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Rowe Scientific Sodium Perchlorate Solution 50-70% W/W Rowe Scientific Sodium Perchlorate Solution 50-70% w/w ROWE SCIENTIFIC Chemwatch Hazard Alert Code: 2 Chemwatch: 20-8057 Issue Date: 13/03/2019 Version No: 5.1.1.1 Print Date: 13/03/2019 Safety Data Sheet according to WHS and ADG requirements S.GHS.AUS.EN SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name Rowe Scientific Sodium Perchlorate Solution 50-70% w/w Synonyms Product Code: CS3050 Proper shipping name OXIDISING LIQUID, N.O.S. (contains sodium perchlorate) Other means of Not Available identification Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Analytical reagent. Details of the supplier of the safety data sheet Registered company ROWE SCIENTIFIC name Address 11 Challenge Boulevard Wangara WA 6065 Australia Telephone +61 8 9302 1911 Fax +61 8 9302 1905 Website http://rowe.com.au/ Email [email protected] Emergency telephone number Association / Not Available Organisation Emergency telephone +61 8 9302 1911 (24 Hrs) numbers Other emergency Not Available telephone numbers SECTION 2 HAZARDS IDENTIFICATION Classification of the substance or mixture HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code. Poisons Schedule Not Applicable Classification [1] Oxidizing Liquid Category 3, Acute Toxicity (Oral) Category 4, Eye Irritation Category 2A 1. Classified by Chemwatch; 2. Classification drawn from HSIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Legend: Annex VI Label elements Hazard pictogram(s) SIGNAL WORD WARNING Hazard statement(s) Continued... Chemwatch: 20-8057 Page 2 of 13 Issue Date: 13/03/2019 Version No: 5.1.1.1 Rowe Scientific Sodium Perchlorate Solution 50-70% w/w Print Date: 13/03/2019 H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H319 Causes serious eye irritation. Precautionary statement(s) Prevention P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P221 Take any precaution to avoid mixing with combustibles/organic material. P220 Keep/Store away from clothing/organic material/combustible materials. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing/eye protection/face protection. Precautionary statement(s) Response P370+P378 In case of fire: Use alcohol resistant foam or fine spray/water fog for extinction. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. P305+P351+P338 Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. Precautionary statement(s) Storage Not Applicable Precautionary statement(s) Disposal P501 Dispose of contents/container in accordance with local regulations. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition of Mixtures Mixtures CAS No %[weight] Name 7601-89-0 50-70 sodium perchlorate 7732-18-5 30-50 water SECTION 4 FIRST AID MEASURES Description of first aid measures If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by Eye Contact occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Skin Contact Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Inhalation Other measures are usually unnecessary. For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway Ingestion and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay. Continued... Chemwatch: 20-8057 Page 3 of 13 Issue Date: 13/03/2019 Version No: 5.1.1.1 Rowe Scientific Sodium Perchlorate Solution 50-70% w/w Print Date: 13/03/2019 Indication of any immediate medical attention and special treatment needed Treat symptomatically. Antithyroid effects produced by the perchlorates may be reversed with iodine. Patients should be warned to report the development of sore throat, fever or rashes since these are indicative of blood abnormalities. For chlorates: For severe intoxication: Empty the stomach by lavage and aspiration or by emesis, give demulcents or sweetened drinks and maintain respiration. Pethidine may be given if required. A 1% solution of sodium thiosulfate may be used for lavage and may also be given by intravenous infusion. Haemodialysis, peritoneal dialysis or exchange perfusions may be of value in removing chlorate from the blood. Forced diuresis should not be attempted if there is inadequate urine input. MARTINDALE: The Extra Pharmacopoeia, 27th Edition The high sensitivity of glucose-6-phosphate dehydrogenase to denaturation by chlorate explains the inefficacy of methylene blue to reduce methaemoglobin formed, as the antidotal effect of methylene blue depends on NADPH formed mainly by the oxidation of glucose-6-phosphate. The observed changes occur only in the presence of methaemoglobin which forms a destabilising complex with chlorate. Methaemoglobin thus autocatalytically increases methaemoglobin formation and destruction of the erythrocyte. Toxic myocarditis may follow ingestion of oxidizing agents such as peroxides. -------------------------------------------------------------- BASIC TREATMENT -------------------------------------------------------------- Establish a patent airway with suction where necessary. Watch for signs of respiratory insufficiency and assist ventilation as necessary. Administer oxygen by non-rebreather mask at 10 to 15 l/min. Monitor and treat, where necessary, for pulmonary oedema . Monitor and treat, where necessary, for shock. Anticipate seizures . DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml water (5 ml/kg recommended) for dilution where patient is able to swallow, has a strong gag reflex and does not drool. DO NOT attempt neutralisation as exothermic reaction may occur. Skin burns should be covered with dry, sterile bandages, following decontamination. -------------------------------------------------------------- ADVANCED TREATMENT -------------------------------------------------------------- Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred. Positive-pressure ventilation using a bag-valve mask might be of use. Monitor and treat, where necessary, for arrhythmias. Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload might create complications. Drug therapy should be considered for pulmonary oedema. Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Fluid overload might create complications. Treat seizures with diazepam. Proparacaine hydrochloride should be used to assist eye irrigation. BRONSTEIN, A.C. and CURRANCE, P.L. EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994 SECTION 5 FIREFIGHTING MEASURES Extinguishing media FOR SMALL FIRE: USE FLOODING QUANTITIES OF WATER. DO NOT use dry chemical, CO2, foam or halogenated-type extinguishers. FOR LARGE FIRE Flood fire area with water from a protected position Special hazards arising from the substrate or mixture Avoid storage with reducing agents. Fire Incompatibility Avoid any contamination of this material as it is very reactive and any contamination is potentially hazardous Advice for firefighters Alert Fire Brigade and tell them location and nature of hazard. May be violently or explosively reactive. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water course. Fire Fighting Fight fire from a safe distance, with adequate cover. Extinguishers should be used only by trained personnel. Use water delivered as a fine spray to control fire and cool adjacent area. Avoid spraying water onto liquid pools. DO NOT approach containers suspected to be hot. Continued... Chemwatch: 20-8057 Page 4 of 13 Issue Date: 13/03/2019 Version No: 5.1.1.1 Rowe Scientific Sodium Perchlorate Solution 50-70% w/w Print Date: 13/03/2019 Cool fire exposed containers with water spray from a protected location. If safe to do so, remove containers from path of fire. If fire gets out of control withdraw personnel and warn against entry. Equipment should be thoroughly decontaminated after use. Will not burn but increases intensity of fire. Heating may cause expansion or decomposition leading to violent rupture of containers. Heat affected containers remain hazardous. Contact with combustibles such as wood, paper, oil or finely divided metal may produce spontaneous combustion
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