Titanium Mineral Concentrates1
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.. & METEORITIC RUTILE Peter R. Buseck Departments of Geology and Chemistry Arizona State University Tempe, Arizona Klaus Keil Space Sciences Division National Aeronautics and Space Administration Ames Research Center Mof fett Field, California r ABSTRACT Rutile has not been widely recognized as a meteoritic constituent. show, Recent microscopic and electron microprobe studies however, that Ti02 . is a reasonably widespread phase, albeit in minor amounts. X-ray diffraction studies confirm the Ti02 to be rutile. It was observed in the following meteorites - Allegan, Bondoc, Estherville, Farmington, and Vaca Muerta, The rutile is associated primarily with ilmenite and chromite, in some cases as exsolution lamellae. Accepted for publication by American Mineralogist . Rutile, as a meteoritic phase, is not widely known. In their sunanary . of meteorite mineralogy neither Mason (1962) nor Ramdohr (1963) report rutile as a mineral occurring in meteorites, although Ramdohr did describe a similar phase from the Faxmington meteorite in his list of "unidentified minerals," He suggested (correctly) that his "mineral D" dght be rutile. He also ob- served it in several mesosiderites. The mineral was recently mentioned to occur in Vaca Huerta (Fleischer, et al., 1965) and in Odessa (El Goresy, 1965). We have found rutile in the meteorites Allegan, Bondoc, Estherville, Farming- ton, and Vaca Muerta; although nowhere an abundant phase, it appears to be rather widespread. Of the several meteorites in which it was observed, rutile is the most abundant in the Farmington L-group chondrite. There it occurs in fine lamellae in ilmenite. The ilmenite is only sparsely distributed within the . meteorite although wherever it does occur it is in moderately large clusters - up to 0.5 mn in diameter - and it then is usually associated with chromite as well as rutile (Buseck, et al., 1965), Optically, the rutile has a faintly bluish tinge when viewed in reflected, plane-polarized light with immersion objectives. -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Titanium Dioxide Nanoparticles: Prospects and Applications in Medicine
nanomaterials Review Titanium Dioxide Nanoparticles: Prospects and Applications in Medicine Daniel Ziental 1 , Beata Czarczynska-Goslinska 2, Dariusz T. Mlynarczyk 3 , Arleta Glowacka-Sobotta 4, Beata Stanisz 5, Tomasz Goslinski 3,* and Lukasz Sobotta 1,* 1 Department of Inorganic and Analytical Chemistry, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland; [email protected] 2 Department of Pharmaceutical Technology, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland; [email protected] 3 Department of Chemical Technology of Drugs, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland; [email protected] 4 Department and Clinic of Maxillofacial Orthopedics and Orthodontics, Poznan University of Medical Sciences, Bukowska 70, 60-812 Poznan, Poland; [email protected] 5 Department of Pharmaceutical Chemistry, Poznan University of Medical Sciences, Grunwaldzka 6, 60-780 Poznan, Poland; [email protected] * Correspondence: [email protected] (T.G.); [email protected] (L.S.) Received: 4 January 2020; Accepted: 19 February 2020; Published: 23 February 2020 Abstract: Metallic and metal oxide nanoparticles (NPs), including titanium dioxide NPs, among polymeric NPs, liposomes, micelles, quantum dots, dendrimers, or fullerenes, are becoming more and more important due to their potential use in novel medical therapies. Titanium dioxide (titanium(IV) oxide, titania, TiO2) is an inorganic compound that owes its recent rise in scientific interest to photoactivity. After the illumination in aqueous media with UV light, TiO2 produces an array of reactive oxygen species (ROS). The capability to produce ROS and thus induce cell death has found application in the photodynamic therapy (PDT) for the treatment of a wide range of maladies, from psoriasis to cancer. -
Electronic Structure and Optical Properties of Prominent Phases of Tio2: First-Principles Study
Pramana – J. Phys. (2017) 89:5 © Indian Academy of Sciences DOI 10.1007/s12043-017-1400-5 Electronic structure and optical properties of prominent phases of TiO2: First-principles study SANTOSH SINGH and MADHVENDRA NATH TRIPATHI∗ Department of Pure and Applied Physics, Guru Ghasidas Vishwavidyalaya (Central University), Koni, Bilaspur 495 009, India ∗Corresponding author. E-mail: [email protected] Published online 19 June 2017 Abstract. First-principles study based on density functional theory (DFT) of two prominent phases, the rutile and the anatase phases, of titanium dioxide (TiO2) are reported within the generalized gradient approximation (GGA). Our calculated band structure shows that there is a significant presence of O-2p and Ti-3d hybridization in the valence bands. These bands are well separated from the conduction bands by a direct band gap value of 1.73 eV in the rutile phase and an indirect band gap value of 2.03 eV in the anatase phase, from to X. Our calculations reproduced the peaks in the conduction and valence band, are in good agreement with experimental observations. Our structural optimization for the rutile and anatase phase led to lattice parameter values of 4.62 Å and 2.99 Å rutile and 3.80 Å and 9.55 Å for anatase for a and c. The static dielectric values 7.0 and 5.1 for the rutile and anatase phases respectively are in excellent agreement with experimental results. Our calculation of optical properties reveals that maximum value of the transmittance in anatase phase of TiO2 may be achieved by considering the anisotropic behaviour of the optical spectra in the optical region for transparent conducting application. -
The I\,Iagnetic Separation of Soi'ie Alluvial I,Iinerals in I'ialaya*
THE AMERICAN MINERAI,OGIST, VOL. 41, JULY AUGUST, 1959 THE I\,IAGNETIC SEPARATION OF SOI'IE ALLUVIAL I,IINERALS IN I'IALAYA* B. H. FnNrant, Minerals Eramination Diaision, GeologicalSurttey D epartment, F'ederotion of M al,aya. Assrnlcr This paper presents the results of a seriesof magnetic separationswhich have been in- vestigated {or a number of minerals occurring in X{alayan alluvial concentrates.The pur- pose of the investigations was to establish,by the isolation of individual mineral species,a reproducible and reliable method for the identification and quantitative estimation of minerals in alluvial concentrates examined by the Geological Survey in Malaya In par- ticular was sought the isolation of columbite from ubiquitous ilmenite. All the separations were made on the small, highly sensitive Frantz Isodynamic Model L-1 laboratory separa- tor, The minerals which have been successfully separated include ailanite, anatase, andalu- site (and chiastolite), arsenopyrite, brookite, cassiterite,columbite, epidote, gahnite, garnet (pink), ilmenite, manganeseoxide (51.6/e Mn), monazite, pyrite, rutile, scheelite,siderite, staurolite, thorite, topaz, tourmaline, uranoan monazite, wolframite, xenotime, and zircon. PnocBpunp When using an inclined feed, the Frantz Isodynamic separator (see Figs. 1(A) & (B)) hasthree inherent variables. These are the field strengLh (current used),the sideslope, and the forward slope. 5;6s $lope wdrd 511)Pe (A) (B) Irc. 1. Diagrammatic representation of side slope and forward slope. The field strength is increasedby means of a rheostat which raises the current from zero in stagesof 0.05 amps. to 1.4 amps. Early in the investigationsit was decidedthat stepsof 0.1 amp. would be sufficiently gradual. -
Combustion Synthesis, Sintering, Characterization, and Properties
Hindawi Advances in Materials Science and Engineering Volume 2019, Article ID 9639016, 9 pages https://doi.org/10.1155/2019/9639016 Research Article Calcium Titanate from Food Waste: Combustion Synthesis, Sintering, Characterization, and Properties Siriluk Cherdchom,1 Thitiwat Rattanaphan,1 and Tawat Chanadee 1,2 1Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University (PSU), Hat Yai, Songkhla 90110, &ailand 2Ceramic and Composite Materials Engineering Research Group (CMERG), Center of Excellence in Materials Engineering (CEME), Prince of Songkla University (PSU), Hat Yai, Songkhla 90110, &ailand Correspondence should be addressed to Tawat Chanadee; [email protected] Received 31 August 2018; Revised 20 December 2018; Accepted 3 January 2019; Published 12 February 2019 Academic Editor: Andres Sotelo Copyright © 2019 Siriluk Cherdchom et al. )is is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Calcium titanate (CaTiO3) was combustion synthesized from a calcium source of waste duck eggshell, anatase titanium dioxide (A-TiO2), and magnesium (Mg). )e eggshell and A-TiO2 were milled for 30 min in either a high-energy planetary mill or a conventional ball mill. )ese powders were then separately mixed with Mg in a ball mill. After synthesis, the combustion products were leached and then sintered to produce CaTiO3 ceramic. Analytical characterization of the as-leached combustion products revealed that the product of the combustion synthesis of duck eggshell + A-TiO2 that had been high-energy-milled for 30 min before synthesis comprised a single perovskite phase of CaTiO3. -
CRYSTAL SRUKTUR of CALCIUM TITANATE (Catio3) PHOSPHOR DOPED with PRASEODYMIUM and ALUMINIUM IONS
CRYSTAL SRUKTUR OF CALCIUM TITANATE (CaTiO3) PHOSPHOR DOPED WITH PRASEODYMIUM AND ALUMINIUM IONS STRUKTUR KRISTAL FOSFOR KALSIUM TITANIA DIDOPKAN DENGAN ION PRASEODYMIUM DAN ALUMINIUM IONS Siti Aishah Ahmad Fuzi1* and Rosli Hussin2 1 Material Technology Group, Industrial Technology Division, Malaysian Nuclear Agency, Bangi, 43000 Kajang, Selangor Darul Ehsan, Malaysia. 2 Department of Physics, Faculty of Science, Universiti Teknologi Malaysia, 81310 Skudai, Johor 1*[email protected], [email protected] Abstract The past three decades have witnessed rapid growth in research and development of luminescence phenomenon because of their diversity in applications. In this paper, Calcium Titanate (CaTiO3) was studied to find a new host material with desirable structural properties for luminescence-based applications. Solid state reactions o 3+ methods were used to synthesis CaTiO3 at 1000 C for 6 hours. Crystal structure of CaTiO3 co-doped with Pr 3+ and Al were investigated using X-Ray Diffraction (XRD) method. Optimum percentage to synthesis CaTiO3 was 3+ obtained at 40 mol%CaO-60 mol%TiO2 with a single doping of 1 mol%Pr . However, a crystal structure of 4 mol% of Al3+ co-doped with Pr3+ was determined as an optimum parameter which suitable for display imaging. Keywords: calcium titanate, anatase, rutile Abstrak Semenjak tiga dekad yang lalu telah menunjukkan peningkatan yang ketara bagi kajian dan pembangunan dalam bidang fotolumiscen. Peningkatan ini berkembang dengan meluas disebabkan oleh kebolehannya untuk diaplikasikan dalam pelbagai kegunaan harian. Dalam manuskrip ini, kalsium titania (CaTiO3) telah dikaji untuk mencari bahan perumah dengan sifat struktur yang bersesuaian bagi aplikasi luminescen. Tindak balas keadaan o pepejal telah digunakan bagi mensintesis CaTiO3 pada suhu 1000 C selama 6 jam. -
INCLUSIONS in AQUAMARINE from AMBATOFOTSIKELY, MADAGASCAR Fabrice Danet, Marie Schoor, Jean-Claude Boulliard, Daniel R
NEW Danet G&G Fall 2012_Layout 1 9/27/12 11:31 AM Page 205 RAPID COMMUNICATIONS INCLUSIONS IN AQUAMARINE FROM AMBATOFOTSIKELY, MADAGASCAR Fabrice Danet, Marie Schoor, Jean-Claude Boulliard, Daniel R. Neuville, Olivier Beyssac, and Vincent Bourgoin grams of translucent to transparent beryl were pro- duced, as well as several tonnes of opaque material In January 2012, aquamarine crystals containing for industrial use. While only a very small percentage interesting inclusions were extracted from the Am- was suitable for faceting, several hundred aqua- batofotsikely area northwest of Antsirabe, Mada- marines in the 1–35 ct range have been cut. In April gascar. These specimens displayed various types 2012, one of the authors (FD) traveled to the locality of eye-visible and microscopic inclusions, and and obtained representative samples. some had an unusual form. Raman microspec- troscopy identified reddish brown plate lets as Location and Geologic Setting. The workings are lo- hematite, while ilmenite was found as black cated less than 1 km north of Ambatofotsikely (a village platelets, black needles, and distinctive dark gray now locally known as Ambatofotsy Carole), 22 km dendrites. Similar inclusions are known in beryl north-northwest of Ankazomiriotra, and 74 km north- from Brazil, India, Mozambique, and Sri Lanka. west of Antsirabe. The deposit is centered at coordinates 19°27.662¢S, 46°27.450¢E, at an elevation of 1,010 m. The site is accessed by a paved road (RN 34) from ining activity near the central Malagasy village Antsirabe to a point 16 km west of Ankazomiriotra. of Ambatofotsikely was first documented nearly From there, a trail extends 15 km to Ambatofotsikely. -
Mineralogy and Origin of the Titanium
MINERALOGY AND ORIGIN OF THE TITANIUM DEPOSIT AT PLUMA HIDALGO, OAXACA, MEXICO by EDWIN G. PAULSON S. B., Massachusetts Institute of Technology (1961) SUBMITTED IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE at the MASSACHUSETTS INSTITUTE OF TECHNOLOGY May 18, 1962 Signature of At r . Depardnent of loggand Geophysics, May 18, 1962 Certified by Thesis Supervisor Ab Accepted by ...... Chairman, Departmental Committee on Graduate Students M Abstract Mineralogy and Origin of the Titanium Deposit at Pluma Hidalgo, Oaxaca, Mexico by Edwin G. Paulson "Submitted to the Department of Geology and Geophysics on May 18, 1962 in partial fulfillment of the requirements for the degree of Master of Science." The Pluma Hidalgo titanium deposits are located in the southern part of the State of Oaxaca, Mexico, in an area noted for its rugged terrain, dense vegetation and high rainfall. Little is known of the general and structural geology of the region. The country rocks in the area are a series of gneisses containing quartz, feldspar, and ferromagnesians as the dominant minerals. These gneisses bear some resemblance to granulites as described in the literature. Titanium minerals, ilmenite and rutile, occur as disseminated crystals in the country rock, which seems to grade into more massive and large replacement bodies, in places controlled by faulting and fracturing. Propylitization is the main type of alteration. The mineralogy of the area is considered in some detail. It is remarkably similar to that found at the Nelson County, Virginia, titanium deposits. The main minerals are oligoclase - andesine antiperthite, oligoclase- andesine, microcline, quartz, augite, amphibole, chlorite, sericite, clinozoi- site, ilmenite, rutile, and apatite. -
The Rutile Deposits of the Eastern United States
THE RUTILE DEPOSITS OF THE EASTERN UNITED STATES. By THOMAS L. WATSON. INTRODUCTION. The titanium-bearing minerals comprise more than 60 distinct species, grouped under a variety of mineral and chemical forms, chiefly as oxides, titanates, titano-silicates, silicates, columbates, and iantalates. These minerals are widely distributed in a variety of associations and in such quantity as to make titanium a relatively abundant element. Clarke* estimates the. amount of titanium in the solid crust of the earth to be 0.44 per cent, equivalent in oxide to 0.73 per cent, the element thus standing in the ninth place in the scale of abundance, next to potassium. Most of the titanium-bearing minerals, however, are rare and are only of scientific interest. The largest concentrations of the element are as oxide (rutile), as iron titanate (ilmenite), and in iron ferrate (magnetite) as intergrown ilmenite. Of these three forms the prin cipal source of the element at present is rutile. The known workable deposits of rutile, however, are extremely few and widely sepa rated, and as the demand for titanium has greatly increased in the last few years it has been necessary for some uses to turn to ilmenite or highly titaniferous magnetites. This paper briefly summarizes present knowledge of the geology of the rutile deposits in the eastern United States and for the sake of comparison discusses several foreign deposits, each of which has produced some rutile. Of the known deposits in the United, States only those in Virginia are of commercial importance. These have been made the subject of a special report 2 by the Virginia Geological Survey, which was preceded by a preliminary paper on the rutile deposits of Amherst and Nelson counties.3 1 Clarke, F. -
Weathering of Ilmenite from Granite and Chlorite Schist in the Georgia Piedmont
American Mineralogist, Volume 87, pages 1616–1625, 2002 Weathering of ilmenite from granite and chlorite schist in the Georgia Piedmont PAUL A. SCHROEDER,* JOHN J. LE GOLVAN, AND MICHAEL F. RODEN Department of Geology, University of Georgia, Athens, Georgia 30602-2501, U.S.A. ABSTRACT Ilmenite grains from weathering profiles developed on granite and ultramafic chlorite schist in the Georgia Piedmont were studied for evidence of morphological and chemical alteration. Ilmenite- rich concentrates from the fine sand (90–150 mm) component were studied to test the assumption that there is no difference between ilmenite in the parent rock and that in colluvium delivered to primary drainage systems. Ilmenite grains in the granite profile are rounded to subhedral, and commonly contain hematite exsolution blebs. Dissolution pits are observed along the boundaries of the exsolution blebs, with goethite occurring as an alteration product. Ilmenite grains in the schist profile occur as fractured anhedral grains with uncommon lamellae of rutile. Grain fractures are filled with goethite and he- matite, particularly in the B-horizon. Ilmenite from the granite profile is Mn rich (7–15 mol% MnTiO3), whereas ilmenite from the schist profile contains only 1–2 mol% MnTiO3 and up to 8 mol% MgTiO3. Two populations of grains develop in both profiles. Grains with abundant exsolution blebs and fractures alter through a proposed two-step reaction mechanism. It is proposed that il- menite first undergoes a solid-state transformation to pseudorutile via an anodic oxidation mecha- nism. Oxidized Fe and Mn diffuse from the structure and precipitate as goethite and MnO2. Pseudorutile is ephemeral and undergoes incongruent dissolution to form anatase, hematite, and goethite. -
Development of Highly Transparent Zirconia Ceramics
11 Development of highly transparent zirconia ceramics Isao Yamashita *1 Masayuki Kudo *1 Koji Tsukuma *1 Highly transparent zirconia ceramics were developed and their optical and mechanical properties were comprehensively studied. A low optical haze value (H<1.0 %), defined as the diffuse transmission divided by the total forward transmission, was achieved by using high-purity powder and a novel sintering process. Theoretical in-line transmission (74 %) was observed from the ultraviolet–visible region up to the infra-red region; an absorption edge was found at 350 nm and 8 µm for the ultraviolet and infrared region, respectively. A colorless sintered body having a high refractive index (n d = 2.23) and a high Abbe’s number (νd = 27.8) was obtained. A remarkably large dielectric constant (ε = 32.7) with low dielectric loss (tanδ = 0.006) was found. Transparent zirconia ceramics are candidates for high-refractive index lenses, optoelectric devices and infrared windows. Transparent zirconia ceramics also possess excellent mechanical properties. Various colored transparent zirconia can be used as exterior components and for complex-shaped gemstones. fabricating transparent cubic zirconia ceramics.9,13-19 1.Introduction Transparent zirconia ceramics using titanium oxide as Transparent and translucent ceramics have been a sintering additive were firstly reported by Tsukuma.15 studied extensively ever since the seminal work on However, the sintered body had poor transparency translucent alumina polycrystal by Coble in the 1960s.1 and low mechanical strength. In this study, highly Subsequently, researchers have conducted many transparent zirconia ceramics of high strength were studies to develop transparent ceramics such as MgO,2 developed.