What's the Best Way to Build a Molecular Machine?
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Aamjuly2020 Tyingmolknotlc Natchem
The University of Manchester Research Knotting a molecular strand can invert macroscopic effects of chirality DOI: 10.1038/s41557-020-0517-1 Document Version Accepted author manuscript Link to publication record in Manchester Research Explorer Citation for published version (APA): Katsonis, N., Lancia, F., Leigh, D. A., Pirvu, L., Ryabchun, A., & Schaufelberger, F. (2020). Knotting a molecular strand can invert macroscopic effects of chirality. Nature Chemistry. https://doi.org/10.1038/s41557-020-0517-1 Published in: Nature Chemistry Citing this paper Please note that where the full-text provided on Manchester Research Explorer is the Author Accepted Manuscript or Proof version this may differ from the final Published version. If citing, it is advised that you check and use the publisher's definitive version. General rights Copyright and moral rights for the publications made accessible in the Research Explorer are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights. Takedown policy If you believe that this document breaches copyright please refer to the University of Manchester’s Takedown Procedures [http://man.ac.uk/04Y6Bo] or contact [email protected] providing relevant details, so we can investigate your claim. Download date:07. Oct. 2021 Author-Accepted Manuscript NCHEM-19102092: Katsonis, et al ‘Knotting a molecular strand…’… 1 Knotting a Molecular Strand Can Invert Macroscopic Effects of Chirality Nathalie Katsonis[a,b]*, Federico Lancia[a], David A. Leigh[c,d]*, Lucian Pirvu[c], Alexander RyaBchun[a,b] and Fredrik SchaufelBerger[c] [a]Bio-inspired and Smart Materials, MESA+ Institute for Nanotechnology, University of Twente, P.O. -
1 Reaction of Researchers to Plan S; Too Far, Too Risky? an Open Letter
Reaction of Researchers to Plan S; Too far, too risky? An Open Letter from Researchers to European Funding Agencies, Academies, Universities, Research Institutions, and Decision Makers We support open access (OA) and Plan S is probably written with good intentions. However, Plan S1, as currently presented by the EU (and several national funding agencies) goes too far, is unfair for the scientists involved and is too risky for science in general. Plan S has far- reaching consequences, takes insufficient care of the desires and wishes of the individual scientists and creates a range of unworkable and undesirable situations: (1) The complete ban on hybrid (society) journals of high quality is a big problem, especially for chemistry. Apart from the fact that we won’t be allowed to publish in these journals anymore, the direct effect of Plan S and the way in which some national funding agencies and academic/research institutions seem to want to manage costs may eventually even lead to a situation where we won’t even be able to legally read the most important (society) journals of for example the ACS, RSC and ChemPubSoc anymore. Note that in their announcement of Plan S, the Dutch funding organisation NWO (for example) wrote that they expect to cover the high article processing charges (APCs) associated with the desired Gold OA publishing model from money freed by disappearing or stopped subscriptions to existing journals2. As such, Plan S may (eventually) forbid scientists access to (and publishing in) >85% of the existing and highly valued (society) journals! So effectively Plan S would block access to exactly those journals that work with a valuable and rigorous peer-review system of high quality. -
Textures of Cholesteric Droplets Controlled by Photo-Switching Chirality at the Molecular Level Jiawen Chen, Emmanuelle Lacaze, Etienne Brasselet, Syuzanna R
Textures of cholesteric droplets controlled by photo-switching chirality at the molecular level Jiawen Chen, Emmanuelle Lacaze, Etienne Brasselet, Syuzanna R. Harutyunyan, Nathalie Katsonis, Ben L. Feringa To cite this version: Jiawen Chen, Emmanuelle Lacaze, Etienne Brasselet, Syuzanna R. Harutyunyan, Nathalie Katso- nis, et al.. Textures of cholesteric droplets controlled by photo-switching chirality at the molecular level. Journal of Materials Chemistry C, Royal Society of Chemistry, 2014, 2 (38), pp.8137-8141. <10.1039/C4TC01297F>. <hal-01068137> HAL Id: hal-01068137 https://hal.archives-ouvertes.fr/hal-01068137 Submitted on 19 Feb 2016 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Distributed under a Creative Commons Attribution - ShareAlike| 4.0 International License Textures of cholesteric droplets controlled by photo-switching chirality at the molecular level† Jiawen Chen,a Emmanuelle Lacaze,b Etienne Brasselet,c Syuzanna R. Harutyunyan,a Nathalie Katsonis*d and Ben L. Feringa*a We demonstrate the ultra-sensitive detection of molecular chirality experimentally, by investigating structural transitions in sessile droplets of cholesteric liquid crystals. By doping the liquid crystal with chiral molecular photo-switches, we demonstrate that both optical and structural transitions can be triggered by light, reversibly. -
ARC CBBC Annual Report 2017
Towards a sustainable route for the synthesis of chemical building blocks ARC CBBC Annual Report 2017 Table of contents 3 Foreword 5 ARC CBBC in a nutshell 6 Highlights of 2017 9 Research projects’ progress 9 Multilateral Program Line 19 Bilateral Program Line 23 Scientific excellence 24 Visibility and collaboration 26 Organization and governance 31 List of abbreviations Contact ARC CBBC Office Budapestlaan 6 3584 CD Utrecht The Netherlands +31 (0)30 253 5202 [email protected] Prof.dr.ir. B. M. Weckhuysen Utrecht University, Scientific Director +31 (0)30 253 43 28 [email protected] Ms. E. Molnar Utrecht University, Managing Director +31 (0)30 253 52 02 [email protected] www.arc-cbbc.nl Composed by ARC CBBC Office, June 2018 Design: WAT ontwerpers, Utrecht Foreword On behalf of the Executive Board, I hereby present the ARC CBBC Annual Report. The report will provide you with an overview of the activities undertaken and the further development of our research programs throughout the second official year of our research center. Our community has gathered several times. During these meetings, inspiring discussions brought us to a more definite formulation of our research topics. They have been reviewed by our Scientific Advisory Board in two rounds, one in April 2017 and the other quite recently, in April 2018. The first projects of ARC CBBC have already started. PhD candidates and one postdoctoral fellow have been appointed on some of our bilateral projects. Furthermore, our first two flagship projects, on bio-based coatings and bimetallic catalysts, have been approved and will start soon. -
What's the Best Way to Build a Molecular Machine?
NEWS FEATURE What’s the best way to build a molecular machine? NEWS FEATURE Chemists are tinkering with a variety of different designs and means of propulsion, though practical uses for these mini-motors have yet to be realized. Stephen Ornes, Science Writer Some of the smallest, most useful machines known to The idea of using molecules to build minuscule science are the biological molecules that keep living machines that perform useful tasks dates back at least things living. The protein myosin drives the contrac- to a lecture given in 1959 by physicist Richard Feynman tion and relaxation of muscle. Kinesin drags cellular titled “There’s Plenty of Room at the Bottom.”*More cargo around the cell. Motor enzymes unwind, rewind, recently, demonstrations of artificial molecular ma- and maintain DNA, and bacteria use a molecular motor chines offer good reasons to think that such devices to rotate their whip-like flagella up to 100,000 times per are feasible. Researchers have forged motors, shuttles, minute, propelling them forward. These machines turn elevators, walkers, and pumps out of molecules, and chemical energy into motion. They’re very efficient at powered them with electrical energy, chemical re- their jobs. actions, or light. Tiny motor by tiny motor, these Now researchers are building synthetic cousins of demonstrations are inching toward future applications these molecular machines, taking inspiration not only that could range from molecular electronics to artificial from their design but also their function. “Nature has muscles. worked with over 3 billion years of evolution to use Today, though, the work is so fundamental that no them for every conceivable thing,” says chemist David one really knows what to do with the machines or how Leigh at the University of Manchester in the United they’ll be useful.