Effect of Quenching Conditions on the Microstructure and Mechanical Properties of 51Crv4 Spring Steel

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Effect of Quenching Conditions on the Microstructure and Mechanical Properties of 51Crv4 Spring Steel metals Article Effect of Quenching Conditions on the Microstructure and Mechanical Properties of 51CrV4 Spring Steel Lin Zhang 1,* , Dehai Gong 2, Yunchao Li 1, Xiaojun Wang 2, Xixi Ren 1 and Engang Wang 1,* 1 Key Laboratory of Electromagnetic Processing of Materials (Ministry of Education), Northeastern University, Wenhua Road, Shenyang 110819, China; [email protected] (Y.L.); [email protected] (X.R.) 2 CRRC Guiyang Co., LTD., Dulaying Road, Guiyang 550017, China; [email protected] (D.G.); [email protected] (X.W.) * Correspondence: [email protected] (L.Z.); [email protected] (E.W.); Tel.: +86-24-8368-3985 (L.Z.); +86-24-8368-1739 (E.W.) Received: 28 November 2018; Accepted: 11 December 2018; Published: 12 December 2018 Abstract: 51CrV4 steel is extensively used in large-size damping springs for trains and vehicles. Quenching conditions play an important role in performance enhancement. The present work investigated the effects of various oil-bath temperatures and out-of-oil temperatures on the microstructure and the mechanical properties of this steel. The morphological examination focused on both the quenched martensite and the tempered troostite. Tensile and hardness tests were carried out to evaluate the mechanical properties. The results showed that a coarsening of the martensite occurred at a high oil-bath temperature. In addition, the size and fraction of bainite islands also increased with the increase of oil-bath temperature. In contrast, the carbide size and the intercarbide spacing both increased with the increase of oil-bath temperature. Thus, the tensile strength and the hardness both decreased with increasing oil-bath temperature in accordance with the Hall-Petch relationship. Correspondingly, the ductility increased as the oil-bath temperature increased. At a relatively high out-of-oil temperature, the martensite underwent an auto-tempering process, which led to the precipitation of many tiny carbide particles in the as-quenched martensite laths. This auto-tempering effect enhanced the width of large-sized carbides and reduced their length in the final microstructure. The intercarbide spacings increased with increasing out-of-oil temperature. As the oil-bath temperature increased, the tensile strength and hardness decreased, and the ductility increased. The fracture morphology was examined to explain the results of mechanical properties. Keywords: 51CrV4; spring steel; quenching; martensite; carbides; strength; hardness 1. Introduction The development of high-speed railway trains imposes rigid requirements on the mechanical properties of coil springs used in freight car bogies. Over the last decades, considerable efforts have been made to develop high-performance spring steels. Most coil springs for railway applications are made of quenched and tempered high-strength steels. Elements such as chromium, manganese, and silicon are added to these steels [1]. 51CrV4 steel has high strength and fatigue performance due to the addition of Cr and V, which is extensively used in large-size damping springs for trains and vehicles [2]. The recommended properties of spring steel include high ductility and toughness at operating temperatures and good hardenability that provides required mechanical properties even at large dimensions [3]. One way to improve the mechanical properties of spring steel could be achieved through the control of alloy composition [4,5]. Thermodynamic calculation was used to identify the effects of element change on the phase fraction and transformation temperature in the soaking Metals 2018, 8, 1056; doi:10.3390/met8121056 www.mdpi.com/journal/metals Metals 2018, 8, 1056 2 of 16 and tempering process [6]. Thermodynamic calculation can be performed using software such as Thermo-Calc. However, composition adjustment means to change the standard of spring steels, which lack feasibility for spring manufacturers. Steels with a similar chemical composition may behave differently due to various mechanical properties as a consequence of their manufacturing route. The mechanical properties can be improved by effective heat treatment [7,8] and thermomechanical treatment [1,9]. Quenching before tempering is a key technique to enhance the mechanical properties of spring steels, in which the final structure is significantly affected by the processing parameters during heat treatment. For this reason, the heat treatment parameters of spring steel are controlled thoroughly by the producers. Large efforts have been made in recent years to investigate the effects of heat treatment parameters during soaking and tempering process [8,10–12], such as the time and temperature of soaking and tempering. The emphasis in the research of spring steels has been focused on increasing the strength while maintaining good ductility [6,13]. One way of improving steel properties is refining its microstructure [14,15], which means to reduce the ferrite grain size, the size of carbides, and the intercarbide spacing. The mechanical behavior of steel is influenced by the inclusions and precipitates, which act as stress raisers [16]. Large inclusions are most harmful to mechanical properties. Fine precipitation can be achieved through microalloying and effective heat treatment [17]. This leads to the enhancement of hardness and strength. Retained austenite is also an important structural component in the spring steel, whose stability is affected by the processing parameters during heat treatment, such as the soaking temperature and the cooling rate [18]. The present work performed soaking, quenching, and tempering on 51CrV4 steel since this kind of heat treatment is a conventional manufacturing route to improve its mechanical properties. Previous researchers have studied the effects of various parameters during heat treatment on the microstructure and mechanical properties of 51CrV4 steels [3,19–21]. However, very few researches have focused on the detailed quenching conditions such as the oil-bath temperature and the out-of-oil workpiece temperature, which is essential to obtain the required strength and ductility. In this work, the heat treatment experiments were carried out on 51CrV4 steel under various oil-bath temperatures and out-of-oil temperatures. The quenched martensite and tempered troostite were examined. The microstructure of the steel was analyzed by scanning electron microscopy. Effects of the quenching parameters on the mechanical properties were evaluated in terms of tensile strength, elongation, hardness, and fracture. The relationship between the microstructure and the mechanical properties was discussed. The purpose of this work is to obtain a technical reference to control the mechanical properties using the oil-bath temperature and out-of-oil temperature. 2. Materials and Methods 51CrV4 spring steels have been processed by soaking, quenching, and tempering. Table1 shows the chemical composition of the commercial 51CrV4 spring steel used in this work, which was identified by chemical analysis. The original specimens were cut from a hot deformed steel bar. The size of the cylinder specimen was Ø20 mm × 300 mm. This work performed the heat treatment according to a technology route usually used to fabricate a train damping spring. First, the steel bars were heated to 930 ◦C and isothermally held for 30 min to form austenite with a uniform distribution of the alloying elements. During this soaking process, nitrogen gas was injected into the furnace to protect the steel bars from oxidization. Afterward, the steel bars were quenched into a stirred oil bath which was set at various oil-bath temperatures (20 ◦C, 50 ◦C, and 80 ◦C). The cooling rates were estimated to be 34 ◦C/s, 30 ◦C/s, and 25 ◦C/s respectively. The surface temperature of the workpiece was measured during the quenching process, and the workpieces were taken out of the oil bath at various temperatures (60 ◦C, 90 ◦C, and 120 ◦C), which was defined as the out-of-oil temperature in this paper. After quenching, the workpieces were cooled in the air to room temperature (about 15 ◦C). Next, the specimens were tempered at 450 ◦C for 90 min. After tempering, the samples were water quenched. Metals 2018, 8, 1056 3 of 16 Table 1. Chemical composition of the as-received 51CrV4 steel (mass percent, %). C Si Mn S P Cr Ni Cu V Al Mo Fe 0.546 0.229 0.951 0.004 0.014 1.08 0.051 0.106 0.168 0.017 0.006 balance Each bar was subsequently sectioned and etched to reveal the microstructure. The microstructure was observed using an Ultra Plus field emission scanning electron microscope (Carl Zeiss AG, Oberkochen, Germany). Image-Pro Plus software (Version 6.0, Media Cybernetics, Inc., Rockville, MD, USA) was used to analyze the size and the area fraction of phases. The phases were identified by the X-ray diffraction analysis using a Philips X0Pert Pro MPD diffractometer (PANalytical Co., Almelo, The Netherlands). In order to evaluate the mechanical properties of the samples, tensile testing and hardness testing were performed. Hardness measurements were taken from a polished but unetched sample, using a Rockwell apparatus (Shenyang Kejing Auto-instrument Co., LTD, Shenyang, China), with a load of 150 kg and loading time of 5 s. Tensile testing was performed in a Shimadzu AG-X 100 kN testing machine (Shimadzu Corp., Kyoto, Japan) in accordance with the requirements and recommendations of the ISO 6892-1:2011 [22]. The round bone-shaped tensile testing specimens were prepared by lathe. The tensile testing specimen had an overall length of 150 mm, a gauge length of 50 mm, and a diameter of 6 mm. An extensometer was set during test to measure the strain precisely. The strain rate was about 2.3 × 10−5·s−1. 3. Results and Discussion Figure1a shows the microstructure of as-received commercial 51CrV4 steel used in this work. The microstructure of the as-received steel appeared to be spheroidite, in which many spherical carbides were distributed dispersedly in the ferrite grains. The XRD patterns of the as-received, quenched, and tempered specimens were analyzed. The XRD result of as-received steel showed a main phase of α-Fe (Figure1b), which is the matrix of the microstructure shown in Figure1a.
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