materials Article Laboratory Study on Improvement of Expansive Soil by Chemically Induced Calcium Carbonate Precipitation Shaoyang Han 1,2, Baotian Wang 1, Marte Gutierrez 2,*, Yibo Shan 3 and Yijiang Zhang 3 1 Key Laboratory of Ministry of Education for Geomechanics and Embankment Engineering, Hohai University, 1 Xikang Rd., Nanjing 210098, China;
[email protected] (S.H.);
[email protected] (B.W.) 2 Department of Civil and Environmental Engineering, Colorado School of Mines, 1500 Illinois St., Golden, CO 80401, USA 3 Geotechnical Engineering Department, Nanjing Hydraulic Research Institute, 34 Hujuguan Rd., Nanjing 210024, China;
[email protected] (Y.S.);
[email protected] (Y.Z.) * Correspondence:
[email protected] Abstract: This paper proposes the use of calcium carbonate (CaCO3) precipitation induced by the addition of calcium chloride (CaCl2) and sodium carbonate (Na2CO3) solutions as a procedure to stabilize and improve expansive soil. A set of laboratory tests, including the free swell test, unloaded swelling ratio test, unconfined compression test, direct shear test, scanning electron microscopy (SEM) test, cyclic wetting–drying test and laboratory-scale precipitation model test, were performed under various curing periods to evaluate the performance of the CaCO3 stabilization. It is concluded from the free swell tests and unloaded swelling ratio tests that the addition of CaCl2 and Na2CO3 can profoundly decrease soil expansion potential. The reduction in expansion parameters is primarily attributed to the strong short-term reactions between clay and stabilizers. In addition, the formed Citation: Han, S.; Wang, B.; cementation precipitation can decrease the water adsorption capacity of the clay surface and then Gutierrez, M.; Shan, Y.; Zhang, Y.