Oscillation Measurements and Creep Test of Bread Prepared from Wheat-Lupin Flours and Wheat Flour-Lupin Fibre Dough’S Blends
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ANNUAL TRANSACTIONS OF THE NORDIC RHEOLOGY SOCIETY, VOL. 20, 2012 Oscillation Measurements and Creep Test of Bread Prepared from Wheat-Lupin Flours and Wheat Flour-Lupin Fibre Dough’s Blends Abdelrahman R. Ahmed1,2, I. Mohammed1,3*and B. Senge1 1 Institute for Food Technology and Food Chemistry, Department of Food Rheology, Technical University of Berlin, Sekr. KL-H1, Königin-Luise-Str. 22, D-14195 Berlin / Germany. 2 Faculty of Education, Home Economics Department, Ain Shams University, Cairo, Egypt. 3 Faculty of Agriculture, Food Science Department, Aleppo University, Syria ABSTRACT the production of palatable fiber-enriched The effects of lupine flour or fibre baked goods and pasta7. Rheology is defined supplementation (5, 10 and 15% of wheat as a study of the deformation and flow of flour) on the dynamic rheological properties of matter8. The applications of rheology have dough were studied. A linear viscoelastic expanded into food processing, food 4 -3 behavior of module at the range of 10- ≤γ≤ 10 acceptability and handling. Many researches was found. The storage modulus (G΄) is have been conducted to understand the greater than the loss modulus (G´´). rheology of various types of food such as food powder9, 10, liquid food11, 12, gels13, 14, 15, 16 17, 18 INTRODUCTION emulsions and pastes . Vast food Lupine flour is widely considered an materials show a rheological behaviour that excellent raw material for supplementing classifies them in between the liquid and solid different food products owing to its high states; meaning that their characteristic varies protein content1 and is largely used as eggs in both viscous and elastic behaviours. This substitute, for example in cakes, pancakes, behaviour, known as visco-elasticity, is caused biscuits, or brioche2, and has been added to by the entanglement of the long chain spaghetti3, pasta, crisps4, and bread5. It has molecules with other molecules. The aim of been also used as a butter substitute in cake, this study was to test the effects of lupin flour brioche, and croissant2. Lupine does not and lupin fibre supplementation on the contain gluten, thus it is sometimes used as a dynamic rheological properties of dough. functional ingredient in gluten-free foods6. Lupine kernel fiber has also a potential as a human food ingredient as it has been used in 145 MATERIALS AND METHODS Creep test Materials The cycle of dynamic tests was followed by Local Egyptian breeds of lupine (Lupinus a 10-min period of relaxation. Then, the dough albus L. variety Giza) were obtained from the sample was subjected to the creep test, Agricultural Research Centre, Giza, Egypt. applying a constant shear stress of 50 Pa for 60 Lupine flours and hulls were obtained after s on the sample and allowing the sample to grinding lupine grains in a laboratory hammer recover the strain in 180 s after removal of mill (Retsch - Germany) until they could pass load. through a 250 µm screen. Commercial wheat flour type 405 was obtained from Lidl Market RESULTS AND DISCUSSION (Berlin-Germany). Oscillation measurements Methods A rheometer UDS 200 from Paar Physica Amplitude sweep (GmbH measurement technique Stuttgart) Figure (1) showed that a collection of with temperature control with a plate-plate storage and loss modulus and loss factor for system (measurement system MP 31) was lupine dough compared with wheat flour used for measuring the rheological properties dough. In the double logarithmic representation of dough samples. of the deformation-dependent behavior of the studied dough is pronounced with a dominant Amplitude sweep LVR solid behavior (G '> G " or detect loss - The amplitude of relative strain was 10 factor <1), followed by a decrease of both 4 1 and fell within the linear viscoelastic moduli and an increase in the Loss factor with region for all samples. The limits of the region structural break (tan δ = 1). The overall were determined based on an experiment in structure and macro-structure is experiencing a which increasing stress was applied, at constant "break down ", will be completely destroyed. A oscillation frequency of 1 Hz. sub-structure is not available. The destruction of deformation γz with G '= G is located at Frequency sweep wheat flour-dough at 0.6, with 0.5 lupine flour- Applying oscillation frequencies within the dough. Compared to the wheat flour dough range from 0.1 to 20 Hz at constant strain = should be noted that despite the higher protein 10-3. Each logarithmic frequency decade content, the higher level structure and the corresponded to 30 measurement points. 146 Amplitude sweep 5 10 2 1.8 Pa 1.6 4 10 1.4 1.2 G' tan() 1 0.8 3 10 0.6 0.4 0.2 2 10 0 0.0001 0.001 0.01 0.1 1 Strain WF LF LF 5% LF 10% LF 15% G' G' G' G' G' tan() tan() tan() tan() tan() Figure (1): Amplitude sweep the flour mixture in dough (5, 10 and 15 % lupine flour) relatively larger particulation in lupine-dough Frequency sweep measurements quickly leads to a structural instability of the To characterize the dough as the dispersed dough, recognizable by the curve of tan δ. The material systems, the frequency-dependent module (G', G" and G*) with increasing behavior of the wheat flour and lupine flour or lupine flour content in the mixtures in fiber depending on the subsequent mixing comparison to the wheat flour with a ratios (5%, 10% and 15% lupine flour or fiber) deformation of γ = 10-3 decreased slightly. A was examined by oscillatory measurements. stable structure in hibernation is determined The relations G', G" and tan δ with based on the dominance of the wheat flour in frequency sweep for pure wheat flour dough, the blends. This result was in agreement with composite flour dough’s and pure lupine flour earlier studies19. dough are presented in fig. (3). The presented The addition of lupine fiber caused a shift data indicate that increase of oscillation of curves G' and G" towards higher values, frequency within the range from 0.1 to 20 Hz while curve tan δ moved towards lower caused an increase in the values of the values. The data indicate that the additions dynamic module – the storage modulus and applied caused an increase in wheat flour the loss modulus for pure wheat- and lupine dough elasticity (G') and viscosity (G"), the flour dough as well as for composite flour increase in elasticity dominating over that in dough. Whereas, the values of the tangent of viscosity, as a result of which tan δ decreased. the phase angle, being the ratio of G' / G", Likewise, Lamacchia et al.20 studying doughs decreased gently. When the oscillation with a constant addition of water (30%), frequency increased from 0.1to approximately recorded significantly higher values of G' and 1 Hz, the higher frequencies caused an G" for oat whole meal dough than for wheat increase of those values. Similar frequency (semolina) dough. Also, oat whole meal dependence was noted by Pedersen et al.21 for dough, compared to wheat dough, was cookie doughs, but not confirmed with characterized by significantly higher values of Rasper22, who is reported that when higher tan δ (Fig. (2). frequencies are used, 147 Amplitude sweep 5 10 2 1.8 Pa 1.6 4 10 1.4 1.2 G' tan() 1 0.8 3 10 0.6 0.4 0.2 2 10 0 0.0001 0.001 0.01 0.1 1 Strain WF LF L.Fibre 5% L.Fibre 10% L.Fibre 15% G' G' G' G' G' tan() tan() tan() tan() tan() Figure (2): Amplitude sweep the flour mixture in dough (5, 10 and 15 % lupine fiber) becomes greater than due to viscoelastic solid increase in elasticity dominating over conversion to elastoviscous liquid. viscosity as a result of tan decreased (Fig 4). In contrast, the additions of lupine fiber at Frequency sweep experiments showed that different concentration (5, 10 and 15 %) had a for all tested dough formulations the elastic similar effect on the run of the mechanical (or storage) modulus, G , was greater than the spectra of wheat dough. Increase in the G percentage share of the additions caused a viscous (or loss) modulus, , in the whole G G range of frequencies and both moduli slightly shift of curves and towards higher increased with frequency which suggests a values. The data indicate that the additions solid elastic-like behavior of the lupine applied caused an increase in tested dough tan G G G G doughs. Therefore, (= / ) values for elasticity ( ) and viscosity ( ), the all dough formulations were lower than 1. FREQUENCY SW EEP 5 10 0.56 0.54 0.52 0.5 Pa 0.48 0.46 0.44 G' tan( ) 4 0.42 10 0.4 0.38 0.36 0.34 0.32 0.3 0.28 3 10 0.26 0.1 1 Hz 10 Frequency f WF LF 5% LF 10% LF 15% LF G' G' G' G' G' tan() tan() tan() tan() tan() Figure (3): Frequency sweep the flour mixture in dough (5, 10 and 15 % lupine flour) 148 FREQUENCY SWEEP 5 10 0.56 0.54 0.52 0.5 Pa 0.48 0.46 0.44 G' tan( ) 4 0.42 10 0.4 0.38 0.36 0.34 0.32 0.3 0.28 3 10 0.26 0.1 1 Hz 10 Frequency f WF. LF L.Fibre 5% L.Fibre 10% L.Fibre 15% G' G' G' G' G' tan() tan() tan() tan() tan() Figure (4): Frequency sweep the flour mixture in dough (5, 10 and 15 % lupine fiber) Creep tests of maximum deformation and creep The creep test was done to compare the compliance as well as having equal weight of properties of the materials science different the restoring force.