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MATERIAL SAFETY DATA SHEET Diisobutylaluminium Hydride, 1.0M Solution in Heptane

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MATERIAL SAFETY DATA SHEET Diisobutylaluminium Hydride, 1.0M Solution in Heptane MATERIAL SAFETY DATA SHEET Diisobutylaluminium hydride, 1.0M solution in heptane Section 1 ­ Chemical Product and Company Identification MSDS Name: Diisobutylaluminium hydride, 1.0M solution in heptane Catalog Numbers: 20105­0000, 20105­1000, 20105­8000 Synonyms: DIBAL­H, 1.0M solution in heptane Company Identification: Acros Organics BVBA Janssen Pharmaceuticalaan 3a 2440 Geel, Belgium Company Identification: (USA) Acros Organics One Reagent Lane Fair Lawn, NJ 07410 For information in the US, call: 800­ACROS­01 For information in Europe, call: +32 14 57 52 11 Emergency Number, Europe: +32 14 57 52 99 Emergency Number US: 201­796­7100 CHEMTREC Phone Number, US: 800­424­9300 CHEMTREC Phone Number, Europe: 703­527­3887 Section 2 ­ Composition, Information on Ingredients CAS# Chemical Name: % EINECS# Hazard Symbols: Risk Phrases: 142­82­5 Heptane (n­) 80 205­563­8 F N XN 11 38 50/53 65 67 1191­15­7 Diisobutylaluminum hydride 20 214­729­9 F C 14/15 17 35 Text for R­phrases: see Section 16 Hazard Symbols: F C N Risk Phrases: 11 14/15 35 50/53 65 67 Section 3 ­ Hazards Identification EMERGENCY OVERVIEW Highly flammable. Reacts violently with water liberating extremely flammable gases. Causes severe burns. Very toxic to aquatic organisms, may cause long­term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Vapours may cause drowsiness and dizziness. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. May cause lung damage. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Section 4 ­ First Aid Measures Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Treat symptomatically and supportively. Physician: Section 5 ­ Fire Fighting Measures General As in any fire, wear a self­contained breathing apparatus in pressure­demand, Information: MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Flammable liquid and vapor. Extinguishing Use dry sand or earth to smother fire. DO NOT USE WATER! Use dry chemical. Media: Section 6 ­ Accidental Release Measures General Use proper personal protective equipment as indicated in Section 8. Information: Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Use a spark­proof tool. Do not expose spill to water. Section 7 ­ Handling and Storage Handling: Do not allow water to get into the container because of violent reaction. Use spark­proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Do not allow contact with water. Use only in a chemical fume hood. Storage: Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables­area. Corrosives area. Water free area. Store under nitrogen. Section 8 ­ Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion­proof ventilation to keep airborne levels to acceptable levels. Exposure Limits CAS# 142­82­5: United Kingdom, WEL ­ TWA: 500 ppm TWA United Kingdom, WEL ­ STEL: 1500 ppm STEL United States OSHA: 500 ppm TWA; 2000 mg/m3 TWA Belgium ­ TWA: 400 ppm VLE; 1664 mg/m3 VLE Belgium ­ STEL: 500 ppm VLE; 2085 mg/m3 VLE France ­ VME: 500 ppm VME; 2085 mg/m3 VME Germany: 500 ppm TWA; 2100 mg/m3 TWA Japan: 200 ppm OEL; 820 mg/m3 OEL Malaysia: 400 ppm TWA; 1640 mg/m3 TWA Netherlands: 400 ppm STEL; 1600 mg/m3 STEL Netherlands: 300 ppm MAC; 1200 mg/m3 MAC Spain: 500 ppm VLA­ED; 2085 mg/m3 VLA­ED CAS# 1191­15­7: Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 ­ Physical and Chemical Properties Physical State: Clear liquid Color: colorless Odor: solvent odor pH: 7 Vapor Pressure: Not available Viscosity: Not available Boiling Point: Not available Freezing/Melting Point: ­70 deg C ( ­94.00°F) Autoignition Temperature: Not available Flash Point: ­1 deg C ( 30.20 deg F) Explosion Limits: Lower: Not available Explosion Limits: Upper: Not available Decomposition Temperature: Solubility in water: vigorous reaction Specific Gravity/Density: 0.700 Molecular Formula: C8H19Al Molecular Weight: 142.22 Section 10 ­ Stability and Reactivity Chemical Stability: Air sensitive. Reacts violently with water. Moisture sensitive. Conditions to Avoid: Incompatible materials, ignition sources, exposure to air, exposure to moist air or water, evaporating to near dryness, allowing solvents to evaporate, temperatures above 120°C. Incompatibilities with Water, acidic conditions, strong oxidizing agents, acids, alcohols, oxygen, Other Materials organic halides. Hazardous Carbon monoxide, carbon dioxide, aluminum oxide, aluminum fumes. Decomposition Products Hazardous Has not been reported. Polymerization Section 11 ­ Toxicological Information RTECS#: CAS# 142­82­5: MI7700000 CAS# 1191­15­7: BD0710000 LD50/LC50: RTECS: CAS# 142­82­5: Inhalation, rat: LC50 = 103 gm/m3/4H; . RTECS: CAS# 1191­15­7:. Carcinogenicity: Heptane (n­) ­ Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. Diisobutylaluminum hydride ­ Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. Other: The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information. Section 12 ­ Ecological Information Other: Harmful to aquatic life in very low concentrations. Section 13 ­ Disposal Considerations Dispose of in a manner consistent with federal, state, and local regulations. Section 14 ­ Transport Information IATA IMO RID/ADR ORGANOMETALLIC SUBSTANCE, LIQUID, ORGANOMETALLIC ORGANOMETALLIC Shipping WATER­ SUBSTANCE, LIQUID, SUBSTANCE, LIQUID, Name: REACTIVE,FLAMMABLE* WATER­ WATER­ (forbidden to ship via REACTIVE,FLAMMABLE REACTIVE,FLAMMABLE passenger air) Hazard 4.3 (3) 4.3 (3) 4.3 (3) Class: UN 3399 3399 3399 Number: Packing I I I Group: Section 15 ­ Regulatory Information European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: F C N Risk Phrases: R 11 Highly flammable. R 14/15 Reacts violently with water liberating extremely flammable gases. R 35 Causes severe burns. R 50/53 Very toxic to aquatic organisms, may cause long ­term adverse effects in the aquatic environment. R 65 Harmful: may cause lung damage if swallowed. R 67 Vapours may cause drowsiness and dizziness. Safety Phrases: S 6A Keep under nitrogen. S 16 Keep away from sources of ignition ­ No smoking. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 43A In case of fire, use dry chemical (never use water). S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 142­82­5: 1 CAS# 1191­15­7: 2 Canada CAS# 142­82­5 is listed on Canada's DSL List CAS# 1191­15­7 is listed on Canada's DSL List US Federal TSCA CAS# 142­82­5 is listed on the TSCA Inventory. CAS# 1191­15­7 is listed on the TSCA Inventory. Section 16 ­ Other Information Text for R­phrases from Section 2 R 11 Highly flammable. R 14/15 Reacts violently with water liberating extremely flammable gases. R 17 Spontaneously flammable in air. R 35 Causes severe burns. R 38 Irritating to skin. R 50/53 Very toxic to aquatic organisms, may cause long ­term adverse effects in the aquatic environment. R 65 Harmful: may cause lung damage if swallowed. R 67 Vapours may cause drowsiness and dizziness. MSDS Creation Date: 3/09/2004 Revision #1 Date 1/04/2005 Revisions were made in Sections: General revision. The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantibility or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the company has been advised of the possibility of such damages. ­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­ .
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