NARMADARIA LABORATORIES PVT. LTD. SY. NO. 127/127, PLOT NO. 8, PHASE II, NADIKUDI INDUSTRIAL PARK, MANDAL, GUNTUR DISTRICT,

1. FORM I

Project No. 0917‐21‐02 September 2017

STUDIES AND DOCUMENTATION BY Narmadaria Laboratories Pvt. Ltd. TEAM Labs and Consultants Door No. 3‐6‐666, 2nd Floor,Barwale Chambers, B‐115‐117 & 509, Annapurna Block, Road No. 10, Himayat Nagar, Aditya Enclave, Ameerpet, Hyderabad – 500 029 Hyderabad‐500 038. Phone: +91 93966 6399 Phone: 040‐23748 555/23748616, E‐mail: [email protected] Telefax: 040‐23748666

SUBMITTED TO STATE LEVEL ENVIRONMENT IMPACT ASSESSMENT AUTHORITY, ANDHRA PRADESH, GOVERNMENT OF Narmadaria Laboratories Pvt. Ltd.

APPENDIX – I (See Paragraph – 6) FORM I

I) Basic Information S.No. Item Details 1 Name of the Project/s Narmadaria Laboratories Pvt. Ltd. 2 5 f – B category - Synthetic Organic Chemicals S. No in the Schedule (Bulk Drug and Intermediates) 3 Proposed capacity/area/length/tonnage to be Production Capacity: 750 Kg/day handled/command area/lease area/number of Total Site Area: 2.85 acres wells to be drilled Project Cost: 8.45 Crores Propose to manufacture 4 products out of 15 products on campaign basis. 4 New/Expansion/Modernization New 5 Existing Capacity/Area etc. Not Applicable 6 Category of Project i.e. 'A' or 'B' “B” 7 Does it attract the general condition? If yes, No please specify 8 Does it attract the Specific condition? If yes, No please specify. 9 Location Plot/Survey/Khasra No. Sy. No. 127/127, Plot No. 8, Phase II, Nadikudi Industrial Park,

Village Nadikudi Village Tehsil Dachepalle Mandal District Guntur District State Andhra Pradesh 10 Nearest railway station/airport along with Nadikudi Railway Station – 1.8 Km distance in kms. Vijayawada Airport – 115 Km 11 Nearest Town, City, District Headquarters Nadikudi – 1.2 km along with distance in kms. 12 Village Panchayats, Zilla Parishad, Municipal Nadikudi Panchayath Corporation, Local body (complete postal address with telephone nos. to be given) 13 Name of the Applicant M. Srinivas 14 Registered Address Sy. No. 127/127, Plot No. 8, Phase II, Nadikudi Industrial Park, Dachapalle Mandal, Guntur District, Andhra Pradesh. 15 Address for Correspondence: Name M. Srinivas Designation(Owner/Partner/CEO) Executive Director Address Door No. 3-6-666, 2nd Floor,Barwale Chambers, Road No. 10, Himayat Nagar, Hyderabad Pin Code 500 029. E-mail [email protected]

Form I Page 1 Narmadaria Laboratories Pvt. Ltd.

[email protected] Telephone Number +91-93966 6399 +91-91546 66644 Fax No. 16 Details of alternative Sites examined, if any. -NA- Location of these sites should be shown on a topo sheet. 17 Interlinked Projects -NA- 18 Whether separate application of interlinked No project has been submitted? 19 If yes, date of submission 20 If no, reason 21 Whether the proposal involves -NA- approval/clearance under: if yes, details of the same and their status to be given. (a) The Forest (Conservation) Act, 1980? (b) The Wildlife (Protection) Act, 1972? (c) The C.R.Z Notification, 1991? 22 Whether there is any Government No Order/Policy relevant/relating to the site? 23 Forest land involved (hectares) No 24 Whether there is any location pending against No the project and /or land in which the project is propose to be set up? (a) Name of the Court (b) Case No (c) Orders/directions of the Court, if any and its relevance with the proposed project.

Form I Page 2 Narmadaria Laboratories Pvt. Ltd.

(II) Activity

1. Construction, operation or decommissioning of the Project involving actions, which will cause physical changes in the locality (topography, land use, changes in water bodies, etc.) S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities /rates, wherever possible) with source of information data 1.1 Permanent or temporary change in land NO The land area used for the proposed plant is 2.85 use, land cover or topography including acres. increase in intensity of land use (with respect to local land use plan) 1.2 Clearance of existing land, vegetation NO The proposed land area is located in Phase II IDA and buildings? Nadikudi Industrial Park. 1.3 Creation of new land uses? NO 1.4 Pre‐construction investigations e.g. bore YES Soil test done and soil load bearing capacity houses, soil testing? established. 1.5 Construction works? YES Construction activity involves creation of new production blocks, utilities like Boilers, Chilling Plant etc ; 1.6 Demolition works? NO 1.7 Temporary sites used for construction NO Construction labor from local villages shall be works or housing of construction employed. workers? 1.8 Above ground buildings, structures or YES Storage facilities shall be constructed. No major earthworks including linear structures, cut and fill or excavation is anticipated. cut and fill or excavations 1.9 Underground works including mining or NO tunneling? 1.10 Reclamation works? NO 1.11 Dredging? NO 1.12 Offshore structures? NO 1.13 Production and manufacturing YES Enclosed in Annexure – I processes? 1.14 Facilities for storage of goods or NO Raw materials and solvents shall be stored with in materials? factory premises. Materials in bags and drums will be stored in properly designed warehouse with adequate safe guards. Bulk quantities of raw materials will be stored in Bulk Storage tanks in the tank farms with retention dykes. 1.15 Facilities for treatment or disposal of YES Effluent is treated with in the plant premises. solid waste or liquid effluents? Organic waste is sent to cement plants for co‐ incineration. Solid waste generated from Multiple Effect evaporators sent to TSDF. Details of waste treatment facilities presented in Annexure II.

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Narmadaria Laboratories Pvt. Ltd.

1.16 Facilities for long term housing of NO Local people shall be employed. operational workers? 1.17 New road, rail or sea traffic during YES Construction materials shall be transported to the construction or operation? site. The traffic density of the existing connecting road is negligible. 1.18 New road, rail, air waterborne or other NO transport infrastructure including new or altered routes and stations, ports, airports etc? 1.19 Closure or diversion of existing transport NO routes or infrastructure leading to changes in traffic movements? 1.20 New or diverted transmission lines or NO pipelines? 1.21 Impoundment, damming, culverting, NO realignment or other changes to the hydrology of watercourses or aquifers? 1.22 Stream crossings? NO 1.23 Abstraction or transfers of water form YES Total water required shall be 151.2 KLD out of ground or surface waters? which 52 KLD shall be drawn from bore well and the balance shall be recycled water 1.24 Changes in water bodies or the land NO surface affecting drainage or run‐off? 1.25 Transport of personnel or materials for YES The construction material shall be drawn from construction, operation or local sources within 10 – 15 km. There is no decommissioning? transport of personnel, as the construction workers shall be drawn from local villages. 1.26 Long‐term dismantling or NO decommissioning or restoration works? 1.27 Ongoing activity during decommissioning NO which could have an impact on the environment? 1.28 Influx of people to an area in either YES The proposed project shall increase the temporarily or permanently? employment potential and hence may lead to migration to surrounding villages. 1.29 Introduction of alien species? NO 1.30 Loss of native species or genetic NO There are no major losses of tree/shrub species. diversity? 1.31 Any other actions? NO

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Narmadaria Laboratories Pvt. Ltd.

2. Use of Natural resources for construction or operation of the Project (such as land, water, materials or energy, especially any resources which are non‐renewable or in short supply): S.No. Information/checklist confirmation Yes/No Details thereof (with approximate quantities /rates, wherever possible) with source of information data 2.1 Land especially undeveloped or NO Land area 2.85 acres agricultural land (ha) Located at Sy. No. 127/127, Plot No. 8, Phase II, Nadikudi Industrial Park, Dachapalle Mandal, Guntur District, Andhra Pradesh. 2.2 Water (expected source & competing YES Total water required shall be 151.2 KLD out of users) unit: KLD which 52 KLD shall be drawn from bore well and the balance shall be recycled water. (Water Balance Enclosed in Annexure III) 2.3 Minerals (MT) NA 2.4 Construction material – stone, YES Shall be sourced from the local villages. aggregates, sand / soil (expected source – MT) 2.5 Forests and timber (source – MT) NO 2.6 Energy including electricity and fuels YES The required energy shall be drawn from (source, competing users) Unit: fuel APTRANSCO. DG set of 500 KVA shall be provided (MT), energy (MW) to cater to energy requirement during load shut downs.

The other energy source is Coal Fired Boiler of 3 TPH capacity to meet the steam requirement. The required quantity of fuel for proposed 3 TPH boiler shall be 13.5 TPD 2.7 Any other natural resources (use NA appropriate standard units)

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Narmadaria Laboratories Pvt. Ltd.

3. Use, storage, transport, handling or production of substances or materials, which could be harmful to human health or the environment or raise concerns about actual or perceived risks to human health. S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 3.1 Use of substances or materials, which are YES Solvents shall be used as reaction media. MSIHC hazardous (as per MSIHC rules) to human rules shall be followed during storage, health or the environment (flora, fauna, transportation and handling of raw materials and and water supplies) hazardous chemicals. 3.2 Changes in occurrence of disease or NO affect disease vectors (e.g. insect or water borne diseases). 3.3 Affect the welfare of people e.g. by YES Shall increase the employment potential for locals changing living conditions? and affect the living conditions for betterment.

3.4 Vulnerable groups of people who could NO No sensitive receptors are present in the be affected by the project e.g. hospital immediate vicinity of the site. The project shall patients, children, the elderly etc., not have any significant impact on vulnerable groups of people. 3.5 Any other causes NO

4. Production of solid wastes during construction or operation or decommissioning (MT/month) S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 4.1 Spoil, overburden or mine wastes NO 4.2 Municipal waste (domestic and or NO Wastes from canteen, other commercial wastes commercial wastes) like paper, empty containers etc. The canteen wastes and commercial wastes shall be in the range of 1 kg/day 4.3 Hazardous wastes (as per Hazardous YES The quantity of hazardous wastes generated Waste Management Rules) during construction contains waste oils and batteries from DG set.

The quantity of hazardous waste generated during operation contain salts from evaporators, distillate, process residue, and solvent residues, sludge and filtration media etc. enclosed in Annexure – IV 4.4 Other industrial process wastes YES Enclosed at Annexure IV 4.5 Surplus product NO 4.6 Sewage sludge or other sludge from YES Sludge from Effluent treatment System shall be effluent treatment sent to TSDF.

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Narmadaria Laboratories Pvt. Ltd.

4.7 Construction or demolition wastes NO Construction activity involves creation of new production blocks, utilities like boilers, Chilling Plant etc., 4.8 Redundant machinery or equipment NO 4.9 Contaminated soils or other materials NO Structures of all waste treatment facilities are made of concrete and also above ground to eliminate the possibility of any contamination due to seepage and for ease of maintenance. 4.10 Agricultural wastes NO 4.11 Other solid wastes NO Enclosed at Annexure IV

5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr) S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 5.1 Emissions from combustion of fossil fuels YES Coal Shall be used as fuel. Quantity of fuel and from stationary or mobile sources emissions details are enclosed in Annexure V

5.2 Emissions from production processes YES Enclosed in Annexure ‐ VI 5.3 Emissions from materials handling NO Material transfer takes place in closed pipeline including storage or transport systems using pumps with mechanical seals. 5.4 Emissions from construction activities YES Dust may rise during transport of material and including plant and equipment construction activity. The dust emissions shall be mitigated by water spraying on the roads within the premises. 5.5 Dust or odors from handling of materials NO including construction materials, sewage and waste 5.6 Emissions from incineration of waste NO 5.7 Emissions from burning of waste in open NO air (e.g. slash materials, construction debris) 5.8 Emissions from any other sources NO

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Narmadaria Laboratories Pvt. Ltd.

6. Generation of Noise and Vibration, and Emissions of Light and Heat: S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data with source of information data 6.1 From operation of equipment e.g. YES Material transport and construction equipment shall be engines, ventilation plant, crushers source of noise, while transfer pumps, vacuum systems, DG sets are the sources of noise during operation. 6.2 From industrial or similar processes YES From DG sets, and controlled by providing Acoustic Enclosures. 6.3 From construction or demolition YES Noise during construction shall be due to construction equipment and emergency DG sets. 6.4 From blasting or piling NO

6.5 From construction or operational NO The increased traffic shall not have any significant traffic impact. 6.6 From lighting or cooling systems NO 6.7 From any other sources NO

7.Risks of contamination of land or water from releases of pollutants into the ground or into sewers, surface waters, groundwater, coastal waters or the sea: S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 7.1 From handling, storage, use or NO All the hazardous materials will be stored in Tanks/MS spillage of hazardous materials drums, in a covered shed and no contamination of soil is expected 7.2 From discharge of sewage or other NO All the wastes from domestic operations are sent to effluents to water or the land septic tank. (expected mode and place of discharge)

7.3 By deposition of pollutants emitted NO Air Pollutants generated are let out into atmosphere to air into the land or into water after meeting the prescribed standards. 7.4 From any other sources NO 7.5 Is there a risk of long term build up NO of pollutants in environment from these sources?

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Narmadaria Laboratories Pvt. Ltd.

8.Risk of accidents during construction or operation of the Project, which could affect human health or the environment S.No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data

8.1 From explosions, spillages, fires etc from YES All Inbuilt Safety precautions will be storage, handling, use or production of adopted and there will not be any hazardous substances damage to environment or human health 8.2 From any other causes NA 8.3 Could the project be affected by natural NO disasters causing environmental damage (e.g? Floods, earthquakes, landslides, cloudburst etc)?

9.Factors which should be considered (such as consequential development) which could lead to environmental effects or the potential for cumulative impacts with other existing or planned activities in the locality S. No. Information/Checklist confirmation Yes/No Details thereof (with approximate quantities/rates, wherever possible) with source of information data 9.1 Lead to development of supporting. YES The project shall enhance the socio facilities, ancillary development or development economic status of the area by stimulated by the project which could have impact increasing the demand for housing, on the environment e.g.: improving the employment. There are • Supporting infrastructure (roads, power supply, no major support industries required waste or waste water treatment, etc.) for this plant. • housing development • extractive industries • supply industries • other 9.2 Lead to after‐use of the site, which could haven NO impact on the environment 9.3 Set a precedent for later developments NO 9.4 Have cumulative effects due to proximity to other NO The baseline environmental status of existing or planned projects with similar effects the surrounding areas is within the prescribed limits as observed from the Secondary data.

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Narmadaria Laboratories Pvt. Ltd.

(III) Environmental Sensitivity S.No. Areas Name/ Aerial distance (within 15 km.) Proposed Identity project location boundary 1 Areas protected under international conventions, NA national or local legislation for their ecological, landscape, cultural or other related value 2 Areas which are important or sensitive for YES Gamalapadu RF – N– 5.5Km, ecological reasons ‐ Wetlands, watercourses or Madinapad RF – NE – 4Km other water bodies, coastal zone, biospheres, Daida RF – NW – 9.6Km mountains, forests Nagaleru Vagu – SE – 4 Km. 3 Areas used by protected, important or sensitive NA species of flora or fauna for breeding, nesting, foraging, resting, over wintering, migration 4 Inland, coastal, marine or underground waters NO 5 State, National boundaries NO 6 Routes or facilities used by the public for access NO to recreation or other tourist, pilgrim areas 7 Defense installations NO 8 Densely populated or built‐up area YES Nadikudi is at a distance of 1.2 km

9 Areas occupied by sensitive man‐made land uses NA (hospitals, schools, places of worship, community facilities) 10 Areas containing important, high quality or scarce NO resources (ground water resources, surface resources, forestry, agriculture, fisheries, tourism, minerals) 11 Areas already subjected to pollution or NO environmental damage. (those where existing legal environmental standards are exceeded) 12 Areas susceptible to natural hazard which could NO cause the project to present environmental problems (earthquakes, subsidence, landslides, erosion, flooding or extreme or adverse climatic conditions)

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NARMADARIA LABORATORIES PVT. LTD. SY. NO. 127/127, PLOT NO. 8, PHASE II, NADIKUDI INDUSTRIAL PARK, DACHEPALLE MANDAL, GUNTUR DISTRICT, ANDHRA PRADESH

ANNEXURES

Project No. 0917‐21‐02 September 2017

STUDIES AND DOCUMENTATION BY Narmadaria Laboratories Pvt. Ltd. TEAM Labs and Consultants Door No. 3‐6‐666, 2nd Floor,Barwale Chambers, B‐115‐117 & 509, Annapurna Block, Road No. 10, Himayat Nagar, Aditya Enclave, Ameerpet, Hyderabad – 500 029 Hyderabad‐500 038. Phone: +91 93966 6399 Phone: 040‐23748 555/23748616, E‐mail: [email protected] Telefax: 040‐23748666

SUBMITTED TO STATE LEVEL ENVIRONMENT IMPACT ASSESSMENT AUTHORITY, ANDHRA PRADESH, GOVERNMENT OF INDIA Narmadaria Laboratories Pvt. Ltd. Form I Annexure

LTD.

PVT.

LABORATORIES

NARMADARIA

Location MapLaboratories Pvt. Ltd. of Narmadaria

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Narmadaria Laboratories Pvt. Ltd. Form I Annexure

6 7 1 3 2 out of Narmadaria Laboratories Pvt. Ltd. Pvt. Laboratories of Narmadaria out y Plant La 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18.

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Narmadaria Laboratories Pvt. Ltd. Form I Annexure

ANNEXURE - I

M/s. Narmadaria Laboratories Pvt. Ltd. proposes to set up Synthetic Organic Chemicals (Bulk Drugs & Intermediates) unit of area of 2.85 acres at Sy. No. 127/127, Plot No. 8, Phase II, Nadikudi Industrial Park, Dachapalle Mandal, Guntur District, Andhra Pradesh. The proposed list products and manufacturing capacity is presented in Table A-1 respectively. Table A-1 Manufacturing Capacity S.No Name of Product C A S No. Capacity (Kg/day) 1 Clopidogrel 113665-84-2 200 2 Carisoprodol 78-44-4 50 3 Cinacalcet 226256-56-0 94 4 Fenbendazole 43210-67-9 200 5 Fluconazole 86386-73-4 200 6 Fexofenadine 153439-40-8 50 7 Gabapentane 60142-96-3 75 8 Irbesartan 138402-11-6 100 9 Itraconazole 84625-61-6 25 10 Levociterizine 130018-77-8 150 11 Memantine 19982-08-2 50 12 Quetiapine 111974-69-7 50 13 Rivaroxaben 366789-02-8 50 14 Simvastatin 79902-63-9 50 15 Ziprasidone 146939-27-7 50 Total – Worst Case any 4 Products on Campaign Basis 750

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Narmadaria Laboratories Pvt. Ltd. Form I Annexure

Process Description of Clopidogrel

Stage I O H Br NHCl O H2SO4 O CH CH 3 NaCl NaBr 3 Na2CO3 H SO CO 2 4 N Sodium ChlorideSodium Bromide2 HO + + Sodium Carbonate+ Sulphur S + + +Carbon Dioxide2 O M. Wt. 58.5 M. Wt. 103 + Cl M. Wt. 106 M. Wt. 9 M. Wt. 44 Wate S M. Wt. Cl C H NS HCl 7 9 C H ClNOS. HSO Thiophene Derivative C9H8BrClO2 16 16 2 2 4 M. Wt. 175.5 Bromo Compound Racemicclopidogrel M. Wt. 263.5 M. Wt. 419.5 Stage II O SO3H

H SO 2 4 O CH3 O Camphorculphonic salt of Na2SO4 N H C Na CO Clopidogrel CO2 H2O S + 3 2 3 Sodium Sulphate + Sodium Carbonate + + Carbon Dioxide Water H3C C16H16ClNO2S. C10H16O4S M. Wt. 142 + M Wt. 106 M. Wt. 44 M Wt. Cl M Wt. 554.5 C H ClNOS. HSO 16 16 2 2 4 C10H17O4S Racemicclopidogrel Camphorsulphonic acid M. Wt. 419.5 M Wt. 233

O Stage III SO3Na

H2SO4 O CH Camphorculphonic salt of 3 O CO2 H2O Na2CO3 H2SO4 N HC Clopidogrel S 3 + Carbon Dioxide+ Water Sodium CarbonateSulfuric acid + M Wt 44 M Wt C H ClNOS. CH OS + + H3C 16 16 2 10 16 4 M Wt 98 M Wt. 554.5 M Wt. 106 Cl C H ClNOS. HSO 16 16 2 2 4 C10H16O4SNa Clopidogrel Camphorsulphonic acid M. Wt. 419.5 M Wt. 245 Process Description for Furoic acid Stage-I: Dimethyl Formamide is charged into the reactor followed by Thieno [3,2-c]-4,5,67- tetrahydropyridine Hydrochloride and cooled. After that sodium Carbonate is added slowly into the reaction mass. Add Methyl Alpha-Bromo-2-Chloro Phenyl Acetate (Bromo compound) to the reaction mass. The reaction mass is filtered and washed with sulfurinc acid and Acetone and collected the stage-I wet material then dried the material.

Stage-II: Methylene Chloride is charged initially into the reactor and stage-1 material is charged into the reactor then cooled. Neutralised salt with soda ash, convert the free base into camphor sulphonic salt and preferentially crystallized to get optically pure Clopidogrel salt. The reaction mass is filtered and washed with Acetone and collected stage -2 wet material then dried.

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Narmadaria Laboratories Pvt. Ltd. Form I Annexure

Stage-III: The resolved clopidogrel salt is neutralized and again converted into sulphate salt and purified the salt in aq. Acetone. Schematic diagram of Clopidogrel Hydrogen Sulfate is shown in Fig A-1 and material balance for Clopidogrel Hydrogen Sulfate is presented in Table A-2.

Clopidogrel

Fig A-1 Process Flow Diagram of Clopidogrel

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Narmadaria Laboratories Pvt. Ltd. Form I Annexure

Table A-2 Material Balance for Clopidogrel Stage I Input Quantity Output Quantity Remarks (Kg/day) (Kg/day) Thiophene deri 90.1 Recemic Clopi 209.9 To Stage-II Bromo compound. 135.3 Sodium Chloride 29 To Wastewater Sodium carbonate 54.4 Sodium Bromide 51.5 To Wastewater Sulphuric acid 50.3 Carbon Dioxide 22.0 Let into atmosphere Methylene Dichloride 500 Water 9.0 To Wastewater (MDC) Acetone 250 MDC Recovered 485.0 Recovered & reused Water 1200 MDC Loss 1.3 Fugitive Loss Sodium Sulfate 12 MDC to Residue 13.8 Solvent in Residue Dimethyl formamide 6.0 Acetone Recovered 240.0 Recovered & reused Acetone Loss 1.3 Fugitive Loss Acetone to Water 3.8 To Wastewater Acetone to Residue 5.0 Solvent in Residue Thiophene deri 2.3 Organic Residue Bromo compound. 3.5 Organic Residue Dimethyl formamide 6.0 To Wastewater Sodium carbonate 1.4 To Wastewater Sulphuric acid 1.3 To Wastewater Sodium Sulfate 12 To Wastewater Water 1200 To Wastewater Total Input 2298.3 Total Output 2298.3 Stage II Input Quantity Output Quantity Remarks (Kg/day) (Kg/day) Stage I 209.9 Stage II 258.6 To Stage-III Camphor sulphonic acid 116.6 Sodium Sulfate 66.2 To Wastewater Sodium carbonate 53.0 Carbon Dioxide 20.5 Let into atmosphere Methylene 1000 Water 8.4 To Wastewater Dichloride(MDC) Acetone 1400 MDC Recovered 970.0 Recovered & reused water 2000 MDC Loss 3.0 Fugitive Loss MDC to Residue 27.0 Solvent in Residue Acetone Recovered 1344.0 Recovered & reused Acetone Loss 7.0 Fugitive Loss Acetone to Water 21.0 To Wastewater Acetone to Residue 28.0 Solvent in Residue Stage I 14 Organic Residue Camphor sulphonic 7.9 To Wastewater acid Sodium carbonate 3.6 To Wastewater water 2000 To Wastewater Total Input 4779.5 Total Output 4779.5

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Narmadaria Laboratories Pvt. Ltd. Form I Annexure

Stage III Input Quantity Output Quantity Remarks (Kg/day) (Kg/day) Stage II 258.6 Clopidogrel 200 Final Product Sodoium Carbonate 49.4 Camphor sulphonic 108.5 Recovered & reused acid Sulfuric Acid 45.7 Carbondioxide 19.5 Letout into atmosphere Acetone 1400 Water 8.0 To Wastewater water 900 Acetone Recovered 1344.0 Recovered & reused Acetone Loss 7.0 Fugitive Loss Acetone to Water 21.0 To Wastewater Acetone to Residue 28.0 Solvent in Residue Stage II 12.9 Organic Residue Sodoium Carbonate 2.5 To Wastewater Sulfuric Acid 2.3 To Wastewater Water 900 To Wastewater Total Input 2653.7 Total Output 2653.7

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Narmadaria Laboratories Pvt. Ltd. Form I Annexure

ANNEXURE – II: Wastewater Treatment Facilities

The effluent generated from the proposed Sri Kusuma Haranadha Agro Fural Limited, Unit-II is mainly from process, washings, and scrubbers, cooling towers & boiler blow downs and domestic effluent. Effluent from Process, Washings, Scrubber, Boiler, Cooling tower and RO Rejects is sent to Effluent Treatment System and treated effluent is reused for cooling towers. Domestic effluent sent to septic tank followed by soak pit. Total Effluent generated and mode of treatment permitted and proposed is presented in Table A-3.

Table A-3 Quantity of Effluent Generated and Mode of Treatment Description Quantity Mode of Treatment (KLD) HTDS Effluents Process 12 Sent to Stripper followed by MEE and Washings 2 ATFD. Stripper Condensate sent to Cement Plants for Co-Incineration. MEE and ATFD Condensate sent to Biological treatment plant followed by RO. RO rejects sent to MEE and permeate is reused in cooling towers make-up. Scrubber Effluent 1 Sent to MEE followed by AFTD, Biological DM rejects 3 treatment plant and RO. Total - I 18 LTDS Effluents Boiler Blow downs 2.5 Sent to Biological Treatment System Cooling Tower Blow downs 30 followed by RO. RO permeate reused for cooling tower makeup. RO rejects sent to MEE. Domestic Wastewater 3.5

Total - II 36 Grand Total (I+II) 54

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Narmadaria Laboratories Pvt. Ltd. Form I Annexure

ANNEXURE – III: Water Balance

Water is required for process, scrubbers, washing, cooling tower makeup, steam generation and domestic purposes. The total water requirement shall be 151.2 KLD, out of which 99.2KLD shall be fresh water and balance 52 KLD shall be recycled water. The required water shall be drawn from ground water/APIIC (Industrial supply) in addition to reuse of treated wastewater. The water balance is presented in Table A-4. Table A- 4 Total Water Balance (Tentative) Purpose INPUT (KLD) OUTPUT (KLD) Fresh Water Recycled Water Loss Effluent Process 11.2 12* Washings 2 2 Scrubber 1 1 Boiler 15 13 2.5 Cooling Tower 60 52 82 30 RO/DM Rejects 3 3 Domestic 4 0.5 3.5 Water for gardening 3 3 Gross Total 99.2 52 98 54 Total 151.2 152 * Process effluents contain soluble raw materials, byproducts, solvents etc.

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Narmadaria Laboratories Pvt. Ltd. Form I Annexure

ANNEXURE – IV: Solid Waste

Solid wastes are generated from process, effluent treatment system, DG sets and boilers. The process residue and solvent residue are sent to cement plants for co-incineration. The evaporation salts are sent to TSDF. Waste oil and used batteries from the DG sets are sent to authorized recyclers. The sludge from effluent treatment plant is considered hazardous and the same is sent to TSDF. Ash from boiler is sold to brick manufacturers. The total solid waste generated and mode of disposal permitted and proposed is presented in A-5.

Table A-5 Solid Waste Details (Tentative) S.No Description Units Quantity Mode of Disposal 1 Ash from Boiler TPD 3 Sold to Brick manufactures 2 Solvent Residue Kg/day 280 Sent to TSDF/Cement Industries 3 Process Organic Kg/day 480 residue 4 Process Inorganic Kg/day 12 Sent to TSDF Residue 5 Spent Carbon Kg/day 20 Sent to TDSF/Cement Plants for Co-incineration 6 Hyflow Kg/day 12 Sent to TSDF 7 Catalyst Kg/day 20 Sent to TSDF 8 Mixed Solvents KLD 11.5 Sent to authorized recovery units/ Cement plants for co- incineration. 9 Spent Solvent KLD 1.8 Recovered within the plant premises. 10 Stripper distillate KLD 0.3 Sent to Cement Industries for Co- incineration. 11 Evaporation Salts Kg/day 560 Sent to TSDF 12 ETP Sludge Kg/day 85 Sent to TSDF 13 Detoxified No.s/year 150 Sent to Authorised agencies after containers detoxification 14 Waste oil Kl/Annum 0.4 Sent to Authorized Recyclers 15 Used batteries No.s/year 6 Sent to Authorized Recyclers

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Narmadaria Laboratories Pvt. Ltd. Form I Annexure

ANNEXURE – V: Stack Emissions Details

The sources of air emission expected from the plant are gaseous emissions from proposed 3 TPH coal fired boilers with Multicone Separators as control equipment and DG set of 500 KVA proposed as standby during load shut down. DG sets shall be provided with stack height based on the CPCB formula for effective stack height. The emission rates of PM,

SO2, NOx and PM from each stack are presented in Table A-6.

Table A-6 Stack Emission Details S.No Stack Attached to Stack Dia of Temp.of Exit Pollutant Emission Rate Height stack exhaust Velocity (g/sec) 0 (m) at top (m) gases ( C) (m/sec) PM SO2 NOx 1 3 TPH Coal Fired 30 0.5 180 8.5 0.09 0.14 0.35 Boiler 2 *DG Set 500 KVA 12 0.2 180 10 0.02 0.03 0.5 *DG sets will be used during load shut down by APTRANSCO.

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NARMADARIA LABORATORIES PVT. LTD. SY. NO. 127/127, PLOT NO. 8, PHASE II, NADIKUDI INDUSTRIAL PARK, DACHEPALLE MANDAL, GUNTUR DISTRICT, ANDHRA PRADESH

STUDIES AND DOCUMENTATION BY TEAM Labs and Consultants QCI: MoE&F OM, List A‐1, S.No.25. (An ISO 9001:2008, ISO 14001:2004 & OHSAS 18001:2007 Certified Organization) B‐115, Annapurna Block, Aditya Enclave Ameerpet, Hyderabad‐500 038. Phone: 040‐23748 555/616, Telefax: 040‐23748666 Email: [email protected]