Smart Plastics Guide Healthier Food Uses of Plastics
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Analysis of Chemical Leaching from Common Consumer Plastic Bottles Under High Stress Conditions
AN ABSTRACT OF THE THESIS OF Paul John Dornath for the degree of Honors Baccalaureate of Science in Chemical Engineering presented on May 29, 2010. Title: Analysis of Chemical Leaching from Common Consumer Plastic Bottles Under High Stress Conditions Abstract approved: ______________________________________________ Skip Rochefort There has been much controversy in recent years over the leaching of chemicals from plastic water bottles. In this study, two of the most common plastics used in water bottles, polyethylene terphthalate (PETE) and polycarbonate (PC) were studied. The leaching of the chemical bisphenol-A (BPA) from polycarbonate (Nalgene ™, Camelback ™) water bottles was studied to examine the validity of these claims by exposing polycarbonate bottles to various conditions and analyzing how much BPA leaches into water contained in the bottles. New polycarbonate bottles were filled with water and exposed to treatment conditions ranging from 65 to 120 ⁰C. A reverse-phase solid phase extraction process was developed to extract BPA from the water and concentrate it into an organic phase. GC/MS was used to analyze the organic extract. BPA was only found to leach in detectable amounts (< 10ppb) when the bottles were exposed to 120 ⁰C water for 2 hours. Polyethylene terephthalate bottles were also tested and were exposed to sunlight for three months during the summer. Small amounts of the plasticizer DEHP were found to leach after several months. A method for determining what chemicals would leach from BPA-Free Tritan™ copolyester was also developed but not tested due to time constraints. An analysis of internal stress due to high humidity and temperature was performed on these BPA-Free bottles. -
Polycarbonate Lenses
Polycarbonate Lenses The most impact resistant of all lens materials is polycarbonate. Children, athletes, anyone working at a job or hobby where they might get hit in the face and need safety glasses, people with only one eye, those who fall a lot, are natural candidates for polycarbonate lenses. If safety is a prime concern, choose polycarbonate lenses. Advantages of polycarbonate lenses : 1. Polycarbonate has four to five times the impact resistance of glass or plastic. When glass or plastic lenses break, they do not break into harmless granules, but can break into sharp shards that can enter your eye and destroy your vision. Poly- carbonate is far and away the safest of all the lenses made. 2. Polycarbonate is the lightest lens material made. 3. Polycarbonate lenses naturally provide protection against ultra-violet light, at no additional charge. 4. Polycarbonate lenses come with a scratch resistant coating (not scratch proof) at no additional charge. 5. Polycarbonate is a high index material, so the lenses will be thinner than if made with glass or plastic. Disadvantages of polycarbonate lenses : 1. People in prescriptions with higher powers sometimes have trouble seeing out the edges of the lenses--your clear field of vision is not as wide as with glass or plas- tic lenses. The lenses are made with different curves than are used to make the same pre- scription power in glass or plastic, so you will see out of these lenses a little dif- ferently. People with prescriptions up to plus or minus three diopters (most people) usually have no problem adjusting to polycarbonate lenses. -
Migration of Bisphenol a from Polycarbonate Plastic of Different Qualities
Migration of bisphenol A from polycarbonate plastic of different qualities Environmental project No. 1710, 2015 [Series Title and year] Title: Editing: Migration of Bisphenol A from polycarbonate Gitte Alsing Pedersen, DTU National Food Institute, plastic of different qualities Søren Hvilsted, DTU Danish Polymer Centre, Department of Chemical and Biochemical Engineering and Jens Højslev Petersen, DTU National Food Institute Technical University of Denmark Published by: The Danish Environmental Protection Agency Strandgade 29 1401 Copenhagen K Denmark www.mst.dk/english Year: ISBN no. 2015 978-87-93352-24-7 Disclaimer: When the occasion arises, the Danish Environmental Protection Agency will publish reports and papers concerning research and development projects within the environmental sector, financed by study grants provided by the Danish Environmental Protection Agency. It should be noted that such publications do not necessarily reflect the position or opinion of the Danish Environmental Protection Agency. However, publication does indicate that, in the opinion of the Danish Environmental Protection Agency, the content represents an important contribution to the debate surrounding Danish environmental policy. Sources must be acknowledged. 2 Migration of Bisphenol A from polycarbonate plastic of different qualities Contents Foreword .................................................................................................................. 5 Conclusion and Summary ......................................................................................... -
Changes in Packaging Impact Recycling Right in Santa Cruz
Page 4 Spring 2016 Changes in Packaging … packaging material is clamshell and (Continued from Page 1) blister packaging—those plastic shells ❝❞ that cover new toys and other products What’s New? in a kid-friendly, squeezable plastic pouch. and the clear, hinged boxes that hold deli Check out the new Plastic pouches may also hold yogurt, rice, foods and produce. Clamshell packaging, Recycle Right! videos soup, coffee beans, cat food and snack which is designed for single-use and has on the City website. foods. Pouches are made up of polyester, practically no value in the recycling market, You can find out exactly aluminum foil, polyethylene, Mylar and is therefore destined for the landfill. Most what’s recyclable in your more, plus added spouts, caps, straws “clamshells” are made out of PET (plastic curbside recycle cart and or zipping mechanisms of various other resin code #1)—a highly recyclable plastic. what’s not. The short types of plastic. This packaging is almost However, clamshells are produced from (831) 420-5160 videos are divided into impossible to clean and difficult to recycle. a process known as “thermoforming,” www.cityofsantacruz.com different materials, so if If you and your kids love squeezable snack which changes the composition of the PET, you have questions about pouches, there is a reusable “kindness making them different from PET plastic Spring 2016 metal recycling, glass pouch” available from Squooshi™. bottles, which are blow molded. This slight or plastic bags, you can Have you ever noticed a number on the difference makes clamshells undesirable watch that segment. -
Blends of Polycarbonate Containing Fluorinated-Bisphenol-A and Polyvinyl Chloride
Europaisches Patentamt European Patent Office © Publication number: 0 576 057 A1 Office europeen des brevets EUROPEAN PATENT APPLICATION © Application number: 93201533.2 int. Ci.5; C08L 69/00, C08L 27/06, C08G 64/10, //(C08L69/00, @ Date of filing: 28.05.93 27:06),(C08L27/06,69:00) © Priority: 01.06.92 US 891032 © Applicant: ENICHEM S.p.A. Piazza della Repubblica, 16 @ Date of publication of application: 1-20124 Milano(IT) 29.12.93 Bulletin 93/52 @ Inventor: Drzewinski, Michael A. © Designated Contracting States: 371 Clarksville Road, Princeton Junction AT BE CH DE DK ES FR GB GR IE IT LI LU MC New Jersey 08850(US) NL PT SE © Representative: Roggero, Sergio et al Ing. Barzano & Zanardo Milano S.p.A. Via Borgonuovo 10 1-20121 Milano (IT) © Blends of polycarbonate containing fluorinated-bisphenol-A and polyvinyl chloride. © Bisphenol A polycarbonate containing at least 15 mole % of 2,2-bis-(4-hydroxyphenyl)hexafluoropropane (6F-Bisphenol A) can be blended with polyvinyl chloride (PVC) to form a thermodynamically miscible, transpar- ent, single phase blend at all compositions. Such blends are flame resistant as well as resistant to attack by acids, bases and many organic solvents. CO Rank Xerox (UK) Business Services (3. 10/3.6/3.3. 1) EP 0 576 057 A1 BACKGROUND OF THE INVENTION Field of the Invention: 5 This invention pertains to mixtures of polyvinyl chloride (PVC) and polycarbonates which contain at least 15 mole % of fluorinated bisphenol monomer units (F-PC) such as 2,2-bis-(4-hydroxyphenyl)- hexafluoropropane (6F-bisphenol A), herein referred to as 6F-PC. -
SOP 408 Biosafety Level-2 (BSL-2) Rodent Husbandry
STANDARD OPERATING PROCEDURES DIVISION OF COMPARATIVE MEDICINE UNIVERSITY OF SOUTH FLORIDA SOP#: 408.14 Date Issued: 10/98 Date Revised: 5/19 Page 1 of 6 TITLE: Animal Biosafety Level-2 (ABSL-2) Rodent Husbandry SCOPE: All Authorized Personnel RESPONSIBILITY: Facility Manager and Technical Staff PURPOSE: To Outline the Proper Procedures for Safe Husbandry Practices for Rodents Housed at ABSL-2. I. PURPOSE 1. To outline the proper procedures for safely conducting husbandry of rodents housed under animal biosafety level 2 (ABSL-2) conditions. 2. Reduce the risk of exposure of research and animal care staff to biohazardous agents within the animal facility. II. RESPONSIBILITY 1. The Facility Manager is responsible for ensuring: a. That staff contributing to husbandry are adequately trained to perform the husbandry practices described. b. Implementation of the procedures described. c. Dedicated ABSL-2 rooms for infectious agents, and animal housing rooms for rDNA and PDX biocontainment at the cage level are clearly labeled with the biohazardous agent present and specific safety practices implemented. d. Appropriate personal protective equipment (PPE) is available. e. Biohazard Safety Data Sheets (SDSs) are accessible, when available. f. Safety practices have been communicated to the relevant personnel. 2. It is the responsibility of the animal care staff to: a. Read, understand, and follow the procedures described. b. Don appropriate PPE and review room signage and SDS prior to implementing the procedures described. III. PROCEDURES 1. Containment -
Nylons: a Review of the Literature on Products of Combustion and Toxicity
— |MH|||| I A111DS l&BTIO NBSIR 85-3280 Nylons: A Review of the Literature on Products of Combustion and Toxicity NBS Reference PUBLICATIONS Emil Braun Barbara C. Levin U S. DEPARTMENT OF COMMERCE National Bureau of Standards National Engineering Laboratory Center for Fire Research Gaithersburg, MD 20899 February 1986 Sponsored in part by: U.S. Consumer Product Safety Commission — • q c — asda, MD 20207 100 • U56 85-3280 1986 NBS keseaech informattojt CENTER NBSIR 85-3280 NYLONS: A REVIEW OF THE LITERATURE ON PRODUCTS OF COMBUSTION AND TOXICITY Emil Braun Barbara C. Levin U S. DEPARTMENT OF COMMERCE National Bureau of Standards National Engineering Laboratory Center for Fire Research Gaithersburg, MD 20899 February 1986 Sponsored in part by: U.S. Consumer Product Safety Commission Bethesda, MD 20207 U.S. DEPARTMENT OF COMMERCE, Malcolm Baldrige, Secretary NATIONAL BUREAU OF STANDARDS. Ernest Ambler. Director 21 TABLE OF CONTENTS Page LIST OF TABLES iv LIST OF FIGURES vii ABSTRACT 1 1.0 INTRODUCTION 2 2.0 CHEMICAL STRUCTURE AND THERMOPHYSICAL PROPERTIES 4 3.0 DECOMPOSITION 5 3.1 VACUUM PYROLYSIS 7 3.2 DECOMPOSITION IN INERT AND AIR ATMOSPHERES 8 3.2.1 GENERAL DECOMPOSITION PRODUCTS 8 3.2.2 SPECIFIC GAS SPECIES 11 3.2.2. PURE MATERIALS 11 3. 2. 2. COMPOSITE MATERIALS 14 4.0 TOXICITY 17 4.1 DIN 53 436 19 4.2 FAA TOXICITY PROTOCOL 20 4.3 NASA/USF TOXICITY PROTOCOL 22 4.5 MISCELLANEOUS 27 5.0 LARGE-SCALE TESTS 31 6.0 CONCLUSIONS 35 7.0 ACKNOWLEDGEMENTS 36 8.0 REFERENCES 37 iii LIST OF TABLES Page TABLE 1. -
FLEX™ Tubing Products
™ FLEX Tubing Products Contents Page The Right Tubing…at the Right Price Selection Guide for FLEX Tubing Products . 3 Tubing Conversion Chart . 3 Quality ClearFLEX 60 PVC Tubing . 4 Premium-quality FLEX tubing is made from the finest virgin resins, with no fillers or extenders. Our precision Crystal clear tubing that complies with USP Class VI, USDA and FDA CFR 21 extrusion process ensures close tol- requirements. Available in metric sizes as erances and excellent concentricity ClearFLEX M60 and vacuum-rated sizes for reliable, leakproof connections. as ClearFLEX V60. Adherence to the strict guide lines of our ISO 9001: 2000-registered ClearFLEX 70 PVC Tubing . 5 Quality Management System ensures consistent tubing – Crystal clear tubing that complies with lot after lot – with full traceability. USP Class VI, NSF 51, 3A, USDA and FDA CFR 21 requirements. Performance FLEX Tu b i ng Products are available in a variety of materi- als and sizes to meet virtually any fluid transfer need. And we offer a full range of regulatory compliance for food, FuelFLEX 65 PVC Fuel Tubing . 6 beverage, dairy, pharmaceutical, biotechnology and med- For intermittent use with petroleum-based ical applications. products such as gasoline, heating oils, cutting compounds and coolants. Service We support you with responsive, personalized service from your initial inquiry to the completion BraidFLEX 70N Braid-Reinforced PVC Tubing . 6 of your order. And our new website For higher-pressure applications, including allows you to check tubing specifications lab, food and beverage use. Complies and submit technical questions and with FDA CFR 21 for food packaging and inquiries at your convenience, 24 hours NSF-51. -
The Recent Developments in Biobased Polymers Toward
polymers Review The Recent Developments in Biobased Polymers toward General and Engineering Applications: Polymers that Are Upgraded from Biodegradable Polymers, Analogous to Petroleum-Derived Polymers, and Newly Developed Hajime Nakajima, Peter Dijkstra and Katja Loos * ID Macromolecular Chemistry and New Polymeric Materials, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands; [email protected] (H.N.); [email protected] (P.D.) * Correspondence: [email protected]; Tel.: +31-50-363-6867 Received: 31 August 2017; Accepted: 18 September 2017; Published: 18 October 2017 Abstract: The main motivation for development of biobased polymers was their biodegradability, which is becoming important due to strong public concern about waste. Reflecting recent changes in the polymer industry, the sustainability of biobased polymers allows them to be used for general and engineering applications. This expansion is driven by the remarkable progress in the processes for refining biomass feedstocks to produce biobased building blocks that allow biobased polymers to have more versatile and adaptable polymer chemical structures and to achieve target properties and functionalities. In this review, biobased polymers are categorized as those that are: (1) upgrades from biodegradable polylactides (PLA), polyhydroxyalkanoates (PHAs), and others; (2) analogous to petroleum-derived polymers such as bio-poly(ethylene terephthalate) (bio-PET); and (3) new biobased polymers such as poly(ethylene 2,5-furandicarboxylate) -
DID YOU KNOW? PET (Polyethylene Terephthalate) Is Actually Polyester. When PET Is Used for Bottles, Containers and Other
355 Lexington Ave., Suite 1500 ▪ New York, NY 10017 ▪ www.PETresin.org DID YOU KNOW? Little-Known Facts about PET Plastic . PET (polyethylene terephthalate) is actually polyester. When PET is used for bottles, containers and other applications, it is called PET or PET resin. When PET is used as a fiber, it is typically called polyester. The PET bottle was invented by Nathaniel C. Wyeth, a DuPont engineer and brother of American painter Andrew Wyeth. The patent was issued to Wyeth in 1973 and assigned to DuPont. According to the EPA, recycling one pound of PET bottles (that’s about 10 two-liter soda bottles) saves approximately 26,000 BTUs of energy. PET bottles and the sun are helping millions of people in developing countries obtain potable water. Using a system called SODIS (solar water disinfection), inhabitants set water-filled PET bottles in the sun for several hours or days – depending on how much sunlight is available – as a simple but effective means of destroying disease-causing bacteria and gaining safe drinking water. More than 1.5 billion pounds of used PET bottles and containers are collected in the U.S. each year for recycling. PET is the most recycled plastic in the U.S. and the world. A single-serve PET bottle (0.5 liter) is strong enough to hold 50 times its weight in water. Chemists keep finding new ways to make PET lighter without losing any strength. A 2-liter PET bottle that weighed 68 grams in 1980 now weighs as little as 42 grams. The average weight of single-serve 0.5 liter PET water bottle is now 9.9 grams, nearly half of what it weighed in 2000. -
Plastic Bottles Today Innovating to Reach Today’S Consumer
PLASTICS MARKET WATCH PLASTIC BOTTLES TODAY INNOVATING TO REACH TODAY’S CONSUMER BETTER INDUSTRY. BETTER WORLD. February 2017 The Plastics Industry Association (PLASTICS) sends special thanks to the Brand Owners, Processors and Equipment Councils, and Rigid Plastics Packaging Group (RPPG) for their guidance and input on this Bottling Plastics Market Watch Report. Materials were compiled, written and edited by William (Bill) Mashek, with editorial assistance from Kim Holmes, George Southworth, Kendra Martin and Ashley Stoney at PLASTICS. Copyright Plastics Industry Association. 02 Plastics Market Watch—Watching: Bottling Plastics Market Watch Plastic Bottles Today Innovating to Reach Today’s Consumer A series examining the business of plastics, including demographics, economics, policy developments and technological trends in specific plastics end markets. Contents 05 Forward 08 Introduction: Plastic Bottles Today— Innovating to Reach Today’s Consumer 11 Role of Plastics in Bottling 16 Growth of Plastics Bottling 20 Innovation 25 Plastic Bottle Economics 29 Bottling Equipment & Machinery 31 Recycling Progress 37 Conclusion 42 Plastic Bottle Glossary 49 Sources 52 Plastics Market Watch Snapshot Plastics Market Watch—Watching: Bottling 03 04 Plastics Market Watch—Watching: Bottling Forward The Plastics Industry Association’s (PLASTICS’) Plastics Market Watch reports provide forward-looking data and insights on key plastics industry end markets. The series examines the business of plastics, including demographics, economics, policy developments and technological improvements for markets including automotive and transportation, healthcare and medical devices, packaging, building and construction, automotive recycling, bioplastics and consumer electronics. Given the role that plastics play in today’s modern society, Plastics Market Watch reports offer a holistic picture of our technology—from beginning-of-life resins and polymers to end-of-life management and recycling efforts. -
Nalgene and Nunc Centrifuge Ware Catalog
Nalgene and Nunc Centrifuge Ware Select the right vessel and spin with confidence Spin with confidence at virtually any scale The process of selecting a centrifuge and rotor can feel like the easy part when faced with choosing the tube or bottle that is the right fit for both the rotor and application. There are several factors to consider when selecting the correct vessel for each application: • Chemical compatibility • Volume • Temperature • Relative centrifugal force (RCF) required • Protocols to be used for loading and sample recovery • Cleaning and autoclaving steps Understanding your requirements before selecting a tube or bottle ensures you make the right choice. Whether your application includes the need for separations, large volume pelleting, protein purification or DNA isolation, the comprehensive selection of Thermo Scientific™ Nalgene™ and Thermo Scientific™ Nunc™ centrifuge ware offers a solution for virtually scales and is available in sizes from 10 mL to 2 L. Such a broad offering means a tube or bottle for many spins – from clinical and bioproduction, to processing bacteria, yeast, tissue, and viruses. Contents Centrifuge tubes 4 Centrifuge bottles 20 Closures and adaptors 31 Resources 36 Simplify performance at every turn with a reliable and safe approach to centrifugation Nalgene Conical-Bottom Centrifuge Tubes polypropylene copolymer Thermo Scientific™ Nalgene™ PPCO conical-bottom centrifuge tubes with molded-in graduations have excellent chemical resistance. Designed for low-speed centrifugation in refrigerated and non-refrigerated centrifuges details • Translucent PPCO is compatible with a wide range of lab reagents • Conical bottoms concentrate pellet in a small area for easy isolation and retrieval • Molded-in graduations last the life of the tube • Last longer than polycarbonate tubes under conditions of repeated Note: Centrifuge tubes must be filled at least 80% for proper performance.