these values are static coefficient of friction or this value belongs to static coefficient of friction. -
Static Friction at Fractal Interfaces
Dorian Hanaor, Yixiang Gan and Itai Einav (2016). Static friction at fractal interfaces. Tribology International, 93, 229-238. DOI: 10.1016/j.triboint.2015.09.016 Static friction at fractal interfaces Dorian A. H. Hanaor, Yixiang Gan, Itai Einav School of Civil Engineering, University of Sydney, NSW 2006, Australia https://doi.org/10.1016/j.triboint.2015.09.016 Abstract: Tribological phenomena are governed by combined effects of material properties, topology and surface- chemistry. We study the interplay of multiscale-surface-structures with molecular-scale interactions towards interpreting static frictional interactions at fractal interfaces. By spline-assisted-discretization we analyse asperity interactions in pairs of contacting fractal surface profiles. For elastically deforming asperities, force analysis reveals greater friction at surfaces exhibiting higher fractality, with increasing molecular-scale friction amplifying this trend. Increasing adhesive strength yields higher overall friction at surfaces of lower fractality owing to greater true-contact-area. In systems where adhesive-type interactions play an important role, such as those where cold-welded junctions form, friction is minimised at an intermediate value of surface profile fractality found here to be in the regime 1.3-1.5. Our results have implications for systems exhibiting evolving surface structures. Keywords: Contact mechanics, friction, fractal, surface structures 1 Dorian Hanaor, Yixiang Gan and Itai Einav (2016). Static friction at fractal interfaces. Tribology -
Tribology of Polymer Blends PBT + PTFE
materials Article Tribology of Polymer Blends PBT + PTFE Constantin Georgescu 1,* , Lorena Deleanu 1,*, Larisa Chiper Titire 1 and Alina Cantaragiu Ceoromila 2 1 Department of Mechanical Engineering, Faculty of Engineering, “Dunarea de Jos” University of Galati, 800008 Galati, Romania; [email protected] 2 Department of Applied Sciences, Cross-Border Faculty, “Dunarea de Jos” University of Galati, 800008 Galati, Romania; [email protected] * Correspondence: [email protected] (C.G.); [email protected] (L.D.); Tel.: +40-743-105-835 (L.D.) Abstract: This paper presents results on tribological characteristics for polymer blends made of polybutylene terephthalate (PBT) and polytetrafluoroethylene (PTFE). This blend is relatively new in research as PBT has restricted processability because of its processing temperature near the degradation one. Tests were done block-on-ring tribotester, in dry regime, the variables being the PTFE concentration (0%, 5%, 10% and 15% wt) and the sliding regime parameters (load: 1, 2.5 and 5 N, the sliding speed: 0.25, 0.5 and 0.75 m/s, and the sliding distance: 2500, 5000 and 7500 m). Results are encouraging as PBT as neat polymer has very good tribological characteristics in terms of friction coefficient and wear rate. SEM investigation reveals a quite uniform dispersion of PTFE drops in the PBT matrix. Either considered a composite or a blend, the mixture PBT + 15% PTFE exhibits a very good tribological behavior, the resulting material gathering both stable and low friction coefficient and a linear wear rate lower than each component when tested under the same conditions. Keywords: polybutylene terephthalate (PBT); polytetrafluoroethylene (PTFE); blend PBT + PTFE; block-on-ring test; linear wear rate; friction coefficient Citation: Georgescu, C.; Deleanu, L.; Chiper Titire, L.; Ceoromila, A.C. -
Galling and Galling Resistance of Stainless Steels
Stainless Steel Advisory Service Tel: 0114 267 1265 Fax 0114 266 1252 A service provided by the SSAS Information Sheet No.5.60 th British Stainless Steel Association Issue 02 12 March 2001 Page 1 of 1 Galling and Galling Resistance of Stainless Steels Introduction Galling, or cold welding as it is sometimes referred to as, is a form of severe adhesive wear. Adhesive wear occurs between two metal surfaces that are in relative motion to each other and under sufficient load to permit the transfers of material between themselves. This is a solid-phase welding process. The load must be sufficient, during relative motion, to disrupt the protective oxide layer covering surface asperities of the metal and permit metal to metal contact. Under high stress and poor lubrication conditions, stronger bonds may form over a larger surface area. Large fragments or surface protrusions may be formed and the result is galling of the surfaces. Severe galling can result in the seizure of metal components. Materials which are highly ductile or which possess low work-hardening rates tend to be prone to galling. Austenitic stainless steels show a tendency to gall under certain conditions. Factors Affecting Wear and Galling The factors affecting wear and galling are related to design, lubrication, environment, and steel properties. The material properties relevant to the issue of galling of stainless steels include: - • design tolerances and surface finish of the steel • surface properties (hardness) and structure of the steel • applied load • contact area and degree of movement. Design tolerances should provide sufficient clearance. The contact load on sliding components should be kept to a minimum, while the contact area should be maximised. -
Vertical Turbine Pumps Models VIT, VIC & VIS
An ITT Brand Vertical Turbine Pumps Models VIT, VIC & VIS Flexibility by Design: This bulletin is designed to assist the user in selecting Three Pump Models, One Common Bowl Assembly the best pump for the conditions required; however, any The three different pump models in the vertical turbine line questions will be answered promptly by calling the Goulds have one thing in common – the hydraulic design of the sales office or representative in your area. pump bowl assembly. Using state-of-the-art techniques in turbine pump design, Goulds vertical turbine line covers a wide range of hydraulic conditions to meet virtually every pumping service in the industry with optimum efficiency. Goulds flexibility of design allows the use of a wide range of materials and design features to meet the custom requirements of the user. No matter what the requirements, Goulds can design and manufacture the pump to best satisfy them, specifically and thoroughly. Driver Discharge Driver Adapter Fabricated Fabricated Discharge Discharge Head Head Bowl Assembly Flanged Flanged Column Column Suction Can Adapter Bowl BoBowlwl Assembly Submersible Assembly Assembly Motor 2 Vertical Turbine Pumps Vertical Turbine Pumps Goulds Vertical Turbine Pumps Pump Bowl Assembly The bowl assembly is the heart of the vertical turbine pump. The impeller and diffuser type casing are designed to deliver the head and capacity that your system requires in the most efficient way possible. The fact that the vertical turbine pump can be multi-staged allows maximum flexibility both in the initial pump selection and in the event that future system modifications require a change in the pump rating. -
Analysis of Fatigue and Wear Behaviour in Ultrafine Grained Connecting Rods
metals Article Analysis of Fatigue and Wear Behaviour in Ultrafine Grained Connecting Rods Rodrigo Luri, Carmelo J. Luis, Javier León, Juan P. Fuertes, Daniel Salcedo and Ignacio Puertas * Mechanical, Energetics and Materials Engineering Department, Public University of Navarre, Campus Arrosadía s/n, Pamplona 31006, Spain; [email protected] (R.L.); [email protected] (C.J.L.); [email protected] (J.L.); [email protected] (J.P.F.); [email protected] (D.S.) * Correspondence: [email protected]; Tel.: +34-948-169-305 Received: 3 July 2017; Accepted: 20 July 2017; Published: 29 July 2017 Abstract: Over the last few years there has been an increasing interest in the study and development of processes that make it possible to obtain ultra-fine grained materials. Although there exists a large number of published works related to the improvement of the mechanical properties in these materials, there are only a few studies that analyse their in-service behaviour (fatigue and wear). In order to bridge the gap, in this present work, the fatigue and wear results obtained for connecting rods manufactured by using two different aluminium alloys (AA5754 and AA5083) previously deformed by severe plastic deformation (SPD), using Equal Channel Angular Pressing (ECAP), in order to obtain the ultrafine grain size in the processed materials are shown. For both aluminium alloys, two initial states were studied: annealed and ECAPed. The connecting rods were manufactured from the previously processed materials by using isothermal forging. Fatigue and wear experiments were carried out in order to characterize the in-service behaviour of the components. -
Low Alloy Steel Susceptibility to Stress Corrosion Cracking in Hydraulic
LOW ALLOY STEEL SUSCEPTIBILITY TO STRESS CORROSION CRACKING IN HYDRAULIC FRACTURING ENVIRONMENT Thesis Submitted to The School of Engineering of the UNIVERSITY OF DAYTON In Partial Fulfillment of the Requirements for The Degree of Master of Science in Chemical Engineering By Ezechukwu J. Anyanwu Dayton, OH May, 2014 LOW ALLOY STEEL SUSCEPTIBILITY TO STRESS CORROSION CRACKING IN HYDRAULIC FRACTURING ENVIRONMENT Name: Anyanwu, Ezechukwu John APPROVED BY: ______________________ ________________________ Douglas C. Hansen, Ph.D. Sean C. Brossia, Ph.D. Advisory Committee Chairman Research Advisor Research Advisor and Professor Senior Vice President and Chemical and Materials Engineering Senior Principal Engineer DYCE USA ________________________ Robert J. Wilkens, Ph.D., P.E. Committee Member Professor Chemical and Materials Engineering _______________________ ________________________ John G. Weber, Ph.D. Tony E. Saliba, Ph.D. Associate Dean Dean, School of Engineering School of Engineering and Wilke Distinguished Professor ii ABSTRACT LOW ALLOY STEEL SUSCEPTIBILITY TO STRESS CORROSION CRACKING IN HYDRAULIC FRACTURING ENVIRONMENT Name: Anyanwu, Ezechukwu John University of Dayton Research Advisors: Dr. Douglas C. Hansen Dr. Sean C. Brossia The pipelines used for hydraulic fracturing (aka. “fracking”) are often operating at a pressure above 10000psi and thus are highly susceptible to Stress Corrosion Cracking (SCC). This is primarily due to the process of carrying out fracturing at a shale gas site, where the hydraulic fracturing fluid is pumped through these pipes at very high pressure in order to initiate fracture in the shale formation. While the fracturing fluid is typically more than 99% water, other components are used to perform various functions during the fracturing process. Research into the occurrence of SCC reveals that SCC is engendered by a number of factors, of which two main contributors are stress in iii the pipe steel and a particular type of corrosive environment in contact with the pipeline in the service setting. -
3Rd Edition A.R
WEAR – MATERIALS, MECHANISMS AND PRACTICE Editors: M.J. Neale, T.A. Polak and M. Priest Guide to Wear Problems and Testing for Industry M.J. Neale and M. Gee Handbook of Surface Treatment and Coatings M. Neale, T.A. Polak, and M. Priest (Eds) Lubrication and Lubricant Selection – A Practical Guide, 3rd Edition A.R. Lansdown Rolling Contacts T.A. Stolarski and S. Tobe Total Tribology – Towards an integrated approach I. Sherrington, B. Rowe and R. Wood (Eds) Tribology – Lubrication, Friction and Wear I.V. Kragelsky, V.V. Alisin, N.K. Myshkin and M.I. Petrokovets Wear – Materials, Mechanisms and Practice G. Stachowiak (Ed.) WEAR – MATERIALS, MECHANISMS AND PRACTICE Edited by Gwidon W. Stachowiak Copyright © 2005 John Wiley & Sons Ltd, The Atrium, Southern Gate, Chichester, West Sussex PO19 8SQ, England Telephone (+44) 1243 779777 Chapter 1 Copyright © I.M. Hutchings Email (for orders and customer service enquiries): [email protected] Visit our Home Page on www.wiley.com Reprinted with corrections May 2006 All Rights Reserved. No part of this publication may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning or otherwise, except under the terms of the Copyright, Designs and Patents Act 1988 or under the terms of a licence issued by the Copyright Licensing Agency Ltd, 90 Tottenham Court Road, London W1T 4LP, UK, without the permission in writing of the Publisher. Requests to the Publisher should be addressed to the Permissions Department, John Wiley & Sons Ltd, The Atrium, Southern Gate, Chichester, West Sussex PO19 8SQ, England, or emailed to [email protected], or faxed to (+44) 1243 770620. -
Tribology Module3: Wear
Tribology Module3: Wear Q.1. Why subsurface cracks are formed due to cyclic load? Ans: Cyclic loading often causes repetitive reversal of stresses, such as compressive stress to tensile stress. Due to such change in stresses, material experiences tiredness. Microstructure in-homogeneity, under tiring load condition, helps the formation of subsurface cracks. Q.2. What is zero wear limits? Ans: “Zero wear” means wear of material surfaces remains within the order of the surface finish. In other words “Zero wear limit” is the initial surface roughness of the material. Q.3. If indium has so high affinity that causes adhesive wear then why do we use it? Can indium be used as lubricant between two steel surfaces? Ans: Because of high affinity of indium, it is used to bond certain non-metallic such as glass, glazed, xeramics, mica, quartz, various metallic oxides, etc. It can be used as solid lubricant between two steel surfaces. Q.4. In adhesion wear taking place between similar materials, which surface is likely to get more damage? Won’t the chuck of particles be with the lower surface in case of similar surface? Ans: The outcome of adhesive wear is growing roughness and creation of lumps above the original surface. Lose of material from the surface depends on the softness of material. Softer material loses more material compared to harder material. In other words nothing can be said about which surface (lower/upper) will lose more material. Lose of material will depend on local hardness of the material. Q.5. What is “back transfer”? Ans: In adhesive wear, material is transferred from one material to other.