Thermal Degradation Behaviors of Sawdust Wood Waste: Pyrolysis Kinetic and Mechanism
Journal(of(Materials(and(( J. Mater. Environ. Sci., 2019, Volume 10, Issue 8, Page 742-755 Environmental(Sciences( ISSN(:(2028;2508( CODEN(:(JMESCN( http://www.jmaterenvironsci.com! Copyright(©(2019,( University(of(Mohammed(Premier(((((( (OuJda(Morocco( Thermal degradation behaviors of sawdust wood waste: pyrolysis kinetic and mechanism MY. Guida1,2,*, S. Lanaya2, Z. Rbihi2, A. Hannioui1,2 1Department of Chemistry and Environment, Faculty of Sciences and Techniques (FST), University of Sultan Moulay Slimane, 23000 Béni-Mellal, Morocco. 2 Organic Chemistry and Analytical Laboratory, Faculty of Sciences and Techniques (FST), University of Sultan Moulay Slimane, 23000 Béni-Mellal, Morocco. Received 25 May 2019, Abstract Revised 22 August 2019, In this study, the thermal behavior of sawdust wood (SW) wastes samples was examined at Accepted 23 August 2019 different heating rates (β) ranging from 2 to 15 °C/min in inert atmosphere using the Keywords technique of thermogravimetric analysis (TGA). As the increment of heating rates, the variations of characteristic parame ters from the TG-DTG curves were determined. Eight Sawdust wood waste ! methods: Friedman (FR), Ozawa-Flynn-Wall (OFW), Vyazovkin (VYA), Kissinger- ! Pyrolysis Akahira-Sunose (KAS), Starink method (ST), Avrami theory (AT), Coats-Redfern and ! Thermogravimetric Criado methods were used in this work to evaluate the kinetic parameters, including analysis apparent activation energy (Ex), reaction order (n) and the appropriate conversion model ! Kinetic analysis f(x). For the range of conversion degree (x) investigated (20 – 80 %), the mean values of parameters apparent activation energy for Sawdust wood waste were 168 KJ/mol, 153 KJ/mol and 164 ! TGA-DTG KJ/mol for FR, OFW and VYA methods respectively.
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