TRANSACTIONS OF THE INSTITUTE OF FLUID-FLOW MACHINERY No. 127, 2015, 63–89 DARIUSZ KARDAŚ1 From biomass towards syngas The Szewalski Institute of Fluid-Flow Machinery of the Polish Academy of Sciences Fiszera 14, 80-231 Gdańsk, Poland Abstract The article presents and overview of selected physical and chemical issues relating to biomass gasification. It also includes the history of the development of thermal wood treatment technology, with particular attention paid to Polish threads. Basic physical and chemical properties of biomass are discussed, using wood and straw as representative examples. Main types of gravitational gasifying reactors are presented, along with the analysis of basic mechanisms of homogeneous and heterogeneous chemical reactions in the reactor bed. The equation of motion of bed particles is derived based on particle volume changes caused by pyrolysis and surface reactions. Keywords: Biomass; Pyrolysis, Gasification; Bed subsidance, Reactions 1 Introduction Wood gasification is not a new technology. Archaeological research has re- vealed that its version consisting in wood carbonisation was already known as early as several thousand years ago. A basic goal of the wood carbonisa- tion technology was to produce charcoal, which until the nineteenth century was the main raw material for various economy sectors. Charcoal was used in smelters and forges, as its high combustion temperature, above 2000 oC, by far exceeded the melting point of iron, which is slightly higher than 1100 oC. Charcoal was also used in medicine and gunpowder production. 1E-mail address:
[email protected] ISSN 0079-3205 Transactions IFFM 127(2015) 63–89 64 D. Kardaś The applications believed to be most important from among all charcoal application areas referred to smelting and working of iron, i.e.