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APPENDIX Introductory Lectures 1. APPENDIX Introductory Lectures 1. "Introduction to the f-Elements", R. D. Fischer. 2. "Introduction to Organometallic Chemistry", T. J. Marks. Contributed Seminars 1. "Magnetic Properties of Trivalent Organometallic Uranium CompoWlds" , Reinhardt Klenze, Clemens M. Aderhold, and Basil Kanellakopulos, Kernforschungszentrum Karlsruhe, Institut fUr Heisse Chemie and Fachbereich Physikalische Olemie der Universitat Heidelberg, Federal Republic of Germany. 2. "Electrochemical studies on Uranocene", Jared A. Butcher, Jr. , James Q. Olambers, and Richard M. Pagni, Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37916, USA. 3. "Organoscandium Complexes Containing Large Organic Rings" , A. Westerhof, B. J. Roesink and H. J. de Liefde Meij er, Laboratoriu m voor Anorganische Scheikunde, RijksWliversiteit, Nijenborgh 16, 9747 AG Groningen, The Netherlands. 4. "Bis(pentamethylcyclopentadienyl)Actinide Alkyls: Facile Activation of Carbon Monoxide and Formation of Oxygen-Bonded Migratory Insertion Products", Juan M. Manriquez, Paul J. Fagan, and Tobin J. Marks, Department of Chemistry, Northwestern University, Evanston, IL 60201, USA; Cynthia Secaur Day and Victor W. Day, Department of Chemistry, University of Nebraska, Lincoln, NE 68588, USA. 5. "The Consistent Interpretation of the Spectroscopic and Magnetic Properties of Octahedral 5fl Halide Compounds of Protactinium(IV), Uranium(V) and NeptWlium(VI)", K. Eichberger and F. Lux, Institut fur Radiochemie der Technischen UniversiUit Munchen, D-8046 Garching, Federal Republic of Germany. 6. "Synthesis and Spectroscopy of Indenyl Uranium(IV) Alkyls and Dialkyls" , Afif M. Seyam and Ghaida' Ala' Eddein, Department of Chemistry, University of Jordan, Amman, Jordan. 7. "New Synthetic Routes in Organoactinide Chemistry", J. C. Green, Inorganic Chemistry Laboratory, South Parks Road, Oxford, Great Britain. B. "Recent Advances in Uranium(III) Chemistry", David C. Moody, Los Alamos Scientific Laboratory, University of California, Los Alamos, New Mexico 87545, USA. 497 498 APPENDIX 9. "Transferred Hyperfine Interaction Between the Rare-Earth Ions and Neighbouring Nuclei of Diamagnetic Ions in Simple Compounds Studied By NMR!I, Rolf Nevald, Laboratory of Electrophysics, 'll1e Technical University of Denmark, DK-2800 Denmark. 10. "An Isotope Effect in IH- NMR and Magnetic Susceptibility of Organo­ metallic Uranium Compounds", R. v. Ammon, C. M. Aderhold and B. Kanellakopulos, Kernforschungszentrum Karlsruhe, Federal Republic of Germany. ll. "Uranium (V) and Uranium (VI) AIkoxides: Preparation, Properties, and Photochemistry", Steven S. Miller, Tobin J. Marks, and Eric Weitz, Department of Chemistry, Northwestern University, Evanston, IL 60201, USA. 12. "Nonaqueous Reductive Lanthanide Chemistry" W.J. Evans, S. C. Engerer, A. C. Neville and A. L. Wayda, Department of 'Chemistry, University of Chicago, Olicago, IL 60637, USA. 13. "Studies on Uranium(V) and Uranium(VI) AIkoxides: Syntheses, 13C NMR, and Magnetic Properties1t, P. Gary Eller and P.J. Vergamini, Los Alamos Scientific Laboratory, University of Claifornia, Los Alamos, New Mexico, 87545, USA. 14. "Reexamination of the Electronic structure of U(NCS)~(N(C2H5)4)4'" Edgar Soulie and Hubert Marquet-Ellis, Division de Chimie, Service de Olimie Physique, Centre DIEtudes Nucleaires De Saclay, B. P. N° 2 - 91190 - Gif Sur Yvette, France. 15. "Anionic Tetra 1'T -Allyl Complexes of Lanthanide Elements~l, S. Poggio, M. Brunelli, U. Pedretti, G. Lugli, Snamprogetti-Diris-S. Donato Milanese, Milan, Italy. 16. "Photoionization of f Electrons With UV Radiation", Russell G. Egdell, Inorganic Olemistry Department, South Parks Road, Oxford, OX! 3QR, Great Britain. 17."Magnetic Investigations on Highly Symmetric Octathiocyanato Complexes of Tetravalent Actinides", Arno H. stollenwerk, Reinhardt Klenze, and Basil Kanellakopulos, Kernforschungszentrum Karlsruhe, Institut fiir Heisse Chemie and Fachbereich Physikalische Olemie der Universitat Heidelberg, Federal Republic of Gemany. 18. "Some NMR Spectroscopic Results on Substituted Uran.ocenes and Thorocenes A. streitwieser, Jr., Department of Chemistry, University of California, Berkeley, california 94770, USA. APPENDIX 499 19. "Non-Aqueous Olemistry of Uranium Pentafluoride", P. Gary Eller and G. W. Halstead, Los Alamos Scientific Laboratory, University of california, Los Alamos, New Mexico 87545 USA. 20. "Preparation and structure of Novel Uranium-Organyls, (,,5_C5H5)3U(IV)XL, with Trigonal-Bipyramidal Coordination", E. Klahne,J.. Kopf and R. D. Fischer, Institut ffir Anorganische und Angewandte Olemie der Universitat Hamburg, Martin-Luther-King-Platz 6, D-2000 Hamburg, 13, Federal Republic of Germany. 21. "structural Aspects of Organoactininide Complexes", Victor W. Day, Sara H. Vollmer and Cynthia S• .Day, Department of Chemistry, Univer- sity of Nebraska, Lincoln, Nebraska 68588, USA; Tobin J. Marks, Richard D. Ernst, William J. Kennelly, Juan M. Manriquez and Paul J. Fagan, Department of Olemistry, Northwestern University, Evanston, IL 60201, USA; and Josef Takats and Anita L. Arduini, Department of Chemistry, Univer­ sity of Alberta, Edmonton, Alberta, Canada. INDEX absorption spectra of uranocenes 167 actinide alkyls, steric crowding and thermal stability 242,243 catalysts 389 complexes, lability of 221,222 cyanides 239 ions, lieand field splitting in 221 tetraalkyls 242 tetrabenzyls 241 activation barrier for hydride exchange 347 for rotations 356 addition, oxidative 133 adducts with metal carbonyl compounds 90 adducts with metal nitrosyl compounds 90 adiabatic transitions 433 a-elimination 101,102 A1R3 385 alkylation reactions catalyzed by uranium complexes 390 alkyl lanthanide anions 241,242 alkyl lanthanide iodides 241 alkyls, actinide 113 bis(indenyl) 126 bis(pentamethylcyclopentadienyl) 117 carbon monoxide, insertion of 138 homoleptic 128 hydrogenolysis 136 metal 262,263 mono (pentamethylcyclopentadienyl) 127 protonolysis 136 thermal stability 132 thermolysis 131 tris(cyclopentadienyl) 113 tris(indenyl) 117 alkyl-~-chloro bridges 208 501 502 INDEX alkynyl complexes 93 allyl anion, vibrational spectrum 491 complexes 93,348 compounds, vibrational spectroscopy 491 allyls, metal 262-265 Am(C5H5)3 28 annulated cycloo~tatetraenes 156 1161annulene 162 aryl lanthanide anions 242 aryls, actinide 113 bis(pentamethylcyclopentadienyl) 117 homoleptic 128 metal 262 tris(cyclopentadienyl) 113 atomic theory 37-40 attenuation of ~Hcon 350 auto ionization processes 425 availability of (depleted) uranium 379 availability of rare earths 380 axially symmetric crystal fields 349 axial symmetry 41,43,51,57,76-79 bimetallic organometallic compounds 107 Birmingham, J.M. 83 bis(allyl)uranium(IV) dialkoxides 236 dichloride 235 bis(arene)uranium compounds 237 bis(cycloheptatrienyl)cerium(IV) dichloride 236 bis(cyclooctatetraene)actinide (IV) PE spectra 454 bis(cyclooctatetraene) complexes, vibrational spectroscopy 486 bis(cyclooctatetraene)neptunium 159 bis(cyclooctatetraene)plutonium 159 bis(cyclopentadienyl)actinide complexes, vibrational spectra 485 bis(cyclopentadienyl)actinide(IV) compounds, (C5H5)2AnX2 8 bis(cyclopentadienyl)lanthanide methyls 240 bis (cyclopentadienyl)uranium(IV)bis (borohydride) 233 bis(cyclopentadienyl)uranium bis(carbamates) 234 bis(dialkylamides) 233,234 dichloride 223 dichloride, disproportionation of 224 dihalides, complexes of 228 dihalides, u.v.-visible spectra of complexes 224,228,229 diphenyl 233 dithiolates 234 bis(indenyl)uranium(IV) dialkyls 235 bis(indenyl)uranium(IV) dichloride 235 INDEX 503 bis(n-allyl) complexes 445 bis(n8-cyclooctatetraene)uranium 149 bis(pentafluorophenyl)ytterbium 95,105 bis(pentamethylcyclopentadienyl) actinide dialkyls 240 actinide dihalides 230 actinide dihydrides 240 bis(phenylethynyl)ytterbium 95,105 bis(I,3,S,7-tetraphenylcyclooctatetraene)uranium 158 bis(2,3,S,6-tetrafluorophenyl)ytterbium lOS Bleaney, B. 359 Bleaney-factor 360 bond, actinide-to-carbon 113 bridged organoactinides 9 bridging benzyne 183 bromocyclooctatetraene ISS bulky alkyl groups, complexes with 97 butadiene lanthanide compounds 237 Cade t, L. D. 8 I Cahours, A. 81 carbene complex 134 carbon monoxide, migratory insertion 138 carbonyl complexes 445 catalytic act~v~ty in diolefin polymerization 388 catalytic aspects 381 Ce(CSHS)4 86 CF-treatments of uranocene 370 charge transfer absorption bands 285 chemical shift 338 CHISi(CH3)3 1 2 -compounds of Sc and Y 99 CH2C(CH3)3-compounds of Sc and Y 99 CH2Si(CH3)2C6H4-o-0CH3-compounds of Sc and Y 99 CH2Si(CH3)3-compounds of Sc and Y 99 CH2Si(CH3)3 ligand 97 (CSHS) 2MBH4 88 (CSHS)2U(BH4)2 347 I (CSHS)2Y(CH3)2AI(CH3)21 lOS (CSHS)3An .CNC 6HI I 30 (CSHS)3EuCNC6HII' variable-temperature PMR 361 (CSHS) 3Ln.CNC6HII 28 (CSHS)3LnCNC6HII 350 5M INMX (CSHS)3Np 27 (CSHS)3Np.CNC6HII 27 (CSHS)3Np.3THF 27 (CSHS)3MBH4 347 (CSHS)3PrCNC6HII 90 (CSHS)3UBH4 364 (CSHS)3UH 34S (CSHS)3UH3R 347 I (CSHS)3U(H20)21+-cation 343 (CSHS)3UNCS.CH3CN 343 (CSHS)3UOR 3S4 (CSHS)3UR-systems, NMR studies 34S (CSHS)3UX-systems 17 {(CSHS)3UXy}±n -systems 343 (CSHS)nMR-systems 96 (CSHS)nUIVXm 341 IC8H7P(t-C4H9)212U 3SS (CSH7Si(CH3)3)2U 369 (C9H7)nMR2-systems 96 coalescence temperature 3S2 complexes of the type LiLn(allyl)4 388 contact term 340 coordinately saturated 161 correlation energy 433 Coulomb interaction 40,47,69-71 coupling, vibrational 471,474 covalence model 314,323-32S,328-331 covalent bonding 64,2SI,2S4,267 cracking of petroleum 381 Crease, A.E. 34S crystal field 41-46,SI-60,64-68,72-7S,76-79,311,317,319,320, 321,323,324,326 crystal field splitting
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