Electronic Nose and Its Applications: a Survey

Total Page:16

File Type:pdf, Size:1020Kb

Electronic Nose and Its Applications: a Survey International Journal of Automation and Computing 17(2), April 2020, 179-209 DOI: 10.1007/s11633-019-1212-9 Electronic Nose and Its Applications: A Survey Diclehan Karakaya Oguzhan Ulucan Mehmet Turkan Department of Electrical and Electronics Engineering, Izmir University of Economics, Izmir 35330, Turkey Abstract: In the last two decades, improvements in materials, sensors and machine learning technologies have led to a rapid extension of electronic nose (EN) related research topics with diverse applications. The food and beverage industry, agriculture and forestry, medi- cine and health-care, indoor and outdoor monitoring, military and civilian security systems are the leading fields which take great ad- vantage from the rapidity, stability, portability and compactness of ENs. Although the EN technology provides numerous benefits, fur- ther enhancements in both hardware and software components are necessary for utilizing ENs in practice. This paper provides an ex- tensive survey of the EN technology and its wide range of application fields, through a comprehensive analysis of algorithms proposed in the literature, while exploiting related domains with possible future suggestions for this research topic. Keywords: Artificial intelligence, machine learning, pattern recognition, electronic nose (EN), sensors technology. 1 Introduction aromas with a chemical electronic sensor array was primarily mentioned in [12] and then in [13] in the early All kinds of innovation are possible with inspiration. 1980s. However, the EN concept could not be actualized As image processing is inspired by the sense of sight, the at that time due to limitations in the sensors technology. electronic nose (abbreviation EN, enose, e-nose) – also In the late 1990s then, the term “electronic nose” was known as an odor sensor, aroma sensor, mechanical nose, mentioned in [14]. According to its initial definition, an flavor sensor, multi-sensor array, artificial nose, odor- EN is composed of a multisensor array responsible for de- sensing system, electronic olfactometry[1] – technology is tect- ing more than one chemical component. Sub- inspired by the sense of smell. The olfactory system eas- sequently, both technological improvements in sensors ily enables living beings to be aware of their environment, and the realization of the potential that the EN holds led of possible dangers, and to identify and classify food[2]. In to a considerable extension of its applications. Recently, technology though, automatic identification and classific- due to the provision of reliable solutions, rapidity, low ation of odor is a very challenging issue because the cost and compactness, the EN concept has become popu- scents in chemical mixtures intercommunicate naturally[3]. lar in agriculture[15], the food and water industry[16], medi- This natural interaction has three types: synergism, com- cine[17], security systems[15] and many other areas[18]. pensation and masking. Synergism is defined as the inter- Fig. 1 demonstrates the similarities between the biolo- action when two or more distinct substances produce a gical olfactory system and the EN technology. The elec- mutual scent which is stronger than those of individual tronic sensor array of the EN corresponds to the olfact- components. Compensation is the case when one compon- ory nose receptors, which detects the traces of chemicals ent counteracts another constituent. Masking is the com- in the air. When these molecules are sensed and captured, bination of one pleasant odor with an unpleasant one. the input signal is sent to the olfactory bulb, where the Even though there exist reported achievements of some odor information is processed. After characterizing the earlier techniques[4–8], such chemical mixtures in general aroma, the smell is recognized in the brain by the olfact- conditions were not able to be analyzed and split up into ory cortex as a last stage in the biological system. Like- its components with high accuracy until the development wise, in the EN case, a preprocessor applies feature ex- of the EN technology. Together with the development of EN devices, several studies were completed to assess odor Odor intensities, to understand mixtures of odor interactions particles and the sensor responses to these interactions, e.g., [9– 11]. Nose Brain Although the first research on detecting distinctive smells began in [4] during the 1920s, the idea to detect Sensor Data Review array analysis Manuscript received August 5, 2019; accepted November 15, 2019; published online December 28, 2019 Fig. 1 Analogy between the biological olfactory system and the Recommended by Associate Editor Jyh-Horng Chou EN technology © The Author(s) 2019 180 International Journal of Automation and Computing 17(2), April 2020 traction to the captured odor signal. Afterwards, data tained signals should be preprocessed to understand those analysis, pattern recognition and machine learning re- physical changes properly and then processed to digital- lated algorithms are generally used for identifying and ize them in order to form a dataset. Hence, the sensed classifying the input scent using the extracted digital sig- signals are appropriately manipulated, e.g., amplified, natures. filtered or converted, in order to be easily used in further After drawing the parallels between the biological ol- stages[22]. The processed signals are later analyzed in factory system and the EN technology, an EN obviously terms of their specific properties in the data gathering consists of both hardware and software components. stage. Subsequently, sufficient data is acquired from these While the software part can be thought as the “brain”, signals and the obtained data is preprocessed according to the hardware part can be seen as the “olfactory recept- the requirements of the employed pattern recognition al- ors” of the EN system. The software part mainly con- gorithm. Lastly, the odor is classified with the pattern re- tains a data processing unit which identifies and classi- cognition stage. fies each individual scent detected using digital signa- tures of the sensed chemicals. The hardware part is basic- Odor Sensor Signal Signal ally a sensor array. Since the main objective of the EN is release array conditioning processing detecting and classifying multiple aromas, the sensing ar- ray should encompass different types of individual sensors, where each sensor is responsible for detecting a Odor Pattern Data Data classification recognition preprocessing gathering different chemical. The selection of suitable sensors to a given specific task is a key point in this technology. It can Fig. 2 A description of EN including both hardware and be concluded here that choosing the suitable hardware software components and efficient software components is very important in designing and implementing a successful EN system for a 2.1 Sensors and chemicals particular problem. Hence, the main aim of this survey is to provide a complete overview of the EN technology The olfactory system can neither detect nor identify while pointing out the task-dependent importance of its scents without the obtaining of chemicals released by the hardware and software components and their character- objects[23]. These chemicals can be found in simple or istic properties. Note that there are several existing re- complex structures. Nevertheless, each individual chemic- views in the literature which focus on a specific sub-topic al has its own unique quality and characteristics. Thus, of the EN concept, e.g., the range of sensors as hardware digital signatures of chemicals, which are to be the input [19] components used in the EN systems , ENs for the food data for both the olfactory system and the EN instru- [20] industry , neural networks as software components for ment, are exclusive. The automatic detection process can- ENs[21]. On the other hand, this paper rather provides a not be achieved without a collected library (dataset) of comprehensive review of broad EN application fields, a the digital signatures of specific aromas. wide range of software related algorithms and commonly The sensor array is responsible for detecting targeted utilized sensor types and their properties as practical chemicals in a medium. Each targeted aroma is detected hardware components. with a specific sensor, in other words each individual The remaining part of this survey is structured as fol- sensor is responsible for sensing a specific type of aroma. lows. The EN device and its main components are intro- Chemical sensors are used for detecting chemicals in the duced in Section 2. Then, a wide range of practical EN medium. These sensors basically convert chemical inform- applications and related topics are described in Section 3. ation into analytical signals[24]. Afterwards, current challenges for this technology are dis- Since the main objective of an EN is to sense more cussed in Section 4, followed by perspectives and possible than one chemical, this aim can be achieved with higher future research directions in Section 5. This paper is fi- accuracy only by combining several distinct sensors in the nally concluded with a brief conclusion in Section 6. array. While keeping in mind that the sensors in the ar- ray have to be chosen carefully by taking the chemicals of 2 Components of an EN interest into account[25], having a proper sensor array for An EN consists of both hardware and software com- specific tasks depends on several conditions as follows[26]: ponents as briefly depicted in an
Recommended publications
  • Hybrid Nanostructures for Artificial Machine Olfaction Landon Joseph Oakes Western Kentucky University, [email protected]
    Western Kentucky University TopSCHOLAR® Masters Theses & Specialist Projects Graduate School 5-2012 Hybrid Nanostructures for Artificial Machine Olfaction Landon Joseph Oakes Western Kentucky University, [email protected] Follow this and additional works at: http://digitalcommons.wku.edu/theses Part of the Physics Commons Recommended Citation Oakes, Landon Joseph, "Hybrid Nanostructures for Artificial Machine Olfaction" (2012). Masters Theses & Specialist Projects. Paper 1150. http://digitalcommons.wku.edu/theses/1150 This Thesis is brought to you for free and open access by TopSCHOLAR®. It has been accepted for inclusion in Masters Theses & Specialist Projects by an authorized administrator of TopSCHOLAR®. For more information, please contact [email protected]. HYBRID NANOSTRUCTURES FOR ARTIFICIAL MACHINE OLFACTION A Thesis Presented to The Faculty of the Department of Physics Western Kentucky University Bowling Green, Kentucky In Partial Fulfillment Of the Requirement for the Degree Master of Science By Landon Joseph Oakes May 2012 ACKNOWLEDGEMENTS I would like to acknowledge the profound assistance I have received from the director of this ongoing research project, Dr. Vladimir Dobrokhotov, and all of the time, effort, and consideration he has put forth over the course of this evolving thesis. I would like to thank Dr. Keith Andrew for his insights and comments regarding the direction of my thesis and his help in finding support for this project. I would like to thank Dr. Alexander Barzilov for directing the Homeland Security program during my time as a student and for his participation as a member of my thesis committee. Lastly, I would like to thank all of my colleagues, friends, and family which have supported me over the course of my educational career.
    [Show full text]
  • Polymer Based Chemical Sensor Array Fabricated with Conventional Microelectronic Processes
    JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, Vol. 12, No. 5, May 2010, p. 1147 - 1152 Polymer based chemical sensor array fabricated with conventional microelectronic processes M. KITSARAa,b, D. GOUSTOURIDISa, E. VALAMONTESc, P. OIKONOMOUa, K. BELTSIOSb, I. RAPTISa* aInstitute of Microelectronics, NCSR “Demokritos”, 15310, Athens, Greece bMaterials Science and Engineering Dept, University of Ioannina, Ioannina 45110 Greece cElectronics Engineering Dept, TEI of Athens, Egaleo 12243, Greece A polymer array fabricated on the same substrate with conventional microelectronic processes is introduced for gas sensing applications. The process is based on photolithographic processes and takes advantage of the balance between UV exposure dose, material tone and developers used. The sensing properties of the lithographically defined films in the array were characterized for various analytes through in situ monitoring of films swelling by white light reflectance spectroscopy. The sensing responses are post processed by Principal Component Analysis and the discrimination between analytes with similar and totally different analytes is presented. (Received January 4, 2010; accepted May 26, 2010) Keywords: Chemical sensors, Polymer deposition, Photolithography, Vapor sorption, Polymer swelling 1. Introduction providing bulk absorption. Vacuum deposition techniques are also possible methods of obtaining thin polymer films One of the most important problems in chemical including mostly sputtering [13], plasma polymerization sensor fabrication is the controlled deposition of the [14]. chemically sensitive layer on the transducer [1]. This In the present work a series of photosensitive problem becomes more critical in the case of sensor arrays polymeric materials is defined on the same substrate using where different sensing materials should be deposited on conventional lithographic techniques only.
    [Show full text]
  • The Whiskey Machine: Nanofactory-Based Replication of Fine Spirits and Other Alcohol-Based Beverages
    The Whiskey Machine: Nanofactory-Based Replication of Fine Spirits and Other Alcohol-Based Beverages © 2016 Robert A. Freitas Jr. All Rights Reserved. Abstract. Specialized nanofactories will be able to manufacture specific products or classes of products very efficiently and inexpensively. This paper is the first serious scaling study of a nanofactory designed for the manufacture of a specific food product, in this case high-value-per- liter alcoholic beverages. The analysis indicates that a 6-kg desktop appliance called the Fine Spirits Synthesizer, aka. the “Whiskey Machine,” consuming 300 W of power for all atomically precise mechanosynthesis operations, along with a commercially available 59-kg 900 W cryogenic refrigerator, could produce one 750 ml bottle per hour of any fine spirit beverage for which the molecular recipe is precisely known at a manufacturing cost of about $0.36 per bottle, assuming no reduction in the current $0.07/kWh cost for industrial electricity. The appliance’s carbon footprint is a minuscule 0.3 gm CO2 emitted per bottle, more than 1000 times smaller than the 460 gm CO2 per bottle carbon footprint of conventional distillery operations today. The same desktop appliance can intake a tiny physical sample of any fine spirit beverage and produce a complete molecular recipe for that product in ~17 minutes of run time, consuming <25 W of power, at negligible additional cost. Cite as: Robert A. Freitas Jr., “The Whiskey Machine: Nanofactory-Based Replication of Fine Spirits and Other Alcohol-Based Beverages,” IMM Report No. 47, May 2016; http://www.imm.org/Reports/rep047.pdf. 2 Table of Contents 1.
    [Show full text]
  • Development of an Electronic Nose for Smell Categorization Using Artificial Neural Network
    Journal of Advances in Information Technology Vol. 12, No. 1, February 2021 Development of an Electronic Nose for Smell Categorization Using Artificial Neural Network Dailyne Macasaet, Argel Bandala, Ana Antoniette Illahi, Elmer Dadios, Sandy Lauguico, and Jonnel Alejandrino De La Salle University-Manila, Philippines Email: {dailyne_macasaet, argel.bandala, ana.illahi, elmer.dadios, sandy_lauguico, jonnel_alejandrino}@dlsu.edu.ph Abstract—Electronic Nose employs an array of gas sensors recognition algorithm and integrating multi-sensor array and has been widely used in many specific applications for therefore creating an artificial olfactory system which we the analysis of gas composition. In this study, electronic technically refer to as electronic nose [3]. nose, integrating ten MQ gas sensors, is intended to model Artificial olfaction had its beginnings with the olfactory system which generally classifies smells based on invention of the first gas multi-sensor array in 1982 [4]. ten basic categories namely: fragrant, sweet, woody/resinous, pungent, peppermint, decaying, chemical, From this, several works have been done in the past citrus, fruity, and popcorn using artificial neural network as attempting to mimic the mammalian olfactory system its pattern recognition algorithm. Initial results suggest that employing different methods. J. White et al. (1998) used four (Pungent, Chemical, Peppermint, and Decaying) an array of fiber-optic chemosensors and sent the outputs among the ten classifications are detectable by the sensors of the sensors to an olfactory bulb [5]. They then used a commercially available today while technology for delay line neural network to perform recognition. In the classifying the remaining six is still under development. year 2000, a study conducted by S Schiffman et al.
    [Show full text]
  • Future Applications of Electronic-Nose Technologies in Healthcare and Biomedicine
    15 Future Applications of Electronic-Nose Technologies in Healthcare and Biomedicine Alphus Dan Wilson USDA Forest Service, Southern Hardwoods Laboratory United States of America 1. Introduction The development and utilization of many new electronic-nose (e-nose) applications in the healthcare and biomedical fields have continued to rapidly accelerate over the past 20 years. Innovative e-nose technologies are providing unique solutions to a diversity of complex problems in biomedicine that are now coming to fruition. A wide range of electronic-nose instrument types, based on different operating principles and mechanisms, has facilitated the creation of different types and categories of medical applications that take advantage of the unique strengths and advantages of specific sensor types and sensor arrays of different individual instruments. Electronic-nose applications have been developed for a wide range of healthcare sectors including diagnostics, immunology, pathology, patient recovery, pharmacology, physical therapy, physiology, preventative medicine, remote healthcare, and wound and graft healing. E-nose biomedical applications range from biochemical testing, blood compatibility, disease diagnoses, drug purity, monitoring metabolic levels, organ dysfunction, and telemedicine. This review summarizes some of the key technological developments of electronic-nose technologies, arising from past and recent biomedical research, and identifies a variety of future e-nose applications currently under development which have great potential to advance the effectiveness and efficiency of biomedical treatments and healthcare services for many years. A concise synthesis of the major electronic-nose technologies developed for healthcare and medical applications since the 1980s is provided along with a detailed assessment and analysis of future potential advances in electronic aroma detection (EAD) technologies that will provide effective solutions to newly-emerging problems in the healthcare industry.
    [Show full text]
  • Development of a Mobile Device for Odor Identification and Optimization
    sensors Article Development of a Mobile Device for Odor Identification and Optimization of Its Measurement Protocol Based on the Free-Hand Measurement Gaku Imamura 1,* and Genki Yoshikawa 2,3 1 International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), World Premier International Research Center Initiative (WPI), 1-1 Namiki, Tsukuba 305-0044, Japan 2 Center for Functional Sensor & Actuator (CFSN), Research Center for Functional Materials, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044, Japan; [email protected] 3 Materials Science and Engineering, Graduate School of Pure and Applied Science, University of Tsukuba, 1-1-1 Tennodai, Tsukuba 305-8571, Japan * Correspondence: [email protected]; Tel.: +81-0-29-860-4988 Received: 30 September 2020; Accepted: 28 October 2020; Published: 30 October 2020 Abstract: Practical applications of machine olfaction have been eagerly awaited. A free-hand measurement, in which a measurement device is manually exposed to sample odors, is expected to be a key technology to realize practical machine olfaction. To implement odor identification systems based on the free-hand measurement, the comprehensive development of a measurement system including hardware, measurement protocols, and data analysis is necessary. In this study, we developed palm-size wireless odor measurement devices equipped with Membrane-type Surface stress Sensors (MSS) and investigated the effect of measurement protocols and feature selection on odor identification. By using the device, we measured vapors of liquids as odor samples through the free-hand measurement in different protocols. From the measurement data obtained with these protocols, datasets of transfer function ratios (TFRs) were created and analyzed by clustering and machine learning classification.
    [Show full text]
  • Review Neurological Connections and Endogenous Biochemistry
    1 Review 2 3 Neurological connections and endogenous biochemistry - potentially useful in electronic- 4 nose diagnostics for coronavirus diseases 5 6 Tiffany C. Miller1, Salvatore D. Morgera1, Stephen E. Saddow1,2, Arash Takshi1, Matthew 7 Mullarkey3, Matthew Palm4 8 9 1Department of Electrical Engineering, University of South Florida, Tampa, FL 33620, USA. 10 2Department of Medical Engineering, University of South Florida, Tampa, FL 33620, USA. 11 3Muma College of Business, University of South Florida, Tampa, FL 33620, USA. 12 4Valhall K-9 International, LLC, Hull, GA 30646, USA. 13 14 Correspondence to: Dr. Salvatore D. Morgera, Department of Electrical Engineering, 15 University of South Florida, 4202 E. Fowler Ave., Tampa, FL 33620, USA, E-mail: 16 [email protected] 17 18 How to cite this article: Miller TC, Morgera SD, Saddow SE, Takshi A, Mullarkey M, Palm M. 19 Neurological connections and endogenous biochemistry - potentially useful in electronic-nose 20 diagnostics for coronavirus diseases. Neuroimmunol Neuroinflammation 2021;8:[Accept]. 21 http://dx.doi.org/10.20517/2347-8659.2021.05 22 23 Received: 23 Feb 2021 Revised: 11 Jun 2021 Accepted: 29 Jun 2021 First online: 14 Jul 24 2021 25 26 27 ABSTRACT 28 As our understanding of infectious diseases, such as coronavirus diseases including, Coronavirus 29 Disease 2019 (COVID-19), as well as human respiratory viral and nonviral diseases, improves, 30 we expect to uncover a better understanding of the pathogenesis of the disease as it relates to 31 neuroinflammation. This may include associated biomarkers of immune response for 1 32 neuroinflammation, central nervous system injury, and/or peripheral nervous system injury 33 emitted from the breath and/or odor of an individual.
    [Show full text]
  • Electronic-Nose Technology and Its Application -A Systematic Survey
    ISSN (Online) 2321-2004 ISSN (Print) 2321-5526 INTERNATIONAL JOURNAL OF INNOVATIVE RESEARCH IN ELECTRICAL, ELECTRONICS, INSTRUMENTATION AND CONTROL ENGINEERING Vol. 3, Issue 1, January 2015 Electronic-Nose Technology and its Application -A Systematic Survey Pranjal kalita1, Manash protim saikia2, N.H.Singh3 Dept. of Electronics & Communication Engineering, Dibrugarh University Institute Of Engineering & Technology, Dibrugarh, Assam ,India1,2,3 Abstract: Electronic Nose is one of the most advance device in the field of sensor technology. It is responsible for the automated detection and classification of gases, odors and vapors. This paper reviews the three components of Electronic Nose i.e. sample handling, detection system, data processing system. It outlines the range of sensors their principles, advantages and disadvantages. It describe the data processing through pattern recognition process. It also outlines the enormous benefits of Electronic Nose in the field of food control, clinical diagnosis, cosmetics, environmental factors, garbage control and detection of plant diseases. Keywords: E-Nose, VOC, ANN, ART. INTRODUCTION E-Nose is a measuring instrument that is designed to signal, amplifies and condition it. A digital converter is mimic the mammalian olfactory system. With the used to convert the electrical signal in analog form to advancement in sensor technology, biochemistry, digital form. The simple or complex mixture is electronics, artificial intelligence it is possible to design characterized by a unique digital aroma signature the biological olfactory system within an pattern.A computer will read the digital signal and instrumentcapable of identifying and classifying the aroma displays the output. mixture. Its capability of recognition of the mixture of A pattern recognition algorithm observe the difference organic sample rather than recognizing individual between the pattern of all analyte type in the reference chemical species in the sample make this device unique library.
    [Show full text]
  • Wearable RF Resonant Gaseous Chemical Sensor Array
    Wearable RF Resonant Gaseous Chemical Sensor Array by Wei Ting Chen A thesis presented to the University of Waterloo in fulfillment of the thesis requirement for the degree of Doctor of Philosophy in Electrical and Computer Engineering Waterloo, Ontario, Canada, 2015 © Wei Ting Chen 2015 AUTHOR’S DECLARATION I hereby declare that I am the sole author of the thesis. This is the true copy of the thesis, including any required final revision, as accepted by the examiners. I understand that my thesis may be made electronically available to the public. ii ABSTRACT Biomarker detection is a major engineering goal that enables numerous applications in the fields of biomedical and law enforcement. By monitoring the conditions of the subject with a dedicated biomarker detection system, the health condition as well as other biomedical parameters of interest can be evaluated in real-time, and further preemptive measures can be taken to improve the safety and chance of survival of the subject. In the pursuit of a better biomarker monitoring system, the ubiquitous and unobtrusiveness of the sensor is proven to be a critical design factor that directly impacts the subject’s safety and the comfort level. The thesis presents the research results obtained for a novel single-port, multi-pole resonant sensor array fabricated on a novel Frame-Flex flexible substrate for a wearable epidermal ethanol sensor system in an attempt to achieve minimal obtrusiveness to the subject under testing. In this system, individual sensors carrying different functional polymers are brought together to share the same electrical input and output, and their resonance behavior along with inter-resonator coupling are captured through a single reflected array response curve (S11).
    [Show full text]
  • A Perspective on Recent Advances in Piezoelectric Chemical Sensors for Environmental Monitoring and Foodstuffs Analysis
    chemosensors Review A Perspective on Recent Advances in Piezoelectric Chemical Sensors for Environmental Monitoring and Foodstuffs Analysis Tatyana A. Kuchmenko 1 and Larisa B. Lvova 2,* 1 Department of Ecology and Chemical Technology, Voronezh State University of Engineering Technologies, Revolution Avenue 19, Voronezh 394000, Russia 2 Department of Chemical Science and Technologies, University “Tor Vergata”, via della Ricercha Scientifica 1, 00133 Rome, Italy * Correspondence: [email protected] Received: 12 June 2019; Accepted: 19 August 2019; Published: 26 August 2019 Abstract: This paper provides a selection of the last two decades publications on the development and application of chemical sensors based on piezoelectric quartz resonators for a wide range of analytical tasks. Most of the attention is devoted to an analysis of gas and liquid media and to industrial processes controls utilizing single quartz crystal microbalance (QCM) sensors, bulk acoustic wave (BAW) sensors, and their arrays in e-nose systems. The unique opportunity to estimate several heavy metals in natural and wastewater samples from the output of a QCM sensor array highly sensitive to changes in metal ion activity in water vapor is shown. The high potential of QCM multisensor systems for fast and cost-effective water contamination assessments “in situ” without sample pretreatment is demonstrated. Keywords: quartz crystal microbalance (QCM) sensors; chemical sensors; environmental monitoring; food quality and safety assessment 1. Introduction Chemical sensors represent one of the most significant tools of analytical chemistry. Relatively simple in preparation and application and inexpensive, these devices allow for the identification and determination of substances in their gaseous and liquid phases and may function in automatic and remote modes while being implemented in various technological processes.
    [Show full text]
  • Microarray Study of Temperature Dependent Sensitivity and Selectivity of Metal/Oxide Sensing Interfaces
    Microarray study of temperature dependent sensitivity and selectivity of metal/oxide sensing interfaces J. Tiffany, R. E. Cavicchi, S. Semancik National Institute of Standards and Technology Gaithersburg, MD 20899 ABSTRACT Conductometric gas microsensors offer the benefits of ppm-level sensitivity, real-time data, simple interfacing to electronics hardware, and low power consumption. The type of device we have been exploring consists of a sensor film deposited on a "microhotplate"- a 100 micron platform with built-in heating (to activate reactions on the sensing surface) and thermometry. We have been using combinatorial studies of 36-element arrays to characterize the relationship between sensor film composition, operating temperature, and response, as measured by the device's sensitivity and selectivity. Gases that have been tested on these arrays include methanol, ethanol, dichloromethane, propane, methane, acetone, benzene, hydrogen, and carbon monoxide, and are of interest in the management of environmental waste sites. These experiments compare tin oxide films modified by catalyst overlayers, and ultrathin metal seed layers. The seed layers are used as part of a chemical vapor deposition process that uses each array element's microheater to activate the deposition of SnO2, and control its microstructure. Low coverage (2 nm) catalytic metals (Pd, Cu, Cr, In, Au) are deposited on the oxides by masked evaporation or sputtering. This presentation demonstrates the value of an array-based approach for developing film processing methods, measuring performance characteristics, and establishing reproducibility. It also illustrates how temperature-dependent response data for varied metal/oxide compositions can be used to tailor a microsensor array for a given application.
    [Show full text]
  • Electronic Nose Chemical Sensor Feasibility Study for the Differentiation of Apple Cultivars
    ELECTRONIC NOSE CHEMICAL SENSOR FEASIBILITY STUDY FOR THE DIFFERENTIATION OF APPLE CULTIVARS W. N. Marrazzo, P. H. Heinemann, R. E. Crassweller, E. LeBlanc ABSTRACT. The ability to analytically differentiate and match intact apple (Malus domestica, Borkh) fruit and fruit juice extracts from different apple cultivars is of interest to the food industry. This study tested the feasibility of detecting the difference among volatile gases evolved from intact ‘McIntosh (Buhr),’ ‘Delicious,’ and ‘Gala’ apples and their extracted juice using a prototype 32−array polymeric detector chemical sensor. All data were first processed to obtain principal components. PCA analysis clearly separated whole ‘McIntosh,’ ‘Gala,’ and ‘Delicious’ samples from juiced on day 1. PCA analysis of day 2 samples showed clustering of whole vs. juiced for all three cultivars, although there was some overlap between the clusters. A soft independent modeling of class analogy (SIMCA) class discrimination of the sensor principal component data sets was then performed to determine the degree of difference. SIMCA analysis of the same samples showed a pronounced difference (SIMCA value >3.00) for only the ‘McIntosh’ samples. SIMCA values between 2.00 and 3.00 were found for the other two cultivars on day 1. For day 2 samples, no SIMCA values greater than 2.00 were found for any cultivar whole vs. juiced. PCA analysis showed clear separation between cultivars for day 1 whole samples. SIMCA analysis showed that there was a difference between ‘Delicious’ and ‘McIntosh’ and between ‘Delicious’ and ‘Gala.’ Neither PCA nor SIMCA showed good separation between day 2 whole cultivars, nor between juiced cultivars on either day.
    [Show full text]