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Background Report Reference

AP-42 Section Number: 10.6.1

Background Report Section: 2

Reference Number: 1

Title: Forest Products Laboratory, Handbook of and Wood Based Materials For Engineers, Architects, and Builders

1989 Insulation Board, , Medium- Density , and Laminated

Page Manufacture. Ropenies, and Uses of Insulating Boards ...... 21-2 Manufacture. Roperties, and Uses of Hardboard ... 21-7 Medium-Density Hardboard ...... 21-7 High-Density Hardboard ...... 21-8 Special Densified Hardboard ...... 21-12 Manufacture, Properties, and Uses of Medium-Density Fiberboard ...... 21-12 Manufacture, Roperties, and Uses of Laminated Paperboards ...... 21-13 Selected References ...... 2 1 -I 5 -

?. &&&ducts l-4. . Insulation Board, Hardboard, Medium- Density CIWt) Fiberboard, and Laminated Paperboards*

This group of panel materials are all reconstituted wood (or oped products within the broad classification, further break- some other lignocellulose like bagasse) in that the wood is downs are necessary to classify the various products ade- first reduced to fibers or fiber bundles and then put back quately. The following breakdown by density places the fiber- together by special forms of manufacture into panels of rela- based panel products in their various groups: tively large size and moderate thickness. These board or panel materials in final form retain some of the properties of the Specific Density I original wood but. because of the manufacturing methods, Gravity (Pco- I gain new and different properties from those of the wood. Insulation board 0.16 to 0.5 IO to 31 Because they are manufactured. they can be and are "tailored" Hardboard .5 to 1.45 31 to 90 II I to satisfy a use-need, or a group of needs. Medium-density hardboard .5 to .8 31 lo 504- 1 Another group of panel materials based on panicles rather High-density hardboard .8 to 1.28 50 to 80 than fibers is described in chapter 22. Special densified hardboard I .35 to 1.45 84 to 90 Fiber-based panel products are made essentially by break- Medium-density fiberboard .5 to .88 31 to 556. ing wood down through thermal-mechanical processes to its Laminated .5 to .59 31 to 37 fibers. These fibers are interfelted in the reconstitution pro- cess and are characterized by a bond produced by that Properties of the various fiber-based panel products are interfelting. They are frequently classified as fibrous-felted determined according to ASTM standards, and to a consider- board products. At certain densities under controlled condi- able extent these properties either suggest or limit the uses. In tions of hot-pressing, rebonding of the effects a further the following sections the fiber-based panel materials are bond in the panel product produced. Binding agents and other divided into the various categories suggested by kind of materials may be added during manufacture to increase manufacture, properties. and use. strength, resistance to fire, moisture, or decay, or to improve some other property. Among the materials added are rosin, Manufacture, Properties, and Uses alum, asphalt. paraffin, synthetic and natural resins, preserva- of Insulating Boards tive and fire-resistant chemicals, and drying oils. Wax sizing is commonly added to improve water resistance. Insulating board is a generic term for a homogeneous panel Since fiber-based panel products are produced from small made from lignocellulose fibers (usually wood or bagasse) components of wood, the raw material need not be in log that have been intetfelted and consolidated into homogeneous form. Many processes for manufacture of board materials panels having a density of less than 31 pcf and more than IO start with wood in the form of chips. Coarse residues pcf. Other ingredients may be added during manUfaCture to from other primary forest products manufacture therefore are provide specific physical propenies. Insulation board is dried an important source of raw materials for fiber-based panel in an oven but not consolidated under pressure during products. Bagasse, the fiber residue from sugarcane, and manufacture. wastepaper are used also as raw material tor board products. There are many different types of insulating board, with Fiber-based panel materials are broadly divided-into four different names and intended uses (table 21-1). Nominal groups-insulation board (the lower density products), dimensions of the different types of in'sulating boards are hardboard, medium-density fiberboard, and laminated - presented in table 21 -2, and their minimum physical proper- board. The dividing point between an insulation board and a ties in table 21-3. hardboard and medium-density fiberboard is a specific grav- Sheathing is regularly manufactured in three grades: Regu- ity of 0.5 (about 31 pcf). Laminated paperboards require a lar density. intermediate, and nail base. Regular-density special classification because the density of these products is sheathing is usually about 18 pcf in density, and when the 2- slightly greater than insulation board, but at the low end of by &foot material is used as sheathing, it is applied with long . Because laminated paperboards are made by lami- edges horizontal. The 4-foot-wide material is recommended nating together plies of paper about 1/16 inch thick, they for application with long. edges vertical. When 25/32-inch- have different properties along the direction of plies than thick regular-density sheathing is applied with the long edges across the machine direction. Other fiber-based panel prod- vertical and adequate fastening (either nails or staples) around ucts have nearly equal properties along and across the panel. the perimeter and along intermediate framing, requirements Ractically, because of the range of uses and specially devel- for racking resistance of the wall construction are usually satisfied. Horizontal applications with the 25/32-inch mate- - rial require additional bracing in the wall system to meet code * Revision by Gary C. Myers. Forest Fmductr Technologist requirements for rigidity, as do some applications of the I/2-

21-2 {le 21 - 1-Types, classes, and intended uses of insuhting bod

Name Intended use 3 Class

-I - Sound deadening board In wall assemblies to control sound -r- transmission - Building board As a base for interior finishes - Insulating formboard As a permanent form for poured-In- -zll place reinforced gypsum or light- weight concrete aggregate roof construction

Sheathing: 1 Regular-density AS wail sheathing in frame wn- struction where method of application or thickness determines adequacy of racking resistance 2 Intermediate-density As wall sheathing where USUd method of application provides adequate racking resistance 3 Nail-base As wall sheathing where USUal method of application provides adequate racking resistance, and where exterior materials, such as wood or asbestos shingles, can be directly applied with special nails

- Shingle backer As an undercoursing for wood or asbestos cement shingles Roof insulating board As above-deck insulation under ./I - built-up roofing

WII Ceiling tiles and panels: 1 Nonacoustical As decorative wall and ceiling coverings 2 Acoustical As decorative, sound-absorbing wall and ceiling coverings

Vlll - Insulating roof deck As roof decking for flat, pitched, or shed-type open-beamed, ceiling roof construction

IX - Insulating wallboird As a general-purpose product used for decorative wall and ceiling covering

source: PS 57-73.

21-3 inch-thick regular-density sheathing applied with long edges will also provide a substantial reduction in noise reflectance. vertical. Intermediate sheathing is usually about 22 pcf in The fissures and special sound traps are designed to provide density; nail base is about 25. Nail-base sheathing has ade- improved appearance over that of the conventional perfora- quate nail-holding strength so that asbestos and wood shin- tions while satisfying the requirements for sound absorption. gles for weather course (siding) can be attached directly to The manUfaCNreIS of insulation board long have recognized the nail-base sheathing with special annular grooved nails. the appeal of esthetically pleasing ceiling finishes. Each of With the other grades of sheathing, siding materials must be them offers finishes in designs that blend with either mdi- nailed directly to framing members or to nailing strips attached tional or contemporary architecture and furnishings. through the sheathing to framing. Because the method and Generally ceiling tiles are 12 by I2 or 12 by 24 inches in amount of fastening is critical to racking resistance. local size. 1/2 inch thick, and have tongue and or butt and building codes should be consulted for requirements in differ- ‘chamfered edges. They are applied to nailing ships with nails, ent areas. staples, or special mechanical fastenings, or directly to a Ceiling tile and lay-in panels are an important use for surface with adhesives. strucNral insulating board. Such board has a finish A panel product similar to tile, but nominally 24 by 24 or applied in the factory for decoration and to provide resistance 24 by 48 inches, is gaining popularity. These panels, com- to flame spread. Interior-finish insulating board, when perfo- monly called “lay-in ceiling panels,” are installed in metal rated or provided with special fissures or other sound traps, tees and angles in suspended ceiling systems. These lay-in

Table 21 - %Nomid dimensions of insulating board

Type 01 Nominal dimensions n insulating r- 1 board Width Length Thickness

TYPE I 48 96 or 108 112 Type II 48 96, 120, or 144 112 Type 111 24, 32, 48 48 to 144 1 ! Type IV: :i .I Class 1 24 96 112 or 25132 48 96 or 108 112 or 25/32 Classes 2 and 3 48 96 or 108 1/2 TYPE V 11-314, 13-112. or 15 48 511 6 or 318 23 47 112, 1, 1-112, 2, 2-112. or3 Type VI 24 48 112. 1, 1-112, 2, 2-112. or3 Type VII: Class 1 12 12 or 24 1/2, 911 6, or 518 12 96 or 120 1/2 16 16 Or 32 112, 9/16, or 518 24 24 or 48 112, 9116, or 518 48 96, 120, or 144 112 Class 2 12 12 Or 24 112. 9/16, or 518 24 24 or 48 112. 9/16, or 518 Type Vlll 24 96 1-112, 2, Or 3 TVD~IX 48 96 Or 120 318 Source: PS 57-73.

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21-6 panels are usually 1/2 inch thick and are supported in place along all four edges. They are frequently used in combination with translucent panels that conceal light fixtures (fig. I 21-1). Finishes and perforation treatments for sound absorption arc the same as for regular ceiling tile. Producers of insulat- ing board are extending their manufacture to specially embossed ceiling panels that can be applied with bun-joint edges and ends that present an essentially unbroken surface, and factory-finished panels that look like real wood planks. Plastic films are being used increasingly for surfacing ceiling tile for applications in kitchens and bathrooms where repeated washability and resistance to moisture is desired. These prod- ucts are especially adaptable for remodeling.

Manufacture, Properties, and Uses : of Hardboard

hum21 - 1-A lay-in csiiing panel baing installed (WnWc.ll1 in a suspended ceiling system.

small ridges or circular nubbins which, when planed or sanded off, yield an S-2-S board. Refmished paneling and siding products account for about 65 percent of the current product mix. An additional 25 per- cent is for industrial uses, including cut-to-size and molded products. # Medium-Density Hardboard kedium-density hardboard is manufactured by the conven-

\ are manufactured in several ways, and the result is reflected ional methods used for other hardboard and is tailored for in the appearance of the final product. Hardboard is described use as house siding. Medium-density hardboard for house , as being S-1-S (screen-backed) or S-2-S (smooth two siding use is mostly 7/16 inch thick and is fabricated for sides). When the mat from which the board is made is formed ion as either panel or lap siding. i.m Panel siding is 4 feet wide and commonly furnished in 8- , 9-, or IO-foot lengths. Surfaces may be grooved 2 inches or more on center parallel to the long dimension to simulate reversed board and or may be pressed with ridges ' simulating a raised batten. Lap siding is frequently 12 inches wide with lengths to 16 feet and is applied in the same way as conventional wood lap siding. Some manufacturers offer their lap siding products with special attachment systems that provide either concealed fastening or a wider shadow line at the bottom of the lap. Most siding is furnished with some kind of a factory-applied finish. At least the surface and edges are given a prime coat of paint. Finishing is completed later by application of at least one coat of paint. Two coats of additional paint, one of a second primer and one of topcoat, provide for a longer inter-

21-7 hardboard by surface finish. thickness, and minimum physi- cal properties. Originally there were two basic qualities of high-density hardboard; standard and tempered. These are still the two qualities used in greatest quantity.- is a panel product with a density of about 60 to 65 wf. usually unaltered except for humidification and trimming to size after hot-pressiniTempereddard is a standardquality nm- matis &=a blend of siccative resins (drying oil blends or synthetics) after hot-pressing. The resins are stabilized by baking after the board has been impregnated. Usually about 5 percent resin solids are required to produce a Flgun 21 - Wamples of medlumdenstly hard- (MMuao2) hardboard of tempered quality. Tempering improves water board mrnrnoniy used for exierior sMing. Top two resistance, hardness, and strength appreciably, but embrinles examples have textured surfaces to slmulate wood the board and makes it less shock resistant. grain, and bottom example is smwm surfad. A third hardboard, -service ; qualiqChas become important. This is a product of lower ensity than standard, usually 50 to val before repainting. There is a trend for complete prefmishing 55 f ade to satisfy needs where the higKer strength of of mediumdensity hardboard siding. The complete prefmishing #ard quality is not required. Because of its lower density, ranges from several coats of liquid finishes to cementing servicequality hardboard has better dimensional stability than various films to the surfaces and edges of boards. Surfaces of the denser products. mediumdensity hardboard for house siding range from very When service hardboard is given the tempering treatment. smooth to textured, many simulating weathered wood with it is classed as tem red 'ce, and property limits have the latewood grain raised as though earlywood has been eroded been set for sY ications. It is used where water resistance away. Three samples of hardboard siding are presented in is required but the higher strength of regular treatment is not. figure 21-2. showing the different surfaces. Underlayment is servicequality hardboard, nominally 114 inch Small amounts of mediumdensity hardboard are prefinished thick, that is sanded or planed on the back surface to provide for interior paneling along with the highdensity hardboards. a thickness of not less than 0.200 inch. Siding is the most important use and others will not become These are the regular qualities of high-density hardboard, extensive until that market is fully developed and exploited. because a substantial amount of this hardboard is manufac- The experience with medium-density hardboard has been tured for industrial use. special qualities are made with differ- good. Dimensional movement with moisture change has not ent properties dictated by the specific use. For example, hard- produced major problems in service. When hardboard siding board manufactured for concrete forms is frequently given a is stored, applied, and finished with highquality in double tempering treatment. For some uses where high impact accordance with the manufacturers or American Hardboard resistance is required, like backs of television cabinets, boards Association recommendations, it has required little paint are formulated from specially prepared fiber and additives. maintenance. Proper finishing, maintenance, and refinishing Where special machining properties like die punching or - .. procedures for hardboard siding are covered in chapter 16 forming requirements must be satisfied, the methods of manu- and in American Hardboard Association literapre. Code facturing and additives used are modified to produce the authorities and others have recognized the evidence submit- desired properties. ted by manufacturers on the performance of medium-density Commercial thicknesses of high-density hardboard gener- hardboard siding. A summary of the properties specified for ally range from 118 to 112 inch. Not all thicknesses are pro- this material in product standard PS 60-73 is presented in duced in all grades. The thicknesses of 1/10 and 1/12 inch are table 21-4. regularly produced only in the standard grade. Tempered hardboards are produced regularly in thicknesses between 1/8 High-Density Hardboard and 5/16 inch. Service and tempered service are regularly produced in fewer thicknesses, none less than I/8 inch and Manufacture of high-density hardboard has grown rapidly not by all manufacturers or in screen-back and S-2-S types. since World War IL Numerous older uses are well established, The appropriate standard specification or source of material and new ones are being developed continually. Property should be consulted for specific thicknesses of each kind. requirements are presented in table 21-5, which classifie. High-density hardboards are produced in 4- and 5-foot

21-8 Table 21 - 4-J'hysical propdes of hardboard siding Pmperty Requirement

Percent water absorption based on weight (maximum average per panel) Primed 15 Unprimed 20

Percent thickness swelling (maximum average per panel) Primed 10 Unprimed 15

Percent linear expansion (maximum average per panel) Lap siding 0.38, for 0.325- to 0,375-in thickness 0.40, for over 0.376-in thickness Panel siding 0.36, for 0.220- to 0.265-in thickness 0.38, for 0.325- to 0.375-in thickness 0.40, for over 0.376-in thickness

Weatherability of substrate (maximum 0.010 and no objectionable fiber swell after five cycles) (in) raising

Sealing quality of primer coat No visible flattening Weatherability of primer coat No checking, erosion, or flaking

Nailhead pullthrough (minimum average per panel) (Ib) 150

Lateral nail resistance (minimum average per panel) (Ib) 150 Modulus of rupture (minimum average 1,800 for 3/8- and 7/16-in-thkk per panel) (psi) siding 3,000 for 1/4-in-thick siding

Hardness (minimum average per panel) (Ib) 450

Impact (minimum average per panel) (in) 9

Moisture content (pct)' 2-9 inclusive, and not more than 3 pct variance between any two boards in any shipment or order

' Because hardboard is a wood-base material. its moisture mntent will valy with environmental humidity mnditions. When the environmental humidity mnditions in the area of intended use are e critical factor, the purchaser should specify a moisture MntOnt range more restrictive than 2 to 9 PBrCanl. sa that fluctuation in lhe moisture mntent of the sidlng will be kept to a minimum.

Source: P8 60-73

21-9 1 widths with the more common width being 4 feet. Standard that the foreign-made item has properties required for the I I commercial lengths are 4. 6, 8, 12, and 16 feet with an use. Canadian products are usually produced to the same 18-foot length being available in the 4-foot width. Most man- standards as United States products. ufacturers maintain cut-to-size departments for special orders. In addition to the standard smooth-surface hardboards. spe- Retail lumberyards and warehouses commonly stock 8-foot cial products are made using patterned cauls so the surface is lengths. except for underlayment, which is usually 4 feet striated or produced with a relief to simulate ceramic tile, i . leather, basket weave, etched wood, or other texture. Hard- I About IO percent of the hardboard used in the United boards are punched to provide holes for anchoring fittings for States is imported. Foreign-made board may or may not be shelves and fixtures (perforated board) or with holes compris- manufactured to the same standards as domestically produced ing 15 percent or more of the area for installation in ceilings 1 products. Before substituting a foreign-made product in a use with sound-absorbent material behind it for acoustical treat- i where specific properties are required, it should be determined ments or as air diffusers above plenums. i I Table 21 - 5--Clnssification of high-densily hardbwrd by su#face finish, thickness, and physical properfies I Water resistanca Modulus Tensile strength (maximum average 01 (minimum average ! per panel) NptUr9 per panel) class Nominal (mini- I thickness Water mum Parallel Perpen- I absorption Thickness average to dicular based on swelling w surface 10 weioht oanell surface I I I Inch Percent Pounds per square inch !

1 1112 30 25 6,000 3,000 130 Tempered 1/10 25 20 i 118 25 20 1 311 6 25 20 1 I4 20 15 I 511 6 15 10 318 10 9 I 2 1112 40 30 4,500 2,200 90 ! Standard 1/10 35 25 118 35 25 311 6 35 25 114 25 20 511 6 20 15 318 15 10 3 1I8 35 30 4,500 2,000 75 Service-tempered 311 6 30 30 1I4 30 25 I 318 20 15

I

I 21-10 More and more effort is being put fortb by industry IO sity it is harder than most natural wood, and because of its modify and finish hardboard so it can be used in mon ways grainless character it has nearly equal propcnies in all direc- with less “on-the-job” cost of installation and finishing and tions in the of the board. It is not so stiff nor as strong to permit industrial users a saving in final product. Most as natural wood along the pin. but is substantially stronger imponant is prefinishmg, particularly wood graining. where and stiffer than wood across the grain. Minimum spceific the surface of the board is finished with lithographic patterns propenies presented in table 21-5 can be compared with of popular cabinet filed in two or more colors. similar properties for wood, wood-base panels, and other The uses for hardboard are diverse. It has been claimed materials. Hardboard retains some of the properties of wood; that “hardboard is the grainless wood of 1.OOO uses, and can it is hygroscopic and shrinks and swells with changes in be used wherever a dense, hard panel material in the thick- moisture content. nesses as manufactured will satisfy a need bener. or more Changes in moisture content due to service exposures may economically than any other material.” Because of its den- be a limiting factor in satisfactory performance. Comct

Table 21 -Mhsijii&n of high-densily hardboard by su@cefinish, thickness, and physical propzrtics-Cnntinued Water resistance Modulus Tensile strength (maximum everage Of (minimum average per panel) rupture wr panel) Class Nom In a I (mini- IhiCkness Water mum Parallel Perpen- absorption Thickness average IO dicular based on swelling per Burface to wsiohl Danel) surfam

Inch Percent Pounds per square inch 4 118 45 35 3,000 1,500 50 Service 311 6 40 35 1I4 40 30 318 35 25 7116 35 25 112 30 20 510 25 20 11116 25 20 314 20 15 13/16 20 15 710 20 15 1 20 15 1-118 20 15 5 1I4 50 30 2,000 1,000 25 Industrialite 318 40 25 7116 40 25 112 35 25 510 30 20 11116 30 20 314 25 20 1311 6 25 20 718 25 20 1 25 20 1-118 25 20 Sourat. ANSVAHA A 135 4- 1982.

21-11 application and attachment as well as prior conditioning to a visors is often hardboard, as are the platforms between seats proper moisture content will give satisfactory service, but and rear windows. Molded hardboard also has been used for improper application or conditioning precludes it. Roper mois- three-dimensional-shaped components like panels and ture conditioning prior to assembly is of particular impor- armrests. Ceilings of station wagons and truck cabs are often tance in glued assemblies. enameled or vinyl-covered thin hardboard. Product development in hardboard has held generally to the line of class and type of board product, in contrast with Special Densifled Hardboard structural insulating board which deals with specific items for particular uses. During the past few years, much of the suc- This special building fiberboard product is manufactured cess of hardboard resulted because the industry developed mainly as diestock and electrical panel material. It has a certain products for a specific use and had treatments, density of 84 to 90 pcf and is produced in thicknesses between fabrication. and finishes required by the use. Typical are 118 and 2 inches in panel sizes of 3 by 4.4 by 6. and 4 by 12 prefinished paneling, house siding, underlayment. and con- crete form hardboard. feet.Special densified hardboard is machined easily wi mac Many uses for hardboard have been listed, but generally tools and its low weight as compared with metals (aluminum they can be subdivided according to uses developed for alloys about 170 pet) makes it a useful material for templates construction. furniture and furnishings, cabinet and store fix- @.&sfor manufactwing, It is relatively stable 1dimensidh- ture work, appliances, and automotive and rolling stock. Sev- ally from moisture change because of low rates of moisture eral examples of hardboard products are presented in figure absorption. It is more stable for changes in temperature than 21-3. the metals generally used for those purposes. The US-inch- In construction, hardboard is used as floor underlayment to thick board is specially manufactured for use as board, provide a smooth undercourse under plastic or linoleum which is a surface on which small-scale plans of a boat design flooring, as a facing for concrete forms for architectural are projected to actual boat size. concrete, as facings for flush , as molded facings for As diestock, it finds use for stretch- and press-forming and interior doors. as insert panels and facings for garage doors, spinning of metal parts, particularly when few of the manufac- and as material punched with holes for wall linings in storage tured items are required and where the cost of making the die walls and in built-ins where ventilation is desired. High- itself is important in the choice of material. density hardboard is being used as a shear-web material for The electrical properties of the special densified hardboard box and I-teams, to be used as load-carrying members in meet many of the requirements set forth by the National building construction. Refinished hardboard. either with baked Electrical Manufacturers Association for insulation resistance finishes or the regular ones like those used generally in wood- and dielectric capacity in electrical components so it is used grain printing, is used for wall lining in kitchens, bathrooms. extensively in electronic and communication equipment. family rooms, and recreation rooms. Other uses where its combination of hardness, abrasion In furniture. furnishings, and cabinetwork, conventional resistance, machinability, stability, and other properties are hardboard is used extensively for drawer bottoms, dust important include cams, gears, wear plates, laboratory work dividers, case goods and mirror backs, insert panels, television. surfaces, and welding fixtures. radio and stereo cabinet sides, backs (diesut openings for ventilation), and as crossbands and balancing sheets in lami- Manufacture, Properties, and Uses of nated or overlay panels. Hardboard also has use as a core Medium-Density Fiberboard material for relatively thin panels overlaid with films and thin veneers, and as backup material for metal panels. In appli- Medium-density fiberboard (MDR is a panel product man- ances other than television, radio, and stereo cabinets, it is ufactured from lignocellulosic fibers combined with a syn- used wherever the properties of the dense, hard sheet satisfy a thetic resin or other suitable binder. The panels are manufac- need economically. Because it can be postformed to single tured to a density range of 31 to 55 pcf (0.50 to 0.88 specific curvature (and in some instances to mild double Curvature) by gravity) by the application of heat and pressurc by a process the application of heat and moisture, it is used in components in which the interfiber bond is substantially created by the of appliances requiring that kind of forming. added binder. Other materials may have been added during In automobiles, trucks, buses, and railway cars, hardboard manufacturing to improve certain properties. is commonly used in interior linings. Door and interior side- The technology utilized to manufacture MDF is a combina- wall panels of automobiles are frequently hardboard, post- tion of that used in the particleboard industry and that used in formed. and covered with cloth or plastic. The base for sun the hardboard industry. Consequently, there was much debate

21-12 over the definition of the product, Tbk was settled by the development of an American National Standard for Medium Density Fiberboard for Interior Use (ANSI A 208.2-1980). cosponsored by the American HardMAssociation and the National Panicleboard Association. Minimum property re- quirements for MDF am presented in table 21-6. MDF fiber- board is available in thicknesses from 3/16 inch up to 1-112 inches, but most board manufactured is 3/4 inch thick and in the 44 to 50 pcf density range for applications in the indus-. trial markets. The furniture industry is by far the dominant MDF market. ! MDF is frequently raking the place of solid wood, . and particleboard for many furniture applications. Compand to particleboard, it has a very smooth surface which facili- tates wood-grain printing, overlaying with sheet materials, and veneering. MDF has tight edges which need not be edge- banded and can be muted and molded lie solid wood, as illustrated in figure 21 -4. Grain-printed and embossed, MDF Flgum 21 -3--Examples of hardboard products. IW -31 is used in many furninrre lines. The potential for MDF in from top 10 bottom. are facing lor flush doors, two types of wood grain printed panellng. standard other interior and exterior markets such as doors, moldings, hardboard. and pegboard. exterior trim, and pallet decking is currently being explored by the industry. Many industry people expect MDF markets will expand significantly during the next decade. Manufacture, Propertis, and Uses of Laminated Paperboards

Laminated paperboards are made in two general qualities, an interior and a weather-resistant quality. The main differ- ences between the two qualities are in the kind of bond used to laminate the layers together and in the amount of sizing used in the pulp stock from which the individual layers are made. For interior-quality boards, the laminating adhesives are commonly of starch origin while, for the weather-resistant Flgum 21 -&Example of mediumdensny fiber- IUB. mswl board, synthetic resin adhesives are used. Laminated paper- board that has been embossed. printed vdh a wood board is regularly manufactured in thicknesses of 3/16, 114, grain,endfinishedforuseasacabinetdrawerfront.

Table 21 - 6-Properiy requirements of medium-densiry fiberboard Nominal Modulus Modulus internal bond ihickness Of 01 (tensile strength Linear Screwholding rupture elasticity pemendicular to expansion surface) Face Edge

In Psi Psi Psi Pct Lb Lb

13/16and below 3,000 300,000 90 '0.30 325 275 7/13 and above 2,800 250,000 80 30 300 ,225

1 F~~ boards having nominal thickness 01 318 in 01 less. the linear expansion value Shaii be 0.35 percent. Source: ANSI A XK).2-1980.

21-13 and 318 inch for construction uses although for such industrial uses as dust dividers in case goods, fUI'niNre, and automotive liners, IB-inch thickness is common. Important properties are presented in table 21-7. Several examples of laminated paperboard products are presented in figure 21-5. A few other uses for laminated paperboards include mirror backing, toys and games, packaging, museum exhibits, photo murals, outdoor signs, and displays. For building use, considerable amounts go into the prefabri- cated housing and mobile home construction industty as inte- rior wall and ceiling finish. In the more conventional building construction market, interior-quality boards are also used for wall and ceiling finish. often in remodeling IO cover cracked 21 -&Three Smaller piecas 01 laminated flgun ,MBI mt0, plaster. Some of the full-wall laminated paper panels meet paperboard are 3/16. and 3/8-inch mickness and illustrate differentsurlacas. Bonom papeftward prod- and exceed racking requirements, when applied according to uct is a fascia for exierlor use. the manufacturer's insmctions.

Table 21 - 'Istrength and mechanical properties of laminated paperbod

Properly Value Density (pcf) 32-33 Specific gravity 0.52-0.53 Modulus of elasticity (compression) (1,000 psi): Along the length of the panel' 300-390 Across the length of the panel' 100- 140 Modulus of rupture (psi): Span parallel to length of panel' 1,400-1,900 Span perpendicular to length of panel' 900- 1,100 Tensile strength parallel to surface: Along the length of the panel' 1,700-2,100 Across the length of the panel' 600-800 Compressive strength parallel to surface (psi): Along the length of the panel' 700-900 Across the length of the panel' 500-800 24-hour water absorption (pcl by weight) 10-170 Linear expansion from 50 to 90 percent relative humidity (~ct):~ Along the length of the panel' 0.2-0.3 Across the length of the panel' 1.1 -1.3 Thermal conductivity at mean temperature of 75 "F (Btu . in/h . ff. "F) 0.51 ' The data presented are general round-figure vaiues. accumulated from numerous sources; lor more exact figures on a specific product, individual manufacturers should be wnsulted or actual tests made. Values are for general laboratofy wnditlons of temperature and humidity. Because 01 directional properties. values are presented for two principal directions, along the usual length of the panel (machine direction) and

across~ ~ it. I 'Measurements made on material at equilibrium at each wndition at rwm temperature.

21-14 I .-- .-- Water-resistant grades are manufactured for use as sheath- American Hardboard Association. Voluntary pmduct standard PS 59-73. ing, soffit linings, and other “exterior protected” applica- Refinished hardboard paneling. Palatine, ILAHA, 1973. tions like porch and carport ceilings. Soffit linings and lap American Hardboard Associalion. Voluntary pmduct standard PS 60-73. Hardboard siding. Palatine. IL AHA; 1973. siding are specially fabricated in widths commonly used and American Hardboard Association. Hardboard siding. Recommendations for are prime coated with paint at the factory. the UY of hardboard siding in manufactured housing. Palatine. IL AHA. The common width of laminated paperboard is 4 feet, 1978. although 8-foot widths are available in 12- , 14- , Idfoot, American Hardboard Association. Tileboard wall paneling. Palatinc. IL and longer lengths for such building applications as sheathing AHA: 1978. American National Standards Institute. Medium density fikrbQard for inte- entire walls. Laminated paperboards, for use where a surface rior use. ANSI A 208.2-1980, Silver Spring, MD: National Paniclc- is exposed, have the surface ply coated with a high-quality board Association: 1980. pulp to improve surface appearance and performance. Sur- American Society for Testing and Materials. Standard methods of resting face finish may be smooth or textured. insulating board (cellulosic fiber), structural and decorative. ASTM C 209-72. Philadelphia. PA: ASTM: 1972. American Society for Testing and Malcrialr. Standard specification for insu- Selected References lating board (cellulosic fiber). strucNral and decorative. ASTM C 208-72. Philadelphia. PA ASTM; 1972. Acoustical and Board Roducrs Association. Product specification for sound American Society for Testing and Materials. Standard methods of test for deadening board in wall assemblies. ABPA-I8 Spec. No. 4. Park Ridge. suuctural insulating mfdeck. ASTM D 21U-65 (reappmved 1977). IL: ABPA, 1975. Philadelphia. PA: ASTM: 1977. hrican Hardboard Association. Application instructionr far basic hard- American Socicty for Testing and Materials. Standard methods of evaluating board pmducts. Palatine. IL AHA. n.d. the pmpenier of wd-baw fiber and panicle panel materials. ASTM American Hardboard Association, Finishing recommendations for new D 1037-78. Philadelphia. PA ASTM; 1978. construction. Utilizing unprimed and primed hardboard siding. Palatine. American Society for Testing and Materials. Standard specification for smc- ILAHA, n.d. Rlral insulating formboard (cellulosic fiber). ASTM C 532-66 (reappvcd American Hardboard Association, Hardboard paneling, 114 inch prcfinishcd. 1979). Philadelphia. PA: ASTM; 1979. Palatine. IL AHA; n.d. Amencan Society far Testing and Materials. Standard specification for fiber- American Hardboard Association. Hardboard siding. Application and stor- board nail-base shcathing. ASTM D 2277-75 (rsapprovcd 1980). age instructions. Palatinc. IL AHA: n.d. Philadelphia. PA ASTM; 1980. American Hardboard AssociLiOn. Maintenance tips for home ownen with McNatt, 1. D. Design svesscs for hardbokffect of rate. duration. and hardboard siding mrcrian. Palatine, IL AHA. n.d. repeatcd loading. Madison, WI: Forest Roducts Journal. 2qI): 53-M): American Hardboard Association. Today’s hardboarband how to handle 1970. it. An AHA guide to selling hardboard siding and paneling. Palatine. IL: McNan. 1. D. Hardboard-wcbbcd bcams: remhand application. Madison. AHA: n.d. WI: Forest Roducts Journal. 3WIO): 57-64. 1980. American Hardboard Association. Today’s hardbo-uilding better than Stem. R. K. Development of an improved hardboard- pallet design. ever. Palatine. IL AHA; n.d. Res. Pap. FPL 387. Madison. W:U.S. Depanment of Agriculture. For- American Hardboard Association. Today’s hardboard for creative people est Service. Forest Roducts Laboratory; 1980. who build almost anything. An AHA guidc for industrial anr Students and Tuomi, R. L.: Gromala. D. S. Racking smngth of walls: let-in corner inruucton. Palatine. IL AHA; n.d. bracing. sheet materials. and effect of loading rate. Rcr. Pap. FPL 301 American Hardboard Association. American National Standard ANSUAHA Madison. Wl U.S. Depanment of Agriculture. Forest Service. Forest A 135.4-1982. Basic hardboard. Palatine. ILAHA; 1982. Products Laboratory; 1977. American Hardboard Association. Voluntary product standard PS 57-73. Cellulosic fiber insulating board. Palatine, IL AHA; 1973.

21-15 Wood-Base Particle Panel Materials

Page Particle Panel Pmcessing Overview ...... 22-2 Rocess Variable Effect on Particle Panel Roperties .. 22-2 Particle Geomehy ...... 22-2 Resin Content ;...... 22-3 Resin Typc ...... 22-4 Density ...... 22-4 Particle Alignment ...... 22-4 Hot Pressing ...... 22-5 Specifications for Particle Panel Prcducts ...... 22-6 Particleboard Properties and Uses ...... 22-9 Mat-Formed Particleboard ...... 22-10 Extruded Particlebod ...... 22-10 Flakeboard Roperties and Uses ...... 22-10 Other Wood-Base Particle Products ...... 22-12 VeneeriParticle Composite Panels ...... 22-12 Mende-Rocess Particleboard ...... 22-12 Molded Particle Products ...... 22-13 Cement-Bonded Particle products ...... 22-13 Selected References ...... 22-13

22-1 a Wood-Base Particle Panel Materials *

The class of "wood-base particle panel materials" inclu&s wood particles are called furnish for the process line (fig. many subgroups known throughout the United States as 22-3). particleboard, flakeboard, , or The furnish is then dried to a uniform moisture content, (OSB). These panel materials are similar because the wood usually ranging from 3 to 6 percent, and then is screened to raw material is fmt reduced to small fractions and then bonded segregate particle sizes. Fine panicles may be used in the back together, through specialized manufacturing methods, faces of traditional particleboard to produce a smooth surface. into panels of relatively large size (4 to 8 A wide by 8 to 60 A or they may be used as dryer fuel in flakeboard plants because long) and moderate thicknesses (1/8 to 1-1/4 in). These board fines are detrimental to the performance of structural panels. or panel materials in final form retain a few of the properties Adhesive hinders at 3 to 7 percent (percent weight of dry of the original wood, but because of the manufacturing wood) and wax at about 1 percent are either sprayed as a methods, gain many new and different properties. As these liquid or metered as a powdered blend while the wood parti- are manufactured wood products, unlike solid wood. they cles are tumbled in a blender. Thermosetting urea-formal- can be and are tailored to satisfy the property requirements of dehyde and phenol-formaldehyde adhesives are the major a specific use or a broad group of end uses. types of binders used, thus requiring the application of heat to Particle panel products are defined as any wood-base panel cure them. product which is made from pieces of wood smaller than Two processes are commonly used for consolidation of the veneer sheets but larger than wood fiber. Information on furnish into the final panel configuration. with the process veneered products may be found in chapters IO and I I and depending on panel thickness. fiber panel products are discussed in chapter 21. In general, For panels over 114 inch in final thickness, a flat press the name particleboard is used as a generic term for all parti- processing method is generally used. The blended furnish is cle panel products3he raw material for these producu comes formed into a mat of uniform height and moved into the from a variety of sources including planer shavings, plywood platen press, where the mat is consolidated under controlled mill waste, roundwood, , and pulp-type chips. The heat and pressure to a given average density. Pressing times residues of planing operations constitute the source material depend upon many factors, but a typical process requires 3 to for a large segment of the particleboard market for uses such 6 minutes of press time to produce 112-inch-thick panels. as floor underlayment, furnilure corestock, and molded items. Complete control of the mat forming process places particles Recently several types of particleboards, termed flakeboards, according to their size, so that smooth-surface panels may be have been widely used as shea;hing or single-layer floor produced. In the processing of flakeboards, flakes may be panels. Depending upon the particle or flake size and the aligned in layers through the mat thickness as a means of panel construction, flakeboards may be further classified as improving mechanical properties. waferboard or OSB. Shown in figure 22-1 are three panel For panels 1/4 inch or less in thickness, the blended furnish materials which can be broadly called particle panel products, may be deposited directly onto a large heated rotary drum, and can be further classified as particleboard, waferboard, where the final mat-pressing or consolidation operation occurs. and OSB. Post-pressing operations for any of these panels may include cooling, trimming, sanding, and cutting to size. Particle Panel Processing Overview ProcessVariable Effect Parlicle panel products are manufactured from residues of on Particle Panel Properties operations such as planer shavings, sawdust, and ply- wood trimmings, or alternatively the wood may be obtained from round logs or woods residue (such as branches, broken Particle Geometry logs, and tops). Milling residues may be further reduced to desired size in a hammermill operation. Roundwood, the Board characteristics influenced by particle geometry usual source of raw material for flakeboard, waferboard, or involve most of the mechanical properties, nailholding and OSB, is usually heat conditioned in water prior to reduction screwholding strength, surface smoothness, dimensional and to flakes in disk, drum, ring, or other flaking equipment (fig. weathering properties, and machining characteristics. In 22-2). After this initial raw material production phase, the addition. the particle geometry influences most other process variables. The intricacy of the interactions is compounded by the fact that the furnish does not consist of one particle geome- try but is a mix of many varying sizes. * Revision by Thedm L. Laufeenberg. General Engineer Assessment of properties of homogeneous unaligned boards

22-2 i

Flgum 22-I-BaSic panicle panel products: A particleboard. B waferboard. and C oriented strand board.

made from particles having various geometries has shown content are larger for boards made with thick flakes. Dimen- that a most important parameter is the ratio of particle length sional changes in the plane of the board are reduced with along the fiber to particle thickness. A rule of thumb for longer particles. obtaining panels with high bending, tensile, and compressive strength and stiffness is to have this ratio higher than 150. Resin Content Tensile strength perpendicular to the plane of the panel (internal bond strength) is enhanced by thicker particles due If other variables are held constant, increasing resin con- to a relative increase in the amount of adhesive per unit tent produces only a moderate improvement of bending, surface area of the particles. tensile, and compressive strengths in the plane of the board. Dimensional stability of particle panel products is related The rate of improvement, however, is not the same for all to particle geometry in that this property is controlled by the properties and is affected by particle geomeby. Internal bond orientations of particles relative to the board surface. Dimen- strength and bond durability improve continuously with sional changes in board thickness due to changes in moisture increased resin levels.

22-3 Resin Type

The bonds produced by different resin systems may be classified in two categories: those sufficiently durable for interior uses and those that are durable enough for protected exterior uses. Urea-formaldehyde resin is typically used to bind particleboard for interior uses. Phenol-formaldehyde or isocyanate resins are typical binders for protected exterior applications. Density

All physical strength and stiffness properties may be impvedby increasing the fddensity of the board. Bending, tensile and compressive strength, and stiffness increase lin- early with density. Internal bond strength. nailholding and screwholding strength, and hardness are very sensitive to board density. Most hot-pressed particleboards possess a gra- dient of density levels through the thickness of the board, which was created during the pressing sequence. This density gradient is characteristically similar for most particleboards (fig. 22-5). but the differences are significant when assess- ing thickness swell or linear expansion properties. Board den- sity also affects the rate of water absorption and the equilib- rium moisture content (fig. 22-6). A controlling relationship for the properties of particle- board is the ratio of board density to species density (compaction ratio). The bending strength (MOR) increases with increasing panel density but decreases with increasing species density (fig. 22-7). This relationship appears to be independent of species mix.

Partide AUgnment

Alignment of the furnish is a processing variable that has tremendous influence on mechanical and dimensional properties. Typically the type of furnish that lends itself to mechanical alignment has particles longer than 314 inch and somewhat narrower in width. These particles may be oriented Flgurs 22-2-Numerous types of furnish suitable IW mso) in either orthogonal direction and may be formed into several for particle panel production: A sirand-type distinct layers in the mat. The aligned particles improve the flakes, 8 fiber bundles. C wafer-type flakes. 0 mechanical and dimensional properties in the direction paral- sawdust. E long flakes, and F planer shaving. lel to the orientation. but these improvements are at the expense of those same properties in the opposite direction. The strength and stiffness of panels with aligned particles is capable of Although the amount of resin does not significantly affect exceeding 2.5 times those of panels with random orientation. some properties, the method of application does. The size of Panel shear strength of an aligned panel is less than a the resin droplets and the uniformity of their distribution on similar panel with random orientation. The alignment of flakes the wood patticles is critical to the development of particle-to- produces planes of weakness parallel to the alignment particle bonds (fig. 22-4). Fine droplets produce a well- direction. Shear strength perpendicular to the plane of the dispersed bond area for particles. which increases the mechani- board (interlaminar shear) is increased significantly due to cal properties of the board. improved bonding between similarly oriented flakes.

22-4 4

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3 FLLIKING DRVNG

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50 PERPENDICUL AR I 25' 20 40 60 80 100 RESIN DROPLETSZE IrM/

~igun22-4-lnlluenca 01 resin droplet size on (MLM Y)13) rop I BOT~OM tensile strength perpendicular and parallel to parli- 05 K- K- 076 /NW cleboard surface. Figure 22- svenicai density gradient oi a three- (Muu yII7l layer particleboard.

Hot Pressing sity gradient through the thickness of the panel (fig. 22-5). Though limited theorerical analysis has been dcne on the Press schedule variables for any one furnish type include rate of closing, moisture content distribution in the mat, press physics of particleboard pressing, a great deal of information is available from empirical studies. The most obvious temperature and pressure (which is influenced by closing and length of time in the press. "signature" from any particular pressing schedule is the den- rate),

22-5

------effectively shortening the time needed in the press to cure the resin. Another effect of the steam shock method is that the surface layer particles are plasticized and easily densified. In the particle panel product these high-density faces enhance bending properties and surface hardness and smoothness at the expense of internal bond strength and edge integrity. Specifications for Particle Panel Products

Two approaches have been taken in providing specifica- tions for particle panel products. The traditional approach is to set prescriptive standards for a particular product with minimum mechanical and dimensional properties. An alter- ‘0 IO 20 3 40 50 60 70 80 90 lo0 nate method is to specify what properties a panel must have RELATIVE HUMIDITY /PERCENT/ to perform in a given end use, allowing any number of materi- -als to qualify under the performance standard for that end Flguro 22-&Absorption isotherms for two pmi- lMl.04 59191 use. cleboards mmpared to wood. at 70 “F. A majority of the particle panel products commercially available are addressed in the American National Standard, ANSI A 208.1. for mat-formed wood particleboard. This standard specifies minimum mechanical and physical proper- ties as well as dimensional tolerances for the panel. A sum- mary of the properties required by that specification may be found in table 22- I. Two panel types are recognized: (a) type I, a particle panel 0.7 I made with urea-formaldehyde (or equivalent) (table 22- I), and (b) type 2, made with phenol-formaldehyde (or equivalent) (table 22-2). Simply stated, type 1 panels are intended for interior use and type 2 panels are for protected exterior and sheathing uses. Three density classes exist within each panel type. High density (H) denotes a density at 5 percent mois- ture content which exceeds 53 pcf; medium density (M), 38 to 53 pcf;and low density (L), less than 38 pcf. All mechani- cal property values listed in table 22- 1 are used for quality control and grade certification and must not be misconstrued

I I I I I as design allowable values. In-service conditions, material 0.4 0.5 0.6 0.7 variability, and installation practices preclude the use of these WOOD DENSITY /GM/CM? test values for engineering design. Roperties of these panels are determined by the test conditions and methods set forth in Flgure 22 -7-Relationship between wood density IMW 59181 ASTM D 1037. Within the type 2 grades (table 22-2) are and modulus of rupture for four particleboard two grades of material that identify a specific particle type to densities. (Use the curves with care. as a board density of 0.5 is not currently possible with wood of be used in their manufacture. 0.6 density.) Phenolic-bonded particleboards. wafehds, and OSB are .. finding increasing use as sheathing and combination subfloor- underlayment. Many boards are recognized for use based on The most common manipulation of the pressing process performance testing rather than on prescriptive standards. utilizes a higher moisture content furnish on the faces of the These are marketed under a quality control program designed mat. As the hot platens contact the mat, significantly greater to assure that structural properties do not fall below those of amounts of steam are produced than during pressing of a mat panels successfully passing performance testing. The Ameri- with lower face moishue. This “steam shock” moves through can Plywood Association has several panel product perfor- the unpressed mat toward the centerline. heating the mat and mance standards that specify the structure of these quality

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h / ' control programs. This program also establishes minimum Particleboard Properties and Uses criteria for physical properties and durability. Some standards on specific uses of particleboard are issued The particle panel product that is typically made from small by hade associations such as the National Particleboard Associ- wood particles of mill residue is designated particleboard. ation (NPA), building code organizations, and government While particleboards arc difficult to characterize bccause of agencies. A summary of these standards and the uses lo which the infinite variations in the process variables discussed I they apply is in table 22-3. previously, the propcnies given in table 22-4 should pro-

Table 22 - 3-PdbM &plication reference table'

~ Applications Grade Product referend Applications Qrade Product reference?

INTERIOR EXTERIOR

Floor 1-M-1 ICBO, SBCC, BOCA, Roof sheathing 2-M-W ICBO. SBCC, BOCA, underlayment HUDIFHA MPS, One One and Two Family and Two Family Dwelling Code Dwelling Code Wall sheathing 2-M-1 ICBO. SBCC, BOCA, Mobile home Class D-2 NPA 1-73 One and Two Family decking Class 0-3 HUD-Mobile Home Dwelling Code Construction and Safety Standards Wall sheathing 2-M-W ICBO. SBCC. BOCA, One and Two Family Shelving 1-M-1 Dwelling Code 1-M-2 1-M-3 Combined 2-M-3 ICBO, SBCC, BOCA, subfloor 2-M-W One and Two Family Countertops 1-M-2 ANSI A 161.2 underlayment Dwelling Code 1-M-3 Factory built NPA 2-72 HUDIFHA UM-57a Kitchen 1-M-1 ANSI A 161.1 decking cabinets 1-M-2 Siding 2-M-1 ICBO. SBCC, BOCA, 1-L-1 NWMA Industry Door core One and Two Family Standard Series IS. Dwelling Code 1-78 (wood flush doors) Siding 2-M-W SBCC, BOCA Stair treads 1-M-3 HUDlFHA UM 70, ICBO RR 3390 Moldings 1-M-3 WMMP Standard WM 2-73

' Grades shown refer to ANSI A 208.1 excapl for mobile home BOCA - Building Olficials and Code Administrators Inlernalional. decking which refers to NPA 1-73 and factory-built decking which Chicago. IL. refers Io NPA 2-72. HUD/FHA - Housing and Urban DevelopmenffFederal Housing iCB0 - lnlemallonal Conference of Building Officials, Whlnier. Authority. Washington. DC. CA. NWMA - National Woodwork Menufacturers Association. Park SBCC - Sournem Building Code Cmgress Intematbnal, Birming- Ridge. IL. ham, AL. WMMP - Wood Moulding and Millwork Producers. Potliand. OR.

22-9 ie an idea of the ranges possible for the mat-formed product. kind of adhesive used, but on the protection afforded by a :ah the primary distinction between flakeboards and parti- finish. This may be a plastic film, paper overlay, or paint :boards is in the size of the particle or flake. The properties which is factory applied. ted do not reflect the properties attainable when using a Manufacturers of mobile homes and factory-built conven- ke furnish. tional housing also use particleboard. Because these uses may require larger sized panels than those used for conven- Mat-Formed Particleboard tional construction particleboard is manufactured in sizes as great as 8 by 60 feet. With mechanical handling available in Approximately 85 percent of interior-type mat-formed par- lactones, large-sized panels can be positioned and attached to leboard produced has traditionally been used as core stock structural members effectively and economically. Two parti- : a wide variety of furniture and cabinet applications and cleboard products have been developed to satisfy these uses. Nor underlayment in light-frame construction. The majority Mobile home decking is used for combined subfloor and production is between 1/2 and 2 inches thick for mat- underlayment. It is a board with a type 1 bond, but is intended med boards. Low-density panels are produced in thick- to be protected from moisture when in use by a subfloor SSeS to 1-112 inches for the solid core door market. which is exposed to the exterior environment. Thus, the board As corestock, particleboard has moved into the market is generally regarded as giving satisfactory service for mobile merly held by lumber-core panels and, to a limited extent, home use. Particleboard decking for factory-built housing is {wood. Certain grades of plywood now permit similar to mobile home decking, but it has a type 2 bond for :use of particleboard as the core ply, where formerly lum- longer life. The National Particleboard Association has estab- r core was specified. The type of facing or finishing system lished separate standards for these products. They are mar- plied commonly controls the construction of the particle- keted under a certified product quality program with each ard produced. A panel to be overlaid with 0.0015-inch product adequately identified. ravioletsured vinyl overlay requires fine particles, or pos- jly fibers;on the surfaces to reduce showthrough. An over- Extruded Particleboard I of veneer or high-density plastic can accommodate a mer face particle. Balanced construction in layups using Extruded products are typically "fluted" in that the prod- rticleboard is important to minimize warping, cupping, or uct is not of uniform thickness over its width. This configura- isting in service. tion is used in flush doors or overlaid with a structural panel Edges of particleboard exposed in furniture or product such as a hardboard, flakeboard, or plywood for : frequently covered as there are coarse particles in the sandwich constructions. The extruded products have distinct wer density core. Edge banding with plastic extrusions or a zones of weakness across the width of the panel as extruded; gh-density plastic are common lreatments. Filling of edge thus they are rarely used without facings of some kind glued lids and subsequent finishing, or bonding solid wood to to them. These facings control the physical and mechanical ;posed edges are other options. properties of the sandwich construction. This type of particle- As floor underlayment, particleboard provides a smooth, board also has a strong tendency to swell in the lengthwise iff, and hard surface for coverings of carpet, resilient tile. direction due to particle orientation and subsequent compres- ,d seamless floor coverings. Particleboard for this use is sion as particles are rammed through the heated die during lduced in 4- by &foot panels 114 to 3/4 inch thick. Specifi- manufacture. :ions for these numerous uses have been written to cover zicleboard floor underlayments, and manufacturers pro- le individual application instructions to ensure proper con- Flakeboard Properties and Uses uction techniques. Particleboard underlayment is sold under :ertified quality program where established grademarks Flakeboard is a generic subset of products included under zrly identify the use, quality, grade, and originating mill. Other uses for particleboard require a more durable type 2 NSI A 208.1) adhesive in the board. Siding, combined density species, such as or , and bonded with an :ing-sheathing, soffit linings, ceilings for carports. porches, exterior-type water-resistant adhesive. The industry began j other protected exterior applications are examples of uses production in the 1950's with a small plant in Sandpoint, proved by some of the model building codes. Satisfactory Idaho. Subsequent plants built in the 1960's in Hudson Bay, formance of particleboard in protected exterior environ- Saskatchewan, proved to be the major developing ground for :nts depends not only on the manufacturing process and the flakeboard industry. Prcducing mills are now located in 8 I i?

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the Great Lakes region, New England, and most Canadian frame construction. Several building codes have approved provinces. flakeboards for siding materials either over sheathing or nailed The Youth of the flakeboard industry has not prevented it directly to the=xterior ceilings, soffits, and interior from making major inroads into the light-frame construction walls or ceilings are other uses in light residential construc- industry. Beginning in the early 1970's. interest in flake- tion that have received building code approval. In nonresiden- boards increased for a variety of reasons including a strong demand for structural board products and an increase in soft- wood plywood prices. Utilization of the lower priced aspen stumpage in the Great Lakes and Hudson Bay regions. cou- pled with closer proximity to the large eastern markets than Other Wood-Based Particle Products western or southern plyWood mills, gave builders a low-cost alternative to plywood for sKeathing uses. VenoedPartiele Composite Panels Two major types of flakebdard are recognized, waferboard and OSB. Waferboard. the product produced almost exclu- Structural composite panels marketed since the mid-70's sively from aspen wafers (wide flakes). traditionally pos- are made with face veneers bonded to a core layer made from sesses no intentional orientation of these flakes, and is bonded oriented strands or random particles. This product (sometimes with an exterior-type isin. OSB is a flakeboard product that referred to as COM-PLY) is marketed as a plywood product emerged in the market place during the early 1980's. Exterior- and is considered to be interchangeable with construction type resin is applied to wood strands (long and nmwflakes) grades of plywood (see ch. 11). Thicknesses of 318 to 1/2 that are formed into a mat of three to five layers. The shands inch are common for sheathing uses of this panel, and thick- in each layer are aligned in a direction 90" from the adjacent nesses up to 1-118 inches have been produced for single-layer layer. Flake alignment gives the OSB bending properties (in flooring applications. The performance standard for structural- the aligned direction) that are generally superior to those of a use panels sponsored by the American Plywood Association randomly oriented flake waferboard. Some important physi- embodies procedures for grademarking this type of panel. cal and mechanical properties for flakeboards are summa- rized in table 22-5. As with any particle panel product, the Mende-Process Particleboard properties are highly dependent upon,the process used to manufacture the panel; the values in tables 22-5 and 22-6 A unique process for producing thin particleboard, the were generated from typical commercially available flake- Mende process. involves continuous pressing of the mat by boards. application of heat and pressure through a large rotating The properties of flakeboards indicate that products are cylinder. The board thickness ranges up to 1/4 inch, which suitable for many applications now dominated by permits it to be formed on this cylindrical platen and subse- plywood. Primary markets for flakeboards are wall and roof quently flattened. Furnish for the process may range from sheathing, single-layer flooring, and underlayment in light- fibers to flakes. The panels produced in this process may be

Table 22 - 6-Effect of waferboard thickness on thermal conductivity and hteral and direct Mil withdrawal

511 6 2.4 200 + 20 + 711 6 1.8 400 + 40+ 510 1.2 550 + 65 + ' For 8d wmmm nails. 2 Edge dllltanCB 1/2 inch.

22-12 used as wall paneling (with printed overlay or other surface MeanSoeicty forTeating and Maluials. Standard methods of evaluating fmish). W~rebacking, drawer bottoms, and case goods. the propmics of wood-basc fiber and Panicle panel materials. ASTM D 1037. Philsdclphia. PA: ASTM: (ICC cymnt edition). Canadian Waferboard Association. Waferboard in residential construction. Molded Partide Roducts Don Mills, ON, Canada; 1982. Gimcr. R. L.; Hmver, W. L.; Hunt. M.0. Design and cmsmction of Moldings from wood particles can be defined as parts that large-wale reconsti~lcdwad mcfdecking. RB 973. West Lafayene. IN: arc formed from furnish blended with less than 25 percent pvrdue University, Agriculnual Experiment Station; 1982. binder resin and cured in dies under heat and pressure. Lim- Gcimer. R. L. Data basic lo the engineering design of a monstitutcd flakeboard. In: Raecdings. 13th Washington State Univcrsiw Intema- ited flow of the furnish during pressing restricts the kind of tional Symposium on Paniclcboard. Pullman. WA: Wash’ @on Slate items that may be profitably molded. Exterior siding, door University:. 1979. 105-125. jambs, window sills, table tops, pallets. casket tops, and Jersomc, A. P. Canadian wafc~ardpmpenicr. Tech. Rep. 523E. Van. many other items may be molded using conventional particles. cwver, BC. Chad?: FORlKlEK Canada Corporation; 1979. By using finer particles which approach wood flour in size, Kclly. M. W. Critical literature review of relationships between pcsring p”meterr .ad Faopnies of panicleboard. Tech. Rep. items with large relief such toilet seats and croquet balls physical Gcn. as FPL- IO. Madison. WI: U.S. Dcparunent of Agriculrurr. Forest Service. may be compression molded. Forest Roducts Laboratory; 1977. Kicaer, 1.; Seck. E. F. The influence of flake orientation on the MOR and Cement-Bonded Particle F’roducts MOE of swndboanis. In: Raecdings. 12th Washington State University Sympimon Particleboard. Pullman, WA Warhiagtm Stale University; 1918: 99-122. Portland cement is commercially used as a binder for a National Panicleboard Aswciation. Slaadard far paniclcboard for mobile special class of wood particle panels. The wood panicles horn decking. NPA 1-73. Silver Springs. MD: NPA; 1973. typically used are called excelsior, or wood-wool. as they are National Panicleboard Asmiation. Standard for panicleboard flmr undcr- long (up to IO in) and stringy. Medium- to lowdensity spe- lpymcnt -led with wax-polymer type hot melt coatings. NPA 3-73. cies am reduced to excelsior. blended with cement, formed Silver Springs. MD: NPA. 1973. National Putklcboard AsSOCiation. Filling panicleboard. Tech. Bull. 9. into mats, and pressed to a density of 30 to 40 pcf. A com- Silver Springs, MD: NPA, 1972. mon use for this product is as roof decking due to its sound- National Phcle- Association. Standard far paniclcboard dcckhg for absorbing .and fuc-resistive properties. Other cement-bonded factory-built housing. NPA 2-72. Silver Springs. MD: NPA 1972. particle products include building blocks and a panel made National Panicle- Association. Edge banding and vcnccring of p.niclc- with flakes that can be used in doors. floors, load-bearing board. Tech. Bull. 7. Silver Springs, MD: NPA; 1971. National Rcseuch Board. APA structural-use panels. Rep. NRB-108. walls, partitions. concrete forms, and exterior siding. Wnier. CA: Council of Amrican Building Mficialr; 1982. Nertler. F. H. M. The formaldehyde problem in woad-bawd pmducu. YI annatalcd bibliogrsphy. an. Tech. Rep. FPL-8. Madison, WI: U.S. Selected References kpmnent of Agriculture. Forest Sewice. Forest Roducu Laboratory; 1977. Snodps1. D. Manufacture of aicnlcd-swnd core facompile plywood. Am&- Narional SmddslartiNte. Mat-fdwood particleboard. ANSI In: Proceedings. I Ith Washington State University Symposium on A 208.1. New Yorl;; 1979. Particleboard. Pullman. WA: Washington State University; 1977: American Plywood Association. Performnncc rlaadards and policies for 453-470. srmcM-uu plr.Tscama. WA: APA, 1982. Stillingcr. 1. R.; Wcntwonh, Irv W. Roduct. -sr and economics o& American Sosiety for Tesling and Muerials. Slaadml deftnitions of tern pmducing strurmrpl woodsemnt panels by the Bison-Wcrke system. Io: relsling m wood-bare fiber and particle punel malcrials. ASTM D 155-4. Roatdings 11th Washington State Univenity Symposium an Paniclc- Philadclphis. PA ASTM; (IO amcm edition). board. Pullrma. WAWashingson State Univmity; 1977: 383-410.

22- I3 Modified Woods and Paper-Base Laminates

Page Modified Woods ...... 23-2 Resin-Treated Wood (Impreg) ...... 23-2 Resin-Treated Compre Untreated Compressed Untreated Heated Wood (Staybwood) Polyethylene Glycol-T Wood-Plastic Combination .... Chemical Modification ...... Paper-Base Plastic Laminates ...... 23-1 1 Industrial Laminates ...... 23- I I Decorative Laminat Lignin-Filled Laminates ...... Paper-Face Overlays ...... Selected References ...... 23-13 ~ ~~ .- ~--- .. (1 i

9. Materials with propenies substantially different than the impregnated with the solution under pressure until the resin base material are obtained by chemically treating a wood or content equals 25 to 35 percent of the weight of dry wood. wood-base material, compressing it under specially controlled The treated wood is allowed to stand under nondrying condi- conditions. or by combining the processes of chemical treat- tions for a day or two to permit uniform distribution of the ment and compression. Sheets of paper treated with chemi- solution throughout the wood. The resin-containing wood is cals are laminated and hot-pressed into thicker panels that verate temperatures to remove the water and then have the appearance of plastic rather than paper, and they are heated to higher temperatures to set the resin. used in special applications because of their structural proper- . Uniform distribution ot Ihe resin has been effectively accom- ties and in items requiring hard, impervious, and decorative p;ished with thick wood specimens only in sapwood of read- surfaces. ily penetrated species. Although thicker material can be Modified woods, modified wood-base materials, and paper- treated, the process is usually applied to veneers up to 1/3 base laminates are normally more expensive than wood inch thick. since treating time increases rapidly with increases because of the cost of the chemicals and the special process- in thickness. Drying thick resin-treated wood may result in ing required to produce them. Thus, their use is generally checking and honeycombing. For these reasons, treatments limited to special applications where the increased cost is should be confined to veneer and the treated-cured veneer justified by the special properties needed. used to build up the desired products. Any species can be used for the veneer except the resinous . The stronger Modified Woods the original wood, the stronger will be the product. Impreg has a number of properties differing from those of Wood is treated with chemicals to increase hardness and normal wood and ordinary plywood. These are given in table other mechanical properties, as well as its resistance to decay, 23- I, together with similar generalized findings for other fire, and moisture. Application of water-resistant chemicals modified woods. Data for the strength properties of to the surface of wood, impregnation of the wood with such impreg are given in table 23 - 2. Information on thermal expan- chemicals dissolved in volatile solvents, or bonding chemi- sion properties of ovendry impreg is given in table 23-3. cals to the cell wall polymer reduces the rate of swelling and The good dimensional stability of impreg has been the shrinking of the wood when in contact with water. Such basis of one use where its cost was no deterrent to its treatments may also reduce the rate at which wood changes acceptability. Wood dies of automobile body pans serve as dimension because of humidity changes, even though they do the master from which the metal-forming dies are made for not affect the final dimension changes caused by long-duration actual manufacture of parts. Small changes in moisture exposures. Paints, , lacquers, wood-penetrating water content, even with the most dimensionally stable wood, pro- repellents, and plastic and metallic films retard the rate of duce changes in dimension and curvature of an unmodified moisture absorption, but have little effect on total dimension wood die; such changes create major problems in making the change if exposures are long enough. metal-forming dies where close final tolerances are required. The substitution of impreg, with its high antishrink efficiency Resin-Treated Wood (Impreg) (ASE) (table 23-4), almost entirely eliminated the problem of dimensional change during the entire period that the wood Permanent stabilization of the dimensions of wood is needed master dies were needed. Despite the tendency of the resins forcerlain specialty uses. This can be accomplished by deposit- to dull cutting tools, patternmakers accepted the impreg read- ing a bulking agent within the swollen structure of the wood ily because it machines without splitting more easily than fibers. The most successful bulking agents that have been unmodified wood. commercially applied are highly water-soluble, thermosetting, Patterns made from impreg also are superior to unmodified phenol-formaldehyde resin-forming systems. with initially low wood in resisting heat when used with shell- tech- molecular weights. No thermoplastic resins have been found niques where temperatures as high as 400 "F were required to that effectively stabilize the dimensions of wood. cure the resin in the molding sand. Wood treated with a thermosetting fiber-penetrating resin andzured w'lthpuf compression is known as impreg. The Resin-Treated Compressed Wood (Compreg) wood (preferably green veneer to facilitate resin pickup) is soaked in he aqueous resin-forming solution or. if air dry, is Compreg is similar lo impreg except that it is compressed .. before the resin is cuwod. The'resin-forming *Revision by Donald S. Fahey. Forest Roductr Technolagiri; Roger M. chemicals (usually phenol-formaldehyde) act as plasticizers Rowell. Chemist: and Theodore H. Wegner. Chemical Engineer. for the wood so that it can be compressed under modest

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23-7 pressures (I ,ooO psi) to a specific gravity of I.35. Some of its of resin-treated veneer in ;I cold press after preheating the properties are similar to those of impreg, and others vary sheets to 200 to 240 OF. The heat-plasticized wood responds considerably (tables 23- I and 23-2). Its advantages over to compression before cooling. The heat is insufficient to impreg are its natural lustrous finish that can be developed on cure the resin, but the subsequent cooling sets the resin any cut surface by sanding with fine-grit paper and buffing, temporarily. These compressed sheets are cut to the desired its greater strength properties. and the fact that it can be size, and the assembly of plies is placed in a split mold of the molded (tables 23- 1 and 23-2). Thermal expansion coeffi- final desired dimensions. Because the wood was pre- cients of ovendry compreg, however, are also increased (table compressed, the filled mold can be closed and locked. When 23-3). the mold is healed, the wood is again plasticized and tends to Compreg can be molded by: (I) Gluing blocks of resin- recover its uncompressed dimensions. This exerts an internal treated (but still uncured) wood with a phenolic glue so that pressure in all directions against the mold equal to about half the gluelines and resin within the plies are only partially set; of the original compressing pressure. On continued heating. (2) cutting to the desired length and width but two to three the resin is set. After cooling, the object may be removed times the desired thickness; and (3) compressing in a split from the mold in finished form. Metal inserts or metal sur- mold at about 300 "F. Only a small flash squeezeout at the faces can be molded to compreg or compre handles molded parting line between the two halves of the mold need be ma- onto tools by this means. Compreg bands have\ been mo e chined off. This technique was used for molding motor-test tu me outside oi turnea wood cylinders without compressing propellers and airplane antenna masts during World War 11. the core. Compreg tubes and small airplane propellers have A ,more generally smmolding technique, known been molded in this way. as eypansion CUQULI' g. has been developed. The method con- Past uses for compreg once related largely to aircraft; sists of rapidly precompressing dry but uncured single sheets h&ver, it is a suitable material where bolt-bearing strength '

Table 23 - Moeffieients of linear thermal expansion per degree Celsius of wood, hydrolyzed wood, and paper products'

~ Linear expansion per "C by 10' Specific Glue plus Perpendicular to Cubical Material2 gravity resin Fiber or fiber or machine Pressing expansion Of wntenf machine direction in direction per 'C product direction plane of by 10' laminations

Pct

Yellow birch laminate 0.72 3.1 3.254 40.29 36.64 80.18 Yellow birch staypak laminate 1.30 4.7 3.406 37.88 65.34 106.63 Yellow birch impreg laminate .86 33.2 4.648 35.11 37.05 76.81 Yellow birch compreg laminate 1.30 24.8 4.251 39.47 59.14 102.86 Do. 1.31 34.3 4.931 39.32 54.83 99.08 Sitka laminate .53 6.0 3.887 37.14 27.67 68.65 Parallel-laminated paper laminate 1.40 36.5 5.73 15.14 65.10 85.97 Crossbanded paper laminate 1.40 36.5 10.89 11.oo 62.20 84.09 Molded hydrolyzed-wood plastic 1.33 25 42.69 42.69 42.69 128.07 Hydrolyzed-woodsheet laminate 1.39 18 13.49 24.68 77.41 1 15.58 ' These coenicients refer to bone-dry material. Generally, air-dry material has a negative thermal coefficientof expansion, because the shrinkage resulting from the loss in moisture is greater than the normal thermal expansion. All wood laminates made from rotary-cut veneer, annual rings in plane of sheet. On basis of dry weight of product. Approximate. 'Calculated value.

23-8 is required, as in connector plates, because of its good spe- prior to World War 11. It was a compressed solid wood with cific strength (strength per unit of weight). Layers of veneer much less dimensional stability than staypak and was known making up the compreg for such uses are often cross lami- as lignostone. Another similar German product was a lami- nated (alternate plies at right angles to each other, as in nated compressed wood known as lignofol. plywood) to give neaily equal propenies in all directions. It is extremely useful for aluminum drawing and forming dies, Untreated Heated Wood (Staybwood) drilling jigs, and jigsmr holding parts in place while welding, because 01 hs e xcellent strength- .. properties. dimensional Heating wodd under drying conditions at higher tempera- stability, low thermal conductivity, and ease of fabrication. tures (200 to MX)" F) than those normally used in kiln drying Compreg has also been used in silent gears, pulleys, water- Froduces a product known as staybwood that reduces the lubricated bearings, fan blades, shuttles, bobbins and picker hygroscopicity and subsequent swelling and shrinking of the sticks for looms, nuts and bolts, instrument bases and cases, musical instruments, electrical insulators, tool handles, and various novelties. Compreg at present finds considerable use Table 23 - Momparison of wood treatments and the in handles for knives and other cutlery. Both the expansion- degree of dimensional stabiliry achieved molding techniques of forming and curing the compreg around Treatment Antishrink efficiency' the metal pans of the handle and attaching previously made compreg with rivets are used. Pct Veneer of any nonresinous species can be used for making compreg. Most propelties depend upon the specific gravity to Simple wax dip 2-5 which the wood is compressed rather than thr species used. Wood-plastic combination 10-15 Up to the present, however, compreg has been made almost exclusively from yellow birch or sugar . StaypaWstaybwood 30-40 lmpreg 65-70 Untreated Compressed Wood (Staypak) Chemical modification 65 - 75 ' Resin-lreated wood in both the uncompressed (impreg) and Polyethylene glycol 80-85 compressed (compreg) forms is more brittle than the original wood. To meet the demand for a tougher compressed product Formaldehyde 82-87 than compreg, a compressed wood containing no resin Compreg 90-95 (staypak) was developed. It will not lose its compression under swelling conditions as will ordinary compressed ' Calculated from: untreated wood. In making staypak. the compressing condi- V2 - V, tions are modified so that the lignin-cementing material s=-xxoo between the fibers flows sufficiently to eliminate VI internal stresses. where Staypak is not as water resistant as compreg. but it is about S = volumetric swelling coefficient. twice as tough and has higher tensile and flexural strength V, = wood volume afler humidify conditioning propenies, as shown in tables 23-1 and 23-2. The natural or welling with water, and finish of staypak is almost equal to that of compreg. Under V, = v& volume of ovendried sample before weathering conditions, however, it is definitely inferior to conditioning or wening. compreg. For outdoor use, a good synthetic resin or then paint finish should be applied to staypak. s* - s, Staypak can be used in the same way as compreg where ASE = -x 100 extremely high water resistance is not needed. It shows prom- S, ise in tool handles, forming dies, connector plaies, propellers, where and picker sticks and shuttles for weaving, where high impact strength is needed. As staypak is not impregnated. it can be ASE = redunion in swelling or antishrink made from solid wood as well as from veneer. Its cost is less efficiency resulting from a treatment. SI = treated volumetric swelling coelficient. than compreg. S, = untreated volumetric swelling A material similar to staypak was produced in Germany coefficient.

23-9 Wood appreciably. The stabilization. however, is always Wood-Plastic Combination accompanied by loss of mechanical properties. Toughness and resistance to abrasion are most seriously affected. In the modified wood products previously discussed, most Under conditions that cause a reduction of 40 percent in of the chemical resides in cell walls; the lumens are essen- shrinking and swelling, the toughness is reduced to less than tially empty. If wood is vacuum impregnated with certain half that of the original wood. Extensive research to mini- liquid vinyl monomers that do not swell wood, and which are mize this loss was not successful. Because of the reduction in later polymerized by gamma radiation or chemical catalyst- Strength properties from heating at such high temperatures. heat systems, the resulting polymer resides almost exclu- wood that is dimensionally stabilized in this manner is not sively in the lumens. Methyl methacrylate is a common mono- used commercially. mer used for a wood-plastic combination. It is converted to polymethyl methacrylate. Such wood-plastic combinations with polymer contents of 75 to 100 percent (based on the dry Polyethylene Glycol-Treated Wood (PEG) weight of wood) resist moisture movement through them. Moisture movement is extremely slow so that normal equilib- The dimensional stabilization of wood with polyethylene rium swelling is reached very slowly. Wood-plastic combina- glyCol-loM) (PEG), also known as Carbowax, is accomplished tion materials are much stronger than untreated wood (table by bulking the fibers to keep the wood in a partially swollen 23-5) and commercial application of these products is largely condition. PEG acts in the same manner as does the pre- based on increased strength properties. viously described phenolic resin. It cannot be further cured. The main commercial use of this modified wood at present The only reason for heating the wood after matment is to is as muet flooring where it is produced in squares about drive off water. PEG remains water soluble. Above 60 per- 5-112 inches on a side from strips about 718 inch wide and cent relative humidity it is a strong humectant and, unless 5/16 inch thick. It has a specific gravity of 1.0. Comparative used with care and properly protected, PEG-treated wood can tests with conventional indicate wood-plastic become sticky at high relative humidities. Because of this, materials resisted indentation from rolling, concentrated, and PEG-treated wood is usually finished with polyurethane impact loads better than white . This is largely ataibuted varnish. to improved hardness, which was increased 40 percent in Treatment with PEG is facilitated by using green wood. regular wood-plastic combination and 20 percent in the same Here, pressure is not applied since the treatment is based on material treated with a fm retardant. Abrasion resistance was diffusicn. Treating times are such that uniform uptakes of 25 no better than white oak; but because the finish is built in, to 30 percent of chemical are achieved (based on dry weight buffing is all that is required to provide the luster. The finish of wood). The time necessary for this uptake depends on the is maintained even under severe traffic conditions. thickness of the wood and may require weeks. This treatment Wood-plastic combinations are also being used in sporting is being effectively used for walnut unstocks for high-quality goods, musical instruments, and novelty items. rifles. The dimensional sta+ I ity of such gunstocks greatly enhances the continued accuracy of the rifles. Tabletops of Chemical Modification high-quality furniture stay remarkably flat and di-mensionally

23-10 65 to 75 percent at chemical weight gains of 20 to 30 percent. with a resinous binder and curing the assembly under heat Reaction of these chemicals with wood yields a modified and pressure. wood with increased dimensional stability and improved resis- tance to termites, decay, and marine organisms. Mechanical Industrial Laminates properties of chemically modified wood are somewhat reduced (10 to 15 percent) as compared to untreated wood. Industrial laminates are produced to perform specific func- The reaction of formaldehyde with wood hydroxyl groups tions requiring materials with predetermined balances of is an interesting variation of chemical modification. At weight mechanical, electrical, and chemical properties. The most gains as low as 2 percent, formaldehyde-treated wood is not common use of such laminates is for electrical insulation. attacked by wood-destroying fungi. An antishrink efficiency The paper reinforcements used in the laminates are of kraft of 47 percent is achieved at a weight gain of 3.1 percent, 55 pulp, alpha pulp, cotton linters, or blends of these. Kraft percent at 4.1, 60 percent at 5.5, and 90 percent at I. paper emphasizes mechanical strength and dielectric strength The mechanical pmpenies of formaldehyde-treated wood perpendicular to laminations. Alpha paper is used for its elec- are all reduced from those of untreated wood. A definite tric and electronic properties, machinability, and dimensional embrittlement is observed, toughness and abrasion resistance stability. The cotton linter paper combines greater strength are greatly reduced, crushing strength and bending strengths than alpha paper with excellent moisture resistance. are reduced about 20 percent, and impact bending strength is Phenolic resins are the most suitable resins for impregnat- reduced up to 50 percent. ing the paper from the standpoint of high water resistance, low swelling and shrinking, and high strength properties Paper-Base Plastic Laminates (except for impact). Phenolics are also lower in cost than other resins that give comparable properties. Water-soluble Commercially, paper-base plastic laminates are of two resins of the type used for impreg impart the highest water types-industtial and decorative. The total annual production resistance and compressive suength properties to the product, is equally divided between the two types. They are made by but they make the product brittle (low impact strength). superimposing layers of paper that have been impregnated Alcohol-soluble phenolic resins produce a considerably

Table 23 - S-Strengfh properries of wood-plastic cornbirdon'

~~~~~ ~ Strength property Unit Untreated2 Treated'

STATIC BENDING

Modulus of elasticity lo6 psi 1.356 1.691 Fiber stress at proportional limit psi 6.387 11.582 Modulus of rupture psi 10,649 18,944 Work to proportional limit in-lb/in3 1.66 4.22 Work to maximum load in - Ib/in3 10.06 17.81

COMPRESSION PARALLEL TO GRAIN Modulus of elasticity lo6 psi 1.113 1.650 Fiber stress at proportional limit psi 4,295 7,543 Maximum crushing strength psi 6,505 9.864 Work to proportional limit in- Ib/in3 11.28 21.41 Toughness in- Ib/in3 41.8 62.6 ' Methyl methacrylate impregnated basswoad. Moisture content-7.2 percent.

23-1 1 tougher product, but the resins fail to penetrate the fibers as of paper. The phenolic-impregnated sheets are brown because well as water-soluble resins and thus impart less water resis- of the impregnating resins and comprise most of the built-up lance and dimensional stability to the product. In practice. thickness of the laminate. The phenolic sheets are overlaid alcohol-soluble phenolic resins are generally used. with paper impregnated with melamine resin. One sheet of Paper-base plastic laminates inherit their final properties the overlay is usually a relatively thick one of high opacity from the paper from which they are made. High-strength and has the color or design printed on it. Then one or more yield higher strength plastic laminates than do low- tissue-thin sheets, which become transparent after the resin is strength papers. Papers with definite directional properties cured, are overlaid on the printed sheet to protect it in service. result in plastic laminates with definite directional properties The thin sheets generally contain more melamine resin than unless they are cross-laminated (alternate sheets oriented with the printed sheet, providing stain and abrasion resistance as the machine direction at 90" to each other). well as resistance to cigarette bums, boiling water, and com- Improving the paper used has helped develop paper-base mon household solvents. laminates suitable for structural use. Pulping under milder The resin-impregnated sheets of paper are hot-pressed, conditions and operating the paper machines to give optimum cured, and then bonded to a wood-base core, usually plywood, orientation of the fibers in one direction, together with the hardboard, or particleboard. The thin transparent (when cured) desired absorbency, contribute markedly to improvements in papers impregnated with melamine resin can be used alone as strength. a covering for decorative veneers in furniture to provide a Strength and some other properties of a paper plastic lami- permanent finish. In this use the impregnated sheet is bonded nate are shown in table 23-2. The National Electric Manu- to the wood surface in hot presses at the same time the resin is facturers Association L1 - 1 specification has further informa- cured. The heat and stain resistance and the strength of this tion on industrial laminates. As paper is considerably less kind of film make it a superior finish. expensive than glass fabric or other woven fabric mats and The overall thickness of a laminate may obviously be var- can be molded at considerably lower pressures, the paper- ied by the number of sheets of kraft-phenolic used in the core base laminates generally have an appreciable price advantage assembly. Some years ago the U16-inch thickness was used over fabric laminates. Some fabric laminates, however, give with little exception because of its very high impact strength superior electrical properties and the highest impact properties. and resistance to substrate showthrough. More recently the Glass fabric laminates can,be molded to greater double curva- 1/32-inch thickness has been popular on vertical surfaces tures than paper laminates. such as walls, cabinet doors, and vertical furniture faces. During World War 11. a high-strength paper plastic known This results in better economy, since the greater strength of as- was used for molding nonstructural and semi- the heavier laminate is not necessary. As applications have structura auplane pans, such as gunner's seats and turrets, proliferated, a whole series of thicknesses have been offered ammunition boxes, wing tabs, and the surfaces of cargo air- from about 20 to 62 mils, or even up to 150 mils when craft flooring and catwalks. Papreg was tried to a limited self-supporting types are needed. The laminate may have extent for the skin surface of airplane structural parts, such as decorative faces on both sides if desired, especially in the wing tips. One major objection to its use for such parts is that heavier thicknesses. it is more brittle than aluminum and requires special fittings. The phenolic sheets may also contain special postforming- Papreg has been used to some extent for heavy-duty truck type phenolic resins or extensible papers that make it possible floors and industrial processing trays for nonedible materials. to postform the laminate. By heating to 325 "F for a short Because it can be molded at low pressures and is made from time. the structure can undergo simple bending to a radius of thin papers, it is advantageous for use where accurate control 1/2 inch readily and of 3/16 lo 1/4 inch with careful control. of panel thickness is required. Rolled furniture edges, decorative moldings, curved counter tops, shower enclosures, and many other applications are Decorative Laminates served by this technique. Finally, the core composition may be modified to yield fire-retardant, low-smoking laminates to Although decorative laminates are made by the same pro- comply with fire codes. These high-pressure decorative lami- cess as industrial laminates, they are used for very different nates are covered by the National Electrical Manufacturers purposes and bear little outward resemblance to each other. Association Specification LD3. They are used as facings for doors and walls, and for tops of Paper will absorb or give off moisture, depending upon counters, tables, desks, and other furniture. conditions of exposure. This moisture change causes paper to These decorative laminates are usually composed of a shrink and swell, usually more across the machine direction combination of phenolic- and melamine-impregnated sheets than along it. Likewise, the laminated paper shrink

23- 12 and swell, although at a much slower rate. Cross-laminating best all-around product. Higher resin contents make the prod- , minimizes the amount of this shrinking and swelling. In many uct too costly and tend to make the overlay more transparent. uses in furniture where laminates are bonded to cores, these Appreciably lower resin contents give a product with low changes in dimension due to moisture changes with the change scratch and abrasion resistance, especially when the panels of seasons are different than those of the core material. To are wet or exposed to high relative humidities. balance the consuuction, a paper plastic with similar proper- The paper faces can be applied at the same time that the ties may be glued to the opposite face of the core to prevent veneer is assembled into plywood in a hot press. Thermal bowing or cupping from the moisture changes. stresses that might result in checking are not set up if the machine direction of the paper overlays is at right angles to Lignin-Filled Laminates the grain direction of the face plies of the plywood. The masking paper-base overlays or vulcanized fiber sheets The cost of phenolic resins at one time resulted in consider- have been used for such applications as wood house siding able effort to find impregnating and bonding agents that were that is to be painted. These overlays mask defects in the less expensive and yet readily available. Lignin-filled lami- wood, prevent bleedthrough of resins and extractives in the nates made with lignin recovered from the spent liquor of the wood, and provide a better substrate for paint. The paper- soda pulping process have been produced as a result of this base overlays improve the across-the-board stability from search. Lignin is precipitated from solution within the pulp or changes in dimension due to changes in moisture content. added in a pre-precipitated form before the paper is made. The structural overlay, also known as the high-density The lignin-filled sheets of paper can be laminated without the overlay, contains no less than 45 percent thermosetting resin, addition of other resins, but their water resistance is consider- generally phenolic. It consists of one or more plies of paper ably enhanced when some phenolic resin is applied to the similar to that used in the industrial laminates described paper in a second operation. The water resistance can also be previously. The resin-impregnated papers can be bonded improved by impregnating only the surface sheet with pheno- directly to the surface of a wood substrate during cure of the lic resin. It is also possible to introduce lignin, together with sheet, thus requiring only a single pressing operation. phenolic resin, into untreated paper sheets. The decorative-type overlay has been described in the sec- The lignin-filled laminates are always dark brown or black. tion on decorative laminates. They have better toughness than phenolic laminates. In most other strength properties they are comparable or lower. In Selected References spite of the fact that lignin is somewhat thermoplastic. the loss in strength on heating to 200 "F is proponionately no Etickran, E.C.O. Mechanical propcnies of laminated modified woods. FF'L more than for phenolic laminates. Rep. 1639. Madison. WI: US. Depanmcnt of Agticulm. Forest Scrvicc. Reduction in costs of phenolic resins has virtually elimi- Forest products Laboratory: 1947. nated the lignin-filled laminates from American commerce. Forest Roducts Laboratory. Physical and mechanical propenies of lignin- filled laminated paper plastic. FPL Rep. 1579. Madison. WI: US. Lk- They have a number of potential applications, however, where panment of AgriculNre. Forest Service. Forest pmducts Laboratory: rev. a cheaper laminate with less critical properties than phenolic 1962. laminates can be used. Hccbink. B. G.lmpanancc of balanced construction in plastic-faced wmd panels. Res. Note FF'L-021. Madison. WI: US.Deparuncnt of Agrieul- Paper-Face Overlays lure. Forest Service. Forest Rductr Laboratory: 1963. Hccbink. E. G.:Harkell. H. H. Effect of heat and humidityonthc pmpenies of high-pressure laminates. Madison. WI: Forest products Journal. 12(1 I): Paper has found considerable use as an overlay material for 542-548; 1962. veneer or plywood. Overlays can be classified into three Langwig. J. E.: Meyer. J. A.: Davidron. R. W. Influence of polymer im- different types according to their use-masking, structural, pregnation on mechanical pmpenicr of basswood. Madison. WI: Forest and decorative. Masking overlays are used to cover minor products Journal. 18(7): 33-36; 1968. Meyer. J. A. Trcatmcnt of wood-palymer systems using catalyst-heat tech- defects in plywood. such as face checks and patches, mini- niques. Madison. WI: Forest products Journal. 15(9): 362-364: 1965. mize grain raising, and provide a more uniform paintable Mcycr. J. A.: Loos. W. E. Treating southern pine wood for modification surface, thus making possible the use of lower grade veneer. ofpmpenicr. Madison. WI: ForeslPrductrjournal. 19(12):32-38: 1969. Paper for this purpose need not be of high strength. as the Mitchell. H. L. How PEG helps the hobbyist who works with wood. FPL overlays need not add strength to the product. For adequate Unnumbered publication. Madison. WI: U.S. Depanment of Agriculture. Forest Service. Forest Prductr Laboratory. n.d. masking a single surface sheet with a thickness of 0.012 to National Electtical Manufacturers Association. Standard specification for in- 0.030 inch is desirable. Paper impregnated with phenolic dustrial laminated thermosetting products. Designation LI - I. Washing- resins at 17 to 25 percent of the weight of the paper gives the ton. DC: NEMA, (see curnnt edition).

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National Electrical ManvfacNren Association. Standard specification for Stamm,A. 1. Effect of polyethylene glycol an dimensional stability of wood. highF=ssum decorative laminates. Designation LD-3. Washington, Madison. WI: Forest Roducu Journal. 9(10): 375-381: 1959. Dc: NEMA: (we cumnt edition). Stamm. A. 1. Wood and ecllulose science. Ncw Yak Ronald Rerr; 1964. Rowell. R. M. Chcmical modification of wood: advantages and diradvan- St-. A. I.: Scborg. R. M. Forest Roductr Laboratory resin-mated lam- tagcs. American Wmd-Reservcn Arsaiation Roccedingr. 71: 41-51; inated. compresd wood (compreg). FPL Rep. 1381. Madison. WI: U.S. 1975. Depanmcnt of Agncul~re.Forest Service. Forest Roducts Laboratory; Rowell. R. M., ed. Tlw chcmisny of sola wood. Amcrican Chcmical So- 1951. ciety. Advances in Chemiroy Series No. 207; 1984. St- A. 1.; Seborg. R. M. Forest Roduets Laboratory resin-mated wmd Seborg. R. M.; Invcrariry. R. 8. Reservation of old. waterlogged wood by (impreg). FPL Rep. 1380. Madison WI: US.Department of AgriculNre. bcament with polyethylene glycol. Science. 13W3516): 649-650: 1962. Forest Service. Forest Roductr Laboratory; rev. 1962. Seborg. R. M.: Millcn, M. A,; Stamm. A. 1. Heat-stabilized compressed Wcathenvax. R. C.; Stm.A. 1. Electrical resistivity ofresin-mated wmd wood (staypak). Mechanical Engineering. 67(1): 25-31; 1945. (impreg and compreg). hydrolyzed-wmd rhcet (hydrorylin). and lam- Seborg. R. M.; Vallier. A. E. Application of imprcg for patterns and die inated resin-mated paper (papreg). FPL Rep. 1385. Madisan, WI: U.S. models. Madison. WI: Forest Roducu Jomal4(5): 305-312: 1954. Department of AgriculNre. Fomrt Service. Forest Pmdueu Laboratory; SEidl. R. J. Paper and plastic overlays far veneer and plywood. Madison. 1945. WI: Forest Products Research Society Roceedingr. I: 23-32; 1947. Wcathcnvax. R. C.; Stamm. A. I. 'he caffiicicnu of thermal expansion of wmd and wmd producU. T~ctionsof Amcrican Socicly of Mechanical Engineering 69(44): 421-432: 1946. The fibrous naNre of wood strongly influences how it is tions primarily in the storage of food and the mechanical used. Specifically, wood is composed mostly of hollow, transpon of water or sap. elongate, spindle-shaped cells that are arranged parallel to The sapwood layer may vary in thickness and in the num- each other along the trunk of a tree. When lumber and other berof growth rings contained in it. Sapwood commonly ranges products are cut from the tree, the characteristics of these from 1-1/2 to 2 inches in radial thickness. In certain species. fibrous cells and their arrangement affect such properties as such as catalpa and black locust. the sapwood contains few strength and shrinkage, as well as grain pattern of the wood. growth rings and sometimes does not exceed 112 inch in A brief description of some elements of wood structure is thickness. The , . ashes, some of the south- given in this chapter. ern pines, ponderosa pine, and cativo (Prioria copaifera). ehie (Guibourfiaehie), and courbaril (HymeMea fourbarin Bark, Wood, and Pith of tropical origin may have sapwood 3 to 6 inches or more in thickness, especially in second-growth trees. As a rule, the A cross section of a tree (fig. 2- 1) shows the following more vigorously growing trees have wider sapwood layers. well-defined features in succession from the outside to the Many second-growth trees of merchantable size consist mostly center: (1) Bark, which may be divided into the outer, corky, of sapwood. dead part that varies greatly in thickness with different spe- In general, heartwood consists of inactive cells that do not cies and with age of trees, and thethin, inner living part; (2) function in either water conduction or food storage. The tran- wood, which in merchantable trees of most species is clearly sition from sapwood to heartwood, however, is accompanied differentiated into sapwood and heartwood; and (3) the pith, by an increase in the extractive content. Frequently these the small core of tissue located at the center of tree stems, extractives darken the heartwood and give species such as branches, and twigs. black walnut and cherry their characteristic color. Species in As the tree grows in height, branching is initiated by lateral which heartwood does not darken to a great extent include the bud development. The lateral branches are intergrown with (except Sitka spruce), hemlock, the true , bass- the wood of the trunk as long as they are alive. These living wood, cottonwood, buckeye, ceiba, obeche, and ramin. branches constitute intergrown knots. After the branch dies, Heartwood extractives in some species such as black locust. the trunk continues to increase in diameter and surrounds the western redcedar, and redwood make the wood resistant to portion of the branch which was projecting from the trunk at fungi or insect attack. All dark-colored heartwood is not re- the time the branch died. Such enclosed portions of dead sistant to decay and some nearly colorless heartwood provides branches constitute the loose or encased knots. After the dead decay resistance, as in northern white-cedar. Sapwood of all branches drop off, the dead stubs become overgrown and, species, however, is not resistant to decay. Heartwood ex- subsequently, clear wood is formed. tractives may also affect wood in the following ways: (I) Most growth in thickness of bark and wood &es by cell Reduce the permeability making the heartwood slower to dry division at a layer of thin-walled living cells called the and more difficult to impregnate with chemical preservatives, cambium. This layer of cells is located between the bark and (2) increase the stability to changing moisture conditions, (3) wood and is invisible without a microscope. No growth in increase the weight slightly, and (4) dull cutting tools. How- either diameter or length takes place in wood already formed; ever, as sapwood becomes heartwood, no cells are added or new growth is purely the addition of new cells, not the further taken away, nor do any cells change shape. The basic strength development of old ones. New wood cells are formed on the of the wood is essentially not affected by sapwood cells be- inside of the cambium and new bark cells on the outside. coming heanwood cells. Thus, new wood is laid down to the outside of old wood and In some species such as the ashes, hickories, and certain the diameter of the woody bunk increases. The existing bark , the pores (vessels) become plugged to a greater or is pushed outward by the formation of new bark, and the lesser degree with ingrowths known as tyloses. Heartwood outer bark layers become stretched, cracked, and ridged and having pores tightly plugged by tyloses, as in white oak, is are finally sloughed off. suitable for tight cooperage, since this prevents the passage of liquid through the pores. Tyloses also make impregnation Sapwood and Heartwood with liquid preservatives difficult.

Sapwood is located between the bark and the heartwood. Growth Rings The sapwood contains both living and dead cells and func- With most species in temperate climates, there is sufficient difference between the wood formed early and that formed * Revision by Regis E. Miller. Botanist. late in a growing season to produce well-marked annual growth

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I

Flpure 2-l--Cross section of a white oak tree mntains both living and dead tissues. is me light- bunk A. Cambium layer (microsmpic)is inside inner wlored wood beneath the bark. Carries sap from bark and forms wood and bark caiis. B. Inner bark roots to leaves. E. Heartwood (inaaive) is formed is moist. son. and mntains living tissue; carries pre- by a gradual change in me sapwood. F, Pith is the pared load from leaves to ail growing parts of tree. dttissue about which ma first wood growth takes C. Outer bark mntaining mrky layers is wmposed piace in the newly formed twigs. G. Wood rays COW of dry dead tissue. Gives general protectionagainst nect me various layers from pith to bark for storage enema1 injuries. inner and outer bark are sepa- and transfer of food. rated by a bark (mrk) cambium. D. Sapwood. which

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rings. The age of a tree at the stump or the age at any cross In addition to their fibers. have cells of rela- section of the trunk may be determined by counting these tively large diameter known as vessels (or pores). These form rings (fig. 2-2). However, if the growth in diameter is inter- the main arteries in the movement of sap. do not rupted by drought or defoliation by insects, more than one contain vessels for conducting sap longitudinally in the tree; ring may be formed in the same season. In such an event, the this function is performed by the tracheids. inner rings usually do not have sharply defined boundaries Both hardwoods and softwoods have cells (usually grouped and are termed false rings. Trees that have only very small into structures or tissues) that are oriented horizontally in the crowns or that have accidentally lost most of their foliage direction from the pith toward the bark. These groups of cells may form only an incomplete growth layer, sometimes called conduct sap radially across the grain and are called rays or a discontinuous ring. wood rays. The rays are most easily seen on edge-grained or The inner part of the growth ring formed fmt in the grow- quartersawed surfaces. They vary greatly in size in different ing season is called earlywood and the outer part formed later species. In oaks and sycamores, the rays are conspicuous and in the growing season, latewood. Actual time of formation of add to the decorative features of the wood. these two parts of a ring may vary with environmental and Wood also has other cells, known as longitudinal or axial weather conditions. Earlywood is characterized by cells hav- parenchyma cells, that function mainly for the storage of ing relatively large cavities and thin walls. Latewood cells food. have smaller cavities and thicker walls. The transition from earlywood to latewood may be gradual or abrupt, depending Chemical Composition of Wood on the kind of wood and the growing conditions at the time it was formed. Dry wood is made up chiefly of cellulose, lignin, hemicel- Growth rings are most readily seen in species with sharp luloses, and minor amounts (5-10 percent) of extraneous contrast between earlywood, last year’s latewood and next materials. year’s earlywood, such as in the native ring-porous hard- Cellulose, the major constituent, comprises approximately woods ash and oak, and softwoods such as southern pine. In 50 percent of wood substance by weight. It is a high-molecular- some other species, such as water tupelo, aspen, and sweet- weight linear polymer consisting of chains of bonded gum. differentiation of early and late growth is slight, and the monomers. During growth of the tree, the cellulose mole- annual growth rings are difficult to recognize. In many tropi- cules are arranged into ordered strands called fibrils, which in cal regions, growth may be practically continuous throughout Nm are organized into the larger structural elements compris- the year, and no well-defined annual rings are formed. ing the cell wall of wood fibers. Delignified wood fibers When growth rings are prominent, as in most softwoods which are mostly cellulose have great commercial value when and ring-porous hardwoods. earlywood differs markedly from formed into paper. Moreover, they may be chemically altered latewood in physical properties. Earlywood is lighter in to form synthetic textiles, films, lacquers, and explosives. weight, softer, and weaker than latewood. Because of the Lignin comprises 23 to 33 percent of softwoods, and 16 to greater density of latewood. the proportion of latewood is 25 percent of hardwoods. It occurs in the wood throughout sometimes used to judge the strength of wood. This method the cell wall, but is concentrated toward the outside of the is useful with such species as the southern pines, Douglas-fu, cells and between cells. Lignin is a three-dimensional phenyl- and the ring-porous hardwoods-ash, , and oak. propane polymer. Lignin shuctm and distribution in wood are still not fully understood. To remove lignin from wood on Wood Cells a commercial scale may require vigorous reagents or high temperatures or high pressures. Wood cells that make up the structural elements of wood Theoretically, lignin might be converted to a variety of are of various sizes and shapes and are quite firmly cemented chemical products but, practically, a large percentage of the together. Dry wood cells may be empty or partly filled with lignin removed from wood during pulping operations is a deposits, such as gums and resins, or with tyloses. The major- troublesome byproduct. It is often burned for heat and recov- ity of wood cells are considerably elongated and pointed at ery of pulping chemicals. One sizable commercial use for the ends: they are customarily called fibers or tracheids. The lignin is in the formulation of oil-well drilling muds. It is also length of wood fibers is highly variable within a tree and used in rubber compounding and in concrete mixes. Lesser among species. Hardwood fibers average about one twenty- amounts are processed to yield vanillin for flavoring purposes fifth of an inch (1 mm) in lenglh, softwood fibers (called and to produce solvents. tracheids) range from one-eighth to one-third of an inch (3 to The are associated with cellulose and are 8 mm) in length. polymers built from several different kinds of sugar monomers.

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a few others are also usually present. A significant dollar value of nonfibrous products is pro- duced from wood including naval stores, pulp byproducts, vanillin, ethyl alcohol, , extractives, and bark products. Identification

Many species of wood have unique physical, mechanical, or chemical properties. Efficient utilization dictates that spe- cies should be matched to use requirements through an under- standing of propenies. This requires identification of the spe- cies in wood form, independent of bark, foliage, and other characteristics of the tree. Field identification can often be made on the basis of read- ily visible characteristics such as color, odor, density, pres- ence of , or grain pattern. Where more positive identifi- cation is required, a laboratory investigation of the microscopic anatomy of the wood can be made. Detailed descriptions of identifying characteristics are given in texts such as "Textbook of Wood Technology" by Panshin and de Zeeuw and "Under- Flgun 2-Z-Cross mion of a ponderosa pine IH(I0 1291 standing Wood: A Craftsman's Guide to Wood Technology" bag showing gmh rings: Llght bands are early- by 9. R. Hoadley. wood, dark bands are latewood. An annual (growth) ring is composed of the earlywood ring and the latewood ring outside it. Selected References

Bran, L. C. Trends in the production of silvichcmicalr in the United States The relative amounts of these sugars vary markedly with and abroad. Atlanta. GA Tappi 480): 46A-49A; 1965. species. The hemicelluloses play an important role in fiber-to- Core. H. A,; CBtC. W. A.; Day. A. C. Wood suucNre and identification. Syracuse. NY Syracuse Univcnity Rcsr: 1979. fiber bonding in the papermaking process. The component Hamilton, 1. K.. ThomDson. N. C. A comparison of the carbohydrates of sugars of are of potential interest for conver- hardwoods and romUmdr. Allanta. GA: rappi 42: 752-760: i959. sion into chemical products. Hoadiey. 8.R. Undentanding wumd: a craftsmen's guide to wood bxhnology. Unlike the major constituents just discussed, the extrane- Newtawvn. CTTaunton Press: 1980. ous materials are not suuctural components of wood. They Kribr. D. A. Commercial woods on the American market. New Yorlt: Dover Publications; 1968. organic and inorganic. The organic component con- are both On. E.; Spudin. H. M.; Grnfflin, M. W. Cellulose and eellulow derive.. tributes to such propenies of wood as color, odor; taste, lives. Volume V. Pans 1. U. and 111 (1955) of High POlymCN. New Yak decay resistance, density, hygroscopicity. and flammability. lnterxicnce Publishes; 1954. Extractives include and other polyphenolics, coloring Panshin, A. 1.; de kuw,C. Textbook of wood technology. 4th ed. New matters, essential oils, fats, resins, waxes, gums, starch. and Yo* Mffimw-Hill; 1980. Ludwig. C. (editom). : occtmence. formation, simple metabolic intermediates. This component is termed Sarkancn. K. V.: H. suueNre and reactions. New York: Wiley-lntencience; 1971. extractive because it can be removed from wood by extrac- Sj6sMm. E. Wood chemistry: f""damenlalr and applications. New York: tion with such solvents as water, alcohol, acetone, benzene, Academic hss; 1981. and ether. In quantity, the exUactives may range from roughly Wise, L. E.;I&. E. C. Wwd chemistry. Volumes 1 and 11. New Yo*: 5 to 30 percent. depending on such factors as species, growth Reinhold; 1952. conditions, and time of year the tree is cut. The inorganic component of the extraneous material gener- ally comprises 0.2 to 1.0 percent of the wood substance, although higher values are occasionally reported. Calcium, potassium, and magnesium are the more abundant elemental constituents. Trace amounts (

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